Organic Chemistry articles

Time frame: 1 May 2025 - 30 April 2026

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Count: 6165

Article ‘Count’ for Organic Chemistry.

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19
Weakening Chaotropic Effect of Li+ in Two-Dimensional Confined Channels via Coulomb Interactions for Efficient Li+/Mg2+ Separation
Programmable Oxygen-Ligand Fields Encode Atomic Cu Coordination for Pathway-Selective CO2–Nitrate Conversion to Urea
Reconfigurable Mechanically Interlocked Metal–Organic Nanocages for Adaptive Guest Recognition and Allosteric Regulation
Micropatterned DNA Hydrogels for Spatiotemporal Programming of Chemical Reaction Networks
A Visual Understanding of Circular Dichroism Spectroscopy
Iridium Nanoantidotes Attenuate Jellyfish Toxin-Induced Hepatotoxicity by Inhibiting Gasdermin D Palmitoylation
Polyacrylonitrile Flower-Like Particles with Tunable Size and Morphology via Scalable Oxygen-Tolerant Polymerization
Charge Transfer between Quantum Dots and Redox Molecules Is Not Auger-Assisted
Self-Assembly of P22 Virus-like Particles in Liquid–Liquid Phase-Separated Condensates for Enhanced Enzyme Catalysis
A Cyclic Photosensitizer Nanoplatform for Effective Pyroptosis and Enhanced Photoimmunotherapy
Autonomous Self-Pulsation of Protein Vesicles via Substrate-Induced Protein Allosteric Cycle
Highly Exposed Subnanometric Palladium Ensembles on Yttrium Oxide Enable Boosted Catalytic Performance for Heck Cross-Coupling Reactions
Tip-Induced Nitrene Generation
Molecular Biomimicry and the Synthetic Synapse: Engineering a Stable Synaptogenic Extracellular Matrix
High-Entropy Metallene Arrays with a Turing Structure for Electrocatalytic Upcycling of Polyethylene Terephthalate Plastics Coupled with Electrosynthesis of Ammonia
Molecular-Scale Memory Generated by Liquid-Like Spins in On-Surface Synthesized Nanoclusters
Design Principles for Engineering Ionic Liquid-Gold Nanoparticles for Therapeutic Delivery to the Brain
Anion Immobilization from Quasi-Icosahedron to Cubo-Octahedron Enhances the Lithium Ion Transference Number in Solid-State Electrolytes
Nonequilibrium Solution-Based Assemblies from Bottlebrush Block Copolymers for Drug Delivery
30
ATP‐Activated Tumor Targeting Therapy via Bioorthogonal Alkyne‐Calixarene Host–Guest Assembly
Aggregation-Induced Stabilization of Boron-Containing Organic Diradicaliods via π-Bridge toward Highly Efficient Light-to-Thermal-Electric Conversion
Electronic Engineering of Lyophobic Surface Shield in Boron Nitride for Stabilizing Propane Oxidative Dehydrogenation
Bifunctional Direct and Oxidative Dehydrogenation of Propane by Balanced Electronic Coupling and Surface States in Pt-M@Silicalite-1
Heteroatom-Engineered Linear Conjugated Polymers for Photocatalytic O2 Reduction and Biocatalytic sp3 C─H Oxyfunctionalization
CoIII/II Redox Couples in Cobaloximes Control Hydrogen-Atom Transfer for Photoredox N-Alkylation of Amines with Lead Halide Perovskite
A Computational Framework to Efficiently Screen Antioxidants for Cross-Linked Polyethylene Insulation
Retractable Cages with Continual Change of Cavity Size and High Iodine Capture
Plasmonic Enhancement Enables Deactivation Resilient TiO2 for Sustainable VOCs Remediation under Practical Conditions
Coral-Like Pd3Pb Nanoarchitectures Enable Poisoning-Resistant Electrosynthesis of Glycolic Acid From PET-Derived Ethylene Glycol
Construction of Fluorenone-Functionalized Porous Organic Polymers for Visible-Light-Driven Oxidative Cleavage of Polystyrene to Acid
Redefining Gold-Ligand Chemistry for Biosensing: Au─C≡C Probe Enable High-Sensitivity and Low-False-Positive Furin Imaging
Oxidation Engineering Activates Ni─Fe Nitrides for Efficient Mechanocatalytic Thiol Coupling
Substrate‐Triggered Surface Activation for Efficient Electrosynthesis of Potassium Formate
Intensifying Internal Electric Field on ZnO Nanoplates with Polar Surface Exposure and Cu Doping for Efficient Photocatalytic Methane Oxidation to Oxygenates
Polyferrocene-Based Cubosomes: Conversion to Magnetic Mesoporous Microparticles, Supramolecular Modification, and Oxidation Response
CuO@TiO2 Hollow Cubes Enable Highly Selective and Stable Photocatalytic Non-Oxidative Methane Coupling to Ethylene
A Biomimetic Self‐Reinforcing Recyclable Multifunctional Sustainable Material Harnessing π‐Conjugated Cinnamene Units
Precisely Controlled Relationship between Sulfur Vacancy and Ni Site for Boosting Photocatalytic Conversion of Polyester into Formate
Laser‐Driven Superfast‐Heating and Quenching Approach to Selectively Upcycle Waste Polyolefin into Long‐Chain Terminal Alkenes and Functionalization
Charge‐Directed Ionic Frameworks Based on Pillar[6]arene for Iodine Capture: Synergistic Confinement and Polyiodide Stabilization
Functional Upcycling Discarded Poly(Ethylene Terephthalate) Bottles for Ultralong Organic Phosphorescence Polymer Elements
Bridging Uranium Uptake and PET Plastics Degradation Within an All‐Inorganic Polyoxoniobate Framework
Alternating Pulse Driven Periodic Reactivation of High-Entropy Mesoporous Film Boosts Continuous Membrane-Free PET Waste Upcycling Coupled with H2 Production
Differential Compartmentalization of Enzymatic Reactions for Lactate Signaling Across Protocells
Boosting Electrochemiluminescence in Ring‐Contracted Porphyrins via Central‐Coordination Modulation
Metastable Sn-O-Pd Sites Modulating the Seesaw Effect Specifically Activate H2O2 for the Identification of Plasticizers
Dual‐Site Synergistic Electrocatalysis Enables Highly Selective Upcycling of Real‐World Plastic Waste to Glycolic Acid
Discrete Chiral Metallacycle-Based Membrane for Highly Efficient Enantioseparation
Bioorthogonal Engineering of Cellular Microenvironments Using Isonitrile Ligations
22
Hierarchically Engineered Multi-Enzyme Nanoreactors for in vitro Drug Biosynthesis and Pathway Transplantation Into Cells
A Bipolar Integrated Electro‐Chemocatalysis System for Continuous‐Flow Paired Synthesis of Cyclohexanone Oxime at Industrial‐Relevant Current Density
Pairs of Zirconium Site and Hydroxyl in MOFs Enable Generating Peroxo Species for Efficiently Tandem Oxidative Condensation of Aromatic Amines
Single‐Atom Photocatalyst as Floatable Artificial Leaf for Upcycling Oceanic Plastic Waste
High-Performance, Recyclable Thermosets Enabled by Thiosemicarbazone Dynamic Bonds via Synergistic Dynamic Covalent and Supramolecular Networks
Bioinspired Quinone Redox Cycling Enables Highly Selective Photocatalytic Hydrogen Peroxide Production via Electron–Proton Relay
Suppressing Hydrogen Transfer and Aromatization Reactions Enables Efficient Photothermal Recycling of Polyethylene into Platform Olefins
Reversible Metal Coordination Switch Enables Activatable Sonodynamic Therapy via Dual-Death and Immune Synergy
Eutectozymes as Soft Hybrid Materials for Advanced Biocatalysis
Dynamic Geminal-Atom Coordination for Highly Efficient Photo-Fenton Catalysis
Electrical Catalysis of Forbidden Transitions in Single‐Molecule Devices
Arresting Microphase Separation Encodes Material Mechanics by Sculpting Microarchitectures and Local Polymer Enrichment
Synergistic Cu2 and Polyoxometalate Clusters in Metal–Organic Layers Enable Oxidant-Free CH4 Photooxidation
Electrochemical Chlorine Shuttle from PVC Waste to Vinyl Ether Acceptors for the Synthesis of Biodegradable Polyester Precursors
Copper-Driven Allosteric and Self-Encapsulating Polymers for Tumor-Specific Fluorescence Imaging and Dual-Enzymatic Cancer Therapy
Upgrading Natural Ores for Efficient Photothermal Polyester Recycling
A Light‐Driven Closed‐Loop Chemical Recycling System for Polypinacols
Deep Eutectic Solvents Formed by Complex Hydrides: A New Class of Hydrogen‐Rich Liquid
A Broad Range of Aromatic Carboxylic Acids for Photocatalytic Methane Oxidation
Modular Molecular Editing of End‐of‐Life PBT for High‐Performance Sustainable and 3D‐Printable Platforms
A Relay-Type Solid-State Macrocyclic Host–Guest System for Selective Isomer Adsorption, Controlled Release, and Turn-On Colorimetric Sensing of 1-/2-Bromoalkanes
Artificial Cells Capable of NO Generation with Light Controllable Membraneless Organelles for Melanoma Therapy
32
A Live-Cell Analytical Platform by Using Strigolactones-Induced Dimerization System
In Situ NMR Tube Extraction Reveals Increased Fluorine Release with Polymer Swelling
Epitope-Directed Antibody Development and Enhancement for Broad-Spectrum Fentanyl-Class Substance Detection: From Rational Hapten Design to On-Site Analysis
An Effective Method for Evaluating Antioxidant Capacity: Integrating Chemical Kinetics and Stoichiometry Based on the Study of the Antioxidant Behavior in the Mixture
Efficient and Selective Arsine Evolution Reaction on the VS4–x-Modified Electrode for Atomic Spectroscopic Quantification of Sub-ppb Level AsIII
A Fluorescent Palladium–Ligand Platform for In Situ Monitoring and Bayesian Optimization of Sonogashira Coupling Reactions
High-Throughput Testing for Unknown Mutagens and Cytotoxica via Duplex Planar Ames–Cytotoxicity Bioassay Including Metabolic S9 Activation
Evaluation of Intermolecular Interactions in HPLC Using Deuterated Mobile Phases
Universal Enrichment and Sequencing of DNA Modifications Using a Click-Coupled IgG-Protein A/G System
Host–Guest Doping Room-Temperature Phosphorescence Sensing Strategy for the Detection of Related Substances in Naproxen APls and in the Production of Dosage Forms
Framework Doping Enhances COF-DNA Nanoplatforms for Dual RNA Imaging and Phototherapy
Retrieval-Augmented Language Models Enable Scalable Chemical Source Classification in Metabolomics Workflows
19F NMR Interpretation Complications with 3-Bromo-1,1,1-Trifluoroacetone (BTFA) and an Alternative 2-Iodo-N-(2,2,2-Trifluoroethyl)acetamide (ITFEA) 19F NMR Probe
Protein Labeling and Intramolecular Cross-Arylation via Rational Tuning of Bis-Halogenated Pyridiniums
Conformation-Locked Near-Infrared Probes for Real-Time Visualization of G Protein-Coupled Receptor Dimers in Living Systems
Time-Domain Quantum Cascade Laser-Based Vibrational Circular Dichroism Spectroscopy with Linear Dichroism Monitoring
Leveraging 11B NMR for Optimization of Boronic Acid–Diol Complexation: Insights for SERS-Based Diol Detection
Complex Olefin Separations by Coordinated Silver(I) Containing Ionic Liquid Stationary Phases Using Comprehensive Two-Dimensional Gas Chromatography
New Analytical Methodology to Reveal Biosignatures on Mars and Ocean Worlds
Efficient Photochemical Generation of Germanium and Arsenic Hydrides in a Sulfite and Iodide Medium
PLANTA Protocol for the Direct Detection and Identification of Bioactive Compounds in Complex Mixtures via Combined NMR-HPTLC-Based Heterocovariance
Spatiotemporal Control of RNA Functions via Bioorthogonal Chemistry for Activatable Biosensing
Identification and Distribution of the Dietary Antioxidant Ergothioneine in Humans and Animal Models Combining NMR, RANSY, and MS Methods
Eutectic Point Determination of Type V Hydrophobic Octanoic Acid-Based Solvents by “Lock-Free” 1H and 13C NMR Self-Diffusion Experiments
Novel Near-Infrared Cyanine Dyes for DNA Sequencing
Photochemical Vapor Generation of Platinum: Mechanism and Analytical Application
A General Strategy for Triggerable Donors and Analyte-Replacement Fluorescent Probes of Hydrogen Selenide
Principal Component Analysis Followed by Mahalanobis Distance Classification for Authentication of iVaccinium/i Berry Ingredients and Supplements via LC-MS/MS-based Anthocyanin Fingerprinting
ArticleJune 11, 2025 Microdroplet Accelerating C(sp2)–H Halogenation in Organic, Pharmaceutical, Analytical, and Environmental Use
In-Column Click Chemistry for the Preparation of Chromatographic Stationary Phase Materials and Online Evaluation of the Reaction by Chromatographic Behaviors
Harnessing the Power of Chemometric Modeling and Plate Readers for High-Throughput Analysis of Biocatalytic Reactions
Bioinspired Chemosensor with Configuration-Dependent Affinity for Localized Tracking of Labile Zn2+ during Neuronal Differentiation
908
A Negatively Curved Pyrene‐Fused Azaacene
Selective Para-Functionalization of Aromatic C(sp2)─H Bonds via Atomically Dispersed Photocatalysis
From [NHC─H]• to Persistent σ-Complex Radicals: Photoinduced Radical Chemistry of Imidazolium Salts
Multicomponent C−H Activation/Annulation Polymerizations Toward Structurally Regular Polyelectrolytes With Light-Boosted Antibacterial Potency
Monoselective Mechanochemical Aromatic Nucleophilic Substitution Enabled by Crystal‐Engineering‐Guided Reaction Design
Enantioselective Synthesis of Inherently Chiral Tetraphenylene Analogues Enabled by NHC‐Catalyzed Benzoin Condensation
Reductive Photocatalysis Unlocks the Hydrodeoxygenation of Polycarbonate Plastic Into Fuel‐Range Hydrocarbons
Integrated CO2 Capture and Conversion Induced by Amines for Effective Electrocatalytic N-Methylation
Catalyst‐Free, Divergent Cysteine Modification via Indole Isocyanide Photochemistry
Integrative, Orientational Self‐Sorting at the Four‐Crossing Level in Molecular Knots and Links
Photo‐click Proteolysis‐Targeting Chimeras Enable Intracellular Generation of PROTACs for Precise Dual Protein Degradation
Radical Cascade Combining Cross-Olefin Coupling with the Smiles-Truce Rearrangement
Site-Selective B─H Activation via HAT Toward Xanthyl-closo-Carboranes as Bench-Stable Precursors of Organosulfur Boron Clusters
Solar-Driven Photocatalytic C─S Coupling for Organosulfur Synthesis Via Upcycling SO2 and Plastic Waste
Azide‐to‐Diazo Transformation Facilitated by Michael Addition via Phosphazide Formation
Sulfur‐Directed Construction of Vinyl Cyclopropanes from 1,3‐Dienes
10.1002/anie.8135901
Convergent Total Synthesis of 16β‐Hydroxylpseudobufarenogin
Diazo Transfer From Nitrous Oxide Employing Phosphorus Ylides
Thermally Induced Macromolecular Sequence Inversion in Triblock Copolymers and Terpolymers
Light-Induced Chiral Aldehyde/Palladium Catalysis-Enabled Asymmetric Allylic C─H Alkylation of Alkenes With NH2-Unprotected Amino Acid Derivatives
Ligand-Switched Regiodivergent Fluoroallylic Alkylation of Secondary Nitroalkanes via an Unusual Inner-Sphere Pathway
Hydroxylamine Hydrochloride as Bifunctional Reagent for Aminochlorination of Alkenes via Iron Catalysis
Iterative Synthesis of Pentacene Derivatives with Continuous Boron–Oxygen Bonds
Electrochemically Driven Enzymatic Oxidative Desymmetrization for the Enantioselective Construction of Silicon Stereocenter
Room-Temperature Gas-Phase CO2-to-C3 Coupling by a 4f-Aromatic Cluster
Study of form factors and observables in B− c → ¯D(∗)0ℓ−¯νℓ and B− c → D(∗)−ℓ+ℓ− decays
Cobalt‐Catalyzed Intramolecular C─H Silylation of Arenes
Steric Hindrance and Secondary Interactions Govern Reconfiguration Between Two Complex CuI Coordination Cages
Palladium/Photoredox-Catalyzed Three-Component Coupling for Glycoconjugation
Converting 1,1-Bisborylalkanes into 1,2-Bisborylalkanes Enabled by Iron Ligand-to-Metal Charge Transfer (LMCT) Photocatalysis
Electrochemical Biomimetic Iron-Catalyzed Benzylic C─H Bonds Hydroxylation
Biocatalytic Access to Natural Mosquito Repellent p-Menthane-3,8-diol via Direct Asymmetric Prins Cyclohydration
Anion Size‐Dependent Conformational Folding of Guanidinopropionate: Enabling Tunable Birefringence and Balanced Second‐Harmonic Generation Performance
Tandem Reactivity of Metal−Carbon and Carbon−Silicon Bonds in Mononuclear α-Silyl Organolithium or Organosodium Complexes Towards CO, CO2 and Heteroallenes
Formal Allylic C(sp3)−H Carboxylation With CO2 via Copper Metallaphotoredox Catalysis
Strain‐Sequenced Synthesis of a Quadruply Twisted Cycloarene With Alternating [4]/[5]Helicenes
Selective π‑Metalation of Nut[6]Arene With Large and Chiral Cavity for Recognition Toward Bulky Anions in Water
Suppressing Metallic Co0 Formation in Co-Based Catalyst by In-Situ Selective H2 Oxidation for Efficient Ethane Dehydrogenation
Discovery of a Plant Pictet–Spenglerase With R-Stereoselectivity
Biocatalytic Synthesis of Isoxazolines Enabled by Cryptic Nitrile Oxide Formation by a Vanadium‐Dependent Chloroperoxidase
Replacing Metabolically Unstable Amides With Stable α‐Trifluoromethylamines via Decarboxylative Synthesis
Isolation and Reactivity of a Square‐Planar Trisamido Silane
Aqueous Upcycling of Polyethylene Furanoate From Mixed Plastic Feeds Into Metal-Organic Frameworks
Regioselective Synthesis of Benzylsilanols from Kobayashi-Type Reagents via C(sp3)─H Bond Activating 1,4-Palladium Migration
Deprotonative C(sp3)/C(sp2)–H (Multi)Silylation of (Hetero)Arenes Mediated by NaTMP
Electrode “Cocktail Effect” Enables Charge Selective C─C Bond Cleavage of Acetonitrile for Aryl Halide Methylation
A 12‐Crossing Vertex‐Fused Double‐Triangle [5]Catenane with Programmed Topological Handedness
Dithioketal Polymers Via Radical Polymerization of γ‐Dithiobutyrolactone
Enantioselective Total Synthesis of Breviones Utilizing a Bio‐Inspired Skeletal Editing Strategy
Stimuli‐Responsive Silsesquioxane Nanozymes for Organocatalysis in Water and Prodrug Activation in Cells
Selective Oxidation of Tertiary Silanes Enabled by Tandem Single Atom Cerium Catalyzed Water Splitting/Non‐Bonding Phosphorus Site Promoted Nucleophilic Substitution
Alkyltransferase Ribozyme for Site-Specific N4-Cytidine Alkylation
RaPID Selection of Backbone Macrocyclic Peptides Targeting Akt2
Nickel‐Catalyzed Enantioconvergent Arylation of Unactivated Cyclic Electrophiles: Asymmetric Synthesis of 3‐Substituted Pyrrolidines
Selective Glycine Electrosynthesis via C‐N Coupling Enabled by Synergistic Mott–Schottky Heterojunction and Oxygen Vacancies
Visible‐Light Sensitized Isomerization in the Lipid Bilayer Enables Activation of a Transmembrane Transporter
Mixed‐Functionalized Acylgermanes Result in Wavelength‐Controlled Fragmentation
The Far Side of Carboranes: Anticancer Active Monocations and Ambiently Stable Dications
Spin‐Correlated Luminescence of Mechanically Generated Radical Species
Bent N‐Heterocyclic Allenes From a Well‐Defined Titanium Vinylidene Complex
Enantioselective Synthesis of Isoquinuclidine Analogs by Synergistic Copper/Amine-Catalyzed Sequential [3 + 3]/[4 + 2] Cycloaddition
Migration at Boron Cage for Selective B–H Functionalization of nido-Carboranes
Organoboron Cycloarenes: Boron‐Carbon Annulated Macrocyclic π‐Systems
Azetidinylideneketenimines as a Multimodal Synthetic Platform: Coordination Chemistry and Cycloaddition-Triggered Transformations
Synthesis, Functionalization, and Reactivity of Vinyl Sulfondiimidamides
Ligand-Intercalated MOFs Enable Reaction-Pathway Engineering in Biomass Electrooxidation via Steric and π-Electronic Microenvironment Control
Enantioselective Synthesis of Polycyclic Spiroheterocycles by Chiral Phosphoric Acid Catalyzed Dearomative Cyclization of γ-Hydroxy Ynamides
One-Pot Amidation/C─H Halogenation by an Efficient Electrochemical Cascade
Cyclooctatetraenyl Metal−Organic Octahedra and Their 3D Cage to 2D Nanosheet Transformations
Molecular-Gate Strategy for Solid-State Selective Recognition of Dioxane Isomers via Reversible Host–Guest and Charge-Transfer Modulation
Acetal[6]Arenes: Rigid Chirality-on-Annulus Macrocycles Promoting Charge-Transfer Co-Assembly With Exceptional (Chiro)Optical Properties
cis-Aziridines From Terminal Alkenes via Diastereoselective Intramolecular Electrocatalytic Hydroamination
Bioinspired Design of F–Zn Sites in Layered Double Hydroxides for Photothermal Catalytic Upcycling of Polyethylene Terephthalate
o-Terphenyl-Based Family of Conjugated Macrocycles: Selective Recognition of Phenylalanine in Water and Interaction With Insulin
Boracycle-Annulation Stabilizes Antiaromaticity and Enhances Diradical Character in s-Indacene/Dicyclopenta[b,g]Naphthalene-Cored Organoboron Polycyclic Hydrocarbons
Enantioselective Intermolecular Photocycloaddition of Indoles
Redox-Neutral Electrochemical Cis-Cyclopropanation of Alkenes With Sulfoxonium Ylides
Iron-Catalyzed Anti-Markovnikov Hydroxyazidation of Unactivated Alkenes
Pillar[6]arene Assemblies With Continuous Hydrophobic Grooves for Capture of π-Conjugated Molecules
Unlocking Efficient Spontaneous Deracemization: A MOF‐Mediated Heterogeneous System Overcomes Catalytic Incompatibility in Cocrystallization
Alkoxysulfonium Salts Unlock Access to New Aryl Sulfonium Salts for Cross-Coupling
Aryl and Alkyl Radiotrifluoromethylation via Metallaphotoredox-Mediated Radical Cross-Coupling
Dissipatively Fueled Unidirectionally Communicating DNA Circuits That Control Biocatalysis
Captodative Radicals Coupling Into Homochiral Molecular Nanotubes With Conglomerate Crystallization
Total Synthesis of the Spirocyclic Bis-Indole Alkaloid (−)-Owerreine via a [4+2] Annulation
Asymmetric Total Synthesis of (–)-Verrucarol
Conformationally Driven Dual Fluorescence Properties of Higher Heteroacenes With Periodically Incorporated Boron Atoms
Ambient One-Pot Electrocatalytic Synthesis of Caprolactam From Cyclohexanone and Nitrate Over Ag-Ag4Sn-SnO2 Nanoparticles
Domino Polymerization for the Synthesis of Reductively Degradable Poly(disulfide)s With Arbitrary Side-Chain Structures
Nickel-Catalyzed Enantioselective Direct Addition of 1,3-Dienes to Aldehydes Enabled by Chiral Monodentate Diamidophosphite Ligands
Regiodivergent C3 and C4 Amination of Quinolines via Radical and Ionic Pathways
Cu/La Cocatalysis Enables 1,4-Aminative Difunctionalization of 1,3-Dienes
Asymmetric Dearomative Dual‐Functionalization via Rearomatization‐Blocked Sulfonium Claisen Rearrangement
Skeleton Editing of Indenes With Metal Carbenes to Access 1,2-Dihydronaphthalenes
Photocatalytic Cross-Coupling of Phenols and Heteroaryl Halides With Machine Learning-Guided Reaction Prediction
Tailored Pyridine Enables Diverse Electrochemical Benzylic C–H Functionalization
Enantioselective Synthesis of Axially Chiral Anthracenes via [4+2] Cycloaddition and Cycloreversion of Cyclopentadienones
Anion-Controlled Structural Interconversion of Palladium Cages Enables Separations by Selective Guest Capture and Release
Water-Soluble Pd8L4 Barrel for Binding of Versatile Hydrophobic Dyes and Visible-Light Promoted Catalysis in Aqueous Medium
α-Trifluoromethyl Substituted α-Hydroxyhydrazides as Dianionic Ligands Enable Cu-Catalyzed Aryl Amination With Higher Turnovers
Single-Atom La Promoter Breaks the Activity–Stability Trade-Off on Al2O3-Supported Pt Catalysts for Propane Dehydrogenation
Photomediated Controlled Radical Homopolymerization of Sulfonated α-Olefins and Vinyl Ethers with Propagating Sulfonyl Radicals
Mapping the Reactivity of the C═C Bond of Cyclic Enol Ether Derivatives of Sugars: Nucleophilicity Parameters of Glycals
Viologen Covalent Organic Frameworks Integrating Synergistic Singlet and Triplet Excitation for Efficient Photosynthesis of Benzazole Pharmaceuticals
1,3‐Dicarbonyl Rhodamines for Live‐Cell Single‐Molecule Super‐Resolution Imaging
Chemical Primary Color Pixels for Full-Color Image Encoding and Decoding
Electrosynthesis of Chlorohydrins From Alkenes in Seawater Enabled by On‐Site Generated Active Surface Chlorine Intermediate
Rapid Assignment of Chemical Shifts From Crystal Structures in Solid-State NMR
Sequential Homo- and Hetero-Coupling of Isocyanide and Carbon Monoxide Mediated by Acyclic Imino(silyl)Silylene
Isolable Monocyclic N-Heterocyclic Radicals Supported by Rare-Earth Organometallics
Lewis Base-Catalyzed DYKAT of Racemic Chlorohydrosilanes With Grignard Reagents En Route to Si-Stereogenic Hydrosilanes
Modular and Direct Synthesis of γ-Sultines From Simple Unactivated Alkenes
Selective Electrochemical End-Group Removal Enhances Polymer Thermal Stability
Enantioselective S-Alkylation of Sulfenamides With Copper-Catalyzed Amino-Radical-Transfer Deboronation
Self‐assembled Helical Tetramer Stack of Terrylene Bisimide in Solution and Crystalline State
Photoinduced Generation of (Boryl)Silyl and (Chloro)Silyl Radicals: Access to Trisubstituted Silylboranes and Chlorosilanes
Unveiling the Electrochemical Reactivity of Urethane Toward Different Bond Formations and Application to Polyurethane Deconstruction via C─N Bond Formation
Macromolecular Condensates as Tunable Scaffolds for Bio‐Inspired Silica Hybrids
Photochemical Cyclization of Tertiary Buta‐2,3‐dienamides to β‐Lactams Upon Triplet Energy Transfer
Desymmetrization of Malonic Monoesters and Malonic Acids via Enantioselective Catalytic C(sp3)─H Oxidation
Trinuclear Heptamethine Dyes for Shortwave Infrared In Vivo Imaging
Enhancing Memory of Chirality in Phosphorus‐Centered Radicals by Inductive Deceleration of Pyramidal Inversion
On the Discorhabdins Leading to the Aleutianamine Ring System: A One‐Step in Situ Transformation Characterized Through Computational and Experimental Studies and Its Implications on Biosynthesis, Synthesis, and Pharmacology
Semi-Reduction of Allenes to Access Deuterated Allylic Isotopomers, Isotopologs and Enantioisotopomers
Traces of Elements in the Electrochemical Reductive Amination of Acetone: Uncovering Bi as Substitute for Pb
Aqua-Oxidation of Polyethylene Into Carboxylic Acids Under Mild Conditions: A Catalyst-Free Upcycling Strategy for Nonpolar Plastics
Biosynthesis of Kaitocephalin: A Neuroprotective Natural Product Featuring a Peptide‐Like yet Nonpeptidic Scaffold
A Modular Approach to N-Fluoroalkyl Amides via Nitrene Insertion Into Fluoroalkylcopper(I)
A Mechanochemical Kolbe–Schmitt Reaction: Catechol Carboxylation Provides Building Blocks for Renewable Plasticizers
Magnesiation of Phenol Derivatives Catalyzed by a Rhodium─Aluminum Complex
Photoswitch Mediated Electron Highway Driving Direct Pollutant‐to‐Oxidant Electron Transfer in Ultrafast Fenton‐Like Reactions
Synergistic Ion‐Pair/Lewis Acid Catalysis Enables Enantioselective Synthesis of Helically Chiral Oxa[6]Helicenes
Millisecond Aliphatic Iodonium-Claisen Rearrangement Enabling Dual Functionalization of Alkenyl Iodanes
Arylhydrazines: Convenient Homogeneous Reductants for Scalable Cross-Coupling
Catalyst-Free Ammonia Formation at the Gas-Liquid Interface Enables Selective Nitrogen-Saccharide Association Under Abiotic Conditions
Continuous Evolution of Calmodulin for High‐Purity Separation of Rare Earth Elements
Mechanism of the Photodecomposition of Stable Triarylmethyl Radicals
Alternately Twisted, Electron‐Rich Rylenes and Their Stable Cations
Bioinspired Total Synthesis of Curtachalasin B and Biosynthetically Related Cytochalasans
Mild Generation of Highly Nucleophilic N-Heterocyclic Carbene Boryl Anion From Neutral sp2–sp3 Diboron Reagents and Its Applications in Nucleophilic Borylation
Regioselective Electrosynthesis of Substituted (deuterated) Pyridines Through Enamine‐Iminium Cross‐Coupling
A Monkey-Saddle-Shaped Nanographene Embedding a Dicyclohepta[cd,fg]-as-Indacene Core and Two Additional Heptagons, and Its Paddle-Wheel Co-Assembly With Fullerenes
Selective Carbocation Functionalization by Catalytic Transchalcogenation Reactions
A Metallosupramolecular Receptor for Squaraine Dyes Enabling Ultrafast Dark Resonance Energy Transfer
Mechanically Triggered Chemical Recyclable Polyethylene‐Like Materials
Light‐Driven Competitive Selection in a Protein‐Catalyzed Dissipative Peptide Replication
Total Synthesis of Limonoids Enabled by Sterically Assisted Boron Chain-Walking
Biocatalytic Regioselective C‐Formylation of Resorcinol Derivatives
Stereospecific Assembly of Triply Chiral Pseudopeptidic Cages Through Dynamic Dual Chirality Transfer
An Iridium‐Catalyzed Conia‐ene Reaction for the Diastereo‐ and Enantioselective Synthesis of Complex Ring Systems
Covalent Protein Inhibitors via Tyrosine and Tryptophan Conjugation with Cyclic Imine Mannich Electrophiles
Hidden Diradical: Conformational Switch for Solvatochromic NIR Emission With Unity Quantum Yield in Thiele's Hydrocarbon
Palladium‐Catalyzed Enantioselective Four‐Component Carbonylative Dicarbofunctionalization of Internal Alkenes With 1 Atm CO
Ligand‐Engineered Metal–Organic Cages Boost Charge Separation for Efficient Photocatalytic Synthesis of Hydrogen Peroxide in Pure Water
Building Molecules by a Self‐Replicator That Catalyzes Acyl Hydrazone Formation
Temperature‐Responsive Near‐Infrared Emission Enabled by Reversible π‐Umpolung with an Alkenyl‐Strapped Diarylboryl Unit
Copper‐Catalyzed Regio‐ and Diastereoselective Dearomative Carbosilylation of Unactivated Arenes by Intercepting the Dienyl Radical
Minimizing H2O2 Loss in Industrial Electrosynthesis via Asymmetric Main-Group Sn Single-Atom Catalysts
Sequential Radical‐Anionic Polymerizations via Consecutive Photo‐Reduction
Predictive, Data‐Driven Design of Red‐Light Photoredox Catalysts for C─Heteroatom Bond Formation
Charge‐Regulated Pyridinic Nitrogen in Covalent Organic Frameworks for Metal‐Free Heterogeneous Photocatalytic C─H Arylation of Pyrroles
Photothermal Conversion Promotes Challenging SNAr for Facile C─N Bond Formation
A Noncovalent Click‐to‐Release Strategy to Control Bond Cleavage and Prodrug Activation
Stable BF2 Boracycles as Versatile Reagents for Selective Ortho C–H Functionalization
Access to Axially Chiral Vinyl Sulfilimines via Copper-Catalyzed Enantioselective Radical Relay Trifluoromethyl-Sulfilimination of Terminal Alkynes
Phosphine-Catalyzed Enantioselective [2 + 2] Annulations of α-Allyl γ-Benzyl Allenoates via a Transannular Cyclization Approach
Synthesis of Axially Chiral Phenanthryl–Aryl Phosphines via Nickel-Catalyzed Atroposelective [4 + 2] Cycloaddition with Broad Ligand Applications
Experimental Isolation of Single Impact, Cumulative Energy, Aging, and Liquid‐Assisted Grinding Effects in Mechanochemical Reactions
Structural Revision of the C16 Sesquiterpene Hegelenether and the Mechanism of C6-Methylation in Terpene Biosynthesis
Pickering Emulsion Interfaces Enhance Photocatalytic Selective Oxidation of Aromatic C─H Bonds
Dibenzazepine Bridged Network Polymeric Phthalocyanines as Degradable Heterogeneous Photocatalysts
Stereospecific Transition‐Metal‐Free Alkylation of Chiral Non‐Racemic Secondary Tosylates with Cyanohydrins: Convenient Access to Enantiomerically Enriched α‐Tertiary Ketones
Nanocrystalline Sn for Photoelectrocatalytic Synthesis of Stereocontrolled Oxime
Energy‐Transfer‐Enabled Skeletal Rearrangement of Cyclic Ketones into Strained Cyclopropane‐Fused Medium Rings
Alkynyltriazenes in Photochemical Metal‐Free Doyle–Kirmse Rearrangements
Selective Singlet Oxygen Generation over a Silver–Porphyrin Single‐Atom‐Site Catalyst for Ultrafast Sulfide Photooxidation
Selective N‐Terminal Modification of Peptides and Proteins Using Fatty Acyl Phosphates
Total Synthesis of (+)-Melonine and (+)-N4-Oxy Melonine Enabled by an Intramolecular Alkene Diamination Reaction
Redox-Neutral Cu-Catalyzed Cyclative γ-C–H Functionalization Enroute to Aza- and Oxo-heterocycles
Synergistic Effects of Electricity and Light for Efficient Iron‐Catalyzed Recycling of Polystyrene Waste
Long‐Wavelength Light‐Induced Group 13–15 Elementalization Reactions of Alkenes/Alkynes
Growth, Dissolution and Segregation of Genetically Encoded RNA Droplets by Ribozyme Catalysis
Strain-Release Diversification of 1-Azabicyclobutanes via Bromide/Nickel Relay Catalyzed 1,3-Bis-Carbofunctionalization
Energy‐Transfer‐Enabled Copper‐Catalyzed Direct Site‐Selective Cycloaddition of Unprotected Oximes with Alkenes
Conjugation Engineering Boosts Alkynyl‐Copper Photocatalysis for Efficient Selective Aerobic Oxidation
Halide Bond Assisted Double Desymmetrization of Meso-Dicarboxylic Acids with Symmetrical Olefins via Asymmetric Halogenation
An Expanded Toolbox for Versatile Chemical Editing of Adeno-Associated Virus
<atl>Photoredox/Cobalt‐Catalyzed Asymmetric Radical Addition to Imines with Furanosyl 1,4‐Dihydropyridines to Access iC/i ‐Glycosyl Amino Esters</atl>
An Electrocatalytic/Heterogeneous Catalytic Cascade for Selective Production of Propylene Oxide via Anodic H2O2 Generation
Engineering Isoquinoline-derived Directing Template for Distal C5−H Functionalization of Bicyclic Aza-arenes
Total Synthesis of (±)-Cristaxenicin A: Construction of Nine-Membered Ring by Eschenmoser–Claisen/Cope Rearrangement Cascade
Formal [4+3] Bridged Cyclization of Pyridines/Isoquinolines with Vinylcarbenes via Dearomatized Oxazinopyridine Intermediates
Late-stage Tyrosine ortho-C(sp2)-H Alkenylation for Macrocyclic Peptide SuFEx Proximity Labeling and Targeted Degradation
Copper-Catalyzed Three-Component Selective 1,4-Amino Oxygenation of 1,3-Dienes
Single‐Atom‐Modulated Reactive Oxygen Species Generation and Network Crosslinking in Porphyrin‐Based Metallacages for Selective Photocatalysis
Nickel-Catalyzed Chemo- and Diastereoselective Dearomative Dialkylation of Indoles with Two Different Alkyl Halides
Skeletal Editing of Hydroxyl Oxindoles via Organoiodine-Catalyzed Oxygen Atom Insertion Reaction
Iron-Catalyzed Enantioselective Deoxygenative Addition of Propargyl, Allyl, and Benzyl Alcohols to Cyclic N-Sulfonyl α-Ketiminoesters Mediated by Visible Light
A Biocatalytic Platform for the Synthesis of Organofunctional Silanes and Siloxanes
Controlled Radical Copolymerization of Hydrofluoroolefin 2,3,3,3-Tetrafluroropropene (R1234yf) via Thermally Activated Delayed Fluorescence Catalysis
A General Strategy to Access Pharmaceutically Relevant Pyridines from Nitroarenes
Selective Hydrodemethylation of Methylalkylbenzenes on Potassium Hydride
Atroposelective Suzuki–Miyaura Coupling to Form 2-Amino-2′-Hydroxybiphenyls Enabled by sRuPhos
Strain-Release Induced 1,2-Metallate Rearrangement of Geminal Diborons: Multicomponent 1,5-Difunctionalization via Ring-Opening Coupling
Photochemical Deracemization of Chromanes and its Application to the Synthesis of Enantiopure Bioactive Compounds
Brominated Pd-on-Au Nanostructures Enable Reductive Relay Isomerization of Alkynes to E-alkenes
A Photoelectrocatalytic Platform for Sequence-Unrestricted Modification of Oligonucleotide Backbones
Dynamic Metal-Organic Tube Isomers
Enantioselective Total Synthesis of (−)-Bisabosqual F via N-Heterocyclic Carbene Catalyzed (4+2) Annulation
Bidirectional Photoregulated Chromism in Pyridinium Derivatives via Secondary Excitation‐Driven Electron Transfer
Stereodivergent Synthesis of Three Contiguous Stereogenic Centers by Cu/Ir‐Catalyzed Borylallylation
Tin—Tin π Bonding as a Conduit for Alkali-Metal Reduction
Harnessing Photoenzymatic Systems for Intermolecular C–H Fluorination
Synthesis of Perdeuterated Pentane and THF Under Mild Conditions by Silica-Supported Ta/M (M = Co, Ir) Heterobimetallic Catalysts
Pulse-Constructed Cuδ+/CuOx Reduces the C─Cl Dipole Moment to Enable Complete Deuterodechlorination of Trichloroacetic Acid
Asymmetric Hydride Shift Reactions Catalyzed by Chiral Aluminium Complexes
Networked Porous Organic Cage Membranes for Precision Separation of Pharmaceutical Ingredients
Pyroglutamate PTMs as Bioorthogonal Reactive Handles: Ru/Ni Photoredox Coupling
From Plastic Waste to Pharmaceutical Precursors: PET Upcycling Through Ruthenium Catalyzed Semi-Hydrogenation
Practical Synthesis of Allylic Heteroaromatic Amines via Pd‐Catalyzed Oxidative Amination of Olefins
Dispersion‐Enhanced Nitrogen‐Centered Photocatalysis of the Direct Hydrogen Atom Transfer
Accessing Molecular Complexity from Methane and Other Gaseous Alkanes via Photocatalytic Cascade Cyclization
A Stable Triindenobenzotrithiophene Triradical with Equilateral Ferromagnetic Spin Coupling
Twist and Shine: The Impact of Halogen Substitution on Thiele Hydrocarbon's Optical Properties
Molecular Cages as Probes in Indicator Displacement Assays: The Case of Scopolamine Detection
A Radical Cascade with Double Intramolecular Hydrogen Atom Transfer for the Generation of Bisfunctionalized Cyclopentanes from Linear Alkynes
Temperature-Controlled Synthesis of Corannulene-Based Multi-Helicenes: Highly Integrated Curvature/Planarity for Enhanced CPL Brightness and Solid-State Luminescence
A Boron-Doped Buckybowl with a C42B2 Core: Synthesis, Crystal Structure, and Optoelectronic Properties
Engaging Tertiary Benzylic Radicals in Metallaphotoredox Catalysis: A Modular Approach to Access Diaryl Quaternary Centers
Stereochemical Dissection of the Strobilurin PKS Reveals the Complex Biosynthetic Logic of Iterative EZE Triene Construction
Fluorothiazynes as SuFEx Ambiphiles: Interconversion to Amino‐sulfurdiimidoyl Fluorides
Minimalist Molecules Drive Liquid–Liquid Phase Separation to Modularly Assemble Functional Coacervate Protocells
Aminoboranes as Rationally Tuned Organic Photosensitizers for Energy Transfer Catalysis
Confined Chiral Center Stacking Induced Twisted Silica Nanoribbons for Tumor Cell Proliferation Regulation
A Para‐Selective Kolbe–Schmitt Reaction
Hydroxyl Radicals Unlock Strong C(sp3)─Si Bonds: Photocatalytic Alkylation and Silacycle Engineering
Mechanochemical Synthesis of X-Vinylbenziodoxol(on)es and One-Pot Conversion to Complex Alkenes
Hybridized Host Functions in Polyaromatic Tube-in-Capsule Composites
Bench-Stable Boryl Thianthrenium Dication Enables Aziridinyl Boronate Synthesis via Metal-Free Late-Stage Aziridination with Diverse Nitrogen Nucleophiles
Novel Sulfonium Reagents for the Modular Synthesis of Spiro[2.3]Hexanes and Heteroatom-Containing Analogues: Synthesis, Application, and Evaluation as Bioisosteres
Enantioselective Synthesis of Chiral Sulfinamidines via Asymmetric Amination of Sulfenamides Using a Chiral Phosphoric Acid Catalyst
Translation‐Promoting Effects of RNA Template Overhangs in the Absence of Ribosomes
Photocatalyzed Ring Expansion of α-Ketosulfonylaziridines: Ready Access to δ-Sultams
A Modularly Integrated Chiral Cavitand
Electrochemical Azolation of Electron-rich Fluoroarenes: A Controlled Redox Chain Unlocks C─N Bond-forming e-SNAr
Divergent Total Synthesis of Denudatine Alkaloids Cochlearenine, Macrocentrine, Dictizine, 15‐Veratroyl‐17‐Acetyl‐19‐Oxodictizine, and the Proposed Structure of Acochlearine
Bifunctional Photoactive Chiral Ligands Enable Visible-Light-Induced Nickel-Catalyzed Enantioselective C−O Coupling
18F-Radiopharmaceutical Diversification Enabled by Deaminative Cross-Electrophile Couplings
Biomarker-Gated Photocatalysis Uncaging in Live System
Total Syntheses of Diketopiperazine Alkaloids via Divergent C3–N1' and C3–C5' Bond Anchor
Regiodivergent Chain-Growth Polymerization of Aza-π-Allylpalladium Zwitterions via Proton Transfer
Electrocatalytic Migratory Carboxylation of Unactivated Olefins or Halides with CO2
Ligand-Promoted Site-Selective Regiodivergent Lactamization of Activated δ- versus Inert γ-Methylene C(sp3)–H Bonds via Open-Shell Copper(II) Nitrenoid Catalysis
Nanoconfined Photocatalytic Cascade Reaction in Vinylene‐Linked Covalent Organic Frameworks
Engineering a Thermally Activatable SpyCatcher/SpyTag Protein Ligation for Injectable and In Situ‐Forming Hydrogels
Synergistic Pd/Cu-Catalyzed Stereodivergent Controlling of the Z/E and R/S Configurations: Synthesis of Non-Natural α-Amino Acids Containing Trisubstituted Olefin
Cobalt(I)-Catalyzed Diels–Alder Sequences Involving Alkynes and Dendralenes
Hydrophobic NIR Photocatalysts for High-Throughput RAFT Aqueous Solution Polymerization: Achieving Ultrahigh Molecular Weights with 4-ppm Dye Colloids
Harnessing Cooperative Energy Transfer and Hydrogen Atom Transfer for Direct Nitrogenations of Non‐Activated Alkanes
Engineering Cyanoarene Photocatalysts to Resolve Deactivation Challenges in Organocatalyzed ATRP
Construction of Biaryl Skeletons Initiated with Benzyne Insertion into C═S Double Bond of Pyridine-2(1H)-thiones
Highly Diastereo‐ and Enantioselective Pd‐Catalyzed Spiroaminoalkylation: One‐Step Construction of Multifunctional Angular Polycyclic Amines
Influence of Rare Earth Elements on Prebiotic Reaction Networks Resembling the Biologically Relevant Krebs Cycle
Copper-Catalyzed Enantioselective Radical Desymmetrizing Cyclization of Cyclopentenes: Access to Chiral 2-Azabicyclo[2.2.1]Heptan-3-ones
Highly Efficient Construction and in Situ Post‐Assembly Modification of Multifunctional Metal–Organic Cages in Microdroplets
Streamlined Sugar Diversification via Photoredox-Catalyzed Regio- and Stereoselective 1,2-Alkylarylation of Glycals
Stereodivergent Construction of Spiropyrrolidine-γ-Butyrolactones Enabled by Cu/Ru Sequential Catalysis and Stereoselective Reduction
Terpenoid Synthesis via Convergent Radical Annulation
Homoleptic Bismuth Alkynes: Isolable Reagents for Selective Alkynyl Radical Transfer
Amination and Para-C─H Arylation of Aryl Fluorides Enabled by α-Methylnaphthyl (MeNAP) Palladium Catalysts
Enantioselective Synthesis of H-Phosphinamidates
Crystalline 90°‐Twisted Carbon‐Centered Non‐Kekulé Diradical Derived from N‐Heterocyclic Carbene
Fluoride‐Transfer Asymmetric Allylic Alkylation Enables Regiodivergent, Stereoselective Cross‐Electrophile Coupling
Synthetic Motifs for Understanding Lewis Acid Interactions with Persulfides and Thioselenides
Inner-Axial Chlorine Engineering Enables Efficient and Selective Phenol Electrocatalytic Upcycling to Benzoquinone on Noble-Metal-Free Catalysts
Radiation-Responsive Coacervates Through Controlled Self-Immolative Demembranization
Bifunctional Aziridines from Photochemically Generated FSO2NH2 for SuFEx Diversification of Alkenes
Synthesis and Upcycling of All‐Carbon‐Backbone Degradable Polyethylene with Dispersed On‐Chain Ketones
Bioinspired Synthesis of Twin abeo-Steroids Bufogargarizins A and B via a Divergent Intramolecular Aldol Addition Reaction
Fragmentation of Isoxazolones to Alkynes Enabled by Anomeric Amides
Predicting the Stability of Base-mediated C─H Carboxylation Adducts Using Data Science Tools
Highly Selective Electrosynthesis of Glycine from Glyoxylic Acid and Nitrate via Stabilizing the NH2OH Intermediates
Frame‐Shifted Synthesis of Oligoheterocycles as a Platform for Molecular Design
Construction of Artificial Cells with Urea Cycle Pathway for Ammonia Detoxification
Carbonyl-to-Silicon Exchange of Aromatic Lactones via Decarbonylation
Compressed Co–O Bonds Resist Chlorine Corrosion to Enhance the Stability of Chlorine‐Involved Anodic Reactions
The Methylbismuth Dication: Pentagonal Pyramidal Coordination and Ligand-Induced Lewis Superacidity
Dual Proton/Anion Binding Through Reciprocal Allostery in Platinum(II) Lantern‐Shaped Cages
Absolute Configuration Determination with Electronically Enhanced Vibrational Circular Dichroism
Time-Resolved SAXS Studies During the Synthesis of Hydrolytically Degradable Poly(ε-caprolactone)-Poly(N,N′-dimethylacrylamide) Diblock Copolymer Nanoparticles in Aqueous Media
Ring Expansion of Oximes via Photochemical Aza‐di‐π‐methane Rearrangement
Direct Access to Acylboranes via Formal Condensation of Carboxylic Acids with Ligated Boranes
Enantioconvergent Access to Chiral S(VI) Stereocenters by Kinetic Resolution of Sulfonimidoyl Chlorides
Enantioselective Miyaura Reaction by Desymmetrizing C(sp2)–B Cross-Coupling of 1,1′-Biaryl-2,6-diyl Bis(nonaflates)
Electrochemical Controllable Divergent Carboxylation and Hydrocarboxylation of Alkynes with CO2
Copper-Catalyzed Phosphorus Radical Transformations for the Assembly of P-Stereogenic Architectures
Homoterpene Biosynthesis in Fungi
Hyalucidin A: A Bacterial RiPP Featuring a Benzofuranoindoline Motif Biosynthesized by Tandem P450 Catalysis
Noble Metal-Free Photosensitive Terpyridine Coordination Assemblies for Efficient Single-Molecule H2O2 Photocatalysis
Csp, Csp2, and Csp3 Hydrocarbyl Group Migration from Pd(II) to P(III): Accessing Metallophosphoranes via Nonspectator Ligand Reactivity
Enhanced Selectivity of Chalcogen Bonding over Halogen Bonding Catalyzed C-glycosylation Through Differentiated Intermediate Activation
Mechanistic Characterisation of Bacterial Terpene Synthases from Chitinophagaceae Producing Marine-Type Diterpenes
Hierarchical, Template-Controlled Self-Assembly of Two Different Organometallic Capsules from a Tetrakisimidazolium Salt
Switchable Phenanthroline‐Cu Catalysts for Enantioselective Alkynylation and Amination of Cyclic Diaryliodonium Salts
Selective, Oxygen‐Tunable, and Metal‐Free Functionalization of Polyethylene Through Dual‐Mode Nitrosation and Carbonylation
Synergistic Enhancement of Photoredox Catalysis Beyond the Singlet Bottleneck Through Triplet Charge Recombination and Magnetic Field Effects
Environment-Responsive Self-Assembly and Coupled-Network Effect in Dynamic Replicating Nucleopeptide Networks
Electron‐Enriched Pt‐In Synergistic Sites for Highly Selective and Direct Photo‐Reforming of PET Plastic Wastes into Acetic Acid
Electrooxidative Divergent Halocyclizations of Ambident Amides
Accelerating Medicinal Chemistry: A C(sp3)-Rich Fragment Toolbox for Redox-Neutral Cross-Coupling
Thiol–Ene Photoclick Chemistry for Efficient Bicyclic Peptide Synthesis and Genetically Encoded Peptide Library
Using Polymerization‐Induced Self‐Assembly in Orthogonally‐Reactive Dispersants to Design Tough Nanostructured Materials: Application to Epoxy Networks
Direct C─H Lactonization of Carboxylic Acids Enabled by LMCT Photoactivation
Pseudohalide-Guided Redox Control Enables Electrochemical Auto-Tandem Nickel Catalysis for Butafulvene Synthesis.
Graphitic C6N6-Supported Dual Cu/Zn Single-Atom Nanozyme Mimicking Allosteric Regulation for Intelligent Switching Biosensing
Triplet Metallovinylidenes of Palladium and Platinum Based on a Chelating P/Diazoalkene Ligand
Bypassing β-Hydride Elimination: Excited-State Pd-Catalyzed C(sp3)–C(sp2) Coupling at Room Temperature
Overcoming Hydrophobicity with Water Enables Ultrafast Hydrolysis of Waste Polyethylene Terephthalate at Very Mild Conditions
Nickel-Catalyzed Enantioselective Reductive Cyclization of 1,3-Dienes Toward α-Chiral Six-Membered Silacycles
Emergent Chemical Reactivity and Complexity of RNA Condensates
Reaction of Blatter and Verdazyl Radicals with Arynes: Synthesis and Investigation of N‐Chiral, Antiaromatic Triazines, and Tetrazinones
Through Stronger Hindrance to Higher Reactivity: Influence of the Alkyl Chains on the Activation Energy of Ether Cleavage on Silicon
Iron/NHC-Catalyzed Regio- and Stereoselective 1,6-Additions of Aliphatic Grignard Reagents to α,β,γ,δ-Unsaturated Carbonyl Compounds: Asymmetric Variants with Chiral NHCs
Grafting Cell‐Penetrating Poly(disulfide)s to Substrates of Interest: Dynamic Covalent Bioconjugation for Traceless Delivery
Defluoroalkylation of Trifluoromethane with Organolithium Reagents: Mechanism and Synthesis of Fluoroalkenes
Site‐Selective Peptide and Protein Functionalization with Cyclopropenium Cations
Ultrafast Single Electron Transfer Enables General Visible Light C─X (S, SS, Se) Coupling via Carbonyl Activation
Aminative Suzuki–Miyaura Coupling: Tackling Alkyl Nucleophiles and Addressing the Viability of the Electrophile-First Mechanism
Integrating the Substituent Effect into the Wade–Mingos Rules for Dicarboranes
Revealing Pathway Complexity in Host–Guest Binding: Allosteric Regulation and Temporal Chiral Inversion During Complexation of Naphtho[2,2]urils
Stereodivergent Access to C-N Atropisomers via Phosphonium Salt-Enabled Desymmetrizing Remote Cyclization/Aromatization Cascade
One Collision – Two Heteroatoms: Gas‐Phase Preparation of Azasilabenzenes
Decarboxylative Arene Ring-Opening of Benzoic Acids
Sequential Heterolytic Carbon‐Halide and Carbon–Carbon Bond Activation in Unactivated Piperidines
Miniature Photoenzyme Enables Organelle-Specific Cellular Control via Deboronative Hydroxylation
Cationic‐Catalyst Strategy Enabling Ultrafast and Controlled Polymerization and Efficient Depolymerization Toward a Circular Polymer Economy
A Photo- and Cobalt-Catalyzed Enantioselective Hydroamination of Unactivated Alkenes with Amines
Integrated Conversion of Polyesters, CO2, and Glycerol via Ethylene Oxide-Mediated Tandem Process
All-Nido-Carborane-Protected Copper Clusters
Synthesis, Isolation, and Reactivity of a Phosphinidene Telluride
Stereoselective Synthesis of 2-Deoxy-β-O-Aryl Glycosides by a One-Pot Strategy Involving C─O Coupling and Catecholborane Reduction
Reactivity of Low Valent Magnesium(I) Complexes with Epoxides and Episulfides
Cooperative Brønsted Acid and Photo‐Promoted Stereoselective Synthesis of Substituted Piperidones
Iridium Porphyrin-Catalyzed Asymmetric Rearrangement of Oxindoles with Aryl Diazoesters: Enantioselective Synthesis of Chiral Tertiary 2-Indolyl Alcohols
Cluster Formation and Phase Transitions Induced by Vibrational Strong Coupling
Anion-Assisted Copper/Chiral Diamine-Catalyzed Aerobic Oxidation for the Kinetic Dearomative Spirocyclization of Arenols
Successive Sulfur Oxidation Directs Topological Transformation From 4 1 Knot to 62 3 Link
Anionic Hofmeister Effect Differentiated Subcellular Distributions of pH-Responsive Metal–Organic Cages for Tumor Photodynamic Immunotherapy
Topochemical Alkyne Nitrile Oxide Cycloaddition for Polymer Synthesis
Generality‐Driven Optimization of Enantio‐ and Regioselective Mono‐Reduction of 1,2‐Dicarbonyls by High‐Throughput Experimentation and Machine Learning
One‐ and Two‐Electron Carbon–Halide Bond Activation at a Phosphorus Center
Biosynthesis of the Biphenomycin Family of Potent Antibiotics
Harnessing Colloidal Dispersion for Laccase‐Driven Enzymatic Depolymerization of Polystyrene
A Family of Cobalt(II) Complexes Exhibiting Record Dissymmetry Factors in Vibrational Circular Dichroism
Site-Selective RNA Modification by Programmable DNA-Small Molecule Conjugates
Divergent Ring‐Opening Functionalization and Reductive Coupling of Pyridines via Zirconium Alkylidene Complexes
Efficient Electrosynthesis of Dinitrile from Nylon-66-Derived Diamine Enabled by Highly Active Mn–O–Co Motifs in Spinel Oxides
Tailoring Spin–Spin Dipolar Interactions by Conformational Locking Toward Room-Temperature Molecular Qubits
Diversity-Oriented Post-Polymerization Modifications by Developing gem-Diboryl Polyolefin as a Platform Polymer
EDA Complex‐Driven Desaturation of Heterocyclic Carbonyl Compounds Enabled by HFIP
C─H Silylation of Unactivated Arenes Catalyzed by a Borenium/Pyridine Lewis Pair
Asymmetric N‐alkylation of Carbazoles by Cooperative Potassium‐Hydrogen‐Bond‐Aryloxide Catalysis
“Noninnate” Ring-Opening Polymerization: Palladium-Catalyzed Stereoselective 1,4-Polymerization of Alkynylcyclopropanes
Synthesis of 2‐Chlorocyclopropene‐Tethered Diazocarbonyl Compounds and Their Cyclization to Form Poly‐Substituted Phenols
Directing the Electrochemical C─N Coupling Toward Efficient Amide Synthesis via Ammonia Activation‐Mediated Pathway
Deciphering Ball Milling Mechanochemistry via Molecular Simulations of Collision‐Driven and Liquid‐Assisted Reactivity
Redox-Acidity Interplay in Eu-Promoted PtSn2 Catalysts for Selective and Stable Propane Dehydrogenation
Complete Recycling of Polyester Wastes with Dialkyl Carbonates
A Photoswitchable HaloTag for Spatiotemporal Control of Fluorescence in Living Cells
Facile (Z)-Selective Synthesis of β,γ-Unsaturated Ketones by a Silicon-based Olefination Strategy
Pd(II)/PIDA-Enabled Migratory Triple Functionalization of Terminal Alkenes via a 1,2-C/Pd(IV) Dyotropic Rearrangement
Access to Inherently and Centrally Chiral Calix[4]Arenes via Rhodium-Catalyzed C─H Activation and Insertion into Diverse Olefins and Alkynes
Construction of Tetrasubstituted α-Amino- and α-Alkoxy Phosphine Oxides via Pd-Catalyzed Regio- and Enantioselective Hydrophosphinylation of Dienes
Catalytic Asymmetric Aza-[2+2] Cyclization Reaction of Simple Ketoimine
[3]CycloBODIPY: A Highly Strained Cyclic BODIPY Trimer with Effective Macrocyclic Conjugation
Catalytic Asymmetric Synthesis of Chiral Allenylic Fluorides Enabled by Multiple Radical Sorting
A General Strategy to Develop Intramolecular Spirocyclic Boron Dipyrromethene Fluorophores for Self‐Blinking Super‐Resolution Imaging
Controlled Dual Activation of Rhenium(I) Photosensitizers and Profluorophores/Prodrugs via a Dissociative Bioorthogonal Tetrazine–Isonitrile Reaction
Stereoselective Synthesis of Alkenyl Fluorides and Alkynes by Defluoro Coupling of Trifluoromethyl Arenes
Mechanism of the Stoltz–Grubbs (KOisupt/sup/iBu/Etsub3/subSiH) Silylation: Single‐Electron Transfer is the Missing Link between the Heterolytic and Radical Pathways
Atroposelective Synthesis of Ultrarigid Chiral Styrenes via Pd-Catalyzed Unconventional 5-exo-dig Cyclization/Carbonylation of 1,5-Enynes
Reductive Cross-Coupling of Alcohol Derivatives with Chlorosilanes via Pyridines-Promoted Si─Cl Activation
Remote Enantioselective Redox ε-Alkylation of Copper Allylic Allenylidenes with Enals
Machine Learning‐Driven Automated Synthesis of Polysubstituted Gentisaldehydes
Unravelling the Dynamic Modulation of Copper (Oxy)Hydroxides for Electrocatalytic Organic Nucleophile Oxidation
Iridium Photosensitizers Immobilized on Metal–Organic Layers Lead to Enhanced Enantioselectivity in Ni/Ir Dual Photocatalysis
Regulating Promiscuous Catalysis via Substrate‐Induced Transient Assembly
Design and Structural Transformations of Zinc(II) Knotted Cage Frameworks
Facile Access to Chelating CAArC‐Phosphine (CAArCPhos) Palladium Complexes
One-Step Assembly of α-Aryl-Substituted DOTAs as Superior and Universal Platforms for Multifunctional Theranostics
Metal-Free Sulfur-Dots Induced Spatiotemporal PhotoRDRP for Multi-Arm Star Functional Polymer
Achiral Catalyst‐Induced Stereoselectivity Switch at Quaternary Stereocenter: Diastereodivergent Ring‐Opening Alkylation and Enantiodivergent Arylation of Oxindoles
Palladium-Catalyzed Enantioselective Three-Component Dearomative Coupling of Bromoarenes: Modular Construction of Terpenoid Scaffolds
Polyoxometalate‐Directed Assembly of Robust Coordination Cages: Overcoming Kinetic Inertness and Conformational Mismatch
Ruthenium-Catalyzed Diversified Kinetic Resolutions of Diaryl-Substituted Cyclobutenones via Asymmetric Transfer Hydrogenation
Dynamic Kinetic Resolution Approach to Chiral Sulfur-Containing Aza-[5]helicenes via Chiral Lewis Base Catalyzed C─H Sulfenylation
Modular Synthesis of Pyritide-Inspired Macrocycles Featuring Bipyridine Motifs
Organocatalyzed Atom Transfer Radical Polymerization (O‐ATRP) Using a Super‐Reducing Photoredox Catalyst
Superbasic Anionic Calcium Alkyl Complexes: Templated Twofold Deprotonation of Benzene
Enantioselective Synthesis of α‐Arylated Allene Ketones Through Sequential Bismuth(V)‐mediated Arylation and Organocatalytic Protonation
Mannich Cyclization of Bifunctional Hydroxylamines by Aza-Kornblum–DeLaMare Rearrangement to Form Cyclopentyl β-Amino Esters
Nor[7]circulenyl Neutral Radical and Its Charged Species: Synthesis, Structures, and Efficient NIR-II Photothermal Conversion for Imaging and Laser Ignition
Isolation of Anionic N-Heterocyclic Olefins and Their Versatile Reactivity
Total Synthesis of Clerodin
Nickel-Catalyzed O-Alkylisourea-Enabled Electrochemical Radical C(sp3)−C(sp2) Cross-Coupling
Photocatalytic Radical Umpolung for Strain-Release Difunctionalization of (Aza)bicyclo[1.1.0]butanes
Synthesis of Degradable Polyimines Through Deborylative Polycondensation
Visible-Light-Induced [2π+2σ] Cycloaddition Enabled by Cage-Confined Photocatalysis for Precise Bicyclo[2.1.1]Hexane Construction
Lithium Iodide Enables Bis‐electrophilic Ring‐Opening of Azabicyclo[1.1.0]butanes
Observation of Near‐Infrared Photothermal and Photoacoustic Effects in a Metallosupramolecular Trefoil Knot
Direct Boron-10 Access: Nickel-Catalyzed Reductive C(sp2)─10B Coupling Utilizing 10BF3
Regio-, Stereo-, and Enantioselective Copper-Catalyzed Allylation of Sulfinylamines with Allenes
Bis(azuleno)pentalenes with Six Consecutive Odd‐Membered Rings
Catalytic Enantioselective Synthesis of Axially Chiral Tetraarylethenes
Collective Total Synthesis of a Unique Class of Liverworts‐Derived Cembrane Diterpenoids
Facile One-Step Synthesis of mathematical equation Link Cages by Coordination-Driven Self-Assembly
Synthesis, Structures, and CPL Property of Inner-Wall Modified Pagoda[5]Arenes Driven by Cavity Microenvironment
Molecular Weight Control in Frontal Ring-Opening Metathesis Polymerization
Si−H Activation via Dynamic Permutational Isomerism: A Ligand-Directed Route to Dehydrogenative Coupling
Engineering Artificial Mitochondria with Self-Amplifying Proton Generation for Autonomous Energy Supply and Metabolic Coupling in Artificial Cells
A Robust Heterometallic Pt2Pd2L8 Double Cage Catenane
Photoredox/Nickel-Cocatalyzed Asymmetric C–O and C–S Couplings for Atroposelective Synthesis of N-Heterobiaryls
N‐Doped Nonalternant Molecular Bowl/Saddle Hybrids
Mn(I)‐Complex Catalyzed Upcycling of Polyethylene Terephthalate to α‐Hydroxy Carboxylic Acids
Ligand Effects in Regio- and Enantioselective Cobalt-Catalyzed Intramolecular [4+2]- and [2+2]-Cycloaddition Reactions of Unactivated 1,3-Diene-8-ynes and 1,3-Diene-8-enes
Ultrasmall Chemogenetic Tags with Group-Transfer Ligands
Amyloid Peptide Nanofibrils Promote Efficient Neurotransmitter Oxidation and Serve as Scaffolds for Melanin Production
Plasma-Electrocatalysis Cascade Synthesis of Deuterated Ammonia
Silylative Amide to Nitrile Conversion Mediated by Simple Lanthanide–Organoamides: Scope and Mechanism
Molecular Recognition Driven Organelle Cross‐Linking Induces Endoplasmic Reticulum Stress and Mitochondrial Dysfunction to Potentiate Cancer Immunotherapy
Silicon-Based Azo Compound-Mediated CO Activation and N2 Release
Visible-Light-Driven α-C(sp3)−H Carboxylation of Primary Benzylamines with CO2 to Access α-Amino Acids
Polycyclic Heteroaromatics with Planar‐Curved Hybrid Skeletons for High‐Performance Photocatalytic Hydrogen Peroxide Evolution
From Solvent to Catalyst: In Situ Amino Acid‐Like Species Enable PET Upcycling Without Added Catalysts
Sequence‐Specific Installation of Aryl Groups in RNA via DNA‐Catalyst Conjugates
Enhancing Cascade Reaction Efficiency by Local pH Regulation for Integrated Anodic H2O2 Generation and Ammoximation
Amine‐Ligated Boryl Radicals Enables Direct C─F Borylation and Cross‐Couplings of Polyfluoroarenes
Stable Iminium Singlet and Triplet Diradical(oid)s with Intense NIR-II Absorptions
Site-Selective α─C─H Functionalization of Saturated Heterocycles via Copper-Photoredox Catalysis
Bicyclic Isosteres of Pyridine/Piperidine: From Synthesis to Applications
Unlocking DAST‐Type Reagents for Modular Synthesis of Sulfur‐Containing Motifs
Bioinspired Peptide‐Phosphonium Salt Catalysis Unlocks Asymmetric Desymmetrization of Phosphoryl Acids: Programmable Synthesis of P(V)‐Stereogenic Molecules
Polymer Ligands with Quaternary Ammonium Binding Motifs on Metal Nanoparticles Enable Selective Ion Transport for CO2 Electroreduction
Reactions of Difluorocarbene with Organogold(I) Complexes: Synthesis of Gem-Difluoromethylene Organometallics via Difluorocarbene Insertion and Cycloaddition Reactions
Aqueous Separation of Styrene from Ethylbenzene Using a Water‐Soluble Cyclophane
Air‐Stable Allyl Radicals and Heterocoupled Dimer: Synthesis, Characterization, and Near‐Infrared Emissions
Atroposelective Synthesis of Enamine‐Based Axially Chiral Styrenes via CuH‐Catalyzed Hydroamination of Internal Alkynes
Transition‐Metal‐Free Carbonyl Redox: A Ketene in Three Oxidation States
Upcycling of Polystyrene to 1,2‐Disubstituted Oxygenated Aromatics Through Backbone Rearrangement and Oxidation Reactions
Rapid Construction of a Tyr C6–Trp C5′ Linkage: Application in the Total Synthesis of Micitide 982, a Noncanonical Cyclic Peptide
Cationic Selenuranes – Bench‐Stable Sources of Se(III) Radicals
BN/BO Doping of peri-Acenoacenes: Modulating Excited States in Trapeziumene Congeners
Computational Study of Ignored Pericyclic Reactions: Rearrangements of 1,2-Bis(Diazo)Alkanes to 1,2,3,4-Tetrazines and Subsequent Fragmentations
Engineering Cavity and Aperture Binding Sites Within a Metal–Organic Cage for Up‐ and Down‐Regulation of Catalysis
Multisite Proton‐Coupled Electron Transfer Facilitates Oxidative Photocatalysis in a Molecular Zr‐Based Coordination Compound
Smiles‐Truce Cascades Enable Heteroaryl Cyclopropane and Sultine Synthesis
Total Synthesis of Calyciphylline F
Chirality Makes or Breaks Chemically Driven Self‐Assembly
Photocatalyzed Synthesis of Unsymmetrical Alkylphosphorus(V) Compounds Using Imidazolium Phosphonites
Chemo- and Regiodivergent Allyl-Propargyl Cross-Coupling Reactions for the Construction of 1,4-Enallenes and 1,5-Enynes
A Highly Selective Nucleophilic and Radical Relay Difluorination of Cyclopropanes and Alkenes
Regioselective Zr5 Nanocluster Photocatalyst for Precise Protein Editing Under Mild Conditions
Cupin-Type Dimethylsulfoniopropionate Lyase from Pelagibacter ubique (DddKPu) Catalyzes Aza-Michael Addition of Primary and Secondary Amines to Acrylic Acid
Efficient Synthesis of Chemically Recyclable Polyamides via Substituent Effects‐Enabled Mechanistic Pathway
Formal C─H Functionalization of Quinolines at the C7 Position Through a Traceless Directing Strategy
Stereoselective Synthesis of Cyclic P(V) Compounds via Stereoconvergent Nucleophilic Substitution
Steering Amide Synthesis from Acetonitrile by Electrochemically Derived Active Superoxide
Temperature-Driven Conformational Switching of Binaphthalene-Based Tetraimidazolium Macrocycles to Enhance Sequence-Selective Recognition of Dinucleotides in Water
Ni‐Mediated High‐Spin Iron(III) for Boosting Electrocatalytic NO to Oxime Conversion
Wavelength Selective Single Molecule Photobase/Photoacid Generator Enabling Dynamic Control of Soft Matter Materials Functions
In Situ Sulfur Modification Enables Electrochemical Selective Deuterated Thiol–Yne Reactions
1,4-Dearomatization of Pyridines and Quinolines Enabled by the Carbodication Lewis Acid
Programmable Vertical Expansion of Bilayer 2D Supramolecular Frameworks via Molecular Pillar Engineering
Platinum-Catalysed Hydrofluorination of Alkynes at Room Temperature Promoted by a Fluoride Shuttle
Functionalized Calix[4]Nanocones
Changing Self‐Assembly Through Degradation: Phenyl Vinyl Ketone Polymer Nanoparticles Under Light
Nondestructive Patterning of Upconverting and Down‐Shifting Luminescent Nanoparticles for Information Encryption
Transient Induction of Chirality from an Activated Carboxylic Acid to a Zinc Complex
Photo-Induced Catalytic Dearomative Coupling of N-Heteroarenes
Copper(II)‐Photocatalyzed Radical Anellation of Nitroalkanes with Alkenes or Alkynes for the Synthesis of Isoxazolines and Isoxazoles
Electrochemical Alkyl Displacement of Thioethers for Streamlined Trideuteromethylation
Synthesis and Structure of Neopentyl Sodium: A Hydrocarbon‐Soluble Reagent for Controlled Sodiation of Non‐Activated Substrates
Single‐Atom Ligation of Four Different Alcohols at One Silicon Center: Methodology Development and Proof of Concept
Efficient Hydrogen Sulfide Separation from Carbon Dioxide Achieved by Carbonyl‐Functionalized Ionic Liquids for Natural Gas Upgrading
Accessing N-Unprotected Unnatural α-Amino Acid Esters by Half-Sandwich Chiral-at-Ruthenium Aldehyde Catalysis: Scope and Mechanistic Study
Transition Metal-Free Formal C─H/C─H Coupling of Arylacetamides and Sulfoxides: An Interrupted Pummerer/[2,3]-sigmatropic Rearrangement Sequence
Ketenimine Multicomponent Strategy for Multifaceted Amidine Functionalization of Peptides on the Solid Phase
Radical C─H-Aroylation of Allenes via Cooperative Photoredox and N-Heterocyclic Carbene Catalysis
Synthesis of Thiophenes from Pyridines Using Elemental Sulfur
Intercalation Chemistry Awakens Transition Metal Hydroxide for Boosted and Sustained Electrocatalytic Sulfion Oxidation
Catalytic Enantioselective Diboration of 1,2‐Dihydropyridines
Enantioselective Synthesis of ε-Lactams via Rh(I)-Catalyzed C─C Bond Activation
Chloromethoxytrityls: Tuning the SOMO Level of Stable Luminescent Radicals
Ligand Type Guided Keto-Arylation Enables Modular Total Synthesis of Polycyclic CBS Xanthones
Dual-Stimulus Programmed Multiphase Separation and Organization in Coacervate Droplets
Catalysis of Radical Coupling Reaction via Synergistic Action of Oriented External Electric Field and Light Irradiation
Oxygen-Tolerant, Red Light-Driven Controlled Synthesis of Easily Degradable and High Molecular Weight α-Lipoic Acid-Vinyl Copolymers
Enantioselective Incorporation of Amine Fragments onto Quaternary Carbons via Metallaphotoredox Catalysis
A Facile and Efficient Route to Achieve Polythiophene‐Based Nanoparticles With Various Morphologies
Nickelaelectro‐Catalyzed C─H Activation to iβ/i‐Arylated Pyrroles ivia/i Multiple Dehydrogenation
Photoactivatable Synthetic Exosomes for RNA‐Based Communication Between Artificial Cells and Living Cells
Unravelling the Functional Diversity of Type III Polyketide Synthases in Fungi
Iron-Catalyzed Asymmetric [4+2]/Cheletropic Retro-[4+1] Cycloadditions of Thiophene S,S-Dioxides with 3-Substituted Indoles
Dendritic Pillar[6]Arenes with Fixed Planar Chirality for Stereoselective Inclusions in Water: A Case of Facile Differentiation of Cocaine Adulterants, Levamisole and Dexamisole
Are Grignard Reactions in Deep Eutectic Solvents Interface-Driven?
Tertiary Phosphine Diversification via Photochemical P─C Chemoselective Cleavage of Phosphonium Salts
Alkali Metal Cations Impact the Selectivity of Radical‐Mediated Electrochemical C─H Chlorination
Photocontrolled Release of Urea Enables the Detection of Urea–Urease Intermediates by Cryo‐FTIR
Regulation of Relay Catalytic Mechanism for Efficient Methanol Oxidation Reaction
Molecular Rotors as Reactivity Probes: Predicting Electrophilicity from the Speed of Rotation
The Overlooked Dual Phosphorescence of Lappert's Diamino Stannylene Sn[N(SiMesub3/sub)sub2/sub]sub2/sub
A Broadly Applicable Strategy to Aminate Azines Enabled by Electronically Tuned Phosphine Reagents
Radical Reactivity of Thioimidates for Diversified Polymeric Amidines with Tunable Properties
Photo‐Mediated Silacyclization by Wavelength‐Dependent Selective C─F or C─H Functionalization
Assessing Fluorosulfonyl Pentafluorooxosulfate (FSO2–OSF5) Reservoir Capacity: Selective SOF4, SO2F2, and [OSF5]– Anion Release
Intramolecular Phosphinyl‐Zincation of Alkynes: A Powerful Entry to Benzophosphole Oxides
Tailoring Tubular Supramolecular Polymers with Polar Lumens to Host Hydrophilic Dye Molecules
Biocatalytic Alkylation of Ambident Nucleophiles Enables Selective iN/i‐Functionalization of Heterocycles and Late‐Stage Modifications
The Origin of the Feedstock Molecules for Life on the Hadean Earth
Stereoselective Self-Assembly of a Topologically Chiral [6]Catenane with 18 Crossings
A C-to-B Atom Swap on Coumarins and Dibenzolactones
Photocatalytic Formamide Synthesis from Plastic Waste and Ammonia via C─N Bond Construction Under Mild Conditions
Organocatalytic Enantioselective [4 + 4] Cycloadditions of Furan iOrtho/i‐Quinodimethanes
The Discovery and Development of an Iridium‐Catalyzed N→C Alkyl Transfer Reaction
Isolable Arylphosphinidene Chalcogenides and their Radical Anions
Enantioselective Synthesis of Cyclobutane‐fused Heterocycles via Lewis Acid‐Catalyzed Dearomative [2+2] Photocycloaddition of Indoles, Benzofurans, and Benzothiophenes with Alkenes
A Tertiary Amine‐Based Electrolyte with Methylation‐Mediated Steric and Electronic Synergy for High‐Performance Lithium Metal Batteries
Copper‐Stabilized Nitrene Radical in N─N Coupling: Facile Synthesis of Hydrazides and Pyrazole
Oxidative Addition of Aryl Bromides at Palladium(I) to form Palladium(III) Complexes
Transsulfurase‐Catalyzed Reversible Modification of C‐Terminal Cysteine and Application for Orthogonal Dual Labeling of Proteins
Degradable Polyketone Thermoplastic Elastomers with Biomass Sourced Composition
In Situ Cation-Switched Organometallic Cage Reconfiguration Enables Highly Selective Li+ Recognition and Extraction
Monomer‐Dependent Selectivity in Sulfur‐Containing Ring‐Opening Copolymerisation: Bimetallic Catalysis for Predictive Design of Degradable Polymers
A Self‐Assembled Protein Platform for Plug‐and‐Play Customization of Multivalent Artificial Antibodies and Antibody‐Drug Conjugates
Construction of Fused–Bridged Tricycles by Molecular Reorganization Involving Prins Cyclization/Dicycloexpansion
Acetone Derivatives for Nickel-Catalyzed Methylation, Trideuteromethylation, and 13C-Methylation of (Hetero)Aryl Chlorides
Efficient Red Light–Driven Singlet Oxygen Photocatalysis with an Osmium‐Based Coulombic Dyad
Selection of Ribofuranose‐Isomer Among Pentoses by Phosphorylation with Diamidophosphate
Twelvefold Dearomative Esterification of (6,6)Carbon Nanobelt
Bicyclic Selenenyl Sulfides with Tuned Bioreductive Step Rates Reveal Constraints for Probes Targeting Thioredoxin Reductase
A Bifunctional Organic Photocatalyst for Efficient Single‐Electron and Energy Transfer Activation
Regio‐, Diastereo‐, and Enantioselective Hydrosilylation of Alkyl igem/i‐Difluoroalkenes to Construct Carbon and Silicon Stereogenic Centers
Total Synthesis and Structural Revision of (−)‐Sodagnitin E
A Phenomenological Symmetry Rule for Chemical Reactivity Under Vibrational Strong Coupling
From Corrosion to Creation: Interfacial De‐Electronation Drives Hydrogenation‐Energy Symbiosis
Intermolecular Spsup3/supC─H Metalation of Non‐Nucleophilic Brønsted Bases Using Simple Lewis Acids
Nickel‐Catalyzed Sila‐Cycloaddition of Dichlorodisilanes: Selective Si─Cl Activation for Cyclic Disilanes and Enantioenriched Synthesis
A Bioinspired Diazafluorenone Catalytic System for Aerobic Oxidative Deamination of Primary Amines
Mechanochemical Degradation of Polystyrene Into Benzene for Recycling and Upcycling
Carbon Dioxide Capture and Functionalization from a Molecular Ti(III) Oxo Anion
Multipoint Coordinative Capture of Olefinic Substrates Utilizing Metal‐Carbon Bonds by Macrocyclic Complex
Chiral Cryptographic Key‐Based Fluorescence Encryption Enabled by Stimuli‐Responsive Metal–Organic Frameworks
A Modular Three‐Component Asymmetric Tsuji–Trost Reaction Enabled by Cooperative Palladium/Lewis Acid Catalysis
Asymmetric Radical Coupling to Form βsup2,2,3/sup‐Amino Acid Esters by Synergistic Chiral Phosphoric Acid and Photocatalysis
Corral[in/i]Bicarbazoles: Redox‐Active Chiral Macrocycles for Air‐Stable Radical Cations Formation and Guest Capture/Release
Enantioselective Synthesis of Chiral Azepines: A Cascade Strategy Featuring 1‐Aza‐Cope Rearrangement
Stereoselective Synthesis of Glycomimetics by Photocatalytic One-Pot C(sp3)─H Acylation and Ring Contraction
Asymmetric Catalytic 1,2‐Azaarene Migration to α‐Azaaryl‐α‐Hydroxy Esters Enabled by a Tailored Ligand
Dual‐Site Modulation of Mgsup2+/sup Desolvation Beyond the Primary Solvation Shell in Magnesium Battery Electrolytes
Hydrophilic Iridium Bis‐iN/i‐Heterocyclic Carbene Complexes Catalyze Linear‐Selective, Additive‐Free Hydroaminomethylation of Long‐Chain Olefins in Water
iN,O/i‐Alternant Belt[3]arene Utilized for Construction of Multi‐Color Supramolecular TADF Materials and Highly Selective Detection of 2‐Cyanopyrazine
Stopping the Chain: Isolated Molecular Intermediates of Anionic Styrene Polymerization
SuFEx‐Enabled Polypeptide: Creating Diversified Properties with Minimal Preset Conditions
Indeno[2,1‐ic/i]fluorene Quasi[8]circulenes Through Intramolecular Cyclization
SmIsub2/sub‐Catalyzed Coupling of Alkyl Housane Ketones and Alkenes in an Approach to Norbornanes
Iron‐Catalyzed itrans/i‐Hydrostannation of Terminal Alkynes
Photocatalytic Synthesis of Unprotected Sulfonimidamides and Their Application in Photochemical Nitrene Transfer Reactions
Radical Ring‐Opening Reaction of Non‐Activated Oximes Catalyzed by Aldoxime Dehydratases
Preparation of Degradable Polymers Containing Tunable Ratios of Dithioacetals and Disulfides via Mixed Mode Polymerization
Low Symmetry Cage Complexes Formed by Metalation of Symmetric Hexa‐Cationic Organic Cages
Visible-Light-Driven Iron-Catalyzed Atom Transfer Radical Addition of CH2Br2 to Alkenes: Facile Access to 1,3-Dibromo Compounds
Direct Asymmetric α‐C Addition of Glycinate to Nitroalkenes by Pyridoxal/Nd Dual Catalysis
Counterintuitive Photochemistry of an Isolated Acridinyl Radical: ConPET via Preassembly, Solvated Electrons or a Long‐Lived Excited State?
Sustainable Closed‐Loop Recycling of Polyester Waste Using Reconstructed Defective‐Metal–Organic Frameworks
Regiodivergent Photocatalytic Annulation for the Synthesis of igem/i‐Difluorinated Cyclic Hydrocarbons
Tunable Endo/Exo Selectivity in Direct Catalytic Asymmetric 1,3-Dipolar Cycloadditions with Polyfunctional Lewis Acid / Azolium–Aryloxide Catalysts
Regioselective C─H Functionalization by the Combination of Enzymatic and Chemocatalytic Reactions in Water
Multicomponent Assembly of High‐Component Covalent Organic Cages
Reversing Blocking Order of Trithiocarbonate‐Mediated RAFT Polymerizations Using Photocatalysis
Overcoming Challenges in Small‐Ring Transfer: Direct Decarboxylative Hydroalkylation of Alkenes via Iron‐Thiol Catalysis
Enantioselective Rhodium‐Catalyzed Cycloisomerization of 1,5‐Bis(allenes) to Access 1,2‐icis/i‐Ethynyl‐ and Vinyl‐Substituted Five‐Membered (Hetero)Cycles
Introducing Steric Bulk Into Silylboranes: Enhanced Bench Stability and Novel Chemical Reactivity
Length Ratio-Driven Configurational Modulation of Heteroleptic Pd6L6L’6 Cages
Photoredox‐Catalyzed Radical Relay for C─N Cleavage and Ring Expansion: Accessing Medium‐Sized Lactams From Unstrained Cyclic Amines
A Streamlined Approach to Indoles, Pyrroles, and Benzimidazoles via Redox-Neutral Aromatization and CO Reduction Mediated by Cs2CO3
Continuous Flow Electrochemistry Unlocks Broadly Applicable Arene C─H Amination
Enhancing the Self‐Assembly of Step‐Growth Polymers by Narrowing Their Molar Mass Distribution: A Dynamic Bond‐Mediated Approach
Postassembly Modification of Interior Spaces Within Msub12/subLsub24/sub Nanospheres
Light-Induced Radical C(sp2)−H Trifluorovinylation of (Hetero)arenes with a Trifluorovinyl Iodine(III) Reagent (TrFVI)
Efficient Glycine Electrosynthesis via CO2-Recyclable Hydrogen Donation on Pb/Pb7Bi3 Heterointerfaces
Node Flexibility Unlocks Structural Adaptability and Guest Versatility of Anionocages
Wacker Oxidation of Trisubstituted Alkenes: Pd(II)‐Catalyzed Oxidative Ring Expansion of Exocyclic iα,β/i‐Unsaturated Carbonyl to 2‐Fluoro‐1,3‐Dicarbonyl Compounds
Mechanoactivated Celite as a Catalyst for C‒H Bond Perfluoroalkylation and Other Radical Reactions
Formal Cyclopropylation of Imines with Cyclopropanols: Stereocontrolled Access to Conformationally Constrained γ‐Amino Alcohols
Electrochemical Deoxygenative Silylation of Alcohols
Social Chiral Self‐Sorting Synthesis of [9]Cycloparaphenylene‐Pillar[5]arene Heterochiral Multicavity Macrocyclic Trimers with Circularly Polarized Luminescence
Metallaphotoredox-Catalyzed Cross-Electrophile Couplings of Aryl Chlorides and Alkyl Halides: Harnessing the σ-Donor/π-Acceptor Synergy of a 2-(1H-Imidazol-2-yl) pyridine Ligand
An Atomically Dispersed Photocatalyst for Undirected para-Selective C─H Bond Functionalizations
Combined Inductive and Dispersion Effects Enhance Bioorthogonal Reactivity of Tetrazines Toward Isonitriles
Flexibility-Aided Orientational Self-Sorting and Transformations of Bioactive Homochiral Cuboctahedron Pd12L16
Unveiling an Alternative Mechanism for Lewis Basic Selenium as a C─H Hydrogen Bond Catalyst and Its Application in the Halogenation of Arenes
Methylthiohexa‐1,3‐Diene: Anionic Polymerization of a Diene with Thioether Moiety Enables Post‐Polymerization Modification and Antimicrobial Materials
Biocatalytic Olefin Difunctionalization for Synthesis of Chiral 2‐Azidoamines Using Nonheme Iron Enzymes
Molecular Insights into the Formation and Functionalization of Carbon Nanodots: From Precursor Intermediates to Surface Chemistry Quantification
Deep Eutectic Solvent Binder Facilitating Reaction Kinetics of Lithium Sulfur Batteries
Catalytic 1,2‐Migratory Insertion in a Bismuth Redox Platform: Reductive Arylation of Aldehydes
Crown Ether–Peptide Rotaxanes
Ruthenium‐Catalyzed Cycloaddition of Azides and Selenoalkynes with Built‐in “Catch‐and‐Release” Functionality
Exo-Selective Intramolecular (4+3) Cycloadditions to Trans-Fused Perhydroazulenes: An Asymmetric Formal Synthesis of (−)-Pseudolaric Acid B
Central Dynamic Conversion of Dicyanomethyl Radicals via Intermolecular Charge Transfer for Ultrabright NIR‐II Fluorescence Imaging‐Guided Mild Photothermal Therapy
Electrochemical Upgrading Plastic to Organosulfurs Through Fe-N3 Single Atom Catalyst Under Ambient Conditions
Metastable Macrocyclic Bis‐Meisenheimer Adduct
Design of Carbon–Carbon Ylides
Adjustable Upcycling of Polyethylene Terephthalate to Biodegradable Polymer Monomers by Mn‐Catalyzed Solvent Switching Strategy
Chemoenzymatic Skeletal Editing of Natural Product Scaffolds via P450‐Controlled Site‐Selective Ring Expansion at Aliphatic C─H Sites
Carbene Insertion and Furyl Migration Cascade Toward Benzofurans
Radical Borylation of Alkyl Bromides by Photoinduced Halogen‐Atom Transfer
Electrolyte‐Controlled Regiodivergent Continuous Flow Electroselenocyclisations
Intramolecular Lithiation‐Borylation for the Stereoselective Synthesis of Cyclopentyl and Cyclobutyl Bis‐Boronic Esters
Ligand-Controlled Stereodivergent Manganese-Catalyzed Hydroalkoxylation of Alkynylnitriles to Access (E)- and (Z)-3-Alkoxyvinylnitriles
Semiconductor Cluster with High Reduction Potential and Efficient Charge Transfer Enables Visible‐Light‐Driven Activation of Inert Organic Substrates
Ligand‐to‐Metal Charge Transfer of Ag(II) CFsub2/subX Carboxylates: Quantum Yield and Electrophotocatalytic Arene Fluoroalkylation Tuned by X
Ligand-Controlled Chromium Catalysis for Tunable Z/E Selectivity in Asymmetric Homoallylic Alcohol Synthesis
An Electrochemical Study of Key Catalytically Active Gold Complexes
Titanium‐Catalyzed C─X and C─H Borylation of Aryl Halides for the Synthesis of Bis(boronate)benzenes
Selective Aerobic Oxidation of Toluene to Benzaldehyde by Parallel Photoinduced Proton‐Coupled Electron Transfer and Energy Transfer Through Multiphoton Excitation
Is Phenylnitrene a Missing Link in the Formation of Polycyclic Aromatic Nitrogen Heterocycles?
Unlocking a Ferrocenium Superoxidizer with the Perfluorinated Cp* Ligand
Identification of Ti(salen) Complexes for Efficient Catalysis in Single‐Electron Steps by Cyclic Voltammetry
Reactivity of Pnictaalumenes Towards 1,3‐Dipole Molecules
Rhodium‐Catalyzed 1,5‐Sigma Migratory Ring Expansion of igem/i‐Difluorodienyl Cyclopropanes and Cyclobutanes
Substrate Preorganization Within Photoactive Ptsub12/subLsub24/sub Nanospheres for Accelerated Decarboxylation Catalysis at Low Concentrations
Splicing Them Together: Construction of Polyoxovanadate–Organic Polyhedra‐Based Pyrgoscages and Catenanes
The Role of Reducibility of PtGaOisubx/sub/i‐Based Catalysts for Efficient and Durable Propane Dehydrogenation
A Monolithium Monohydrogen Porphyrin
Metal‐Free Electrochemistry‐Driven Decarboxylative Primary Alkyl‐Alkoxylation of Olefins
Hetero‐Selective Cross‐Linking of Primary and Secondary Alkyl Amines with CSsub2/sub Under Ambient Aerobic Oxidation for Bioconjugation
Multiply Substituted (Hetero)acenes Containing Phosphonate Group at the Central Unit as High‐Efficiency Light Emitters
Isothiourea‐Catalysed Acylative Kinetic and Dynamic Kinetic Resolution of Planar Chiral Paracyclophanols
A Shelf‐Stable Reagent for Photocatalytic Radical Pentafluorosulfanylation of Styrene Derivatives
Methanol‐Facilitated Cascaded Polyolefin Upcycling Enabling the Efficient Generation of High‐Value Csub9+/sub Alkylaromatics
Synthesis of Chroman Derivatives by Group Transposition and Atom Swapping in 1‐Tetralones: Single‐Atom Editing Enabled by Oxidative Ring Contraction of Benzoxepine Silyl Ketene Acetals
Lignin Dissolution and Direct Ultrasmall‐Lignin‐Nanoparticle Formation in Acidic and Alkaline Deep Eutectic Solvents: A Molecular‐Level Insight
Organocatalyzed Copolymerization of CO, Se, and Oxetane: O/Se Exchange Reaction Determining Chain Structure
HFIP-Promoted E-selective Asymmetric Crotylboration of Quaternary α-Silyl Crotylboronate with Aldehydes
Enantioselective Divergent Total Syntheses of Cycloaurenones and Dysiherbols
Enantioconvergent Synthesis of α‐Fluoroalkyl Alcohols Enabled by Photocatalytic Radical Brook Rearrangement
Organocatalytic Asymmetric Cycloaddition for the Construction of Chiral Indole‐Fused Medium‐ and Large‐Sized Rings
Blocky Selective Postpolymerization C–H Functionalization of Polyolefins
Breaking Symmetry of Active Sites in Metal‐Organic Frameworks for Efficient Photocatalytic Valorization of Polyester Plastics
Deconstructive Functionalization of Cyclic Ketones via Electrochemical Interrupted Dowd–Beckwith Reaction
Dynamic Hydrogen Bonding Tuned Enantioselectivity Control in Cobaloxime‐Chiral Amine Cooperative Catalysis
Enantioselective Total Synthesis of (–)‐Psiguadial A
Atomic Cu–O–Zr Sites for Highly Selective Production of p-xylene from Tandem Upcycling of PET and CO2
Shaping of a Reactive Manganese Catalyst Enables Access to Polyfunctionalized Cyclohexanes via Enantioselective C(sp3)─H Bond Oxidation of 1,3-meso Diethers
Rapid Access to an Enantioenriched Spiro Bisindole Directly from Indole and Acetone
Nonconjugated Structural Distortion Promoting the Formation of NIR Triplet States in Phenothiazine Dyes for Cancer Photoimmunotherapy
Palladium‐Catalyzed Alkyl Amination of Olefins via Radical‐Polar Crossover at Room Temperature
Liquid Coordination Polymers with Anhydrous Proton Conductivity
A Visible-Light-Driven O-Glycosylation with Selenoglycosides Mediated by Chalcogen Bonding to Umemoto's Reagent
Intracellular Polymerization Induced Self‐Assembly and Gold Nanocomposite Synthesis in Living Bacteria
Charge Relocation Enables a Modular and Diastereoselective Synthesis of icis/i‐Substituted Tetrahydrofurans
Crystallization/Precipitation Driven Nonequilibrium Ring‐Opening Polymerization of Thiovalerolactone Toward Closed‐Loop Recyclable Polythioester with Excellent Barrier Properties
Lewis Acidity of the SbClsub3/sub/io/i‐chloranil System
Nickel‐Catalyzed Cross‐Electrophile Coupling to Access Polysubstituted Cyclobutenes
iZ/i‐Selective Alkyne Semireduction by an Organic Photoreductant
N‐Insertion of Diazonium Salts Into Ketone Derivatives
Asymmetric Aziridination of Allylic Carbamates Using Ion‐Paired Rhodium Complexes and Extrapolation to C─H Amination of Phenethyl Carbamates
Modular Access to Fluorinated Quaternary Stereocenters via Palladium/Lewis Base Synergistic Catalysis
Fluoride Enhances Alcohol Binding Within a Trigonal‐Prismatic Metal‐Organic Capsule
Divergent Construction of Cyclobutane‐Fused Pentacyclic Scaffolds via Double Dearomative Photocycloaddition
Identifying the Role of Solvation Entropy for the Solvation Chemistry in Nonaqueous Electrolytes
Decavanadate‐Catalyzed Oxidative Cross‐Dehydrogenative Coupling: an Efficient and Sustainable Approach toward P(O)─S Bond Formation
Insight into Lysine Selection via Controlled Degradation of 2,4‐Diaminobutyric Acid and Ornithine Polypeptides
Total Synthesis of Isodaphlongamine H by Iridium‐Catalyzed Reductive [3 + 2] Cycloaddition of iN‐/iHydroxylactam
Organophotoredox‐Catalyzed Postfunctionalization of Poly(methacrylate) Derivatives via Radical–Polar Crossover Phosphonylation
Photocatalytic Boron Insertion into Thiaarenes via Boryl Radicals
Asymmetric Intramolecular α‐Arylation of Polar Amino Acids Bearing β‐Leaving Groups
Hyperbranched Polymer‐Based Multipath Proton Transmembrane Transport System with Redox‐Switchable Characteristics for Cancer Cell Apoptosis
Transient Supramolecular Polymers by pH‐Gated Conformational Control of a Self‐Assembling Cyclodextrin
Biomimetic Hydrogen‐Bonded Base Pairing of Nucleoside Triphosphates in Water by a Tetraphenylethene‐Based Octaimidazolium Cage
Electrochemical Benzylic C─H Sulfation beyond the iO/i‐Sulfonation Limitation
From Amino Acids to α‐Keto Acids via β‐Elimination and Transamination Initiates a Pathway to Prebiotic Reaction Networks
Preparation of Cyclic Olefin Polymers via Group Transfer Radical Cyclopolymerization for High Performance in Anode‐Free Batteries
Stereocontrol in Conformationally Stable C(sp2)─C(sp3) Atropisomers
On‐Demand Ligate and Release Strategy Based on Photoclick Reaction in Tandem with Pd‐Mediated Deallylation
Tri‐Coordinated Boron Species in Confined Boron Oxide Catalysts for Enhanced Low‐Temperature Oxidative Dehydrogenation of Propane
Chiral Spirobipyridine Synthesis by Cobalt‐Catalyzed Enantioselective Double [2 + 2 + 2] Cycloaddition
Cost‐Effective and Low‐Carbon Scalable Recycling of Waste Polyethylene Terephthalate Through Bio‐Based Guaiacol‐Enhanced Methanolysis
Enantioselective Palladium‐Catalyzed α‐Arylation of Acyclic Esters
Rhodium/Indium Heterobimetallic Alloy as an Effective Catalyst for Reductive C(spsup3/sup)─O Silylation of Ethers with Chlorosilanes
Access to iN/i‐Monofluoromethylated (Thio)Carbamates, Formamides, Alkynamides, and Related Derivatives
Iridium‐Catalyzed Asymmetric β‐Selective Hydroamination of Enamides for the Synthesis of 1,2‐Diamines
Phenacetin[3]Arenes: Mannich‐Type Macrocyclization, Unique Structure, Versatile Functionalization, and Strong Allosteric Binding
Modular Access to Arylethylamines Enabled by Ni‐Catalyzed iMarkovnikov/i‐Selective Hydroarylation of Allylic Amines
Hierarchically Self‐Assembled Anion‐Coordination‐Driven Gels for Guest Segregation and Electrical Sensing
Ternary Aldehyde–Copper–Iridium Catalysis Enables Stereodivergent Allylation via α‐C‐H Functionalization of Primary Amines
Revealing the Nature of Non‐Covalent Interactions in Ionic Liquids by Combined Pulse EPR and sup19/supF NMR Spectroscopy
Modulation of Photoluminescence of BODIHY Dye Using Water‐Soluble Coordination Cages With Different Shapes
Enantioselective Divergent Cyclization of Amide‐Type 1,6‐Enynes Enabled by H–[Pd]–CN Catalysis
Iron‐Catalyzed Radical Allylic Substitution of Unprotected Allylic Alcohols
On‐Surface Synthesis of Nanographenes Through Domino Cyclization Reactions
Valence Tautomerism and Alkaline Properties of Global Aromatic Imine‐ and Methine‐Bridged all‐Benzenoid Macrocyclic Superpyrazine and Supertriazine
Dinitrogen Activation with Low‐Valent Strontium
Xanthopinacol Boronate: A Robust, Photochemically Assembled and Cleavable Boronic Ester for Orthogonal Chemistry
Nitrate Reduction for Deaminative Suzuki–Miyaura Coupling of Anilines
Streamlining SuFEx Inhibitor Development: A Unified Approach Using Photolabile and Orthogonal Sulfinate Protecting Groups
Generation, Capture, Storage, and Release of Singlet Oxygen from a Perylene Diimide‐Based Metallacage for Oxygen Sensing
icloso/i‐Carboranyl Analogs of β‐Arylethylamines: Direct Synthesis from Alkenes via EnT‐Catalysis
Direct Synthesis of Poly(adipate)Esters via Catalytic Isomerizing Dual Hydroesterificative Polymerization of 1,3‐Butadiene
Electrochemically Promoted Activation of Light Alkanes at Ambient Conditions
Clsub3/subAl‐PHsub3/sub Is a Weak Lewis Pair Allowing the Synthesis of Sterically Highly Hindered Primary and Secondary Alkyl Phosphanes
Design, Synthesis, and Application of a Family of Chiral Non-C2-Symmetric NHCs with a Fused Sidechain
Biomass‐Derived Functional Polyacetals via Controlled Cascade Enyne Metathesis Polymerization: Tunable Degradability, Postpolymerization Modification, and Self‐Assembly
Phosphorescent Iridium(III) Phenanthrolinedione Complexes as Lifetime‐Responsive Bioorthogonal Probes for Wash‐Free Time‐Resolved Bioimaging of Cellular Labeling
Control over S(VI)‐Stereogenic Center: NHC‐Catalyzed Enantioselective Synthesis of iN/i‐Acyl Cyclic Sulfonimidamides
Metal-Controlled Enantiodivergent Tandem Rearrangement to Synthesize 2H-Azirines
Natural Sunlight‐Driven Activation of Inert Aryl Halides Using Plasmonic Cu@CdS with Polysulfide Active Sites
Hyperpolarization Modulation of the T‐Type hCasubv/sub3.2 Channel by Human Synenkephalin [1–53], a Shrew Neurotoxin Analogue without Paralytic Effects
Palladium‐Catalyzed Enantioselective Arylative Dearomatization of Naphthols and Phenols for Constructing Quinazoline‐Containing Spirocycles
Introducing Photochemical Action Plots as a Tool for Unlocking On–Off Switchable Behavior in a Polymeric Eosin Y Photocatalyst
Unsaturated Phosphine Oxides for Modular Antibody Rebridging and Single Reagent Peptide‐Cyclisation‐Bioconjugation
Automated Iterative N─C and C─C Bond Formation
Polyolefin‐based Multiblock Copolymers from Cascade ROMP‐RAFT Polymerization
Peptide‐Carbazolyl Cyanobenzene Conjugates: Enabling Biomolecule Functionalization via Photoredox and Energy Transfer Catalysis
Electrocatalytic C─S Cross‐Coupling via Engineered Frustrated Lewis Acid‐Base Pairs for High‐Efficiency Methanesulfonate Synthesis
Ligand‐Controlled Chemoselectivity in the Rhodium‐Catalyzed Synthesis of Pentafulvenes via (2 + 2 + 1) Alkyne Cyclotrimerization
Modular Access to P(V)‐Stereogenic Compounds via Cu‐Catalyzed Desymmetrization of (Thio)Phosphonic Dichlorides
Visible Light‐Driven Deracemization of Cyclic Sulfonamides by Quinuclidine and Chiral Arylthiol Catalysis
An Atomically Precise Copper Cluster Nanoreactor for Efficient Catalysis in Chemical Fixation of Low‐Concentration COsub2/sub
Regioreversed Carbosulfenylation of Fluoroalkenes via Nickel‐Mediated Radical Sorting
Chiral Self‐Sorting of Flexible Covalent Organic Pillars for Adaptive Molecular Recognition
Synthesis of a Linear Tetraboron Cation via Deprotonation of a Nonsupported Dimeric Hydroborylborenium Ion
Proteome‐Wide Ligand and Target Discovery by Using iβ/i‐Nitrostyrene Electrophiles: Supporting Targeted Protein Degradation
Development of a Vinylated Cyclic Allene: A Fleeting Strained Diene for the Diels–Alder Reaction
Linking Metallacycle Transfer with Ring‐Opening Metathesis to Generate Polyacetylenes of Unprecedented Structure
Merging Photocatalysis with Chiral Lewis Acid Catalysis for Enantioselective Hydrosilylation/Hydrogermylation of Electron‐Deficient Alkenes
Divergent Asymmetric Synthesis of Bonnadiene and ient/i‐Polytrichastrene B
A Polyaromatic Metallotube With a Dual Multi‐Functionalization Ability
Advancing Sulfinyl Radical Chemistry: An Asymmetric Smiles Rearrangement with Chiral Sulfoxides
Strain‐Induced Benzannulation of Oxaquadricyclanes Promoted by a Polyoxometalate Photocatalyst
Highly Efficient Suzuki–Miyaura Polymerization Enabled by Direct Transmetalation with Boronic Esters
Modular Synchronous Synthesis of Amides and α‐Ketoamides Realized by Matching Electrolysis‐Paired Tandems
The Mechanism of Ruthenium‐Catalyzed Directed C─H Arylation of Arenes: The Key Role of Bis‐Cyclometalated Intermediates
Catalytic Enantioselective α‐Ethynylation of Oxindoles: Total Synthesis of (‐)‐Corynoxine, (‐)‐Isorhynchophylline, (‐)‐Aspidospermidine, and (‐)‐Limaspermidine
A General Strategy for Enhanced Single‐Molecule Imaging Through Intramolecular Energy Transfer
Desulfurizative Fluorination of iN/i‐CFsub3/sub Thioformamides for the Efficient Synthesis of iN/i(CFsub3/sub)(CFsub2/subH) Amines with Enhanced Stability
Nitrogen‐Centered Organic Persistent Radicals Catalyze Redox‐Neutral C─C Bond Forming Reactions
Ruthenium Catalyzed Ortho-Arylation Reaction of Benzoic Acids with Arylthianthrenium Salts
Manganese‐Catalyzed Enantioselective Dearomative Epoxidation of Naphthalenes with Aqueous Hydrogen Peroxide
Concise Enantioselective Total Syntheses of Rearranged ient/i‐Trachylobane Diterpenoids (–)‐Wallichanols A and B
Probing the Catalytic Degradation of Unsaturated Polyolefin Materials via Fe‐Based Lewis Acids‐Initiated Carbonyl–Olefin Metathesis
Modulating Electron Transfer via Cerium Photocatalysis for Alkoxy Radical‐Mediated Selective Hydroetherification
Catalytic Enantioselective Reductive Arylation and Alkenylation of Sulfinylamines to Access Sulfinamides Enabled by Cobalt Catalysis
Copper‐Catalyzed Asymmetric Cyanation of Propargylic Radicals Derived From Silyl‐Substituted Allenes and Alkynes
Iron(III)‐Catalyzed C─H Hydroxylation of Low‐Density Polyethylene Coupled with Short Chain Branching Growth
Enantioselective Abiotic Synthesis of Ribose on Chiral Mesostructured Hydroxyapatite
Absolute Asymmetric Synthesis of a Homochiral Polymer from an Achiral Monomer
Synergistic Mechanism for Unconventional Anodic Reaction of Aldehyde Oxidation for Hydrogen Production
β‐Quaternary α‐Amino Acids via Iridium‐Catalyzed Branched and Enantioselective Hydroalkylation of 1,1‐Disubstituted Styrenes
Bio‐Sourced 4‐Aryl‐1,2‐Dithiolanes for Recyclable Poly(disulfide)s with High Performance
Constructions of Biaryl‐Bridged Macrocycles Through Phosphine‐Ligand‐Controlled Switch of Selectivity Between Intra‐ and Intermolecular Cyclizations
Enantiomerically Enriched Aziridine‐2‐carboxylates via Copper‐Catalyzed Reductive Kinetic Resolution of 2iH/i‐Azirines
Metal Synergistic Dual Activation Enables Efficient Transesterification by Multinuclear Titanium Catalyst: Recycling and Upcycling of Polyester Waste
Mixing and Matching of Hybrid Megasynthases is a Hub for the Evolution of Metabolic Diversity in Cyanobacteria
Divergent Upcycling of Polystyrene into Phenol and Hydroquinone Derivatives by Photocatalysis and Electrocatalysis
Unnatural Triggers Converted From Tetrazine‐Attached Sialic Acid for Activation of Optoacoustic Imaging‐Guided Cancer Theranostics
Adaptive Defluoroamination of Aryl Fluorides: Harnessing the Catalytic Potential of a Unique Zinc Amide Compound
Ribozyme‐Catalyzed Site‐Specific Labeling of RNA Using iO/isup6/sup‐alkylguanine SNAP‐Tag Substrates
Catalytic α‐Site‐Selective Hydrogen‐Deuterium Exchange of Benzylic Alcohols by Palladium Single‐Atom Catalyst
Selective Functionalization of Benzene Ring via Carbene‐Initiated [4,5]‐Rearrangement
Internally BN‐Doped Coronene
A Nitrogen‐Containing Graphenic Buckybowl for Photocatalysis and Assembly With Fullerenes
Copper‐Catalyzed Radical Enantioconvergent C─O Bond Formation for Asymmetric Cross‐Coupling of Allylamines and COsub2/sub
Reduction‐Induced C─C Cleavage and Site‐Specific Hydrogenation of a Highly Strained Bilayer Spironanographene
Catalytic Activation of Acceptor–Acceptor Bicyclobutanes Enabled by Lewis Base Catalysis
Efficient Electro-Oxidation of Ethylene to 2-Chloroethanol on SnO2 Through Dual-Adsorbate Pathway
Rapid Methylation of Aryl Bromides Using Air‐Stable DABCO‐Bis(Trimethylaluminum) via Nickel Metallaphotoredox Catalysis
Redox‐Switchable Poly‐Lewis Acids Allow the Controlled Release of Guests
Direct Activation of Sulfides by C–H Oxidation with Photoexcited Nitroarenes: Formal Manipulations of the C─S Bond
Electrochemical Enantioselective Oxidation of Indoles via Chiral Phosphoric Acid Catalysis in Cooperation with H3PO4 in Aqueous Media
Enantioconvergent Cobalt‐Catalyzed Hydroalkylation for the Construction of Fluoro, Chloro, and Trifluoromethyl Stereogenic Centers
Self‐Assembly of a Customizable Library of Nickel Trifluoromethylation Catalysts via Selective C─F and C─O Bond Cleavage
Mixed‐Metal Ce‐Zr‐Mn Clusters as Photo‐Catalysts for Decarboxylative Functionalization of Carboxylic Acids
Redox-Driven In Situ Formation of Bimetallic Catalysts via Sn2+/Sn4+ Interconversion
Synthesis of Porous Carbon‐Based Network Containing Ultranarrow Nonplanar Nanopores on Surfaces
Chlorine Radical‐Mediated Photocatalytic C─C Coupling of Methanol to Ethylene Glycol with Near‐Unity Selectivity
Remote Silyl Groups Enhance Hydrolytic Stability and Photocleavage Efficiency in Carbamates for Protein Release
α-Amination of 1,3-Dicarbonyl Compounds and Analogous Reactive Enolate-Precursors Using Ammonia under Oxidative Conditions
Visible‐Light‐Driven Photocatalytic Methanol Activation on Hexagonal CdS for Triggering C─H Methylation
Catalytically Active Coacervates Sustained Out‐of‐Equilibrium
An Enzymatic Platform for Asymmetric Synthesis of Si-Stereogenic Silanols
Excited‐State Basicity Diverts the Site‐Selectivity of Aromatic Deuteration: Application to the Late‐Stage Labeling of Pharmaceuticals
Indole‐Quinoline Transmutation Enabled by a Formal Rhodium Carbynoid
Core‐Shell Hyperbranched Polymers via Catalytic Ring‐Opening Metathesis Polymerization
Total Synthesis of Dactyloquinone A and Spiroetherone A via a Metal‐Hydride Hydrogen Atom Transfer (MHAT) Process and a Quinol–Enedione Rearrangement
Photoelectrochemical Iron(III) Catalysis for Late‐Stage C─H Fluoroalkylations
Iron‐Catalyzed Reductive Allylic C─H Amination of Olefin with Nitroarenes via Intermolecular Nitroso Ene Reaction
Reactive Cysteines in Proteins are the Dominant Reductants for Platinum(IV) Prodrug Activation in Live Cells
A Cobotic, Digitally Controlled Schlenk‐line Unlocks Access to Elusive Lewis‐Base Stabilised Copper Bis(Disilylamides)
Sustainable and Simple Water‐Induced Separation of Ionic Liquid Mixtures
Facile Synthesis of Polyorganosiloxanes via Photo‐Induced Anionic Ring‐Opening Polymerization Using a Latent Catalyst
Engineering of Transmembrane Alkane Monooxygenases to Improve a Key Reaction Step in the Synthesis of Polymer Precursor Tulipalin A
Synthesis of Versatile DNA‐Conjugated Aldehydes by Controlled Oxidation of Amines
Scalable and Practical Electrooxidation of Electron‐Deficient Methylarenes to Access Aromatic Aldehydes
Diastereoselective Synthesis of Cyclopropyl Diboronates via 1,2‐Boronate Rearrangement
Visible Light‐Driven Benzaldoxime Synthesis by Glutathione‐Modified CdS Quantum Dots
Ionized Water Facilitates the Sustainable Radical-Mediated Reduction of CO2 to Multi-Carbon Hydrocarbons and Oxygenates
Oxidative Rearrangements of the Alkaloid Intermediate Geissoschizine
Rhodium‐Catalyzed Atroposelective Synthesis of Axially Chiral 1‐Aryl Isoquinolines via De Novo Isoquinoline Formation
Acyclic Quaternary Stereocenters via Catalytic Asymmetric Cross‐Couplings with Unactivated Alkyl iN/i‐Hydroxyphthalimide Esters
Site‐Selective Carbonylation of Azetidines via Copper‐Catalyzed Difluorocarbene Insertion
Nickel‐Catalyzed Umpolung Difluoroalkylation of Imines Enables General Access to β‐Difluoroalkylated Amines
Synthesis and Characterization of Circumtetracene: Unraveling Structure‐Property Relationships of Circumacenes
Cobalt-Metalated 1D Perylene Diimide Carbon-Organic Framework for Enhanced Photocatalytic α-C(sp3)─H Activation and CO2 Reduction
Cobalt-Catalyzed Enantioselective Hydrotrifluoromethoxylation of Aromatic Alkenes
Nitrogen Insertion via Asymmetric Condensation and Chirality Transfer: A Stereodivergent Entry to Cyanocyclopropanes
Redox‐Controlled, Sequential Self‐Sorting of Supramolecular Assemblies in Model Protocells
Octalenobisterphenylene and Its Diradical Dianionic Cyclodimer: Synthesis, Structural Analysis, and Properties
Remote Spin-Center Shift Enables Activation of Distal Benzylic C─O and C─N Bonds
Electrochemical Amination of Aryl Halides with NH3
Late‐Stage Cross‐Electrophile Coupling of Arylthianthrenium Salts with (Hetero)aryl (Pseudo)halides via Palladium Catalysis
Development of an Automated Workflow for Screening the Assembly and Host–Guest Behavior of Metal‐Organic Cages Towards Accelerated Discovery
N-(Acyldithio)Saccharin: Design, Synthesis and Applications in Catalytic Enantioselective Disulfuration/Amination of Alkenes
Synthesis of Chiral δ‐Aminoboronic Esters by Enantioselective Hydrogenation of 1,2‐Azaborines
Effect of Alternating Polarity in Electrochemical Olefin Hydrocarboxylation
Ligand‐Controlled Regiodivergent Carbosilylation of 1,3‐Dienes via Nickel‐Catalyzed Three‐Component Coupling Reactions
Thio-Tetracosulene: A Highly Twisted Molecular Plectoneme
An Immobilized Rh‐based Solid Molecular Catalyst for the Reductive Hydroformylation of 1‐Octene
Hydrogenation of “Readily Activated Molecule” for Glycine Electrosynthesis
Asymmetric Synthesis of Noradamantane Scaffolds via Diphenylprolinol Silyl Ether‐Mediated Domino Michael/Epimerization/Michael (or Aldol)/1,2‐Addition Reactions
Routes to Pt Derivatives of High‐Valent Sulfur Oxofluorides S(═O)sub2/subF, S(═O)Fsub2/sub, and S(═O)Fsub3/sub by Fluorination and Oxygenation
Regiospecific 2,3‐Dialkylindole Synthesis Enabled by Alkylpalladium 1,2‐Migration to In Situ Formed Aldimine
Enantioselective Photochemical Generation of a Short‐Lived, Twisted Cycloheptenone Isomer: Catalytic Formation, Detection, and Consecutive Chemistry
Reaction of Nitrate Radicals and DMPO in Non‐Aqueous Media: A Novel Detection Tool to Highlight the Nitrate Radical Role in Photocatalytic Processes
Stereocontrolled Phenol‐Yne Click Polymerization Toward High‐Performance Bioplastics with Closed‐Loop Recyclability
Single‐Step Synthesis of a Heterometallic [Cusub2/subPdLsub4/sub]sup2+/sup Hybrid Metal–Organic Coordination Cage
Enantioselective Spirocyclization of Pd‐Enolates and Isocyanates
Prebiotic Interconversion of Pyruvate and Lactate over Zeolite‐Supported Ni Catalyst
Photocatalytic Generation of a Ground‐State Electron Donor Through Water Activation
Introducing the Aziridination of Fluorinated Olefins by Metal‐Catalyzed Nitrene Transfer
Controlling the Chirality of Metallo‐Cages by Manipulating the Stereochemistry of the Metal Centers
Interfacial Lithium Cations Catalyze Biomimetic Aerobic Oxygenation via Short‐Range Electrostatic Interaction
Bio-Inspired Self-Activating Polydimethylsiloxane-Modified CrOx/Al2O3 Catalyst for Acetylene Semihydrogenation
Environmental History is Transferred via Minerals Altering Formose Reaction Pathways
Mechanism‐Driven Bioactive Indazole Frameworks: Photoinitiated Demethylation–Aromatization Synthesis and Biosensing Applications
Programmable Mono-/Di-alkylation of Amines with Aldehydes Over a Pdδ−–H Electrocatalyst
Novel Light‐Promoted Bioorthogonal Reaction via Molecular Recombination for the Synthesis of Polysubstituted Pyrrole and Its Application in In Vitro and In Vivo Studies
Chalcogen-Bonding-Enabled, Light-Driven Decarboxylative Oxygenation of Amino Acid Derivatives and Short Peptides Using O2
Construction of Multistep Charge Transfer Pathways in Bi0@Bi3+-KNbO3 for Significantly Accelerated Photoconversion of Waste Plastics
Selective Recognition and Extraction of Short‐Chain Perfluoroalkyl Carboxylates by a Supramolecular Receptor
Catalytic Ring Expansion of Furyl Hydrosilanes: Synthesis of 1,2‐Oxasilines as Diels‐Alder Diene Components
Molecular Stiffening by Macrocycle Clustering
Online Coupling High‐Temperature Electrolysis with Carbonylation Reactions: A Powerful Method for Continuous Carbon Dioxide Utilization
Conversion of Bestmann Ylide into Carbophosphinocarbene
Cobaloxime‐Based Metalloradical Catalysis: A Versatile Strategy for the Synthesis of Cyclopropenes and Oxazoles
Low‐Temperature Depolymerization of Polymethacrylamides
Phosphorus‐Doped Single Atom Copper Catalyst as a Redox Mediator in the Cathodic Reduction of Quinazolinones
Total Synthesis of Lugdunomycin via Sequential Photoinduced Spiroketalization and Isobenzofuran Diels–Alder Reactions
Brønsted Acid‐Catalyzed Atroposelective Coupling of Carboxylic Acids with Amines and Alcohols via Ynamide Mediation
Atroposelective Construction of C─B Axial Chirality via N‐Heterocyclic Carbene‐Catalyzed Dynamic Kinetic Resolution
Enantioconvergent Deacylative Functionalization toward α‐Quaternary Nitriles
Direct Observation of Cyclo-Pentazolate Anion Decomposition in a Tailored Molecular Trap
Intervalence Charge Transfer and Exothermic and Isoenergetic Symmetry Breaking Charge Separation in Far‐Red Capturing Zinc Phthalocyanine Dimers
Metal‐Free Electrochemical C─H Chlorination of Terminal Alkanes
Alternating Binary Droplets‐Based Protocell Networks Driven by Heterogeneous Liquid–Liquid Phase Separation
Low‐Symmetry Face‐Capped Fe(II) Tetrahedra Through Anisotropic Ligand Extension
Versatile C─H Alkylation and Alkylidenation via Catalytic Alkylidene Transfer of Enones
Indirect Anti‐Markovnikov Hydrofunctionalization of Terminal Alkenes via an Alkenyl Thianthrenium Intermediate
Identification, Characterization, and Catalytic Mechanism of Regioselective UbiA Prenyltransferases in Morus Plants
Stable Cobalt–Zeolite Propane‐Dehydrogenation Catalysts Enabled by Reaction‐Driven Reconstruction
1,2‐Bis‐Triazenylarenes Enable Vicinal Sandmeyer‐Type Reactions
Unlocking Reactivity of Unprotected Oximes via Green‐Light‐Driven Dual Copper/Organophotoredox Catalysis
Synthesis of Abiotic Supramolecular Polymers Inside Living Cells via Organocatalysis‐Mediated Self‐Assembly
Hydrogen Bonding Interaction Enabled Asymmetric C─H Acylation of Trifluoroethanol by Dual Nickel/Photoredox Catalysis
A Key Fragment in Carbon Schwarzite Unit Cells and Its Triple [6]Helicene Precursor
Convergent Assembly of Homo‐ and Heterotypic Ubiquitin Chains from Functionalized, Expressed Monomers via Thiol‐Ene Chemistry
Synthesis of Linear and Cyclic Poly(allenamer)s by Powerful Cyclic–Alkyl–Amino–Carbene (CAAC) Ruthenium Catalysts and Facile Post-modification
Photocatalytic Stereochemical Editing for the Concise Syntheses of (25S)-Δ7-Dafachronic Acid, Demissidine, and Smilagenin
Mechanism Switch Between Radical‐Polar Crossover and Radical Buffering
An Olefin Radical Based Thiele's Hydrocarbon Derivative and Macrocyclic Tetraradical
PPh3/Isocyanide and N2/Isocyanide Exchange: Pathways to Isolable Alkali Metal Keteniminyl Anions
Understanding and Tuning Singlet–Triplet (S1–T1) Energy Gaps in Planar Organic Chromophores
Activating Molybdenum Peroxide Scissors for Converting Polyamide Plastic into Low Carbon Alcohols
Radical Chemistry of Tetrazenes: Access to Polymers with Pristine Tetrazenyl Chain Ends and Depolymerization Applications
Silylation of Aryl and Alkyl Chlorides by a Seven‐Membered Dialkoxysilyl Group Si(pan)Me via an In Situ Generated Silylpotassium
Asymmetric Synthesis of S(IV)‐Stereogenic Sulfinimidate Esters by Sulfinamide Activation
Photogeneration and Visualization of a Surface‐Stabilized Dinitrene
Modulated Multicomponent Reaction Pathway by Pore-Confinement Effect in MOFs for Highly Efficient Catalysis of Low-Concentration CO2
Highly Strained Electron‐Rich Molecular Bowl and Nanographene
Host‐Guest Chemistry in a Capillary Applied to the Facilitation of the Crystalline Sponge Method
Formation of the Diketopiperazine Moiety by a Distinct Condensation‐Like Domain in Hangtaimycin Biosynthesis
Enantioselective Acylation of Benzylic C(sp3)−H Bond Enabled by a Cooperative Photoredox and N-Heterocyclic Carbene Catalysis
Isoselenourea‐Catalyzed Enantioselective Pyrazolo‐Heterocycle Synthesis Enabled by Self‐Correcting Amide and Ester Acylation
Regio‐ and Enantioconvergent Hydroallylation of Acrylates Enabled by γ‐Silyl‐Substituted Allyl Acetates
Site‐Selectively Accelerating the Generation of β‐Linked Residue Isoaspartate in Proteins
Unusual 1,1-Dicarboxylation Selectivity in the Domino Hydrocarboxylation of Alkynes with Formate and Application in Polyimide Photoresists
Homologation of Alkenes Using Acetylene as a Csub2/sub Feedstock
Electrochemical Amino-Oxygenation Cyclization via Alkene Radical Cation/Bisnucleophile Engagement to Saturated N/O-Heterocycles
Selectively Deoxygenative Deuteration of Aldehydes by Superwetting Porous Carbon‐Supported Palladium Catalysts
AIE Bottlebrush Polymers: Verification of Internal Crowdedness in Bottlebrush Polymers Using the AIE Effect
Electrocatalytic Hydrogenation of Olefins
Enantioselective Synthesis of Inherently Chiral Pillar[5]Arenes Through Copper‐Catalyzed Azide–Alkyne Cycloaddition
Advancing Propylene Epoxidation: the Role of Ethyl Acetate Autoxidation via Cobalt‐Nickel Catalyzed C(acyl)─O Bond Scission
“Pulsed” Chain Transfer Anionic Polymerization: A Green and Cost‐Effective Approach for Controlled Polymer Synthesis
Palladium‐Catalyzed Meta C─H Alkoxylation and Amidation via Polarity Reversal of Nucleophilic Reagents
Artificial Photosynthesis of Formamide via an Oxidant‐Free Photoinduced Radical Coupling Route over Pt‐CdS
2
From waste plastic to hydrogen fuel: selective conversion through advanced catalytic technologies
Advanced monometallic and bimetallic catalysts for energy efficient propylene production via propane dehydrogenation pathways–A review
1
Orbital inversion mechanisms hidden in strongly correlated radical systems
1
Detection of the linear SiC3 and SiC5 radicals in IRC+10216⋆
2
Pan-modification profiling facilitates a cross-evolutionary dissection of the thermoregulated ribosomal epitranscriptome
Snake venom protection by a cocktail of varespladib and broadly neutralizing human antibodies
647
Silver-catalysed asymmetric [3+2] cycloaddition for the construction of 5–5-membered 1,3′-indolyl pyrrole atropisomers
When mechanochemistry meets fluorine
Squaratides: a tunable platform for anion binding in peptide-inspired macrocycles
Active-template CuAAC enables high-yield synthesis of (2)handcuff [2]rotaxanes
Regio- and diastereoselective synthesis of multi-substituted silacyclopentanes by catalytic cyclosilylborylation of styryl(vinyl)silanes
Desaturative arylaldehyde synthesis by synergistic carbocatalysis and organocatalysis
Fabrication of lithium phenoxide complexes for hydrogen storage evaluation
Coordination cages as tunable ligands for the synthesis of porous salts
Imine linkers enable the formation of robust single-molecule junctions
Correction: Iridium-catalyzed intramolecular asymmetric allylic amination of anthranilic acid derivatives: enantioselective construction of chiral benzodiazepinones
Copper-catalyzed three-component radical relay alkenylation of sulfenamides
Copper-catalyzed three-component thiocyanosulfonylation of allenes
A route to asymmetrically substituted secondary phosphines
Lewis acid–promoted annulation of electron-deficient indoles toward indoloindoles and higher fused architectures
Electrophilic substitution reaction of benzeneselenyl bromide (chloride) for the selective modification of the tryptophan side chain in peptides
Unveiling a PhSeSePh/I2-mediated radical cyclisation of 2-alkynyl-N-alkyl-N-tosylanilines: access to 3-sulfonyl indoles via 1,3 tosyl-relocation
Phosphine-catalyzed sequential [4+1]/[2+3] annulation of o-amino arylaldimines with Morita–Baylis–Hillman (MBH) carbonates
Recent advances in α-oxo nitrenes: from fundamental properties to reactivity
Attempted halogenation of ambiphilic 1,2,3-benzodiazaborines: balancing Lewis acidity and Lewis basicity
Electrooxidative C–N coupling of seven-membered cyclic sulfonylimines with piperazines
Electrochemical nitrogen atom insertion enabled by a manganese complex
Copper-catalyzed synthesis of 2-substituted quinolines via transmetalation/cyclization of (E)-2-(2-(trimethylsilyl)vinyl)-anilines and aldehydes
Total synthesis of (±)-cyclopeltain B
Electrochemical synthesis of 5-selenylbenzo[a]carbazoles via cascade cyclization of indoles with diselenides
Generation of mono(amino)carbenes from N-triftosyl amino hydrazonates with blue light
Iridium-catalyzed intramolecular asymmetric allylic amination of anthranilic acid derivatives: enantioselective construction of chiral benzodiazepinones
Nonenzymatic carbamoylation and phosphorylation via urea nitrosylation under mild aqueous conditions
Catalytic electron donor–acceptor complex triggered cascade radical trifluoromethylation/cyclization of N-isopentenyl aldehyde hydrazones
Metal-free direct amidation of alkynes using N-Boc-O-tosyl-hydroxylamine via Cope-type hydroamination and Beckmann rearrangement
D˙–A radicals fabricated from polychlorinated trityl and pyridinium featuring a SOMO–LUMO electronic transition
Backbone deprotonation defines a hidden decomposition pathway of diphosphine ligands
Catalyst-free synthesis of pyrazolo[5,1-a]isoquinolines from hydrazine hydrate
Catalyst-free insertion of carbon monoxide into terminal Mg–C(sp3) bonds
Constructing dual-redox polyimides for enhanced hybrid capacitive deionization performance
Enantioselective construction of chiral quinoline scaffold via a Michael addition/O-alkylation sequence
Palladium-catalyzed denitrative C–N coupling of amides with nitroarenes enabled by Al(OTf)3
Chemical emulation of the biosynthesis of (±)-arnebidin
Flow-driven non-covalent synthesis
Pd-catalyzed enantio- and diastereoselective synthesis of N–N atropisomeric indoles via N-alkylation reaction
H-bond-directed photocatalytic site-selective α-C–H functionalization of alcohols with p-quinone methides
A possible non-enzymatic pathway for metabolite oxidation under early Earth conditions
Photocatalytic coupling of silyl enol ethers with oxime phosphonates for streamlined β-ketophosphonate synthesis
Organocatalytic asymmetric [3+3] annulation reaction between 5-aminopyrazoles and enynones: synthesis of pyrazolo[3,4-b]pyridines
Synthesis of bisenarsan; an organoarsenic metabolite from streptomycetes
Facile generation and reaction of densely trifluoromethylated alkyl radicals by dual photoredox and acid catalysis
Enantioselective reductive cyclization of alkynals via cobalt catalysis
Nickel-catalyzed intramolecular defluorinative [4+2] cycloaddition for the construction of monofluoroarenes with gem-difluoroalkenes
Enantioselective synthesis of chiral cyclic hydroxylamine ethers via NiH-catalyzed cyclization of alkyne-oxime ethers
Copper-mediated photoinduced perfluoroalkylation of arylsulfonium salts
Stibine-catalyzed selective conversion of nitroarenes to hydroxylanilines through deoxygenation and hydroboration processes
Copper-catalyzed spirocyclization–oxytrifluoromethylation of alkynyl-bicyclo[1.1.0]butanes for spirobutyl quinolone synthesis
1,4-Bromoboration of nitroalkenes
Silver-catalyzed fragmentation of all-carbon quaternary centers from sp3 to sp2 carbon via C–C bond cleavage
A solid-phase click2 strategy for chromophore–DNA conjugates and their application as a light harvesting system
Copper-catalyzed stereodefined synthesis of halogenated spirodihydrofurans
Direct carbonylative amidation of benzylic alcohols with alkylamines via palladium catalyzed C–O bond activation
Direct C–H magnesiation of thiophenes with an Mg–Mg-bonded compound
Cu–guanidine-catalysed asymmetric protoboration of internal 1,3-dienes for one-pot access to chiral homoallylic alcohols
From molecular tweezers to pliers: a significant enhancement of fullerene grasping capability
Domain-adapted discovery of PET depolymerisation routes using in-house curated scientific literature
Photocatalyzed generation of acyl radicals from aryl/alkyl acyl halides via nucleophilic substitution
Small cavitand macrocycles from direct C–C coupling of s-aryl tetrazine units
Copper-catalyzed allylic substitution of nitroallyl derivatives with Grignard reagents
A mechanochemical construction of C–P bonds through radical–radical coupling
π-Stacked dimerization of an antiaromatic homoHPHAC monocation
Stereoselective thiosulfonylation of alkynes using sodium thiosulfate as a sulfur transfer agent to access bis-(Z)-vinyl sulfones
Interfacially modified Si–Pd/carbon catalyst for selective pulegone (C[double bond, length as m-dash]C bond) hydrogenation to menthone-isomenthone
Late-stage diversification of pharmaceuticals and natural products via a direct electrochemical decarboxylative platform
Opposite enantioselectivities displayed by supramolecular helical catalysts with non-enantiomeric “sergeants”
Shaking things up: exploiting the potential of mechanochemistry to enhance deracemization of racemic compounds
Recent advances in silanecarboxylic acids as versatile reagents for modern organic synthesis
Unveiling a host–guest assembly composed of an emissive Ir(iii) complex salt and a concave aromatic host at a local minimum state
Make the ylides shine: synthesis and structure–property relationships of phospha-squaraines
Solvent- and heat-induced polymorphic transformation with single-crystal integrity in Cu(ii) paddle wheel metal complexes
Fast-track discovery of MOF-derived M@NC catalysts for HMF-to-FDCA oxidation via DFT prescreening and Box–Behnken optimization
Reaction of dearomatized heterocycles with sulfur hexafluoride (SF6) and the pentafluorosulfanyl (SF5) group
Concise synthesis of triasteranones from barbaralones
Mantis-shaped bifunctional tridentate HoMPy-PI-NO ligands capable of cooperatively activating nucleophiles and electrophiles: empowering asymmetric addition reactions
Enantioselective Pd&Cu-catalyzed coupling of imine esters with gem-difluorinated cyclopropanes
Metal-free, iodine-mediated multicomponent synthesis of bis-pyrazolo-pyridine derivatives
Tunable regioselectivity for C–H alkynylation of weakly coordinating amides that tolerated strongly coordinating heterocycles
Photoredox-catalysed arylamination of non-anomeric exoglycals with aryl sulfinamides via radical Smiles rearrangement
Cationic iridium-catalyzed enantioselective decarboxylative aryl addition of aromatic carboxylic acids to bicyclic alkenes
Light-driven silane functionalization using disulfide and dichloromethane
Chiral bowl-shaped thiazole-embedded B(iii)-azatriphyrins(2.1.1): a nonaromatic platform via triple core-modification
Chemoselective synthesis of α-fluoromethyl amides via the controlled addition of LiCH2F to N-aryl and N-alkyl isocyanates
Switchable N–H vs. C3–H carboxylation of indoles using dual-function reagents
Visible-light-induced upcycling of perchloroethylene into trichloroacetamides using chlorine dioxide
Regioselective chalcogenation of glycals: DBU and iodine-mediated, transition-metal-free synthesis of heteroaryl thio- and seleno-glycoconjugates
Visible light-induced sulfonylation reaction of copper-catalyzed thianthrenium salts
Efficient spin-doublet near-infrared emission beyond 800 nm via intramolecular charge transfer in a quasi-planar donor–acceptor structure
Selective nucleophilic addition of aryllithium reagents to α-ketonitriles giving ketones under microflow conditions
A direct route to ynones: Pd-catalyzed Sonogashira carbonylative coupling of ethers with alkynes via C–O cleavage
Enantioselective access to chiral phosphonothioates via iridium-catalyzed asymmetric allylic substitution
Tuning the reactivity of an osmium–peroxo unit by modulating metallacycle aromaticity
Bis(N-heterocyclic carbene)-borylene-mediated heteroallene activation
Optimizing the chloroallene pathway toward the one-pot synthesis of rubrene
Photoinduced transformations of oxime derivatives via electron donor–acceptor complex activation
A new atom-transfer radical cyclization (ATRC) mediated by photocatalytically-generated aminyl radicals that do not have an α-C–H bond
Potassium-ion-responsive chiral supramolecular hydrogels exhibiting long-range chirality transfer from d- or l-alanine to achiral frameworks
From local to global or semilocal aromaticity: singlet–triplet switching in porphyrin tapes
Red CPL from water insoluble achiral carbon dots assisted by cyclodextrin MOF templating
Base-catalyzed switchable reactivity of N-acyl-α-aminonitriles: oxidative decyanation to imides and hydrolysis to amides in batch and flow conditions
A novel photochemical vapor generation medium: diketone as a medium for the determination of tellurium(iv) and bismuth by ICP-MS
Stable radical cations based on indolo[3,2,1-jk]carbazole: synthesis, characterization, and theoretical calculation
Light-induced controlled synthesis of arylsulfonyl oxindoles and arylsulfonyl amides under catalyst- and oxidant-free conditions
Pd-catalyzed synthesis of deuterated olefins from (hetero)arenes and ketones via a cross-coupling approach
Oxidant-controlled divergent construction of sulfenylsuccinimides and sulfonylsuccinimides via Mo-catalyzed C–S cross-coupling
Ruthenium-catalyzed site-selective C–H allylation of aryl ketones using Morita–Baylis–Hillman alcohols: access to α-benzyl acrylates
Alternating current polarity for electrochemical de novo synthesis of 3,3′-bisoxindoles
Photocatalytic Heck-type coupling reactions of alkyl chlorides mediated by halide-exchange of CsPbBr3 nanocrystals
Diastereoselective intramolecular O-allylation with alkynes using palladium/Brønsted acid combined catalysis: access to substituted chiral oxazolidines
Enantioselective photoredox- and Cu-catalyzed alkoxycyanation of styrenes to synthesize chiral β-cyanoethers
BODIPY-based photouncaging – green light triggered dual cargo molecule release
Iridium-catalyzed P(iii)-directed ortho-C–H silylation of arylphosphines with hydrosilanes
Oxetanes in heterocycle synthesis: recent advances
Purple-light-induced synthesis of spiro-oxindole oximes from BCBs and TBN via strain release
Azahelicene-fused Blatter radicals: chiral paramagnetic NIR absorbers
Palladium-catalysed imidoylative difunctionalization of allenes: access to quinolines and indeno[1,2-b]quinolines
Synthesis of S-alkyl sulfilimines via ring-opening sulfilimination of sulfonium salts
Photocatalytic bifunctionalization of indole to access multi-substituted benzopyrrolizidinones
Cathodic oxygen-reduction-reaction-mediated active peroxide for oxidizing cyclohexanone to ε-caprolactone
Tandem [2+4] annulation/aromatization reaction of yne–enones with o-sulfonamidobenzaldehydes
From solution to thin films: unravelling excited-state behaviour in halogenated diradicaloids
Unified approach to indolosesquiterpene alkaloids: total syntheses of anti-viral agents, xiamycin A and oridamycin A
Visible-light-induced perfluoroalkylation cyclization to access perfluoroalkylated benzazepines and benzoxepines by EDA complexes
Photosensitizer-free polarity-mismatched electrophilic α,α-bis-functionalization of acetone with quinoxaline and maleimide
Trimercarbazole-based aggregation-induced fluorescence-to-phosphorescence-active gold(i) complexes: isomeric engineering of an auxiliary ligand for high-contrast hypsochromic phosphorescent mechanochromism
Photoredox mediated synthesis of propargylic sulfoxides: a one-step aerobic approach
Construction of oxindole spiro medium-sized S-heterocycles via ring expansion [2,3]-sigmatropic rearrangement
Nitrogen-centred helical acridiniums with a 6–7–6–6 fused ring skeleton
Regioselective electrochemical 7-endo-dig selenocyclization of N-benzyl propiolamides to access selenated benzo[c]azepinones
Metal and additive-free synthesis of 2,4-disubstituted oxazoles via thiourea-mediated cyclization reaction
Controlled ROS generation in pyridinium-functionalized nanocatalysts for selective photooxidation
Silver nanoparticle-immobilized benzimidazole-linked porphyrin polymers for efficient carboxylation of terminal alkynes with CO2
Visible-light-mediated β,β-thio- and selenosulfonylation of N-ethyl tertiary amines
Photocatalytic S-alkylation of sulfinamides: access to sulfoximines
Quantifying the enamine-type nucleophilic reactivity of α-aryl vinyl azides
Dual pharmacokinetic modifier strategy for synergistically enhanced tumor accumulation of PSMA-targeting radioligand
Oxime-modified pillar[5]arene-based hybrid supramolecular polymers: construction and antibacterial performance
Synthesis of thieno[2,3-b]indoles by Cloke–Wilson rearrangement of spiro donor–acceptor cyclopropanes
Unveiling a novel GC-globulin host for supramolecular recognition
Sunlight-triggered photochromism of imidazole-based 2D polymer via open–shell diradicalization
Iridium-catalyzed [5+1] cyclization of terminal alkynes with CF3-imidoyl sulfoxonium ylides to construct 2-trifluoroquinolines
Gate-opening cooperative methanol binding to multi-bladed benzenes bearing 1,2-diboryl functionality
[11]Cycloparaphenylene incorporating a redox-active dithiafulvene moiety provides access to a carbon nanohoop with an unpaired electron along the core
One-pot asymmetric sulfoxidation using in situ generated H2O2 from H2 and O2 catalyzed by rhodium and vanadium complexes
Cobalt-catalysed (4+3)-annulation of oxiranes with 4-vinyl indoles: stereospecific access to fused oxepinoindoles
Photoinduced three-component alkylpyridination of alkenes via spiro-dihydroquinazolinone fragmentation
Divide and correlate: mapping electronic correlations in proteins via local cut-wise reconstruction
Bridging the hydrophobic gap: visible-light-driven photocatalysis of organic reactions in water with soft-matter nanoreactors
Synthesis of multifunctional lactam-substituted alkyl sulfones using rongalite as an electron donor, sulfone source, and C1 synthon
Synthesis of isoquinolin-1,4-diones via photocatalytic C(sp2)–C(sp3)-scission/oxidation of 4-(hydroxy(aryl)methyl)-isoquinolin-1(2H)-ones
From benzyl to fluorenyl: enhancing photostability and modulating optoelectronic properties of para-azaquinodimethanes
Exploration of heteroatom doping in modulating the two-electron selectivity of M–N–C catalysts for the oxygen reduction reaction
Reactivity of ketenyl anions towards ammonia
Palladium photocatalysis: a strategic approach for visible-light-mediated C(sp2)–H arylation
Visible light-mediated cyclopropylamide [3+2] cycloaddition with maleimides to synthesize cyclopentylamide derivatives
PhI(OCOCF3)2-mediated metal-free 2,3-difunctionalization of indoles: direct access to carbochalcogenated scaffolds
Carbene-catalyzed [2+2] cycloaddition of chloroaldehydes and isatin-derived ketimines for enantioselective synthesis of spirocyclic β-lactams
Constraint driven modulation of N,N-diarylamine(s) under space limitations imprinted in 7.6.6 defect
A 2nd-generation scalable synthesis of the HIV-1 entry inhibitor CJF-III-288 enabled by photoredox catalysis
A face-regulated tetrahedral cage for selective and efficient encapsulation of perylene dimers
Upcycling thermosetting polysiloxanes into thermoplastics via UV-induced surface photopolymerization of acrylates
DABCO-directed EDA-complex mediated regioselective C4-sulfonylation of quinoline N-oxide
Visible-light-driven N[double bond, length as m-dash]N bond functionalization of azobenzenes
Aryldiazonium ion-initiated C–N bond cleavage for regioselective ring-opening of N-sulfonylazetidines with thiol nucleophiles
Photoinduced benzylic C–H thiocyanation enabled by triphenylphosphine oxide and N-thiocyanophthalimide
Dynamic regulation of nucleic acid replication beyond the Watson–Crick base-pairing rule
Atom-efficient iron-catalyzed cascade synthesis of pyrroles from nitroarenes under low-pressure conditions
Invisible architects: traceless directing group strategy towards late-stage functionalization and synthesis of drug derivatives
Facile synthesis of multisubstituted 2,3-dihydrofurans via intermolecular cyclization of enals or alkyl/aryl aldehydes with acyl-stabilized sulfur ylides
A facile strategy for π-extended BOPYINs: transformation into six-membered BODIPY analogues and their optical properties
Photocatalyst-free access to α-arylethanone oximes enabled by sequential HAT/SET of aryl iodides with TBN and alkenes
C7-Sulfonamide functionalization of 7-deazaadenosines: sangivamycin analogues with Haspin inhibitory activity
Molecular communication system using Zn2+ selective supramolecular nanochannel to induce photoregulated catalysis
Interphasic separation of cis/trans perylene-based nanographene isomers driven by selective encapsulation in a supramolecular cage
Photocatalytic oxidative cyclopropanation of aza-1,6-enynes: construction of 3-aza-bicyclo[3.1.0]hexane derivatives
Stable acidic H2O2 electrosynthesis via in situ Ti–N bridging sites
One-step synthesis of porous ionic liquids via proton transfer for natural gas purification
The one-step formation of four chemical bonds toward dithiophosphinates via a multicomponent reaction
Cu-catalyzed tandem cross-coupling/cyclization of aryl diazophosphonates with phenylacetylene derivatives
Visible-light-induced generation of alkenyl radicals from alkenyl sulfonium salts: direct synthesis of 11-alkenyl-substituted dibenzodiazepines
Copper(ii)-mediated deoxychlorination synthesis of glycosyl chlorides from glycosyl hemiacetals
Emergent properties of supramolecular peptide assemblies
Palladium-catalyzed ring-opening defluorination of gem-difluorocyclopropanes: expedient synthesis of fluorinated 1,3-dienes and arenes
Metal-free oxidative all-halogen–compatible halogenation of methylenecyclopropane for accessing benzoxazines
Kolbe radical-initiated electrochemical desulfurization of thioamides under aerobic conditions
Native-carboxylate-assisted enantioselective C–H annulations with allenes and 1,3-dienes on ferrocene
Chloride-incorporating cascade dearomatization of isoquinolines with chloroformate and DMAD achieving 100% atom economy
Organocatalytic α-deuteration of carbonyl compounds: a pTSA/D2O strategy for bioactive and natural products
Edge-centred chirality-induced enantiopure square-like sulfonylcalix[4]arene-{Coii16} cages for selective (+)-/(−)-α-pinene adsorption
Investigating the bioorthogonality of isocyanides
Metal-free halogen atom transfer for carbocyclization of N-arylacrylamides enabled by visible light-excited ligated boryl radicals
Photo-induced and azide anion-facilitated atom transfer cyclization of N-allyl-2-bromoamides
Unlocking reactivity potential of gem-dihaloolefins: access to Halo-functionalized 1,4-naphthoquinones via intramolecular radical oxidative cyclization
Expanding icosahedral frameworks: structure and bonding of bicapped icosahedral cluster [(Cp*Co)4Fe(CO)B9H11]
Recent developments in the synthesis and synthetic applications of borane–amines
The iron-catalyzed selective hydrodeoxygenation and hydrodesulfurization of (thio)esters by hydrosilylation under blue light activation for access to (thio)ethers
Expect the unexpected – Li+ migration governing the substitution of 7H-benzo[de]anthracene with main-group fragments
1,4-Dihydropyridine compounds as versatile dehalogenation reagents under visible-light irradiation
Supramolecular light-harvesting systems enabled by amphiphiles
The atroposelective synthesis of barbiturate-substituted chiral styrenes
Amine-based anion receptor enables an improved magnesium plating/stripping reversibility
Turn left and turn right: recent advances in selectivity controlled carbonylation
Enantioselective synthesis of N-arylpyrrole aldehydes via NHC-organocatalytic atroposelective desymmetrization followed by kinetic resolution
Efficient synthesis of benzo(hetero)aryl-5-yl(2-hydroxyphenyl)methanones via mechanochemical benzannulation
Minimal-tag polyamines for in situ probing of their intracellular distribution
Efficient Pd/AntPhos-catalyzed α-arylation of benzyl aryl ketones with aryl thianthrenium salts
An anthraquinone-based covalent organic framework for sustainable photocatalytic oxidative degradation of polystyrene
Chirality amplification step of temperature cycle-induced deracemization
Chemoselective nickel-catalyzed difluoromethylation of aryl halides with (SIPr)AgCF2H as transmetalation reagent
From oxygen atom transfer by stibine oxide to hydroxo–antimony formation via Lewis acid capture
A palladium inverse crown: synthesis and characterisation
Annulated oxazolium salts as anion–π+ interaction-enabled solid-state room-temperature phosphorescent materials
Pre-targeted delivery of a tetrazinylated albumin–zinc(ii) porphyrin complex for tumor photodynamic therapy
Alkynes and azides: beyond click chemistry
Base-controlled divergent synthesis of cyclopropyl aryl methanones from homopropargylic alcohols with DMTST
Electro-oxidative [3+2] cycloaddition for the synthesis of 5-selenyltetrazoles
Metal- and photocatalyst-free CF3-modification of N-containing fusion skeletons in photo-flow chemistry
Iodine/iron oxide-catalysed aerobic oxidative coupling of phosphites and alcohols via in situ iodophosphate formation
EnT-catalysis-enabled, radical-relay cascade cyclization to access multisubstituted cyclohexane/cyclohexene
Mechanochemical one-pot Barbier/Simmons–Smith reaction via sequential zinc activation
Biosynthesis inspired asymmetric total synthesis of camptothecin
Strong ligand-modified polyaniline decorated with cobalt nanoparticles optimizes surface electron density for efficient oxygen evolution
Radical-triggered annulation-haloazidation of alkynyl-bicyclo[1.1.0]butanes: an efficient route for the construction of spiro-cyclobutyl quinolinones
Synthesis of pyrrolo[3,4-c]pyridines via metal-free cross-coupling/cyclization cascades of β-ketothioamides with 2-aroylmalononitrile at room temperature
Regioselective synthesis of allylic/propargylic alcohols from conjugated dienes/enynes catalyzed by CuCl under aerobic conditions
Integration of perylene diimide into a two-dimensional cobalt–organic framework for enhanced photocatalysis
Tuning the fate of the triplet by changing the degree of branching in phenothiazine–trithienyltriazine nanoaggregates
G-quadruplex DNA/iron cationic porphyrin catalyzes enantioselective carbon–silicon bond formation
Adaptive crystals of homothiacalix[4]arene capable of molecular recognition, with preferential uptake of benzene over cyclohexane
Bridged chemistry of macrocyclic arenes: from sp3-carbon bridges to π-conjugation and heteroatom bridging
Cavity-size-directed supramolecular assembly of AIEgen networks for aqueous white-light emission
Metal-free regioselective B–O coupling in carboranes for constructing aggregation-induced emission luminogens
Pd-catalyzed acceptorless dehydrogenative aromatization of cyclohexyl rings via benzylic C–H bond activation
Advances in heterogeneous catalysts for sustainable PET upcycling: from mechanistic understanding to catalyst design
Direct decarboxylative 18F-fluorination of benzoic acids using visible light catalysis
Controlling Lewis acid-catalysed bicyclobutane cycloadditions: carbonyl substituents dictate electrophilic vs. nucleophilic addition pathways
Electrochemical hydro- and seleno-amination of 2,3-dihydrofurans
Asymmetric synthesis of chaetogline A: expedient preparation of the indolizino[8,7-b]indole template and optical properties in a push–pull configuration
Ru-catalyzed C–H annulation: accessing quinazolinone–BCP hybrids from stable precursors
Stable Zr-based polyoxometalate as a green catalyst for selective oxidation of aniline
Nucleopalladation strategy towards regioselective N-alkylation of indoles with unactivated olefins
Supramolecular confinement as a tool to control the dynamic molecular assembly of o-nitrosocumene in water
Functionalized pillar[5]arenes with pH-responsive fluorescence and chiroptical properties
A general iron-catalyzed highly selective mono- and bis-alkylation of indene using primary and secondary alcohols
Design, synthesis and structural investigation of a novel class of aggregation-induced emission (AIE) molecular scaffolds
D2h HZn4S4−: an elongated planar tetracoordinate hydrogen star
Photocyclisations of o-iodobenzyl-indanones and tetralones infer the intermediacy of triplet aryl cations
Transition-metal–free borylative functionalization of aryl fluorides with boron alkoxide in the presence of sodium dispersion
Exploring the limits of inductive electron withdrawal in fused bicyclic azaheterocycles
Ag(i)-mediated mono-selective C(sp2)–H chalcogenation of α-aminotropones and their peptides at room temperature
Cu-catalyzed selective coupling of alkynes with danB–Bpai
Catalytic asymmetric reactions of indolylmethanols for the synthesis of chiral indole derivatives
Photoredox-catalyzed multicomponent transformation towards functionalized trans-2,3-disubstituted indolines
Palladium-catalysed asymmetric allylic alkylation of hydantoins using bench-stable chiral palladium precatalysts
Chalcogenylation of 4-hydroxycoumarins and 4-hydroxyquinolinones in water at room temperature
Ammonia reactivity with ferriotetrylenes: a structural snapshot of a highly dynamic process
Temperature-jump QCL spectroscopy of peptide dynamics: expanding spectral accessibility by dual-combs
A novel bivalent albumin binder for enhanced tumor retention of a fibroblast activation protein-targeted radioligand
Chiral amplification of prebiotic peptide synthesis induced by chemical–physical interactions on calcite surfaces
Rh(ii)-catalyzed and Cu(i)-mediated synthesis of furopyridones using N-substituted pyridones and diazonaphthoquinones: applications in photophysical studies
Molybdenum-catalyzed synthesis of 2,3-disubstituted indoles via imine condensation and C(sp2)–H insertion
CuH-catalyzed stereoselective desymmetrization of prochiral cyclopentane-1,3-diones via alkoxyallylation
A homemade and simple solid-state photoreactor for solvent-free benzylic oxidation
Atroposelective synthesis of isoquinolinone bearing two distinct C–N axes via cobalt-catalyzed enantioselective C–H activation/annulation
Synthesis of ketones and mono-fluoro ketones via boron enolates formed by substitution of esters with benzylboronic esters
Metal- and photocatalyst-free benzylic C–H halogenation via an electron donor–acceptor complex
Towards a glutathione-cleavable azobenzene linker for antibody–drug conjugates
Triplet nitrene-mediated photocatalytic azidation of tertiary C(sp3)–H bonds
NORA: non-adiabatic dynamics with force-field based representation. Application to photoisomerization in biomimetic photoswitches
Dependence of an anion template on amino acid binding in DMSO/H2O by a chiral Ag/urea-based tweezer
Regioselective postmodification of aryl sulfonyl fluorides via iridium(i)-catalysed C–H borylation
Deracemization by coupling electrochemically assisted racemization and asymmetric crystallization
Ru(ii)-catalyzed stereoselective C(7)–H α-fluoroalkenylation of indolines
Regioselective functionalization of sulfenamides: S-arylation with cyclic diaryl λ3-bromanes and λ3-chloranes
Electrochemical upcycling biomass-derived methyl 2-furoate and CO2 into monomers for recyclable polyesters
Palladium(ii)-catalysed intramolecular hydroamination of 3-alkynyltetrahydroquinolines to methanobenzo[b]azepines
Delineating the roaming and non-roaming pathways for the NO release in o-nitrofuran and o-nitrothiophene
One-pot synthesis of novel triazine/piperazine-based macrocycles and investigation of their porous properties
Ligand exchange of tris(2,4-di-tert-butylphenyl) phosphite: a practical and efficient route to organo gold(i) complexes
Dynamic activation of alcohols by an electrophilic phosphinine
EDA complex-directed streamlined synthesis of isoxazolidines from nitroarenes
Recent advances in photochemical diradical hydrogen atom transfer (DHAT) reactions of C–H bonds
Biochar-supported Cu catalyst for low-temperature base-free oxidative N-formylation of amines with paraformaldehyde in green solvent
Rh(iii)-catalyzed C–H activation/β-F elimination/Michael addition: diastereoselective access to dihydroisoquinolinones featuring β-amino α-fluorocarbonyl motif
Electrophilic aryl migration of N-benzyl propiolamides to functionalized-acrylamides
Aryl semicarbazides as aryl sources for mechanochemical oxidative Heck coupling by C–N bond activation
Rh(ii)-catalyzed synthesis of furo[2,3-b]indoles from 3-diazooxindoles and electron-rich arylacetylenes
Reducing rotatable bonds in one substrate accelerates a bimolecular Diels–Alder reaction in a bis-calix[4]pyrrole cage
Photocatalytic (3+3) cycloaddition of arylaminocyclopropanes with nitrones: highly diastereoselective synthesis of 1,2-oxazinan-6-amine derivatives
Size-selective formation of metallonanobelts via tethering-template-directed self-assembly
Oxidative cyclization of active methylene amides: efficient synthesis of functionalized 3-azabicyclo[n.1.0]alkanes
Photoredox-driven tandem ring-opening and vinylation: a route to distal alkenyl ketones from cyclopropenes
Highly emissive boron-α-thioimidinates: substituent control of photophysics and charge transport properties
Stirring chemical reaction landscapes through strong light–matter interactions
Understanding nonbonded interactions between molecular fragments
Vinyl benzotriazole to indole: an iodine-mediated denitrogenative transannulation approach for the synthesis of indoles
Iridium-catalyzed [3+2] cyclization of terminal alkynes with sulfoxonium ylides to construct 2,5-disubstituted furans
Carbon monoxide as the key: carbonylation triggered (hetero)aryl migration transformations
Recent advances in transition-metal-free deconstructive functionalization of saturated N-, O-, P-, and S-heterocycles
Synthesis of 11C-epoxides, aziridines, and cyclopropanes from structurally modified 11C-sulfur ylides
Diversity-oriented transformation of methyl triazine via sulfur-mediated pathways: access to 2,4-disubstituted triazines functionalized with thioamides and amides
Halide-free deep eutectic solvents with low viscosity and corrosion for efficient SO2 capture and conversion under environmental conditions
A study of 1-(hydroxymethyl)isoquinoline as a new member of the photoremovable protecting groups
Enzymatic trifluoropropylation by a trifluoropropyl S-adenosylmethionine analogue
Cobalt(iii)-catalysed annulation of indoles with phenylethynyl ether for the synthesis of the ABC ring system of ergot alkaloids
Key role of oxygen and base in catalytic thioetherification: access to sulfur bridged poly-aromatic hydrocarbons
Less is more? Probing the template amount required for solid-state olefin [2 + 2] photocycloaddition in a ball mill
Ligand tricks for faster clicks: bioconjugation via the CuAAC reaction
Size-matched supramolecular assembly between an asymmetric Anderson-type polyoxometalate hybrid and α-/γ-cyclodextrins
Tailored ionic liquids for microfluidic paper-based analytical devices: boosting colorimetric performance for enzymatic glucose assays via cellulose surface modification
Leveraging cascade annulation of 2-alkynylcyclopropanes with substituted azides to access fused N-heterocyclic scaffolds
Visible-light-promoted synthesis of imidazo[1,5-a]indole-3-ones via cascade carbene N–H insertion and oxidative cyclization
Palladium-catalyzed aminoalkynylation/alleneamination of urea-tethered alkenes: access to imidazolidinones bearing alkynes and allenes
Photocatalytic carboxylation of aryl halides/alkenes with a copper(i) complex bypassing the demand for dual catalysts
Use of tailored boronic acids both as a radical donor and acceptor in a visible light-mediated di-functionalization of maleimides: rapid access to fused benzo[e]isoindole-1,3-diones
Nickel-catalysed Suzuki-type cross-coupling of α-iodosilanes with arylboronic acids: direct and efficient access to benzylic silanes and gem-silylboronate esters
Total synthesis of brevianamides X, Y and Z
Photocatalyst-free decarboxylative cross-coupling of α-keto acids with aryl sulfinates for the synthesis of S-aryl thioesters
Acylation of N-heterocycles via ligand to metal charge transfer on bismuth(iii)
Mechanically interlocked porphyrinoids: self-assembly of metal-stabilised catenaphyrins
The direct photochemical cross-esterification of alcohols via site-selective C–H bromination
Targeted synthesis of a positional isomer of aromatic N-methyl N-confused corrole and its organocopper(iii) complex
Bromine sequestration by advanced functional porous materials
Electrosynthetic access to allyl sulfones via sulfonylation of allyl bromides
A radical path to 1,2-diphosphacyclobutenes
Versatile benzannulation strategies with vinyl sulfoxonium ylides and electron-deficient alkenes/alkynes
Cysteine-activated hydrogen selenide (H2Se) delivery from isoselenocyanates
Synthesis of [1,3]-thiasilolanes via rare-earth-catalysed intramolecular α-C(sp3)–H silylation of alkyl sulphides with hydrosilanes
Divergent late stage functionalisation of luminescent europium(iii) complexes for targeting and imaging applications
β-Carboxyphospholes via carboxylative desilylation: luminophores with a versatile connectivity attached
Photosensitizer-free synthesis of benzochalcogenophenes via photoinduced cascade cyclization
Chiral pool-engineered homochiral covalent organic frameworks for catalytic asymmetric synthesis of drug intermediate
Pore-confined trimerization of terephthalonitrile in MAF-5
Seeded control of symmetry-directed diverse chiral π-stacked benzothiadiazole assemblies with leucine-based diamide units
Cobalt-catalyzed regioselective (4+2)-annulation of benzamides with allenyl carbinol acetates: access to 3-vinylisoquinolinones
Cobaltaelectro-catalyzed C–H acyloxylation of aromatic and vinylic amide derivatives at room temperature
An ultra-simple construction strategy for uncommon 3,4-diaryl-modified maleimide luminophores and their unique aggregation-induced asymmetric effect (AIAE) on conformation
Eco-friendly synthesis of highly emissive benzothiadiazole-based fluorophores via a solvent-free hand-grinding Horner–Wadsworth–Emmons reaction in ≤1 minute
Remote asymmetric conjugate addition of naphthoquinone methides: constructing adjacent tertiary-quaternary carbon stereocenters
Electrochemically driven bromochlorination of alkenes
TMSCl-promoted allylic phosphorothiolation and intermolecular difunctionalization of alkenes
Photo-induced tandem cyclization of unsaturated amides with thiocyanates to access thiocyanated heterocycles
Photoinduced iron-catalyzed reduction of nitroarenes for multicomponent synthesis of α-branched secondary amines
Accessing [6,6,5,6] tetracyclic indeno-quinolines via a photomediated cascade reaction of electron-rich 1,7-enynes
Generation of alkyl radicals via C(sp3)–C(sp3) bond cleavage of xanthene-based precursors for photocatalytic Giese-type reaction
Direct and affordable alcohol phosphorylation through ambient electrochemical oxidation of phosphorous acid
meta-NTf2 substituted diaryliodonium salts: novel nitrogen-substituted aryne precursors for trapping reactions and rearrangements
Photoelectrocatalytic XAT strategy for the generation of alkyl radicals to synthesize alkylated 3-CF3-2-oxindoles
The photoluminescence behaviour of monosubstituted non-benzenoid polycyclic-aromatic-substituted ortho-carboranes
Fe(iii)/NaBD4-mediated regioselective deuteration/cyclization of 1,7-enynes and 1,7-dienes
An EDA complex-driven multicomponent reaction of Br–Rf with alkenes via radical-polar crossover
A multicomponent approach for the stereoselective synthesis of atropisomeric N–N peptide analogues
Sustainable synthesis of hydrosilanes and alkoxysilanes in a sequential one-pot olefin hydrosilylation and dehydrogenative coupling with alcohol under phenoxyiminato cobalt(ii) catalysis
Asymmetric C–H hydroarylation and annulation cascade for the skeletal diversification of dihydrofuran-fused-phthalimides
An aldehyde-stabilised alkoxyaluminium dication
Mesoporous polyphosphamide catalyzed heterogeneous one-pot Wittig olefination
A tetraphenylethylene-based dicyclophane with an o-carborane framework exhibiting dual-state emission
Heme-based catalysis for sustainable carbene transfer chemistry: computational mechanistic investigations
A direct comparison of lithium tetra(n-butyl) manganate(ii) and magnesiate: structural insights and catalytic hydroamination of styrenes
Non-covalent interaction-controlled site-selective benzylic C(sp3)–H oxidation
Visible-light-induced stereoselective trifluoromethylselenolation of arylalkenyl iodides with [Me4N][SeCF3]
Photocatalytic cyclization reaction of 2-vinylarylamines with CF3SO2Na and arylaldehydes to access 3-(2,2,2-trifluoroethyl)-3H-indoles
Glycosyl thiosulfonate: a stable electrophilic reagent for the synthesis of thioglycosylated indoles and total synthesis of isatindigotindolosides
Solid-state polycyclotrimerization of diynes to porous organic polymers
Trace water-induced anomalous diffusion in chlorinated imidazolium ionic liquids
Catechol-facilitated Sn2+ transport enables ultrahigh utilization rate of aqueous metallic tin anodes
Ir(iii)-catalyzed selective C–H acylmethylation and dicarbonylation of indolizines with β-ketosulfoxonium ylides
Photo-induced ruthenium-catalyzed alkene C–H-arylation at room temperature
Dehalogenation hydrolysis of CF2Br2 enables four-component aminocarbonylation via photocatalytic radical-polar crossover
Additive-controlled chemodivergent multi-component domino reaction between salicylaldehydes and Morita–Baylis–Hillman (MBH) carbonates
Iminophosphonamido stannylenes enable quantitative CO2 conversion to isocyanates
Multistage control of near-infrared and magnetic properties via π-dimer modulation in TCNQ radical anion salts
Nitrogen atom insertion into N[double bond, length as m-dash]N double bonds: straightforward access to triazenes
A diazadiphospholenium cation featuring a reactive P[double bond, length half m-dash]P bond: synthesis and reversible main-group bond activation
Sulfonium salt-mediated phosphorodithioation of alkynes with P4S10 and alcohols to access Z-vinyl phosphorodithioates
Nitrile hydration and α-deuteration of amides catalyzed by a PCNHCP Mn(i) pincer complex
Palladium-catalyzed cyanation and alkynylation of allylic gem-difluorides via Hiyama-type coupling
Light-induced intramolecular carbene C(sp3)–H insertion of N-tosylhydrazones; synthesis of functionalized coumarans and indolines
Additive-free synthesis of α-keton thiol esters via oxyacylthiolation of vinyl azides with thioacids and water
Design and synthesis of triphenylamine-substituted vinyl sulphide and its derivatives for fully transparent-to-black electrochromism
Electrochemical dehydrogenative α-vinylation and α-allylation of cyclic β-ketoesters
Auto-oxidation-driven vicinal C(sp3)–H desaturative cyclization of tertiary alkylamines for the synthesis of pyrido[3,2-c]coumarins
Enantioselective C–H amination catalyzed by homoleptic iron salox complexes
PIDA-mediated segment coupling for the synthesis of azido-methyl substituted ketones via 1,5-hydrogen atom transfer (HAT)
Rh(iii)-catalyzed cyclization of 5-amino-pyrazoles with maleimides to pyrazoloquinazolines
Copper-catalyzed 1,4-alkylcyanation of CF3-containing 1,3-enynes: alkoxy radical-mediated selective cleavage of fused azabicycles
Pd-catalyzed electrophilic cross-coupling of pyridylphosphonium salts with arylthianthrenium salts to access C4-arylated pyridines
Photoredox mediated one-step syntheses of aryl C-glycosides from unprotected glycosyl sulfinates
Visible-light photoredox catalyzed thioesterification of sulfoxonium ylides with elemental sulfur and α-ketoacids
Divergent coupling of ortho-alkynylnaphthols and p-quinone monoketals through a Michael addition/intramolecular annulation cascade to access benzofuryl β-naphthols
Efficient synthetic approach to m-terphenyl derivatives via arylation of azolium salts
Harnessing the power of α-diazo compounds: emerging strategies and expanding applications
A facile route to cis-olefin-linked phosphino-phosphonium salts of the form: [Ph2PC(R)C(H)P(R′)2H][AlCl4]
Iridium catalyzed intramolecular cyclization of allyl alcohol-indole hybrids: rapid access to photoluminescent 5H-benzo[b]carbazoles
Covalently linked triarylborane–iridium(iii) complex as a photocatalyst for CO2 reduction
A copper(ii) metal–organic hydrogel as a heterogeneous reusable catalyst for the synthesis of 1,3-oxathiolane-2-thiones from the reaction of CS2 and epoxides
Metal–metal interactions in an open d-shell system with cuprite structure
Indole ring expansion into quinolines with TMSCCl3/TMSCBr3
Cu(ii)-catalyzed synthesis of 3-functionalized benzofurans via sequential nucleophilic cyclization and C–C bond activation
Electrochemical dehydrogenative intramolecular C–C coupling for expedient carbazole synthesis
Di-π-methane rearrangement in 1-phosphabarrelenes: formation and reactivity of an unprecedented 2-phosphasemibullvalene
Visible-light-driven cascade cyclization: a modular approach to functionalized 4-pyrrolin-2-ones
Concise synthesis of phosphonylated heteroarenes from nitroheteroarenes by dearomatization/elimination
Palladium-catalyzed Heck/polyfluoroarylation of alkene-tethered carbamoyl chlorides with polyfluoroarenes
Constructing stable solid electrolyte interfaces and facilitating Li transport via an electrolyte additive for lithium metal batteries
Size- and shape-selective substrate deuteration catalyzed by a water-soluble synthetic receptor
Direct palladium-catalyzed C–H arylation of bioactive triazolyl-C-nucleosides on a key position of the heterocyclic base
Photo-triggered tandem cyclization of arylethynyl quinazolin-4(3H)-one for difluoroalkylated quinolino[2,1-b]quinazolines
Visible-light-driven borylation and phosphorylation of aryl halides by phosphonium ylide organophotoredox catalysis
Visible light promoted oxygenation of oxazolidinones by an anthraquinone-resorcinol based donor–acceptor polymer as a heterogeneous photocatalyst
B2Pin2-enabled reductive thioesterification of aryl triflates with thiocarbonates
Predicting the glass transition temperature of conjugated polymers via cheminformatics from monomer structures
Regioselective C7 sulfinylation of 4-aminoindoles with sulfinates
Atom-efficient synthesis of BN-heterocycles from oligoboranes and isonitriles
Exploring the multifaceted applications of antimony(iii/v) corrole complexes
Utilizing an elemental sulfur and molecular hydrogen combination: cobalt silicate-catalyzed thiol synthesis from carbonyls
Iridium-catalyzed [(5+1)−1] annulation of pyridinium 1,4-zwitterionic thiolates and sulfoxonium ylides: a versatile platform to indolizines
Electrochemical synthesis of phosphorylated oxazolines from N-allylamides
Visible-light-induced energy-transfer-mediated hydroacylation of alkenes with alcohol-derived oximes
Oxidation of dihydrotetrazine triggered by near-infrared photocatalysis for photoclick chemistry
Se-Aryl-N-phenylphenoselenazinium salts: aryl radical precursors incorporating a photosensitizer unit
Solvent-regulated electro-oxidation of iodide and its electrocatalytic performance towards acetylacetone oxidation
Nickel-catalyzed hydroacylation of acrylates with carboxylic acids
Imidazopyridine substituted cyclic selenonium(iv) salts as chalcogen bond catalysts
Aggregation-induced emission in synthetic macrocycle-based supramolecular systems
Accessing diverse fluorinated organic molecules by fluoro-functionalization reactions of enaminones
Construction of dibenzo[1,4]oxazocines via palladium-catalysed arylalkylation of allenamides
Enhanced N-terminal glycine modification with electron deficient o-oxyacetate aromatic aldehydes
Viologen–cucurbit[n]uril supramolecular interactions: a comprehensive overview
General and versatile electrochemical α-C(sp3)–H amidation for N-Mannich base synthesis
One-pot electrochemical synthesis of N-trifluoromethylthio sulfoximines from sulfoximines via N-SCN intermediates
Room-temperature synthesis of 3-keto-iC/i-disaccharides from unprotected glycal donor ivia/i palladium-catalysed Heck-type reaction
Ruthenium(ii)-catalyzed C-2 alkenylation of indole with olefins via a quinazolin-4(3H)-one directing group: a platform for selective fluorescent anion sensors
Lanthanide complexes of aminopolycarboxylates reveal deuteration of aminoacetate carbons in alkaline aqueous media
(4+3) annulation of enone-tethered indoles with α-alkylidene succinimides: access to seven-membered azepino[3,2,1-ihi/i]indole scaffolds
Pillar[5]arene-based crosslinked covalent network for efficient heavy metal ion adsorption
Azides as an unconventional source of iminyl radicals: electrochemically induced synthesis of iO/i-imido oximes from benzyl azides and iN/i-hydroxyimides ivia/i N–O coupling
Synthesis of a highly strained deep cavitand
Sulfoxonium ylides as carbon radical precursors in three-component carbohalogenation of alkenes
Copper-mediated intramolecular C(spsup3/sup)–H amination of alicyclic amines: regio- and site-selective access to imidazolidin-4-one
KOsupit/i/supBu-mediated annulation for the pot-economical synthesis of quinazolinobenzoxazepines
Catalytic asymmetric construction of planarly and centrally chiral [2.2]paracyclophanes by combining photochemical and cobalt-catalyzed desymmetrization
A preorganized triarmed bis-triazolylpyridine-calix[4]arene with high affinity and selectivity for minor actinides for nuclear waste treatment
Photocatalytic Shono-type oxidation of iN/i-alkylamides with hydrogen evolution
Electrochemical seleno-/tellurocyclization of propargyl carboxylic acids
Nickel-catalyzed Barbier-type reaction of carbonyl derivatives with unactivated alkyl halides
Synthesis of 1,4-aminoalcohols from substituted dienes and anilines via molybdooxaziridine catalysis
Visible-light–enabled reduction of arylsulfonyl and benzoyl azides to access primary arylsulfonamides and benzoyl amides
Dithiane-initiated cascade to eight-membered sulfur-containing pyrazoles via decarboxylative aromatization
Isolation of 1,4,5,8-tetraazanaphthalene radicals
Thermolysis of bismuth(III) dithiolates toward cyclic disulfides with tunable ring size and near-unity conversion
Switchable synthesis of benzimidazole/quinoxaline C-glycosides with o-phenylenediamines and sulfoxonium ylide glyco-reagents
Esterification of carboxylic acids using carbon disulfide (CSsub2/sub) as a coupling agent
Cobalt(scpiii/scp)-catalyzed C–H functionalization of 2-arylthiazoles with maleimides or allyl acetate
Unconventional diastereoselectivity and mechanism of Cp*Co(iii)-catalyzed C–H functionalization of asymmetric dienes: a DFT perspective
Sulfonium triggered one-pot synthesis of dihydrofurans via [3+2] annulation of alkenes and active methylene compounds
Achieving a dramatic blue colour stability in anthocyanins bearing acylated sugars in position 3′,5′
Photochemical rearrangements of a [2.2]paracyclophane-based nitrene studied by vibrational CD spectroscopy
Divergent hetero-[8+n] higher order cycloadditions of tropothione and enals catalyzed by N-heterocyclic carbenes
Redox-associated phase transition of a marginally stable synthetic polymer
Low-coordinate calcium peroxide and oxide complexes
Phthalimide: a potential warhead for switchable and bioorthogonal conjugation
Potentially Prebiotic Isocyanide Activation Chemistry Drives RNA Assembly
Biphen[3]arenes based on V-shaped units: synthesis and macrocyclization-enhanced thermally activated delayed fluorescence
Scalable biocatalytic oxygenation of aliphatic amine derivatives using a class I unspecific peroxygenase
Hydroaminoalkylation of 1,3-dienes by dual photoredox and nickel catalysis
Zn3BSi5+: a two-layer molecular rotor with a planar pentacoordinate boron
A planar pentacoordinate sulfur atom
Organophotocatalytic acyltrifluoromethylation of unactivated alkenes enabled the efficient synthesis of CF3-substituted chroman-4-ones
Dimeric boron complexes bearing isoquinolyl-pyrrole ligands
Pd-catalyzed asymmetric (6+2) dipolar cyclization for medium-sized spirooxindoles
Light/copper catalysis in 1,2-alkylarylation of allylic alcohols with sulfonium salts involving radical 1,2-aryl migrations
Computational design of gallium imides for methane activation
Flow electrochemical oxidation of iN/i-nitrosamines to iN/i-nitramines
Lighting up peptides: direct dehydroalanine formation from diselenides ivia/i Rose Bengal photocatalysis
Three-component reaction of isocyanates and 3-aminoacrylates: selective synthesis of N-2-aryl-1,2,3-triazoles and hydrazones
Diastereoselective synthesis of 1,4-diaryl piperazines through the dimerization of 3-aminooxetanes with cooperative indium–diphenyl phosphate catalysis
Divergent synthesis of alkylphosphonate-containing indanes and indenes via norbornene derivative-controlled palladium-catalyzed three-component systems
Homologation of alkyl thiocyanates through photochemical group transfer radical addition (GTRA)
The Lewis basicity of amines on the Legault iodonium Lewis acidity scale
Unsymmetrical bis(anilido)xanthene ligands: development and use in the preparation of magnesium diamide complexes
Electrochemical hydrotrifluoromethylation of alkynes
Metal-free photocatalytic oxidative coupling of cyclic ethers and alcohols
A sulfonic acid-functionalized donor–acceptor conjugated organic polymer for enhanced photocatalytic hydrogen peroxide production
Unveiled open-shell nature of an antiaromatic molecule by surface–molecule interaction: a concept suggestion by spin-projected density functional theory
Palladium-catalyzed aromatic C–H alkylation of 1-naphthylamines with dichloroalkanes and its application in fused polycyclic amine synthesis
C(sp3)–H functionalization of N-protected dialkylpyrrole derivatives with azodicarboxylates
Dearomatization–scission–aromatization of anilines: En route to synthesis of 3,3-disubstituted oxindoles with a wide range of heteroatom nucleophiles
Palladium-catalyzed tandem cyclization reaction: access to isoxazoline-benzofuran bis-heterocycles
Electrochemical oxidative cleavage of C(OH)–C bonds for sustainable synthesis of esters
Calcium(scpii/scp)-catalyzed [2+3] annulation of enynones: a sustainable approach to 9iH/i-pyrrolo[1,2-ia/i]indole frameworks
Decarboxylative chlorination of α,β-unsaturated acids
Cascade C–H functionalization/annulation of arylamides: access to succinimide-tethered isoquinoline-1,3-diones
Environment-sensitive fluorescent tryptophan analogues ivia/i indole C-2 alkenylation reactions
A pillar[5]arene- and calix[4]pyrrole-based supramolecular polymer for selective removal of naphthols from water
Decarboxylative sulfinamidation of N-sulfinylamines with carboxylic acids via a photochemical iron-mediated ligand-to-metal charge transfer process
Light-switchable divergent C–H activation and cross-coupling of cyclic ethers with aromatic aldehydes
C–H functionalisation of [2.2]paracyclophane under copper catalysis
A Mn(scpiii/scp)-catalysed domino process for C-3 substituted dihydrocoumarins from 2-hydroxybenzyl alcohols and 4-hydroxy-2iH/i-chromen-2-ones
Nickel-catalyzed sequential 1,2-iN/i-migration/BCBs ring-opening to access spirocyclobutyl β-amino acid esters
Diphanes: cage-like compounds featuring two cavities
Angle-controlled synthesis and redox properties of a tetraphenylethene-based hexacationic triangular macrocycle
Acid-triggered cascade cyclization pathways of enynes: A rapid access to fused polycyclic products
Photoredox radical Truce–Smiles rearrangement of N-sulfinyl acrylamides with sulfoxonium ylides
Electrochemically driven direct C–H difluoroethylation of (hetero)arenes under metal/catalyst-free conditions
Total synthesis and algaecidal activity of questiomycins against harmful bloom forming dinoflagellates
Organophotoredox-catalyzed deconstructive alkylation/Truce–Smiles rearrangement cascade involving spiro-dihydroquinazolinones and activated alkenes
Kinetics and thermodynamics of CO2 binding to a metal centre promotes CO2 reduction
Pd-catalyzed enantioselective reductive Heck reaction of mono-fluoro, igem/i-difluoro, and trifluoromethyl tethered-alkenes
Engaging visible light-induced triplet sensitization towards intramolecular [4+2] cycloadditions of naphthalenes and quinolines
Electrosynthesis of a cyclo-N5− anion via TEMPO-mediated selective C–N bond cleavage in aryl-pentazole
Rhodium(iii)-catalyzed oxidative [3+2] annulation of arylboron reagents and 7-azabenzonorbornadienes via transmetalation-initiated C–H activation
Electron donor–acceptor complex of aryl sulfonium salt enabling hydrogen/halogen atom transfer: C(sp3)–H alkylation of glycine derivatives and late-stage modification of peptides
Diastereo-, enantio-, and chemoselective sequential allylations of iN/i,iN/i′-alloc 3,3′-dimeric 2-oxindoles: formal total synthesis of (–)-idiospermuline
Electrochemical synthesis of cyclic sulfites using diols and sulfur dioxide
Synthesis of ferrocenyl/phenyl isothiazole-3-thione and isoselenazole-3-selenone as new heterocycles
One-pot synthesis of primary phosphines from white phosphorus
Visible-light-induced radical 1,2-aryl migration in diaryl allyl alcohols for efficient synthesis of 1,5-dicarbonyl compounds
Dearomatization [4+2] cycloaddition for constructing bridged polycyclic lactams
Switching between type I/II photosensitization processes for of an unconventional dye as modulated by the tumor microenvironment for inducing immunogenic death
Asymmetric total syntheses of immunosuppressive diterpenoids triptobenzenes N and R ivia/i a remote Cspsup3/sup–H functionalization
Electrochemical iS/i-vinylation of sulfinamides with β-bromostyrenes
Twisting of aryl groups affects thermal back reactivity of diarylbenzene photoswitches
Catalyst-free efficient synthesis of functionalized 1,2,4-triazole ivia/i ring opening/cyclization of arylidene thiazolone with aryl/alkyl-hydrazine
Palladium-catalysed carbonylation of aryl diazonium salts to access bioconjugation-ready esters
Electrochemical site-selective C(sp3)–H amination of alkyl substituted indoles and pyrroles
Spiro-fluorene-indenoindenyl-Ir(scpi/scp) complex-catalyzed, 1,3-azole-directed C(spsup3/sup)–H borylation with pinacolborane
Revisiting 3-azidoindoles: overcoming the trade-off challenges between stability and reactivity of iin situ/i-generated azidoindoles
Structure and reactivity of a triflimide-bridged bis(trimethylsilyl) cation
Geminal homologative fluorination of carbonyl derivatives ien route/i to 1-fluoro-2-haloethyl skeletons
Synthesis of cyclopropanes ivia/i palladium-catalyzed [2+1] annulations of sulfoxonium ylides and norbornenes
Asymmetric synthesis of venezuelaene's core with a trans-fused [5-5] ring system
Copper(scpii/scp)-mediated metalloradical activation: denitrogenative/decarboxylative annulation to 3-arylimidazo[1,2-ia/i]pyridines using tetrazolo[1,5-ia/i]pyridines and cinnamic acids
Halogenase-mimicking selective chlorination of unactivated C–H bonds by a Fe-complex
Regioselective construction of pyrido[1,2,3-ide/i]quinoxaline-2,5-diones through acid-mediated post-Ugi rearrangements
Development of electronically tuneable N-heterocyclic borates
Synthesis and isolation of less stable cyclopropene-1-carboxylates
Encasing the paramagnetic copper(scpii/scp)-ion by the ring-contracted corrin ligand of vitamin Bsub12/sub
Electrochemical synthesis of PhSe/CF3-containing dibenzazepines via radical cascade cyclization of alkynes
Diastereoselective synthesis of succinimide-fused polycycles ivia/i intermolecular interception of indanone–allene intermediates with maleimides
Stereoselective synthesis of chalcogen-tethered iγ/i-lactams ivia/i 5-iexo-dig/i cyclisation under visible-light irradiation
Macrocyclic skeletal modification approach to the anti-trypanosomal macrolides, actinoallolides
Cusup(I)/sup/Pdsup(0)/sup cooperative catalysis enabled regioselective C(spsup2/sup)-carboboration of 1,3-diynes
Pseudorotaxane monolayers of pillar[5]arene and linear fatty acids at the air–water interface
Divergent [3+2] annulations of oxime acetates with thioaurones/aurones leading to benzothiazino-/benzoyl-pyrroles
C–H bond activation of fluorene over a TiOsub2/sub photocatalyst by ligand-to-metal charge transfer under visible light irradiation
Visible-light-induced radical 1,3-hydrosulfonylation of allylketones with sulfonyl chlorides
Syntheses and characterisation of terephthalonitrile radical salts
A Pd-tannic acid-loaded ceramic catalytic membrane for the flow-through Sonogashira reaction
Cyclometallated phosphonium ylide-based iridium(iii) photocatalysts
Efficient photocatalytic C-3 thiocyanation of indoles over tetraphenylsilane-based porous aromatic frameworks
Efficient supramolecular artificial light-harvesting systems based on an AIE-active calix[4]arene derivative for cross-dehydrogenative coupling reaction
Alkylaluminium-catalyzed regioselective hydrophosphinylation of α,β-unsaturated ketones into γ-ketophosphine oxides
Visible-light-induced radical switching using benzothiazolyl sulfides for geminal carbon–carbon bond formation
Visible-light-driven oxidative coupling of arylhydrazines with sulfinates catalyzed by polyoxometalates for aryl sulfone synthesis
Enhancing the CuAAC efficiency of a Cu(scpi/scp)–NHC complex in biological media by encapsulation
Lewis acid-promoted cascade reactions of cyclopropenes: a unified approach to stereoselective synthesis of cyclic ethers and oxaspirolactones
Photoredox catalyzed three-component tandem cyclization of 1,5-dienes with α-keto acids and water to access pyrrolidinones
Unexpected cyclization of β-(hydroxymethyl)phosphole into 1-phospha-1,6a-dihydrophosphapentalene: a fused 1,3-butadiene-based luminophore
Cascade heteroarylation/annulation of arylphosphonic acid monoesters with benzothiophenes: access to benzothieno-fused oxaphosphacycles
Donor/acceptor-substituted radiaannulene segments of 6,6,12-graphyne
Copper-catalyzed three-component radical aminoazolation of vinylarenes with N-fluorobenzenesulfonimide and trimethylsilylazole derivatives
Reduction of nitrobenzene to phenylhydroxylamine with anthraquinone-2-sulfonic sodium as an electron mediator
Solvent-free photochemical formation of cubane-type Ru complexes from organometallic ionic liquids with cyanoborate anions
Oxidative N-functionalization of primary sulfonamides with aliphatic aldehydes: a green synthesis of α-sulfonamido acetals
Highly regio- and diastereoselective (3+3)-cycloannulation of carbonyl ylides and 2-(1-alkynyl)-2-alken-1-ones enabled by silver catalysis
Nickel-catalyzed reductive coupling of α-haloboronates to access internal vicinal bis(boronate) esters
Cascade C–H functionalization/annulation of 2-aryl-1,3-dicarbonyls with Morita–Baylis–Hillman adducts: access to α-iso-/benzochromenyl acrylates
Oxidative [3+2] annulation of activated pyridines for the synthesis of indolizinyl sulfonyl fluorides: a class of important pharmacophores
Visible-light triggered Cu-catalyzed C–H bond activation to afford isocoumarin and isoquinolinone scaffolds at room temperature
Radical [3+2] Cycloaddition Enables Polysubstituted Pyrrole Synthesis via Visible-Light-Mediated
Boramidine: A boron-based photoacidic fluorophore
Visible-light induced 1,2-dicarbofunctionalization of alkenes with quinoxalin-2(1H)-ones and malonic esters
Pillar[5]arene-based ionic single crystals formed by dual self-assemblies through host–guest and ionic interactions for iodine capture
Transition metal/photocatalyst-free skeletal editing of indene with iodonium difluorodiazo reagent to access 2-(difluoromethyl)naphthalene
Direct N-methyl C–H esterification of O-tosyl hydroxamates to enable facile synthesis of hemiaminal esters
Coupling Dy3 toroics in macrocycles
Electrochemical C–H functionalization reaction of N-heterocycles with alkyl iodides
Dual-nickel/photoredox-catalyzed acylation of spiro-dihydroquinazolinones with carboxylic acids via an aromatization-driven deconstructive strategy
Visible-light-driven decarboxylative C(sp3)–H alkylation of glycine derivatives via in situ formation of NHPI esters
Visible-light-driven photocatalyst-free deoxygenative homologation of alcohols to access tertiary alcohols
Carbene-organocatalyzed enantioselective [5+5] annulation of dienols and dienals towards tetrahydroisochromen-1-ones
An Ir(ppy)3 encapsulated metal–organic tetrahedral cage for photocatalytic dehydrogenation cross-couplings
Organocatalytic asymmetric electrophilic tandem selenylation semipinacol rearrangement of 1-(1-arylvinyl)cyclobutanols
Dearomatizative aminoetherification and diamination of indoles enabled by photochemical nitrene transfer reactions
Reductive alkylation of azoarenes to iN/i-alkylated hydrazines enabled by hexafluoroisopropanol
Acyl migrations sensitive to supramolecular encapsulation
Dual ipso-hydroxylation and para-C–H chalcogenation of arylboronic acids using an NDI photocatalyst in visible light
Modifications of terpenoids via inert aliphatic C–H bond heteroarylation with heteroarenes
Site-selective alkylation of electron-deficient aromatic cycles: visible-light photoredox-catalyzed radical di-functionalization of [1.1.1]propellane
Amphoteric tetrazole-substituted eleven-ring-fused acene derivatives with multiple fluorescent protonation states
MHAT-enabled cascade radical annulation to access iN/i-fused indoles and pyrroles
Substrate-controlled regioselective C(spsup2/sup)–H sulfonylation of iortho/i-aminophenols
Arylative double bond transposition of allylic alcohols ivia/i silicon-tethered intramolecular benzyne–ene reactions
Conversion of simple alkenes into 1H-1,2,3-triazolium salts by oxidative cycloaddition and subsequent dehydrogenation
A TBADT-enabled photo-induced radical cyclization pathway: concise access to functionalized oxindoles
Stereoselective construction of 5-6-5 aza-tricyclic scaffolds ivia/i catalytic asymmetric aza-Piancatelli/Diels–Alder reactions
Asymmetric synthesis of quinolinone-based polycyclic indoles through [1,3]-rearrangement/cyclization reaction
Dispersion-controlled C6-selective C–H borylation of indoles
DNA-inspired design of organic electrode materials for high-performance aqueous Zn-ion batteries
Carbazole-functionalized MOFs for efficient selective photocatalytic oxidation of thioethers to sulfoxides
Palladium-catalyzed sequential [3+2] cyclization/C–H activation of o-iodostyrenes with cyclopropenones as C2 synthons
Thiocyanate: a visible-light-driven traceless auxiliary for stereoselective cyclopropyl ketone construction
Multi-cavity discrete coordination cages encapsulating up to four units of pyrazine-N,N′-dioxide: molecular soybeans
A multi-stack porphyrin oligomer with three cleft-like cavities for efficient guest encapsulations
Confinement-supported aurophilic interaction
Zinc(ii)-catalysed cyclocondensation of oxime ethers triggered by polarity inversion: construction of fused pyrroles
Stereoselective synthesis of C-glycosides from glycals and organotrifluoroborate salts
Harnessing phosphorus-centered radicals for the synthesis of cyclopenta[b]indole and pyrrolo[1,2-a]indole frameworks
PCP and POCOP complexes of calcium
On the sulfide oxidation to sulfoxides using sodium orthovanadate in water
Dicationic dibenzo[1,4]azaborine with an open-shell electronic structure
Rh-catalyzed [3+3]-annulation of quinolines with cyclopropenones: access to functionalized 2-quinolones
Organocatalytic atroposelective fluorooxindole addition to coumarin Michael acceptors
Visible-light-initiated selective synthesis of thiolated-, sulfoxinated-, and sulfonated benzoxazines from N-(2-vinylaryl)amides and thiols
Recent advances in chiral recognition using macrocyclic receptors
Dearomative 1,6-enyne cycloisomerization of alkyne-tethered benzofurans and indoles via a 6-endo-dig cyclization
Facile synthesis of R4NF(HFIP)3 complexes from KF and their application to electrochemical fluorination
Harnessing visible light for metal-free trifluoromethylation/cyclization of unactivated alkenes
Unveiling the CO2 electrocatalytic mechanism in ionic liquids via real-time AFM and voltammetry
Copper-catalyzed multicomponent polymerization of elemental selenium for regioselective synthesis of poly(5-diselenide-triazole)s
Electrochemical reaction of indole-tethered alkynes enabling stereoselective synthesis of iodovinyl spiroindolenine-cyclopentanes
Visible-light-induced acridinium-catalyzed selective N-dealkylation of N-heterocycles
Circularly polarized luminescence from decamethylcucurbit[5]uril-triggered chiral supramolecular hydrogels
Direct hydroacylation of arylacrylonitriles toward β-ketonitriles assisted by an EDA complex
Bioinspired single-atom nanozymes for microplastic degradation
Photoinduced Ni-catalyzed carbohalogenation of monofluoro, gem-difluoro, and trifluoromethyl tethered alkenes
Structural isomers of imine-linked covalent organic cages with divergent photocatalytic properties
Nickel-catalyzed enantioselective reductive iminodisulfuration of alkene-tethered oxime esters with dithiosulfonate
Regulating photochromic behavior of a cyanostilbene by cucurbit[n]uril hosts in aqueous solution
Palladium/norbornene cooperative catalysis triple functionalization: carbamoylation/double-annulation of (hetero)aryl iodides
Facile synthesis of 1-silaacenaphthenes by transition metal-catalyzed intramolecular C(sp3)–H silylation
[18F]Radiolabeling fluorination of monofluoroalkyl triflates for the synthesis of [18F]difluoromethylated alkanes
Remote radical alkynylation of unactivated C(sp3)–H bonds of ethynesulfonamides
Metal cations switch geometry of β-cyclodextrin complexes
Harnessing sulfilimine as an oxidizing directing group in Cp*Co(iii)-catalyzed [4+2] annulation with alkynes and 1,3-diynes
A dual-radical process for tri/di-fluoromethylarylation of alkenes enabled by indirect electroreduction
Rhodium(iii)-catalyzed directed C–H naphthylation of aryl esters with 7-oxabenzonorbornadienes
The reaction between CO2 and chloroform in anion-functionalized ionic liquids with the formation of trichloroacetates
The facile preparation of mixed-valence metal–organic frameworks through reduction
Electrochemical oxidation of propargyl alcohol: rapid access to an unprecedented dioxo-orthoester under mild conditions
Cu-catalyzed borylative cyclization of N-(o-alkynylaryl)imines
Photocatalytic reductive incorporation of carbon dioxide into double bonds
Visible-light organophotoredox-catalyzed fluoroalkyl aminoxylation of unactivated and activated alkenes
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Jahn–Teller distortion controls electron transfer in photoexcited Cu(i) donor–acceptor systems
Three wrongs make a right: a computational investigation of [4n]–[4n]–[4n] fused π-systems
Lipid-donor-anchored genome mining uncovers dioxanopeptins, antibacterial lipopeptides with a 1,3-dioxane functionalized polyunsaturated lipid tail
Polarization-induced reversible electron–hole migration and redox reaction switching in ferroelectric single-atom photocatalysts
Non-covalent assembly-enabled selectivity in aqueous microdroplets
Al(ii) transfer harnessing a well-defined cadmium precursor
Regioselective synthesis of aza-saccharins via anionic [1,4] Fries-type rearrangement of aryl sulfonimidoyl fluorides
Non-radical pathways control methane sulfonation versus oxygenation C–H functionalization selectivity with Hg(ii) and Au(iii) catalysis
Peptide–based artificial cytoskeleton enhances colocalized cascade reactions in cell-like microreactors
Diboron- and digermanium-doped dihydrodibenzohexacenes: Ge–B exchange to access boron-doped extended acenes
Asymmetric synthesis of planar-chiral metacyclophanes via aromatic amination enabled enantioselective desymmetrization
Supramolecular protecting groups can impart prosthetic stereoselectivity to catalytic systems employing unmodified achiral heterogenous catalysts
Electrochemical control enables high-concentration, one-pot macrolactonization
One-pot multi-substrate screening of ligation reactions using PNA tags
Acridinium amidate as a hydrogen-bonding photocatalyst for direct decarboxylative alkylation of native carboxylic acids
Photoinduced deacylative epoxidation of ketone derivatives with allylic peroxides
Through-space donor–acceptor homoconjugation strategies for emissive radical species
Taming boroloborinines: toward photostable polycyclic antiaromatic hydrocarbons
Direct metathesis of carbon–carbon σ-bonds at a versatile macrocycle-supported diiron platform
A general route to β,β-carbocyclic sidechains in peptides: an aqueous metallaphotoredox approach driven by green light
Metal-free deoxygenative borylation of pyrazinyl ethers via an unusual boron-walking mechanism
eCyclopropanation – a safe and scalable electrochemical route to cyclopropanes
Stereospecific alkenylation of carboranes: copper-catalyzed access to pyridylcarboranyl alkenes
Deoxygenative phosphonation of ketones by titanium
Pushing the boundaries of BODIPY chemistry: 2-(dimethylamino)methyl BODIPYs as enablers of diversification with nucleophiles
A new class of customisable stable boronic ester assemblies
Synthesis of bacteriochlorophyll a
Stepwise B≡N bond cleavage by isocyanides: access to the 3-azaborole structural motif
Photochemical cyclization of α-amino esters to access 3-azetidinones
Reductive desymmetric silylation of biaryl bis(triflates) enabled by a chiral nickel/picolinamide complex
High brightness in bis(tri-isopropylsilyl)ethynyl-functionalized polycyclic aromatic hydrocarbons: localized representation versus Clar's model
Vibrational snapshots of ultrafast C–H bond photoactivation inside a water-soluble nanocage
Wavelength-resolved heterodimer [2 + 2] photocycloadditions for reversible surface grafting
A mechanochemical route to triazatrinaphthylenes: building blocks for π-extended, nitrogen-enriched two-dimensional metal–organic frameworks
From alkynes to spiroindole δ-lactams via a copper-nitrenoid intermediate featuring unusual 1,1-addition and high Z-selectivity
Nickel-catalyzed hydroxymethylation with α-silicon N-methoxyphthalimides via radical Brook rearrangement
Negative cooperativity in the formation of two H-bonds with an oxygen H-bond acceptor
Heterogeneous photocatalytic C4 remote fluorosulfonamidation of pyridines
On-complex three-component cascade reactions involving phosphorescent cyclometalated Ir(iii) chloro-isocyanide complexes, nitriles, and propylamine
Neutral anion-detecting organic cages based on anion–π interactions
Remote α- and β-C(sp3)–H alkenylation of amines via visible-light supported paired electrolysis
Making room for reactivity in topochemical transformations under pressure
Undirected ruthenium-catalyzed C–H activation using arylsulfonium salts: direct arylation without ruthenacycle intermediates revealed by computation and data science
Enantioselective electrophilic α-fluorination catalyzed by an artificial metalloenzyme
Highly stereoselective synthesis of allylic β-lactams via enzymatic C(sp3)–H amidation
A dicationic ionic liquid strategy to enhance the thermal stability of manganese bromide scintillators
A visualizable and widely applicable steric repulsion descriptor for guiding experimental chemistry
Toward functional and structurally complex Frank–Kasper phases via creating concavities on supramolecular micelles
Solvent-controlled, chemodivergent oxidative anionic Fries rearrangement of O-aryl carbamates under aerobic conditions
Non-innocent behaviour of aromatic isocyanides under visible light: a pathway to thioformimidates and dehydroalanine
Alumanyl silanides as multifunctional reagents for olefin cycloaddition, CO hydrosilylation, and reductive CO coupling
Abiotic formation of nitrile precursors to amino acids and nucleobases in interstellar ice analogues
Water-enhanced electrochemical hydrogenolysis of aryl C–O bonds
Probing the weak interaction between silver and boron
Widely-used boronic esters as synthetically-versatile directing groups for C–H activation and hydrogen isotope exchange
Self-induced charge transfer activation enables metal-free C–H coupling of polycyclic aromatic hydrocarbons under photo irradiation
Interplay between diradical character, aromaticity and conductance in oligothiophenes
Hypervalent chalcogenonium organocatalysis for the direct stereoselective synthesis of deoxyglycosides from hemiacetals
Expanding the chemical space of peptides via biocompatible tryptophan C7-arylation
Photoinduced intramolecular S-α-C(sp3)–H functionalization enabled by an electron donor–acceptor complex-Mediated radical relay
Red-light photoredox catalysis with bridged fluorescein derivatives: mechanistic insights and application to fluoride-responsive photopolymerization
Fully protected pyrophosphates via phosphorobromidates for the synthesis of biopolymers
Rh(iii)-catalyzed heteroannular-selective heteroarylation of biaryls: facile access to heteroacenes with sulfur-embedded 5–7 ring topology
Photocatalytic CO2 reduction using a diazabenzacenaphthenium photosensitizer and a Mn catalyst
Cation radical-mediated semi-pinacol and n+2 ring expansions via organic photoredox catalysis
Expanding the chemical space of ionic liquids using conditional variational autoencoders
Controllable copper-catalysed photo-induced carbonylative cyclization to access dihydroquinolinones and oxindoles
A general aqueous synthetic strategy towards 1-benzylTHIQs enabled by umpolung hydrazone
Selective photocatalytic oxidative cleavage of terminal alkynes to carboxylic acids within a water-soluble Pd6 nanocage
Bead mill-driven acceleration in catalytic methanolysis reaction of poly(ethylene terephthalate) toward low-energy chemical recycling of polymers
A difluorocarbene-triggered annulation/ring expansion cascade via sequential single-atom-insertions: direct assembly of 2-fluoroquinazolinones from azo compounds
Unlocking radical reactivity of cyclic diaryl λ3-chloranes through NHC-catalyzed three-component coupling
Automated closed-loop continuous flow block copolymer synthesizer
Stereodivergent access to α- and β-azanucleosides via catalyst-free, achiral modulator-controlled iodocyclization: a concise synthesis of forodesine
Controlled intra- and extracellular localization of bioorthogonal polymeric nanozymes
L-region-selective annulative π-extension through dearomative activation of polycyclic aromatic hydrocarbons
Why is a dicationic digallene so reactive towards activation of strong covalent bonds? Scope and mechanistic investigations
Isolation of arylhalodiphosphenes: periodic trends in R–P[double bond, length as m-dash]P–X bonding (X = Cl, Br, I)
Steric augmentation of three-coordinate Cu(i) β-diketiminate isocyanide chromophores to achieve microsecond excited-state lifetime
Gas-phase synthesis of the bicyclic silicon tricarbide molecule (c-SiC3) as a precursor to silicon carbide nanoparticles in space
A Polycondensation–depolymerization strategy enables closed-loop recyclable polyoxalates via ring-opening polymerization of six-membered cyclic oxalates
Photocatalytic construction of N-acyl-N,O-acetal-linked pyridines via aminocyclopropane ring opening
Reductive rearrangement of substituted quinolines to 2,3-disubstituted indoles enabled by water activation
Visible light-induced 1,2-alkoxy shift of α-diazoacetates for Wolff rearrangements – access to oxyketenes
Characterization of the ketoreductase domain of pikromycin module 2
Guest-induced emission enhancement in the permanent porous conjugated carboracycle crystal
Modular synthesis of benzothiophene-fused pentalenes reveals substituent-dependent antiaromaticity
N-Arylsulfonamidocalix[4]arenes with narrow pH-responsive binding near neutral pH
A donor–acceptor photosensitizer-catalyst dyad for light-driven nicotinamide hydrogenation
N-terminal protein-macrocycles enabled by conjugate addition/ring expansion cascade reactions
Diastereoselective synthesis of cyclopropyl sulfoxides via hydrosulfenation
Visible photon energy storage by [2+2] cycloaddition of Pd-oxazolones
HCl-mediated silylation of C–H bonds in (hetero)arenes with trialkylsilanes
Uncovering outer-sphere mechanisms governing chemoselectivity in copper-photocatalyzed ATRA reactions of CF3SO2Cl with alkenes
Directing robust built-in electric fields via imine linkage orientation in COFs for efficient dehydrogenative organic transformation coupled with H2O2 photosynthesis
Peptide ligand isomerism drives divergent stability and guest binding in Pd3L4 metal-peptidic cages
Intramolecular exciton coupling modulates the convergent singlet-triplet energy gap toward NIR-emissive heavy-atom-free Oligo-BODIPY photosensitizers
Se-catalyzed enantioselective lactamization enabled by a N-fluorosulfonyl group: total synthesis of diaporisoindole A
Visible-light-mediated synthesis of 2-oxetanes via Giese addition to α-oxy radicals
On-surface synthesis of nitrogen-doped nanographenes assisted by self-assembly
Conformational adaptability enabled higher-order self-sorting processes in coordination cages
Chiral Lewis base/Lewis acid/Brønsted acid cooperative catalysis enabled regio- and enantioselective electrophilic sulfenylation/semipinacol rearrangement of allenols
Boraindenes as versatile precursors to benzannulated boron heterocycles
Metal ligand cooperativity in the direct carboxylation and esterification of terminal alkynes by Cu-CNC complexes bearing 2,6-lutidine linkers
Shining light on the mechanism of photochemical alkene formation in vitamin B12
Solar-driven upcycling of plastic waste using plasmonic black gold
Isoenergetic symmetry breaking charge separation in far-red absorbing orthogonal BODIPY dimer – a classic case of no energy loss during the process of light capture and conversion
Interfacial photocycloaddition polymerization: a synthetic approach for structurally functionalized degradable polymer particles from naturally derived monomers
Pyrene-based conjugated porous polymers as photocatalysts for oxidative cycloaddition of phenols
Unveiling the molecular dynamics of a nitrile-containing 5-lipoxygenase-activating protein antagonist in primary macrophages through Raman spectroscopy
Metal-free visible-light carbonylation of alkyl iodides to amides via consecutive photoinduced electron transfer
Biomimetic sulfur-catalyzed carbonyl transfer enables the carbonylative difunctionalization of unactivated alkenes
Fully automated and high-fidelity robotic platform enabling accelerated discovery of nanocatalysts
Ag-triggered Co4+ active sites enable OH* nucleophilic attack for efficient electrocatalytic oxidation of alcohols to acids
Chemoselectivity in the cationic Phospha-Wittig reaction: accessing phosphorus heterocycles, phosphaalkenes, and their annulated [4 + 2] dimers
Heteroaryl iminothioindoxyl (HA-ITI) photoswitches via regioselective aza-Wittig synthesis: unifying red-shifted absorption, large E/Z band separation, and tunable thermal recovery
Unusual nitrene reactivity: imine formation in the photochemical reaction of a borylnitrene with ethene
Halogen bonding-induced 1,3-carbohydroxylation of allyl carboxylates via 1,2-cationic acyloxy migration (1,2-CAM)
Asymmetric vicinal C(sp3)–H difunctionalization of saturated cyclic amines via synergistic photoredox, copper and chiral phosphoric acid catalysis
Ru(ii)-catalyzed regioselective (3 + 2)-annulation of anilines with allenes to access 2-vinylindoles
Cooperative borane activation by tuning hemilability of different Os-κ2-N,Se-chelated complexes
Catalytic asymmetric P(III)-additions to salicylaldehydes enable divergent stereoselective dearomatizations of phenols
Photoredox catalysed reductive cleavage of dibenzothiophene dioxides enabled by a temperature-controlled photoreactor
Efficient and rapid cell surface functionalization: a sub-minute selenol-yne click reaction for bioconjugation
DiICz MR-TADF emitters as potent energy transfer photocatalysts
Cu-catalyzed enantioconvergent oxygen-centered radical cyclization
Extended white-box cyclophanes for the synthesis of mechanically interlocked derivatives of single-walled carbon nanotubes in water
Palladium-catalyzed amidocarbonylation of thioethers: access to α-amide-substituted thioether derivatives
CO-to-sugars conversion from one-pot two-step electro-organocatalytic process
Acetic anhydride as a versatile carbon source in carbonylation reactions
Compositional selection of phospholipid compartments in icy environments drives the enrichment of encapsulated genetic information
Thiyl radical reversible-deactivation polymerization via degenerative transfer with vinyl sulfides
Photocatalyzed hydrogen atom transfer enables multicomponent olefin oxo-amidomethylation under aerobic conditions
Chemo- and atroposelective Boc protection for asymmetric synthesis of NH2-free axially chiral biaryl amino phenols
Regioselective C(sp3)–H borylation via a diarylboryl anion surrogate in sp2–sp3 diboranes(5)
Synthesis of wave-shaped Cu(ii) porphyrin arrays and their electrocatalytic hydrogen evolution activity
Pd-catalyzed regiodivergent arylation of cyclic allylboronates
Access to allyl-gem-difluorides via allylation and Cope rearrangement
Sequential oxidative dearomatization/asymmetric homologation: from simple naphthols to chiral benzocycloheptanes
Narrowing emission spectra based on indolocarbazole molecular model system: an experimental and theoretical study
Diselenide-enabled photocatalytic hydroazolation of gem-difluoroalkenes
Photogenerated-radical cyclopropylation of in situ generated iminiums mediated by NaI/PPh3: direct access to α-cyclopropyl tertiary alkylamines
MMP-cleavable linker platform for tumour-responsive homo- and heterobivalent antibody–drug conjugates
A neutral homoaromatic heavy allene as a platform for selective conversion to a germylene-coordinated digermavinylidene
Watch out electrons!: positron binding redefines chemical bonding in Be2
Palladium-catalysed asymmetric annulations of Morita–Baylis–Hillman carbonates with allenes or alkenes via migratory insertion
Synthesis and separation of two stereoisomers of deuterated tetrasubstituted allylic alcohols via consecutive dual 1,2-metallate shifts
Friedel–Crafts acylation via interrupted Beckmann fragmentation of activated ketones
Supramolecular host–guest modulated thermally activated delayed fluorescence for photodynamic therapy
Interfacial polarization enables dual pathways for electrosynthesis of propyl acetate
Thinking outside the library: cluster synthesis of diverse molecules on a single robotic platform
Enantioselective synthesis of vicinal amino alcohols promoted by fluorine-containing counteranions
A 4,4′,4″-nitrilotriphenoxyl radical derived from Yang's biradical
N-centered, yet persistent: isolation of N2O-based radicals through FLP-type stabilization
Palladium-catalyzed carbonylative synthesis of acrylamides from alkenyl thianthrenium salts
Carboxylate positional isomerism in metallacycles governs hierarchical assembly pathways
Heterologous expression of an in planta-upregulated gene cluster in the wheat pathogen Parastagonospora nodorum establishes the biosynthesis of methylene-bridged depsides
Single atom-bridged Au nanozymes boost glucose oxidase-like activity in acidic media
SynTwins: a retrosynthesis-guided framework for synthesizable molecular analog generation
Acyl-oxyallenes as α,β-unsaturated ketone surrogates for Giese radical addition
Enantioselective copper-catalysed defluorinative alkylation of polyfluoroarenes with alkenes and 1,3-dienes
Genetically encoded green-light-responsive photocaged lysine for sequential control of protein function
Spatially confined single-molecule folding achieves multicolor phosphorescence
Borate intercalation optimizes the electro-oxidation kinetics of α-Ni(OH)2 nanosheets for selective electrochemical conversion of benzylamine to benzonitrile
Photocatalytic generation of alkoxysulfonium ions for selective oxidation of benzylic/allylic halides to carbonyls under base-free conditions
Inherently chiral homo-heteracalixarenes: design and synthesis via an enantioselective intramolecular Sonogashira cross-coupling reaction
Oxidative rearrangement of alkynes to chiral α-arylalkanoic esters
A photochemical strategy for aromatic nitrogen ortho-isomerization
Catalytic asymmetric synthesis of indole-based atropisomers bearing silicon-stereogenic centers
Unraveling the role of counter-cations in Pd-catalyzed carboxylic acid C–H activation
<atl>Nickel-catalyzed decarbonylative addition of acylsilanes across alkynes ivia/i the cleavage of a carbon–silicon bond</atl>
Visible-light induced click reactions of acylsilanes with pyruvate electrophiles
Aromaticity switching by quantum tunnelling
High-valent sulfur fluorides as reactivity switches for PFAS-free benzene–azepine skeletal editing
Synthesis of dibenzoarsole derivatives from biarylborates via the twofold formation of C–As bonds using arsenium dication equivalents
Insights into the initial steps of the thiamin pyrimidine synthase (ThiC)-catalyzed reaction through EPR spectroscopic characterization of radical intermediates
Intermolecular transposed Paternò–Büchi reactions enabled by triplet sensitization
Organic–inorganic perovskite ferroelectric catalytic selective alkyne coupling under ultrasound sonication
A printable, unimolecular, core–shell polymer bottlebrush-based signal transducer using solvatochromatic reporting
Droplet-mediated kinetic-to-thermodynamic transition for the fabrication of uniform 1D and 2D nanostructures from conjugated homopolymers
A radical strategy to the synthesis of bicyclo[1.1.1]pentyl C-glycosides
Activatable self-reporting cyclization reaction for in-cell synthesis of cyclocyanines
Interstellar formation of 1,2-propanediol (CH3CH(OH)CH2OH) and 1,2-ethenediol (HOCHCHOH)—key precursors to sugars and sugar derivatives
A self-assembled macrocycle with a non-closed structure for hierarchically upgraded self-assembly
An Intelligence Programmable Intrathecal Injection System Based on Tween 80-Confined Halide Perovskite Optoelectronic Memristor
Synthesis of chiral lactams by asymmetric nitrogen insertion
Pd-catalyzed sequential distal C–H alkenylation and π-allylic amination of arylacetic acids using MBH acetates: access to macrocyclic lactams
Cis-difluoromethyl hetarylative dearomatization by a radical docking-migration cascade
A facile route to ‘naked’ Ag+ ions enabling the coordination of the weak Lewis base Ni(CO)4
Nickel-catalyzed aminocarbonylation of aryl chlorides enabled by a newly designed CO source
Chelation-assisted multiple and relay C–H functionalization of unactivated aliphatic E-alkenes
1,2-Hydrogen atom transfer of aminyl radicals under photoredox catalysis for the synthesis of α-amino phosphine oxides
Design and synthesis of macrocycles with tuneable diameters and helical foldamers with customizable peripheral side chains
Exploring the formation of medium-sized cyclic amines within self-assembled yoctoliter inner-spaces
Catalytic asymmetric construction of remote P or other heteroatom (Si/S) stereogenic axially chiral scaffolds
Distinct hydrogen atom transfer and radical capture reactivity of copper(iii) OH/F complexes enables site-selective C(sp3)–H 18F-fluorination
Imaging intracellular zinc by stimulated Raman scattering microscopy with a small molecule vibrational probe
Electricity-driven site-selective deuteration of pharmaceuticals
Highly selective and AI-predictable Se–N exchange chemistry between benzoselenazolones and boronic acids for programmable, parallel, and DNA-encoded library synthesis
Photochemical activation of pincer-ligated phosphoranides: mechanistic insight for reduction of aryl halides
Fused 3D boron heterocycles via EnT catalysis: synthesis, modification and validation as beta-lactamase inhibitors
Surface dynamic engineering of discontinuous cobalt dopants on copper sulfide for enhanced electrosynthesis of hydrogen peroxide
Gas-phase synthesis of naphthalene through an unconventional thermal alkyne–alkene [2 + 2] cycloaddition mechanism
Molecular-level insight into the multiple mechanistic pathways in iron-catalysed alkene dimerisation
Aggregation of DNA oligomers with a neutral polymer facilitates DNA solubilization in organic solvents for DNA-encoded chemistry
One-pot synthesis of sequence-controlled macromonomers via living anionic addition reaction and subsequent acyclic diene metathesis polymerization
Ligand substituents modulate excited-state lifetime and energy-transfer reactivity in Cu(i) photosensitizers supported by salicylaldimine and isocyanide ligands
The organophosphorus synthesis triangle: introducing methods for the missing quaternization and de-quaternization routes
All-boron analogue of planar benzene on an osmium template
Elucidating the reaction kernel and probing the effect of anharmonicity in the ring-closing reaction of fulgide single crystals
Desulfurative modification of cysteine residues in peptides and proteins via the installation and photoexcitation of thieno[2,3-c]-pyrroles
Iron photocatalysis towards site-selective C(sp3)–H alkylation of glycines and peptides
Captivating bimolecular photoredox dynamics of a ligand-to-metal charge transfer complex
Dynamics-based transition states reveal solvent cage effect and SN2 transition state motion in Lewis acid catalyzed stereoselective tertiary alcohol nucleophilic substitution reactions
Autonomous optimisation of biocatalytic reactions: enzymatic synthesis of N-benzyl acetoacetamide in continuous flow
Pd-catalyzed desulfonylative fluorination of electron-deficient (hetero)aryl sulfonyl fluorides
Cobalt-catalyzed direct carbonylative 3-acylation of (N–H)Indoles with alkyl halides
Noncovalent immobilization of chiral Lewis acids on single-walled carbon nanotubes as a tool for synthetic organic aquachemistry
Chemoselective Cu-catalyzed acylsilylation of vinyl arenes using silylboronates and acyl fluorides
Lewis-acid induced mechanochemical degradation of polyvinylidene fluoride: transformation into valuable products
Cyclopropylmethyl S-adenosyl-l-methionine: an enzymatic cyclopropylmethyl donor
Optimizing semi-hydrogenation of unsaturated hydrocarbons by electrolyte engineering approach
Carboxylato-prism[6]arene as a supramolecular catalyst in water: exploiting its deep hydrophobic cavity for green oxidation of aromatic amines
Sulfenate anion catalyzed enantio- and diastereoselective aziridination
Switchable supramolecular polycationic assemblies for tunable antibacterial strategies against antibiotic resistance
eCarbonyls: an electrochemical thioether mediated oxidation of alcohols to aldehydes and ketones
N-heterocyclic carbenes as clickable molecular anchors for electrochemical surface functionalization of metals and glassy carbon
Catalytic asymmetric isomerization/hydroboration of silyl enol ethers
A dual-engineered covalent organic framework with charge-oxygen synergy promotes photocatalytic dipolar [3 + 2] cycloaddition
Molecular functionalization of Ni(OH)2 promotes electrosynthesis of adipic acid
A titanium redox-switch enables reversible C–C bond forming and splitting reactions
Silver- and gold-catalyzed divergent cascade cycloisomerization/[3 + 2] versus [2 + 2 + 1] cycloaddition towards a stereoselective access to heterohexacyclic derivatives
Photomediated C–H trifluoromethoxylations enabled by bis(trifluoromethyl)peroxide
Asymmetric ring contraction of 2-hydroxypyranones by borrowing hydrogen biocatalysis
Cerium-mediated site-selective cysteine functionalization
Silver(i)-mediated oxazoline formation: a mild route to 2,4-oxazoles in peptides
Construction of α-quinonyl-α-hydroxy/amino acid esters through the redox chain reaction
Modular and diverse synthesis of oxaheterocycles via Pd-catalyzed migratory 1,n-cycloannulation of alkenes
Remote generation of N–N axial chirality through asymmetric hydrophosphinylation/hydroamination of maleimides
Gram-scale synthesis of (+)-elacestrant streamlined by iridium-catalyzed dynamic kinetic asymmetric hydrogenation of α-substituted tetralones
Dynamic surface radical confinement in a compact CdS–CdIn2S4 semi-coherent heterojunction for highly efficient synergetic photocatalytic selective oxidation of toluene and enhanced hydrogen production
Cooperative reversible assembly in triply interlocked Al6L4 and Ga6L4 cages
A new generation of N-heterocyclic carbene (NHC) gold–selenolato complexes as potent anticancer agents: distinct synthetic routes and evaluation in 2D and 3D cancer models
Rigid cationic ligands enable high-efficiency NIR-II photoluminescence in copper(i) iodide hybrid semiconductors
Learning radical excited states from sparse data
Catalytic enantioselective construction of two N-stereogenic centers of ethano- and propano-Tröger's bases
Enantioselective lactonization catalyzed by chiral N-heterocyclic carbenes enables access to inherently chiral eight-membered lactones
Enhancing photoredox catalysis by suppressing back electron transfer with the aid of a spin catalyst
Decoding information entropy of fatty acid and phospholipid vesicles via ordering combinatorial output of hydrazones
Copper-catalysed oxy-alkylation of styrenes enabled by halogen-atom transfer
Theory-guided multifunctional Zn-Salen molecular catalyst for sustainable polyester plastic recycling
Water-soluble pyridinium redox mediators for pH-swing CO2 capture
Hosting of [Cs(crown ether)2]+ type host–guest complexes by a nano-sized molecular cuboid
Inverted azolophanes: alternant o-heteroarene/p-arene macrocycles
Depolymerization of PLA catalyzed by guanidine-modified microgels
Enantioselective synthesis of C–C and C–N axially chiral pyrazole-based heterobiaryls
Enantioselective synthesis and racemization dynamics of trithia[5]helicenes derived from the dithieno[2,3-b:3′,2′-d]-thiophene unit
Encapsulating NHC–capped copper(i) complexes inside cyclodextrin for catalysis in living cells
Synthesis of N-CD3 aryl amines via iron-catalysed site-selective aromatic C–H amination
Atroposelective synthesis of sterically hindered stereochemically complex BINOL derivatives via central-to-axial chirality induction
Photochemical deracemization of 2,3-allenoic acids mediated by a sensitizing chiral phosphoric acid catalyst
Oxidative benzylic C(sp3)–H functionalisation of electron-poor substrates with photoexcited DDQ
Cu-catalyzed enantioconvergent deborylative alkynylation
Versatile method for the synthesis of aminobenziodoxolones and its application to one-pot coupling of arylboronic acids with simple amines
Revisiting aromaticity and stability in the diboron actinide compound Pa2B2
Two-carbon ring expansion of bicyclic aziridines to oxazocines via aryne insertion into a σ C–N bond
Thiol-free arene C–H thioesterification enabled by a photoactive electron donor–acceptor complex
Chiral benzo[2.2.1] α-hydroxyketones from a dirhodium(ii)/bisphosphine-catalyzed desymmetrization addition reaction
A biomimetic supramolecular platform enables sequential four-step energy transfer and reactive oxygen species modulation for selective photocatalytic oxidations
Unveiling the migration reactivity of bicyclic diaziridines: enantioselective synthesis of chiral pyrazolines
Bis-subporphyrin-like boron(iii) complexes derived from indolo[2,3-a]carbazole-based cyclic bis-BODIPYs exhibiting persistent helical chirality
Matere bond identification in non-crystalline materials by using X-ray photoelectron spectroscopy
Multifaceted photocatalysis enables cobalt catalyzed enantioselective C–H activation and APEX reaction for C–N axially chiral molecules
Two-step coupled photoelectrochemical chlorination and oxygenation of C(sp3)–H bonds mediated by chlorine radicals over a modified BiVO4 photoanode
Synthesis of perhalogenated silylboranes (X = Cl, I) and their application in regiodivergent alkene silaboration
Harnessing the copper surface for direct mechanocatalysis: a case study on mechanochemical sulfonylurea synthesis
Coordination sphere interactions drive isomer selection in heteroleptic Pd(ii) cages with low-symmetry ligands
Regulating enol–keto tautomerism at the single-molecule level with a confined optical field
Synthesis of biodegradable vinyl copolymers via enforced regular sequence distribution from automated radical ring opening polymerisation
Tailoring multi-dimensional hierarchical self-assembly of metallacages through balancing non-covalent interactions
Measuring the efficiency of synthetic routes and transformations using vectors derived from similarity and complexity
Photoactive monofunctional Pt(scpii/scp)–cyanine complex for nucleus and mitochondria dual-targeted antitumor therapy
Spontaneous chiral symmetry breaking in a single crystal
Force-induced transition state rupture enables mechanistic control in aziridine mechanochemistry
Homolytic fracture of inorganic crystalline materials enhances the mechano-chemical degradation of polypropylene
Sulfur fluoride exchange with carbon pronucleophiles
Phototoxicity of hydroxymethyl-BODIPYs: are photocages that innocent?
Photosensitized diradical rearrangement of alkenyl oxime ethers towards amino-featured oxiranes: reaction, mechanism, and structural prediction
Lateral π-extended helical nanographenes with large spin polarization
Isolation of a phosphinidene sulfide and selenide
Construction of helicates based on six-coordinated silicon centres
Acceleration and regioselectivity switching in 1,3-dipolar cycloaddition reactions confined in a bis-calix[4]pyrrole cage
Photostable triphenylmethyl-based diradicals with a degenerate singlet-triplet ground state and strong photoluminescence
BiVO4/BiOCl heterostructure photoanodes for highly selective photoelectrochemical oxidation of benzylic C(sp3)–H bonds
Manganese-mediated C(sp)–Si cross-electrophile coupling of alkynyl halides with chlorosilanes
Dimerization of pillar[5]arene: length-adaptive encapsulation of long-chain guests
Electrochemically promoted defluorinative sulfoximination and fluorosulfonylation of non-activated aryl fluorides at room temperature
ThDP-dependent Enzymes Catalyzed Oxidation of Aldehydes
Cluster iversus/i coordination: the chemistry of cyclopentadienyl titanium and vanadium complexes with B- and C-functionalized carborane-thiols, [Csub2/subBsub10/subHsub12−in/i/sub(SH)subin/i/sub] (in/i = 2 or 3)
Palladium-catalyzed redox diversified entry to axially chiral styrenes via asymmetric olefination with alkynes
A practical photocatalytic strategy for radical (deuterio)difluoromethylation using imidazolium reagents
Diastereoselective arylation of bis-lactim ethers catalyzed by N-coordinating ylide-functionalized phosphine (NYPhos)
Photocatalytic regioselective four-component radical relay carbonylation for α-aminoketones synthesis
Modulating ion migration realizes both enhanced and long-term-stable nanozyme activity for efficient microplastic degradation
Sunlight-driven photoinduced electron/energy transfer-reversible addition-fragmentation chain transfer polymerization at a large scale
Mechanisms of Kobayashi eliminations for the generation of highly strained arynes, cyclic cumulenes, and anti-Bredt olefins
Chiral population analysis: a real space visualization of X-ray circular dichroism
Non-spectator behavior of a neutral phosphine ligand driven by a redox-active boron cluster
Multifunctional chiral silanol ligands for enantioselective catalysis
Hydroxy-pendant tetrazole as the cage group for photoactivatable push–pull fluorophores
A unified approach to highly functionalized clovane-type terpenoids: enantiocontrolled total synthesis of rumphellclovane E and sarinfacetamides A and B
Host–guest interaction-induced selective oxidation of a substrate inside an aqueous Pdsub6/subLsub4/sub cage
Single solvent molecule effect over SN2 and E2 competition in the hydroperoxide anion reaction with ethyl-iodide
Difluoroenol phosphinates as difluoroenolate surrogates: synthesis and applications in defluorination and deoxygenative coupling
Isomer-dependent reactivity in the solid state: topochemical [4 + 4] ivs./i [4 + 2] cycloaddition reactions
A new P3N ligand for Pd-catalyzed cross-couplings in water
Biochemical dissection of a fungal highly reducing polyketide synthase condensing region reveals basis for acyl group selection
Phosphonium fullerides: isolable zwitterionic adducts of a phosphine with Csub60/sub
Structural control of dynamic covalent cages: kinetic vs. thermodynamic assembly and PFAS removal from water
On the synthesis and structure of reactive halonium ions
Tautomer aspects in the excited-state dynamics in 2-thiocytosine: intersystem crossing in the absence of the thiocarbonyl group
Visible light activation of C–Cl and C–F bonds in persistent organic pollutants using cerium(iii) triamidoamine complex
Probing substrate binding and release events in iridium-catalysed hydrogen isotope exchange reactions
Asymmetric intramolecular reductive coupling of bisimines templated by chiral diborons
A pair of strongly reductive and oxidative photocatalysts for the general upcycling of biomass derivatives and plastic wastes
Electrochemical synthesis of aziridines, pyrrolidines and oxazolines enabled by azo-free alcohol amination
Single electron/energy transfer photocatalysis: α-/β-switchable synthesis of 3-deoxy-scpd/scp-manno-oct-2-ulosonic acid iO/i-glycosides
Crown ether–cycloparaphenylene hybrid multimacrocycles: insights into supramolecular gas sensing and biological potential
Photoactivated solid-state self-assembly: a mechanochemistry-free route to high-purity aromatic amine crystals
Machine learning photodynamics reveal intersystem-crossing-driven ladderdiene ring opening
Designing molecular qubits: computational insights into first-row and group 6 transition metal complexes
Transformation of a Pd6 trifacial barrel to a Pd8 tetrafacial barrel by C70 as guest and oxidative photolysis of alkenes using the C70 encapsulated barrel under red light
A diastereoselective Scholl reaction: point-to-helical chirality transfer in molecular nanographenes
Base-promoted dynamic amide exchange: efficient access to isotopically enriched tertiary amides
Copper-catalyzed direct regioselective C5–H alkylation reactions of functionalized indoles with α-diazomalonates
Cu(scpi/scp)-catalyzed enantioselective and stereospecific borylative annulation of cyclic 1,3-dione-tethered 1,3-enynes
Carbene-stabilized 6,12-diboraanthanthrenes: unveiling the multistage redox properties of polycyclic aromatic hydrocarbons featuring electron-rich boron centers
Extraordinary kinetic inertness of lanthanide(scpiii/scp) complexes of pyridine-rigidified 18-membered hexaazamacrocycles with four acetate pendant arms
Ppm level palladium catalyzed regioselective remote arylation of alkenyl alcohols
Rh-catalyzed enantioselective hydrosilylation of unactivated alkenes
Achieving highly efficient carbon radical-mediated cross-coupling reaction in a confined radical microenvironment within a metal–organic framework
Access to amidines via C(sp2)–N coupling of trifluoroborate-iminiums with N-fluorobenzenesulfonimide
Enantioselective synthesis of 1,2-disubstituted thiocyclobutanes ivia/i Michael addition
Predicting pore-carrier solubility and size-exclusivity towards the rational design of type II porous liquid solutions
Photoaffinity SAM analogues for the identification of SAM-binding proteins
General palladium-catalyzed cross coupling of cyclopropenyl esters
Convergent and divergent synthesis of dihydroisoquinoline-1,4-diones enabled by a photocatalytic skeleton-editing [4 + 2] strategy
Hexamethylbenzene elimination enables the generation of transient, sterically unhindered multiply bonded boron species
Photochemical synthesis of carbazole-fused Blatter radicals: effective spin injection to the carbazole system
Preferential survival of prebiotic metallopeptides in the presence of ultraviolet light
Metal-catalyzed methylthiolation of chloroarenes and diverse aryl electrophiles
Bio-inspired total synthesis of daphnepapytone A
Decarboxylative sulfation by persulfates
Visible-light-initiated metal-free Csp3–Csp3 to Csp3–N conversion in homobenzylic sulfonamides with N-iodoimides
Photoexcited and ground-state diradical(oid) character in a triquino[3]radialene
Chemodivergent C-to-N atom swap from benzofurans to benzisoxazoles and benzoxazoles
Concise total synthesis of the cage-like sesquiterpenoid (+)-daphnepapytone A
A mechanochemical [2+2+2] cycloaddition facilitated by a cobalt(scpii/scp) catalyst and piezoelectric materials
Backbone editing and deconstruction of polyethylene by Beckmann rearrangement and hydrogenolysis
Rapid and precise synthesis of acrylic polymers driven by visible light
Crosslinking 1,4-polybutadiene ivia/i allylic amination: a new strategy for deconstructable rubbers
Activation of perfluoro(methyl vinyl ether) at Rh(scpi/scp) complexes: metal-centered iversus/i phosphine-mediated decarbonylation
N-Heterocyclic carbene-catalyzed enantioselective (dynamic) kinetic resolution for the assembly of inherently chiral macrocycles
A conformationally adaptable tetrahedral cage with different guest encapsulation models
iso-TEtraQuinoline (i-TEQ): an inherently chiral N4 macrocyclic quinoline tetramer
C=O methylenation mediated by organo-alkali metal reagents: metal identity and ligand effects
Precise construction of spiro stereocenters ivia/i enantioselective radical addition through modulating photocatalysis from redox to energy transfer
Isothiourea catalysed enantioselective generation of point and axially chiral iminothia- and iminoselenazinanones
A platform for SpyCatcher conjugation to native antibodies
Synthesis of gem-di(boryl)cyclopropanes from non-activated olefins via Mn-photocatalyzed atom transfer radical addition
Oxidation-induced double aromaticity in periodo-polycyclic hydrocarbons
Potassium itert/i-butoxide mediated stereoselective/direct Mannich reaction of α-substituted-γ-lactams with iin situ/i generated aryl iN/i-silyl imines
Alkali metal salts of 1,2,3-benzodiazaborines: platforms for late-stage iN/i-functionalization and metal complexation
Access to spirocyclic vinyl sulfones via radical cyclization and functional group migration
The genesis of OH-stretching vibrational circular dichroism in chiral molecular crystals
α-iN/i-phthalimido-oxy isobutyrate-mediated deoxygenative arylation: total synthesis of alanenses A and B
A mechanistic continuum of nucleophilic aromatic substitution reactions with azole nucleophiles
Catalytic alkoxysilylation of C–H bonds with tert-butyl-substituted alkoxysilyldiazenes
Switching mesoionic carbene-organocatalysis from radical to ionic pathway through base-controlled formation of Breslow intermediates versus Breslow enolates
Electrochemical hydrogenative coupling of nitrobenzene into azobenzene over a mesoporous palladium–sulfur cathode
Photoinduced copper-catalysed enantioselective amination of allylic and propargylic C–H bonds
A general copper catalytic system for cross-coupling of aryl iodides with chlorosilanes under reductive conditions
Post-coordination of Ru(ii) controlled regioselective B(4)–H acylmethylation of o-carboranes with sulfoxonium ylides
π-Expansion as gateway to viologen-based pimers
Towards trans-dual deuterated cyclopropanes via photoredox synergistic deuteration with D2O
Ligand non-innocence and an unusual σ-bond metathesis step enables catalytic borylation using 9-borabicyclo-[3.3.1]-nonane
Pyridine-N-oxide catalyzed asymmetric N-acylative desymmetrization of sulfonimidamides
Visible-light-mediated site-selective C(sp2)–H alkylation of tropones facilitates semi-synthesis of cephafortunoids A and B
A highly selective C–H bond fluorination unlocks conformational reporting in a complex natural product derivative
Carbene-catalyzed enantioselective construction of a quasi-symmetrical spirocyclic hydroquinone with a minor chiral distinction
Introduction of flavin anions into photoredox catalysis: acid–base equilibria of lumichrome allow photoreductions with an anion of an elusive 10-unsubstituted isoalloxazine
Asymmetric total synthesis of penicilfuranone A through an NHC-catalyzed umpolung strategy
Double helicene possessing B–N dative bonds built on 1,4-dihydropyrrolo[3,2-b]pyrrole core
A unified approach to meta-selective methylation, mono-, di- and trifluoromethylation of arenes
Multi-stimuli-responsive polymers enabled by bio-inspired dynamic equilibria of flavylium chemistry
Coordination of ethane, pentane and cyclopentane to a cationic osmium complex: comparisons in alkane binding
O-Trifluoromethylation of ketones: an alternative straightforward route to alkenyl trifluoromethyl ethers
Computational framework for discovery of degradation mechanisms of organic flow battery electrolytes
Catalytic asymmetric construction of 1,5-remote Si- and C-stereocenters via desymmetrizing ene reaction of bis(methallyl)silanes
Merging directed sp3 and nondirected sp2 C–H functionalization for Pd-catalyzed polydeuteration of (hetero)arenes
Diazomethyl-λ3-iodane meets aryne: dipolar cycloaddition and C-to-N iodane shift leading to indazolyl-λ3-iodanes
Organocatalytic atroposelective de novo construction of monoaxially and 1,4-diaxially chiral fused uracils with potential antitumor activity
Minimal catalytic dissipative assemblies via cooperation of an amino acid, a nucleobase precursor and a cofactor
Boradigermaallyl: inhibition of CH bond activation by borane CO adduct formation followed by CO insertion
Regioselective access to B–N Lewis pair-functionalized anthracenes: mechanistic studies and optoelectronic properties
Orbital contributions to magnetically induced current densities using gauge-including atomic orbitals
Water-soluble BODIPY dyes: a novel approach for their sustainable chemistry and applied photonics
Generating the Pd-catalyzed δ C–H chalcogenation of aliphatic picolinamides: systematically decreasing the bias
Chiral ring-in-ring complexes with torsion-induced circularly polarized luminescence
4
An Asgard archaeon from a modern analog of ancient microbial mats
Environmentally controlled production of pagoamide A in marine macroalgae by an intracellular bacterial symbiont
The human fingerprint of medicinal plant species diversity
Long-term monitoring of a North American cheese cave reveals mechanisms and consequences of fungal adaptation
2
Performance Evaluation of Tetrabutylphosphonium Trifluoroacetate Ionic Liquid-Water Solution as Refrigerant for Adsorption Refrigeration in Chilled Storage Applications
Photocatalytic energy driven building sustainable power, air purification and air dehumidification
2
Continuous-flow organic electrosynthesis of a conjugated bipolar polymer cathode for high-performance low-temperature aqueous aluminum-ion batteries
Molecular engineering of an ether–nitrile constructs robust dual-interphases for ultra-stable 4.5 V lithium metal batteries
9
Cyanidin-3-O-glucoside alleviates aflatoxin B1-induced splenic immunotoxicity via gut microbiota remodeling
6-acetyl-1,1,2,4,4,7-hexamethyltetraline (AHTN) induces abnormal macrophage polarization and nuclear lamina remodeling under low-dosage and long-term exposure
Exploring PFRs, ROS, PAHs, nitro-PAHs, and health risks of the nonthermal plasma intervention size-segregated smoldering incense and mosquito coils aerosols
Evolution of environmentally persistent free radicals on tire wear particles under UV irradiation: Contributions of relative humidity and ozone concentration
Enhancing Effects of Glycine on Methanesulfonic Acid-driven New Particle Formation: Mechanistic Insights and Implications for Atmospheric Pollution
Formation and stability of environmental persistent free radicals (EPFRs) from the reaction between phenolic compounds and Fe(III)-loaded particles
Terrestrial inputs of synthetic musks from Chinese mainland to the East China Sea
Assessing the toxicological impact of DEGDB plasticizer exposure on glioblastoma multiforme via network toxicology, machine learning and in vitro methods
The global distribution characteristics, concentration correlations, and risk assessments for synthetic musks (SMs)
5
Bimetallic isotypic heterojunction Mn-CN/Co-CN for enhanced PMS activation: Unraveling the synergistic Co(III)/Mn(II) catalytic redox cycle
Naphthenic Acid Exposure Disrupts Mitochondrial Function and Locomotor Behavior in Marine Medaka (Oryzias melastigma) via G Protein–Coupled Receptor Signaling: A Multi-Omics Perspective
Recycling plastic waste into nitrogen plasma-enriched polyethylene terephthalate@aluminum oxide counter electrodes for sustainable Dye-Sensitized Solar Cells
Tuning Fe-P covalency via regenerative phosphorus vacancies for efficient aqueous cyclohexanone degradation
Diluted Alkaline Pretreatment in Hexafluoroisopropanol Facilitates Chemoenzymatic Depolymerization of Polyethylene Terephthalate
20
Selective Photocatalytic Upcycling of Polystyrene Plastic to High-Value Chemicals by a Single-Atom Fe Catalyst
Oxygen Vacancy Defects in Hematite Enhance Maillard Reactions and Promote Recalcitrant Organic Carbon Formation
Converting Low-Value E-Waste into Phenolic Resole Resins: A Route to Value-Added, High-Performance Advanced Materials for Multifunctional Applications
Comprehensive Mapping of Ionic Liquid Degradation Pathways and Toxicity Risks in UV/NaClO Treatment via Integrated Molecular Networking and In Silico Toxicology
pH-Dependent Activation of EPFRs and Kinetics of Hydroxyl Radical Generation
Mechanisms Underlying Tralopyril-Induced Olfactory Dysfunction in Marine Medaka: Disruption of the Dopaminergic System and the Complement Alternative Pathway
Novel Cross-Linking Behavior in Addition to Chain Scission during Free-Radical Degradation of Water-Soluble Polymers
Enhanced Fluorine Resistance and Catalytic Performance of the Zirconia-Supported Ru Single-Atom and WOx Cluster Catalysts for Elimination of the Typical Hydrofluorocarbon (HFC-134a)
A Humidity-Tolerant Photocatalyst for Methane Removal
Oxygen-Independent Mineralization of Acetaldehyde by a Cyclodextrin-Anchored WO3 Photocatalyst under Visible Light
Deciphering the Role of Heavy Metals in Zero-Valent Iron-Driven Dechlorination of PVC Microplastics under Mild Condition
In Vitro Identification and In Vivo Confirmation of Metabolites of High Molecular Weight Synthetic Phenolic Antioxidants
Stranger Rings: How Heteroarenes and the Degree of Methyl Group Fluorination Affect Photolysis Kinetics and Fluorinated Product Formation
Iron- and Manganese-Catalyzed Maillard Chemistry: Molecular Characteristics, Evolution Pathways, and Implications for Soil Organic Carbon Formation
Air-Exposed Nano-TiO2 for Rapid and Sustainable Hydrolysis of Gaseous Phthalate Ester: The Remarkable Facet and Humidity Effects
Modeling the Effect of Microbially Induced Calcium Carbonate Precipitation (MICP) on CO2 Trapping
Net-Zero Upcycling of Mixed Polyolefins by Spatially Homogeneous Joule Heating
Environmentally Persistent Free Radicals on Black Carbon Induce Rapid Degradation of Phenolic Acids
Enhancing Photocatalytic Decarboxylation by Frustrated Lewis Acid–Base Pairs for Efficient Degradation of Perfluorooctanoic Acid
Selective Depolymerization of Poly(ethylene terephthalate) in Mixed Plastic Waste Using Magnetically Recoverable nZVI Catalyst
3
Investigating terrestrial ethane sources with molecular-average and clumped isotopes
Kinetic study of the effect of Mg2+ and Ca2+ on the hydrolysis of ATP up to 120 °C
Atomic-level insights into nanoclay for prebiotic nucleoside phosphorylation
1
Dietary anthocyanins alleviate age-dependent hepatic steatosis by expanding Limosilactobacillus reuteri and modulating gut microbiota-bile acid-hepatic FXR signaling.
204
Imparting Water Solubility and Aqueous Electrochemical Activity to Ferrocene upon Confinement
Design, Synthesis, and Evaluation of an Ammonium-Terminated Superchaotropic Boron Cluster: Effects on the Transmembrane Delivery of Neutral and Charged Cargos
Rational Design and Development of an Acyclic Chelator H4pyox for Theranostic Radiometal Labeling under Mild Conditions
Synthesis of Carborane-Containing Esters of Natural l-Amino Acids via Construction of a Carborane Cage Using Alkyne-Insertion Reactions
Silylated Stannanes and Stannides
Controlled N-Substitution of a B(8)-Ammonium Cobalt Bis-Dicarbollide
DFT Insights on Ligand Photodissociation Pathways in Ruthenium–Terpyridine Complexes: 3MLCT- or 3MC-Triggered?
Stable Au(III) Benzohomoporphyrin: Synthesis, Structure, Near-Infrared Absorption, and Superoxide Radical Generation
Tailoring a Polyoxometalate-Based Metal–Organic Framework for Photocatalytic Oxidative Cross-Coupling Reactions to Synthesize Benzo(naphtho)thiazoles
Influence of Ligand Backbone Functional Groups on the Stability of Metal–Organic Cages in Solution
Revealing Low-Barrier Conformational Flexibility in Perfluoropropanoyl Halides: A Structural Gas Phase Study of CF3CF2C(O)X (X = Cl, Br, I)
Singlet–Triplet Transitions in the Dianionic Complex of Fullerene C60 with Iron Carbonyl: (TBA+)2{[Fe2(CO)6]-η2,η2-C60}2–
Gradient Construction of High-Efficiency Lanthanide Polynuclear Nanocages for Three-Component Ugi Reactions
Hemin Molecular Catalyst with Axial Cl–Fe Coordination for Selective and Stable Acidic Chlorine Evolution
Tuning the Lewis Basicity of Pyridine: Structural and Theoretical Characterization of the SO3 Adducts of Pyridine Derivatives
Magnesium-Catalyzed CO2 Reduction to Formic Acid or Methanol: Solvent or No Solvent Settles the Selectivity
Dual-Site Molecular Recognition in a Truncated-Octahedral Pd6L8 Cage via Symmetry-Selective Endo and Peripheral Binding
N-Heterocyclic Carbene-Based Tetradentate Platinum(II) Complexes for Deep-Blue Phosphorescent Emitters: Safe Synthesis and Photophysical Study
Synthesis and Selective Carboboration Reactivity of a Flexible P-Stabilized Bromoborenium
Multifunctional Photocatalysts Based on Half-Sandwich Cyclometalated Ir(III) Complexes with π-Extended Ligands
Circular Dichroism Reveals Positive Cooperativity through Compensatory Motion in Stepwise Cage Metalation
An Fe(II)-Based Hexagon-Fused Wheel Constructed via Post-Synthetic Transmetalation
O©Li5F52–: A Global Minimum with a Planar Pentacoordinate Oxygen
Comparisons and Contrasts in a Complete Set of Alkali Metal Cumyl Structures
Guest Exchange among Distinct Water-Soluble Supramolecular Nanocages
Light-Assisted Akamptisomerization: Excited-State Bond-Angle Reflection (ESBAR) as a Molecular Photoswitching Element in B2OF2–Porphyrins
A Substrate-Dependent Redox Catalysis of Tellurenyl Species Involving Oxidation States +I, +II, and +IV
Figure-Eight Macrocyclic Salen Dimers Synthesized from ortho-Phenylene-Bridged Bissalicylaldehyde
Adaptive Self-Assembly of Lanthanide-Covalent Organic Polyhedra: from Triangular Prism to Octahedron
Diimino(NHC)-Stabilized Stannylone: Synthesis and Reversible Coupling with Isocyanates
Structural, Thermodynamic, and Spectroscopic Characterization of Diphosgene and Triphosgene
Butadiene-Based Multidentate Ligand Formation via Stannylene Assisted C–C Coupling
Ligand Side-Chains Control the Formation of an M8L4 Molecular Barrel: Unveiling Selective Encapsulation and Sequential Separation Properties
Electrostatic Potential at the Iodine Nucleus as a Predictive Descriptor for Lewis Acidity in Diaryliodonium Ions
Challenging the Macrocycle Paradigm: Four-Arm, High-Denticity Acyclic Chelators for Radiopharmaceuticals Incorporating Actinium and Lanthanides
Generalizing Reversible Triplet–Triplet Energy Transfer as a Strategy to Increase Excited-State Lifetime in Copper(I) Charge-Transfer Chromophores
Isoselenocyanates with Sterically Encumbered Substituents─Synthesis, Structures, and Spectroscopic Properties
A Robust, Redox-Active Cerium Metal–Organic Framework for the Aerobic Oxidation of Benzylamines to Benzylimines
Copper Halide Hybrids Driven by Irreversible Structural Transitions for Anti-Counterfeiting and Traceability
Electron Pool Enrichment of Polyhedral Carboranes: A Key to Isomerization and Nucleophilicity
Exothermic and Spontaneous Covalent Interaction of Trivalent Lanthanides with Diglycolamide and Carbamoylmethylphosphine Oxide-Functionalized Ionic Liquids: Spectroscopic, Electrochemical, and Computational Investigations
Mechanism of Direct Dissolution of PuO2 in the Task-Specific Ionic Liquid [Hbet][NTf2]: An Insight from Density Functional Theory
Metallophilicity Under Confinement: The Iminopyrrole Cage Promoting the HgII···MII (M = Hg, Cd) Interactions
Mechanistic Insights into Scandium-Catalyzed Cascade Cyclization of Aromatic Aldimines with Tethered Alkenes via C–H Activation
Three-Component CO2 Conversion to Carbonyl Carboxylates Catalyzed by a Copper-Based Metal–Organic Framework under Mild Conditions
Stereocontrolled Synthesis of Chiral [2]Catenanes by Coordination-Driven Self-Assembly
Mechanistic Revision of Ir(III)-Catalyzed Allylic C–H Alkynylation through DFT Calculations: An Ir(III)-Only Pathway via Alkyne Insertion and Ag-Assisted Debromination
Rapid Sequestration of Mercuric Ion as HgSe by a Selenocysteine-Inspired System
Study on the Quenching Mechanism of Radicals by Fullerenes (C60 and C70)
Noncovalent Bonding of Group 4 Metals
BN-Polarized Azaboracyclophanes as Tunable Electrostatic Molecular Cavities for Host–Guest Binding and Capture
Anion- and Conjugated Building Block-Driven Construction of Handcuffs and Cages, Featuring In Situ Topological Transformation from Handcuff to Double-Z Cage
Synthesis of Tetra-Porphyrin Tubes for Catalysis and Host–Guest Chemistry
Design Rules for Sb and Bi Porphyrin Capsules: Para-Substitution Effects and Pnictogen Bond Conformational Control
Bis(pentafluoroethyl)arsinous Acid and the Bis(pentafluoroethyl)arsinite─Synthesis, Structural Characterization and Transition-Metal Complexes
Au-Mediated Enhanced Charge Separation in Cs2AgBiBr6/Au/UiO-66 for Photocatalytic Synthesis of Thiosulfonates
Zinc Metallacarborane Chemistry
Bicyclic (Alkyl)(Amino)Imine-Anchored Diphosphine and Its Radical Cation
More is Different: Theoretical Investigation on the Origin of Ligand Loading-Dependent Switching Regioselectivity in Ir-Catalyzed C–H Borylation
Direct Arylation of Unactivated Arenes Using Earth-Abundant Iron/Tetra-Aza Macrocyclic Complexes
Increasing Cage Escape Yields for Halide Oxidation in Aqueous Solutions Using Ir(III) Photosensitizers with π-Extended Aromatic Ligands
The Supramolecular “Just Right” Principle in the CB[n]S8 Goldilocks Triad: Dynamic and Interaction Energy Considerations in the CB[n]S8 (n = 6, 7, 8) Formation from MD+EDA Calculations
The Effect of a Single Trifluoromethyl Substituent on the Reactivity of Chelating C2 and Cs-Symmetric Bis(alkoxide) Ligands on a Terphenyl Platform
Unveiling Cooperative Effects of Two Bidentate Pyridone-Pyrazole Ligands in the Regioselective C–H Activation: A Theoretical Study
Solid-State Synthesis, X-ray Structure, and Guest Inclusion in Octahedral M6L4 Cages Self-Assembled by Tris-pyridyl-benzene (TPB)
Dealkylation as a Strategy to Synthesize Unconventional Lithium Salts from ortho-Phenyl-phosphonate-boranes
Mechanistic Insights into E(II)-Catalyzed (E = Si, Ge, Sn, Pb) C–F Activation/C–C Cross Coupling Reactions
Utilization of Oxidovanadium(IV) Porphyrin as a Catalyst for One-Pot, Four-Component Synthesis of Bioactive Pyranopyrazoles and its Anticancer Potential
Visible–NIR Photodynamic and Photothermal Mono- and Bis-Rhodium(I) Complexes of a Pyrrole-Appended N-Confused Porphyrin
Non-IPR Chlorofullerenes Obtained from IPR C60 by Stone–Wales Rearrangements, #1809C60Cl10 and #1806C60Cl26
Arene-Fused o-Carboranes via C–B(3) Bond Formation: Synthesis and Properties
A Dual Luminescent and Chromogenic Pt-NCN Complex for the Detection of GTP and CTP in Aqueous Media
Structure and Spectroscopy of Triruthenium Dodecacarbonyl, Ru3(CO)12
Steric Bulk Controls Δ/Λ Handedness Enabling Stereodivergent Self-Assembly of FeII2L3 Cages
Induction of Platinum(II) Coordination-Bonded Network Formation in Coacervates of Single-Stranded DNAs
In Situ Synthesis of Cu-CP by Cleavage of the C–N Bond for CO2 Fixation into Oxazolidinones through Aziridine/Propargylamine under Ambient Conditions
Reaction of Diazo Compounds with Borenium Ions: C–H Bond Activation/Annulation vs 1,1-Carboboration
4-Fold Protonation of Tetracyanometalates in Superacids: Hydrogen and π-Hole Bonding in the Solid State
Interaction of η2-C2B10H10 and Its Derivatives with Group-X Transition Metals: A Theoretical Study Using DFT
Anionic Supramolecular Cluster with [Cu4Br7O]2– Core: Self-Assembly and Photocatalysis for Organic Transformations
Martin’s Spirophosphorane: A Platform for the Design of [OPO] Pincer Ligands and Their Group 4 Complexes
Modification of Alkylpyridine Ligands in the Reactions of Osmium(III) Complexes with Anions
Formation of Cationic Silanols via Hydrolysis of Carbodiphosphorane-Stabilized Trichlorosilane
Meso-Modified Porphyrinoids: Stimuli-Driven Conformational Plasticity, Modulation of π-Conjugation, and Bis-Rh(I) Complexation
Laterally Distorted 1,2-Dibora-4-gallatacyclopentane Anion
DFT Calculations Reveal the Origins of Chemo-, Regio-, and Stereoselectivities in Nickel-Catalyzed Synthesis of Chiral Tetrasubstituted Allenes with Simultaneous Construction of Central and Axial Chirality
Quinoxaline-Based Cationic Cyclometalated Iridium Complexes for Deep-Red Light-Emitting Electrochemical Cells
Sequestered Aerial CO2 and Phosphate-Assisted Formation of 2D Nanosheets
Photo-Migration of Chloride Ions Associated with Amide Substituents on Ruthenium Polypyridyl Complexes
Accessing Self-Illuminated, Luminescent Lanthanide Probes by Enzymatic Radiophosphorylation
Reactivity of a Sodium Anion with Alkenes: 1-Electron vs 2-Electron Reductions
Asymmetric Antipodal β-Functionalized Push–Pull Porphyrins Based on β,β′-Fused Imidazole Rings: Synthesis, DFT, Photophysical Studies, and the Base-Dependent Equilibrium Characterization in Nonaqueous Solutions
Interception of a Uranium Alkyl–Carbene Complex Utilizing a Bulky Phosphaylide
Lewis Acid-Assisted Generation of Iodenium(I) Ions: A Computational Approach
N-Indolylsilylene Cobalt(I) Chloride: A Base Metal Catalyst for Alkene Hydrosilylation
The Mechanism of Photocatalytic C(sp3)-H Activation by Decatungstate Anion: CPET or HAT?
Ring Strain Energies in Four-Membered Heterocycles Containing an Element of Groups 13–16
Stereogenic-at-Metal Ir(III) Complexes as Platforms for the Construction of Asymmetric Bimetallic Complexes
Cu(I)-Anchored NHC-Functionalized Covalent Organic Framework (COF) for Catalyzing CO2 Chemical Fixation into High-Value Compounds
Electronic Structure Tuning of Lanthanidocene Photocatalysts for C–F Bond Cleavage
Stable Radical Iridium(III) Complexes with Tunable Panchromatic Absorption
Cavity-Mediated Global Thermodynamic Control in Heteroleptic Coordination Cage Assembly via Endohedral Noncovalent Interactions
Bimetallic Activation of SF6 by a Bis(Gallylene)
Syntheses and Solid-State Structure Analyses of Pentafluoroethylated Arsanes
Synthesis, Characterization, Electronic Structure, and Excitation Dynamics of Dinuclear Copper(I) Complexes with a Naphthyridine Diimine Ligand
Following CO and H Insertion into Ru–C Bonds with X-ray Photoelectron and Absorption Spectroscopies
Hexavalent/Tetravalent Tellurium-Based Chalcogen Bond Catalysis on the Cyclization of 1,6-Diyne: Mechanistic Insights and Computational Design
Well-Defined syn Multimetallic Complexes Supported by a Geometrically Flexible Tetraamidodiamine Ligand
Phosphinidene Transfer by an N-Heterocyclic Carbene-Parent Phosphinidene Complex
Guest Binding Mechanism of Polycyclic Aromatic Hydrocarbons by Au(I) Metallo-Tweezers Revealed by Computation
Carbocation-Coupled Electron Transfer: An α-Ferrocenylmethylium as a Masked Primary Alkyl Radical
A Series of Trigonal Arylimido Iron Complexes and the Influence of Oxidation State and Steric Demand on Reactivity
A Recyclable Supramolecular Redox Mediator for Reductive Electrosynthesis
Electronic Structure and Hypercorrole Features of Deprotonated Free-Base and Reduced Copper Corroles
Activation of Sulfur Dioxide by a Phosphazene Base: Synthesis and Solid-State Structure of a Phosphazenium SO2 Adduct
Directed Dynamic Resolution of an Atropisomeric Silver Complex in Solution: Role of π–π Interactions
Mechanistic Discovery of a Nucleophile–Electrophile Coupling Mechanism in Binuclear Gold(I)-Catalyzed Photoredox Alkynylation of Tertiary Aliphatic Amines with 1-Iodoalkynes
Tautomerizable Flavin Ligands for Constructing Primary and Secondary Coordination Spheres
A Mismatch Minimization Strategy for Sorting in [Pd2L2]4+ Macrocycles
A Comprehensive Study of the Sc(III)–OPC2A–Fluoride Interaction: Equilibrium, Kinetics, and 44Sc-Labeling
Trinuclear Copper(I) and Silver(I) Complexes of a Pentafluorosulfanyl-Decorated Pyrazolate
Carboxylic- and Amide Donor-Functionalized Pyridine-N-trans-Substituted Cyclen-Based Chelators for 203Pb/212Pb Theranostic Radiopharmaceuticals
A General Approach for the Synthesis of Arylxenonium(II) Tetrafluoroborates
Designing a Photoactive Polyoxometalate-Based Metal–Organic Framework for Solar-Powered Hantzsch Reactions in a Divergent and Mild Pathway to Thermal Methods
Recognition and Detection of Phenylmercapturic Acid and a Pair of Stereoisomers Based on a Cucurbit[6]uril Supramolecular Assembly
Gas-Phase Molecular Structure of 1-Chlorosilatrane: Electron Diffraction Study and Assignment of Photoelectron Spectrum
Trans-Influence in Dinuclear Pt(III) Complexes: Electronic Structure, σ-Donation, and Pt–Pt Spin–Spin Coupling
Water-Soluble Rhenium Nitride Complexes Supported by Multidentate Phosphinite Ligands Provide Insights into Aqueous Ammonium Synthesis Using Samarium Diiodide
Chemical Bonding Trends in Y2M3Si5 (M = Mn–Cu, Tc–Pd, Re–Pt): A Study within the Broad R2M3X5 Intermetallic Family
Reactions of Borafluorene with Iminophosphines: PN Insertion and Skeletal Editing to Phosphafluorene
Preparation of Boron–Nitrogen-Containing Conjugate Polymers via Controlled Hydroboration of Imines
Aromaticity in Ancient Zeise’s Salt
Realizing the Magnetostructural Correlation of a Highly Anisotropic Fe(III) Porphyrin Complex through Ab Initio Approaches
Synthesis and Reactivity of an Iminoborane-Boraalkene Adduct via the Complete Cleavage of the Carbon–Nitrogen Triple Bond of Isonitrile
Ambident Reactivity of (Selenocarbamoyl)Phosphines: Transformation into a Crystalline (Phosphino)(Seleno)Iminium Salt and Transition-Metal Complexes
Selective B(9)–H Bond Oxidation of o/m-Carboranes with mCPBA
Vertex Engineering of the Dodecaborate-Based Broadband Membrane Carriers
Benzimidazolinylidene-Amide and -Imine Ligands: Donor Strength Determination and Catalytic Studies
Two Imidazole-Functionalized Mixed-Valence Oxidovanadium Clusters for Catalytic Oxidation of Sulfides
Minisci Substitution with C–C Bond Formation in Reactions of Trityl Radicals with a Ruthenium-Bound Pyridyl-Imidazole Ligand
Facial and Meridional PNN-Ruthenium Pincer Complexes in Base-Free Nitrile Hydration with Concurrent Ligand Backbone Oxidation
Computational Studies of cis- and trans-Isomer Preferences of d0 MX4L2 Complexes: Overcoming the trans Influence with Steric Demands
Probing Proton Coupled Electron Transfer and Fluorine Atom Transfer in CoII–Catalyzed Oxidative Hydrocarbon Fluorination
Uncovering an IS-PC2ET Mechanism that Facilitates I(III)-to-I(V) Oxidation: an Experimental and Computational Study
[9-{2-(Dimethylamino)ethyl}fluorenyl] as a Ligand on Magnesium Leads to a THF Ring-Opening by the Fluorenyl Moiety
51V NMR Spectroscopy and Ring-Size Effects on Catalytic Oxidative Alcohol Dehydrogenation in {V(O)(μ2–O)(pinF)}n Oligomers
Bioinspired Oxidized Dicobalt Porphyrin Dimer-Catalyzed Cycloaddition Reactions: Cooperative Catalysis and Spectroscopic and Mechanistic Investigation
Polytantalotungstates Stabilized Iron Catalysts for Carbonylation of Benzylic C–H Bonds
Phenylpyridine-Based Boron Azides: Tuning Reactivity and Accessing Fluorescent Triazoles
Copper-Substituted Polyoxotungstates as Catalysts for the Electrocatalytic Oxygenation of Light Alkanes
Octahedral Cs2AgBiBr6 Double Perovskite Microcrystals for C–C Coupling Reactions under Visible-Light Irradiation
Design of a Pd/SWCNTs/TiO2 Photocatalyst for Enhancing Cross-Coupling Reactions by Assistance of Surface Plasmon Resonance
Semicoordinate versus σ-Hole Bonding of Group 10 Metal Atoms in a Square Planar Motif
Coordination Polymers Driven by Urea-Diisophthalate Linkers: From Hydrothermal Assembly and Structural Diversity to Catalytic Applications
N–H Bond Activation of Ammonia Using Intramolecular cAAC-Borane Lewis Pairs
Structural Chemistry of AlCl3–N-Methylformamide Deep Eutectic Solvent: Study on Spectroscopy Techniques and Quantum Chemical Calculations
Reduced Cobalt Corroles: Isolation, Reactivity, and Electronic Structure
Supramolecular Assembly of Chiral Lanthanide Triple-Decker Metallocyclophanes Ln3(Lmeta)3(LR/S)3 or Tetrahedral Cages Ln4(Lpara)4(LR/S)4 and Their Chiroptical Properties
Synthesis of Bench-Stable (CO)5Mn(I)–Aryl Compounds by Transmetalation of Arylboronic Esters
Computational Characterization of Unsupported Au(I)···Ir(I) Metallophilic Interactions: Evidence for Strong Dispersive Stabilization
Magnetospectroscopic Studies of a Series of Fe(II) Scorpionate Complexes: Assessing the Relationship between Halide Identity and Zero-Field Splitting
Synthesis and Reactivity of [SF3]+ Adducts with Organic Bases
Diverse Reactivity of a Pincer-Type Dialuminum Complex
Antimony and Bismuth Complexes as Visible Light Photosensitizers in Catalytic Oxidation Reactions
Supported Copper(II) Arylhydrazone Complex on Synthesized Fe3O4 Nanoparticles Boosted with TiO2 for the Catalytic Oxidation of Alcohols
Selenolated Copper Hydride Clusters for Visible-Light Photocatalytic Iodofluoroalkylation of Alkynes
Luminescent Cyclometalated Iridium(III) Polypyridine Complexes Modified with a Dendritic Guanidinium Moiety as Molecular Glues for Combined Chemo-Photodynamic Therapy
Hydrolytic Cleavage and Deborylation of Boron(III) Subphthalocyanines─A Synthetic Approach to Fused Diazatripyrrins
Emerging Trends in the Coordination Chemistry of Thiazolidinone-Containing Polydentate Ligands: Unconventional Binding Modes in Silver Complexes
Synthesis of NH3·B9H13 and Its N-Alkyl Analogues: Toward the Polyhedral Azaboranes, M[NH2B9H11] (M = Na, K)
Unveiling Unusual Reactivity of SOsub2/sub and Unusual Type of S–X Long Bonds
Thwarting Isomerization through Rigidity: A Promising HBED Derivative for the Chelation of Gallium-68
Rhenium(I)-Based Tetranuclear Metallorectangles from Linear BODIPY and Bischelating Aminoquinonato Ligands: Anticancer Properties, Host–Guest Interactions, and Molecular Docking Studies
Structure and Bond Dissociation Variations in Dialumenes: A Comparative DFT Study on N,P- versus N,N-Bidentate Ligand Effects
Preparation and Characterization of Phosphazenium Trifluoromethylselanide and Trifluoromethyltellanide Salts Starting from HCF3
Characterization and Reactivity of Iron Triazametallacyclohexadiene Complexes: Toward Iron-Catalyzed Multicomponent Reactions
Homochiral Coordination Polymers Exhibiting Second-Harmonic Generation and Photo-Induced Structural Transformation
Experimental Evaluation of the Hydricity of Hydrosilanes
Sequential Separation of Metal Cations Using Nor-seco-cucurbit[10]uril as a Supramolecular Material
Silver(I) Ions Bridging Oxadiazole-2-thione Derivatives with Mitochondriotropic Agents: A Promising Strategy for Potent Anticancer Chemotherapy
Cationic π-Stacked 3a,6a-Diaza-1,4-diphosphapentalenes (DDP): Tuning the Energy of Electronic Transitions by Changing the Interdeck Distance in a Triple-Decker DDP
High-Pressure Selective Topotactic Synthesis of Ordered Trans-Polymeric CS2 in a Zeolite
Synergistic Photoredox and High-Spin Cobalt Cluster Dual Heterogeneous Catalysis: Visible-Light-Driven C(sp2)–H Bond Functionalization
Investigating Molybdenum and Tungsten Carbonyls as a Bridge between Elemental Chalcogens and CO: Formation of Carbonyl Sulfide and Selenium Complexes
Ga5Li12+: A Doubly Aromatic Ga511– Ring Stabilized by Lithium Cations
Oxidovanadium(IV) Porphyrin-Imidazole Complex-Catalyzed One-Pot, Three-Component Green Synthesis of Biologically Active Pyrano[2,3-d]pyrimidine and 4H-Chromene Heterocycles
Rhenium-Selenido Corroles: Reflections on 5d Metalloporphyrins and Metallocorroles as Triplet Emitters and Photosensitizers
Tailoring Gold Corroles via Regioselective Nitration: Near Infrared Emission, Singlet Oxygen Sensitization, and Photocatalytic Oxidation of Sulfides
Akamptisomerism as a Switching Element: Substituent Effects on Bond Angle Reflection and Photophysical Properties of B–O–B Porphyrins
Rhodium-Catalyzed Selective Chalcogenation of B(4)-H of o-Carboranes
Controlled Mono- and Double-Insertion of Sulfonamide Fragments into Ni–S Bonds of Nickel(II) Dithiocarbamate Complexes via Sulfonyl Azide Reactivity
A Pd(II) → Pd(0) → Pd(II) Catalytic Cycle Enables the Generation of Bis(o-carborane)s: Confirmed by Reproduced Yields and Ratios, Regioselectivities, Additive and Substituent Effects
Aromatic Tempering Unlocks the Unseen Bonding Behavior of Phosphorus/Boron FLPs at the Trade of Reactivity
Fe(III)(TIM) Bis-Aryl Complexes: Molecular and Electronic Structures and Metal–Ligand/Ligand–Metal Charge-Transfer Spectra
Palladium-Catalyzed Regioselective B(3,4,5,6)–H Tetra-Arylation of io/i-Carboranes
Activation of C(sp2)–X and C(sp3)–X σ-Bonds (X = F, Cl, Br, and OMe) by Rhodium Complex with Pincer-Type Aluminyl Ligands: Theoretical Insight into High Reactivity and Flexible Reaction Mechanism
Linker Engineering of High-Nuclearity {V12@P8W48}-Based Metal–Organic Frameworks for Green-Light-Driven Oxidative Coupling of Amines
Portal Substituent Modulations in Chiral Imido–Pd(II) Cages for the Enhanced Separation of Styrene Oxide Enantiomers
Mechanochromic Phosphorescence of Rhodium(I) Isocyanide Complexes in the NIR-II Window
Self-Assembly and Dynamic Equilibrium of Trinuclear and Tetranuclear Cu(I) Supramolecules Featuring nido-Carborane-Supported N-Heterocyclic Carbene Ligands
The 12-Ethynylmonocarba-closo-dodecaborate Anion: A Ligand for Metal Alkynide Complexes (M = Li, Na, Ca, Zn)
Hydrogen-Bond-Assisted Chalcogen Transfer between Phosphine Selenides and Arsine Oxides
Synthesis, Photophysical and Redox Properties of Highly Stable Radicals of Nickel(II) Bis(2-aminophenyl)-azadipyrromethene
Cu(II)-Doped ZIF-8 as a Sustainable Catalyst for the Dehydrogenative Coupling of 2-Aminobenzamide with Methanol
16
Generation of nitrogen-containing compounds by cellulose nitrogen-rich pyrolysis under CO2/N2 atmosphere: Influence mechanism of different catalysts
Valorization of waste polyolefins to butene, unsaturated fatty alcohols, and branched alkenes using CO2 and plasma catalyst
Deep eutectic solvent-enzyme complex system for green extraction of essential oil, flavonoids and pectin from citrus peels: Optimization, composition and mechanism
Low-cost slow-release fertilizers fabricated by hot-melt encapsulation from biomass waxes
From mechanism to design: The mechanism of π bond effect and molecular flexibility synergistically regulating the reaction of coal oxidation
Enhanced and sustainable extraction of acetic acid from wastewater using a novel ternary deep eutectic solvent
Sustainable utilization of citrus biowaste through pharmacoinformatic and green extraction approaches to develop polymethoxyflavones-rich extract targeting xanthine oxidase in gouty arthritis
Comparative analysis of ethylene-vinyl acetate debonding with D-limonene and Trichloroethylene in a life cycle perspective: Towards the directional separation of end-of-life photovoltaic panels
Towards cleaner production of methyl glycolate: Techno-economic-environmental optimization via hybrid physics-machine learning modeling
Separation of alginate and recycling of deep eutectic solvents using temperature-responsive aqueous two-phase systems
Electrostatic interaction-driven surface engineering for fabrication of uniform and size-controllable polymer microspheres in green solvent
Conceptual process design-based solvent selection: Optimization of solvent combinations with application to Suzuki–Miyaura coupling
SolvSpace: Towards sustainable solvent selection for micro- and nanomanufacturing
Data-driven design of ionic liquids for targeted desulfurization: Integrating machine learning prediction with structure-performance analysis
Amino acid mediated hydration of caustic calcined magnesia: dual-function for efficient conversion and purification
Tox-Scapes: A visual and quantitative tool for selecting safer chemical reactions by means of cytotoxicity assessment
1
Epigenetic and metabolic reprogramming support plasma cell differentiation in germinal centers
1
Construction of general N-body lattice operators with arbitrary momenta
1
CaMKII drives synaptic maturation by coordinating spine remodeling and receptor segregation via liquid-liquid phase separation
1007
Enantioselective Pyrazole Alkylation via Iridium and Squaramide Catalyzed N–H Insertion
Deoxygenative Olefin Insertion of Cyclic Alcohols Promoted by Sulfoxide Cation Radicals
Enantioselective Synthesis of Boron-Stereogenic Compounds with Multiple Chiral Elements via Cobalt-Catalyzed Desymmetric Annulation
Unlocking Selenium Chemical Space via a Programmable Synthesis Platform Bearing Cannabinoid Receptor Recognition Motifs
Cage-on-Cage Evolution toward Rigid Metallo-Organic Giant for Enhanced Fluorescence
Coordination Chemistry of a Star of David [2]Catenand
One-Shot Carbon Insertion Unlocks Polycyclic Frameworks and Near-Infrared Photocatalysts
Unexpected Chemoselectivity in Radical Aryl Translocation via Photosensitization
Asymmetric Synthesis of S-Trifluoromethyl Sulfoxide and Sulfoximine Pharmacophores
Visible-Light-Promoted Continuous-Flow Iodination of Primary C(sp3)–H Bonds: An Undirected and Regioselective Approach
Low-Temperature Pyrolysis of Aliphatic Polymers Using a Fluorinated Amorphous Silica–Alumina: Cooperative Reactivity between a Redox-Active Radical and an Aluminum Lewis Site
Selective Covalent Assembly of Gram-Negative Bacteria and Synthetic Polymers into Functional Living Materials
Nickel-Catalyzed Selective Defluorinative Deuteration of Polyfluoroarenes
Alkyl Radical Coupling with Phenoxy(imine)–Nickel(II)–Aryl Complexes: Evidence for a Multistep Process in C–C Bond Formation
Nanoscale Interfacial Organization Governs Maturation and Collapse in Passive versus Active Condensates
Ultrafast Formation of Aza-Quinone Methides from Suitably Substituted o-Hydroxymethylanilines Involves Higher Excited States
Redox-Active Doubly Boron-Doped Indenofluorenes: Isomer-Directed Access to Open- and Closed-Shell Electronic States Induces Strong Near-Infrared Activity
Universal Approach for the Depolymerization of Polyamides via Photothermal Conversion
Bringing Silicon to Drugs: Modular Construction of Sila-Pharmacophores for the Development of Target Protein Degraders
Overcoming the Barrier to Intermolecular Alkoxy Radical Reactivity: Proton-Coupled Electron Transfer-Mediated Alkene Hydroetherification
Controllable Difluorocarbene Elongation via Copper Catalysis
Generalizing Pore-Space Partitioning in Metal–Organic Frameworks
Electroenzymatic C1 Fixation to Glycine via Dithiothreitol Regeneration on Functionalized 1T′-MoS2
Electroreductive Radical Olefin Difunctionalization with Fluorinated Gases Enabled by Dosage Delivery from a Metal–Organic Framework
Electrode-Orthogonal Non-Covalent Self-Assembly Programs Microenvironments around Molecular Electrocatalysts
Distorted Nanographenes by Embedding a Cyclopenta[a]heptalene Core and Multiple Additional Heptagons: Chiral Supramolecular π-Dodecamer and Co-crystal with Fullerenes
Engineered Modular Polyketide Synthases Elucidate How Enoylreductases Collaborate with Downstream Acyl Carrier Proteins and Ketosynthases to Set Stereocenters
Selective Construction of Pseudo-Mortise-and-Tenon-Type Molecules
Silicon and Low Pt Loading Improves Redox Dynamics and Regenerability in PtGa Propane Dehydrogenation Catalysts
Distance-Dependent, Rate-Accelerating and Diastereoselective Directing Effects in Decatungstate-Mediated Stereoediting Reactions
The Pyridylketenyl Anion: Entry to Diverse N-Heterocycles
Hexacoordinate Ti-Anchored Single-Atom Pd Catalyst for High-Efficiency Cyclohexanone Ammoximation with H2 and O2
Thiol-Retaining N-Terminal Cysteine Chemistry for Dual Modification and Bicyclic Peptide Construction
Photochemistry of an Anti-Bredt Olefin through the Lens of Multistate Multireference Quantum Chemistry
Geometry-Governed Symmetry-Breaking Charge Separation and Photocatalysis of Benzoperylenetriimide Dimers
Probing Bowl-to-Bowl Inversion in Enantiopure Subphthalocyanines: Cofacial SN2 vs SN1 Pathways at a Tetracoordinate Boron Center
Group 4 Metallocenes Supported on Sulfated Zirconium Oxide Catalyze Benzene C–H Borylation
Enabling Fluoroalkyl-Sulfonylalkylation and Fluoroalkyl-Halogenation of Alkenes and Alkynes via Photoredox Catalysis
Catalyst-Free Photoinduced Deaminative Functionalization of Amino Acids and Glutarimide Precursors
Chlorosyl Nitrite (OClNO): An Elusive Intermediate in the Photochemistry of Nitryl Chloride
Access to Planar- and P-Chiral Macrocyclophane-Based Phosphines via Palladium-Catalyzed Asymmetric Hirao Reaction
Copper(I)–NHC-Catalyzed Enantioselective Borylation and Silylation of Ketimines
Controlled Pyrolysis of Polystyrene Using Metal–Organic Frameworks
Catalytic Enantioselective Elimination of Cyclobutanols
The Salting-Out Effect Enables Highly Selective Electrochemical Ammoxidation of Aldehydes to Nitriles
Designer Aromatic Cations for Photoinduced Protein Ligation, Imaging, and Intracellular Labeling at Extended Wavelengths
A C66 Polycyclic Aromatic Hydrocarbon with Six Azulene Units and NIR-II Absorption: Toward Azulene-Based Carbon Allotropes
Enantioselective Palladium-Catalyzed Intermolecular Four-Component Acylcarbonylation of Alkenes: A Modular Approach to Chiral γ-Keto Esters
Direct Synthesis of Pure Aqueous H2O2 Solutions Catalyzed by C60-Buffered Proton–Electron Transfer on Palladium Adatoms
Fast and Selective Labeling of Serine and Threonine in HFIP for Facile Editing of Peptide Alcohol Side Chains
Visible-Light-Induced C–S Bond Cleavage Enables Alkyl Radical Generation from Redox-Inert Substrates
Seven-Step Total Synthesis of Conidiogenone B Enabled by Radical Cyclizations
Enantioselective Total Syntheses of Grayanoid (−)-Mollfoliagein A and (−)-Rhodomollein XXV
A pH-Responsive Cu-Corrole-Based Cage That Reversibly Encapsulates Fullerene in a Shapeshifting Low-Symmetry Cavity
Total Synthesis of Euphopia B and Discovery of a Selective Inhibitor of Potassium Efflux-Independent NLRP3 Inflammasome Activation
Rhodium-Catalyzed Desymmetric Addition of Boronic Acids to Malononitriles
Pyridine to Pyridazine Skeletal Editing via CN-to-NN Atom-Pair Swap
Electrochemical Synthesis of Boron-Centered Carboranyl Radical for Modular Carboranyl N-Heterocycles
Facile Synthesis of Gem-Difluoroalkene-Based Bis(silanes) via Copper-Catalyzed Disilylative Defluorination of 1-Chloro-1-trifluoromethylalkenes
Enantioselective Synthesis of Quaternary Stereocenter Aldehydes by Palladium-Catalyzed Intermolecular Propargylation Reaction
Stereo-Switchable Electrochemical Glycosylation
Unraveling Quinone Degradation Enables Stabilization Using Redox Helpers in Biological and Electrochemical Systems
Interior Editing via Dynamic Molecular Recognition
Mechanistic Insights into Chemoselective Reduction of Engineered Cysteine Residues in Antibodies Using Computational Modeling and Rationally Designed Phosphines
Femtosecond-to-Second Time-Resolved Spectroscopy Brings Unparalleled Insight Into the Life Cycle of the Versatile Manganese Photocatalyst [Mn2(CO)10]
Radical Sampling Enabled Saturated N-Heterocycle Cyclization
Optimized Xanthenium Photocages with Fused Ring Systems for Photoactivated Chemotherapy and G Protein-Coupled Receptor Photopharmacology
Chemoselective Reduction of Nitroarenes to Anilines Using a Nickel Foam
A Magnetically Bistable Rigid Carbene─2,3-Benzofluorenylidene
The Emergence of Chirality in Time and Space: Transient Asymmetry in Supramolecular Polymers Triggered by Visible Light
Enantioselective Iridium-Catalyzed C–H Bond Alkylation for the Synthesis of N–N Atropisomeric Phosphines
Catalytic C-Demethylation of Phenols and Anilines Enabled by a Removable Mono-Directing Group
Chiral Pyridoxals Enabled Efficient Enantioselective Synthesis of α-Substituted Tryptophan Derivatives
Dynamic Double Carbaporphyrin-Fused Nanographene: Facile Monolayer and Persistent Bilayer Switching
Unlocking Hexahydrotriazine Chemistry for Multifold Thermoset Circularity
Asymmetric Alkene Boration and Z-Retentive Allylic Substitution Reactions under Cu/Pd Relay Catalysis
Total Synthesis of Ussuriedine via a Late-Stage Stevens Rearrangement: Implications for Biosynthesis
Chemical Proteomics Reveal the Inventory of Pyrroloquinoline Quinone Binding Proteins in Bacteria
Photocatalytic, Regioselective Enone Deconjugation: An Enabling Platform for Terpene Modification
Diastereo- and Enantioselective Construction of Vicinal Stereocenters through Tandem Electrochemical Dearomatization and Allylic Alkylation
Excited-State SNAr Reactions of Nitroarenes
Photoinduced Palladium Catalysis Enables Dynamic Kinetic Asymmetric Allylic Imidation
A High-Purity Ethylene Epoxide Stream Produced Using a Supported Electrocatalyst
Electrolyte-Guided Selectivity Unlocks Pathway Control in Electrochemical Olefin Functionalization
Active Site Structure and Mechanism of a Molybdenum Catechol Dehydroxylase
Unlocking Interfacial Catalytic Halogen Atom Transfer at Ag Electrodes with Brønsted Acids
Photo-Induced Aliphatic C–H Amination Mediated by Hydrogen Atom Transfer of an Alkoxycarbonyloxyl Radical and Its Utilization for Diastereoselective Modification of Proline Residues in Peptides
The Synthesis of Tertiary Alkylamines from Alkyl-Substituted Alkenes Using Amine Umpolung Strategy
Direct Polymer-on-Polymer Grafting of Polyolefins under Visible Light
Copper-Catalyzed Enantioconvergent Nucleophilic Fluorination of Alkyl Electrophiles to Generate α-Fluoroamides
Coenzyme-Mediated Enantioselective Carboligation via Cross-β Amyloid Microphases
Pyrrole-Bearing Porous Network Polymers Synthesized via Halogen-Bond-Assisted Radical Solid-Phase Polymerization for Highly Efficient and Selective Adsorption of Lithium Ions from Model Seawater Reverse Osmosis (SWRO) Brine
Selective Deoxygenative Electroreduction of Amides
Linker Torsional Angle Engineering in Metal–Organic Frameworks Enables Boosted O2 Photoactivation for Organic Synthesis
Influence of Phosphate Activation Chemistry on the Selection of the Primordial Genetic Alphabet
Adsorption-Biased, Halide-Tuned Perovskite Photocatalysts for Aerobic Oxidation of Primary Alcohols to Benzimidazoles
Cu-Catalyzed Stereoconvergent and Enantioselective C–S Cross-Coupling of Alkenyl Halides with Sulfenamides via Alkenyl Radicals
Radical Copolymerization of Formaldehyde with Vinyl Acetate: Direct Incorporation of C–O Bonds in Vinyl Polymer Backbones
Enantioselective [2π+2σ] Cycloaddition to Bicyclo[2.1.1]hexanes Enabled by an Artificial Photoenzyme
Direct Observation of Selective Migratory Insertion of Unactivated Terminal Alkenes into Ir–N Bonds
Highly Efficient Alkene Radical Difunctionalization toward Alkyl Azide and Nitrile Achieved by Copper Single-Atom Catalysts
Stereodivergent Inverse Electron-Demand Diels–Alder Reactions Enabled by Modification of Prolinol-Derived Catalysts
Singlet-Oxygen-Driven C(sp2)–P Bond Cleavage Enables Red-Light Uncaging of Phosphorus(V) Prodrugs on Gold Nanoclusters
Boryl Homolytic Aromatic Substitution Enables Radical Borylation via Inverted B–H Polarity of Hydroborane
Spin Alignment in Cr–W–Cr Motif Promotes N, N-Dimethylformamide Electrosynthesis from Dimethylamine Self-Coupling
Cavity Constriction and Chiralization of Polyaromatic Subnanotubes via Post-assembly Ligand/Metal Modification
Navigating the Landscape of Cycloartanyl Cations: Synthesis of Fortunefuroic Acid I, Parkeol, 25,26,27-Trinor-3α-hydroxy-17,13-friedolanosta-8,12-dien-23-one, and Spirochensilide A
Programmed Oxidation-Guided Divergent Total Syntheses of (±)-Anisatin, (±)-Neoanisatin, (±)-Majusanols A and B
Tandem Auxochrome Design Enables Ready Access to Deep Shortwave Infrared Dyes
Synergistic Transition Metal and Hydrogen Bonding Phase-Transfer Catalysis Enables Enantioconvergent Allylic Fluorination with KF
Synthesis of 1,3-Dienes from Alkenes via Alkenyl Thianthrenium Salts
One-Step-Three-Ring Propellanation Reaction of Yne-Vinylcyclobutanones Catalyzed by Nickel: Reaction Development, Mechanism, and Formal Synthesis of Modhephene
Cascade Radical Isomerization Polymerization to Engineer Polymer Backbones
Conformational Switching Controls Biradical Spin Dynamics in Flavin–Tryptophan Dyads
Nitrogen Doping at the Periphery of a Quadruply-Fused Porphyrin and Its Multi-Step Proton-Coupled Electron Transfer to Form a 34π Aromatic Molecule
Methylene Cycloalkene as a Reactive 1,3-Diene for Enantioselective Hydroamination
Enantio- and Site-Selective Synthesis of α-Substituted Hydrazines, Pyrazolidines, and Tertiary Alcohols by Copper-Catalyzed Allylic C–N and C–O Bond Formation
Unraveling the Single-Site Origin of Strong Brønsted Acidity in Fluorinated γ-Al2O3
Synthesis and Isolation of α-Diazophosphonium Ylides
Stereodivergent Construction of trans-Decalin-Based Terpenoids
3,5-Dimethylorsellinic Acid (DMOA)-Derived Meroterpenoid Ortholactones (−)-Novofumigatonin, (−)-Asnovolin F, and (−)-Asnovolin G: Total Syntheses and Related Studies
SPSiP-Enabled Pd-Catalyzed Enantioselective Alkynylamination of Alkenes
Reductive Cyclopentamerization of Carbon Monoxide to the Elusive Croconate Radical Trianion
Evolution of a Synthetic Strategy for Complex Diterpenes from Euphorbiaceae and Thymelaeaceae
Single-Electron Reactivity of Thianthrene S-Oxide and Its Synthetic Application in Late-Stage Thiocyanation and Selenocyanation
Catalytic Asymmetric cis-Dihydroxylation of Quinones Enabled by a Functional Mimic of Rieske Dioxygenases
The RAvIN Platform: A Noncarbohydrate Platform for Oligonucleotide Synthesis
Surface Coordination-Promoted Electrosynthesis of 1,4-Butanediol from Ethylene and Water via 2-Bromoethanol
Confinement Catalysis Enables Macrocyclization at Up to 0.6 M: Selective Formation of Mono- and Dimeric Glycosidic Macrocycles
Divergent Radical and Ionic Electroreductive Regulation for Disulfuration
Deciphering the Stepwise N–O Activation of Nitroarenes: Electronic Structure and Reactivity of Iron-Nitrosoarene Intermediates
Stereocontrolled Synthesis of Polysubstituted Housanes via gem-Bismetalated Cyclopropanes
Chiral Binaphthyldimethyl η6-Benzene Ligands: Design, Synthesis, and Application in Ruthenium-Catalyzed Asymmetric C–H Activation
Facile Synthesis of Nonalternant π-Conjugated Azaborines via Boron-Deleting Annulation
Perfectly Alternating Copolymerizations of Methacrylates and Coumarin to Robust C–C Main-Chain Polymers with Full Degradability and Depolymerizability
Electroreductive Cleavage of C(sp3)–N Bonds in Saturated N-Carbonyl Heterocycles
Polymerization Chaperone for the Controlled, Homogeneous Synthesis of Proline-Based Homo- and Copolypeptides
Unlocking the Silent Proteome: Chemoselective Asn/Gln Activation for Multidimensional Protein Diversification
Automated Discovery of Algorithms for Molecular Electronic Structure Calculations Using Physics-Informed Program Synthesis
Inverse Al-ZrO2/Cu Catalysts Enable the On-Purpose Production of Separable Para-Xylene and Ethylene Glycol from PET Wastes
Aminyl Radical-Enabled Photoredox/Nickel-Catalyzed C(sp3)–C(sp3) Suzuki–Miyaura Cross-Coupling via Halogen-Atom Transfer Strategy
Unveiling Orthogonal Mechanochemical Pathways via 19F NMR under a Three-Arm Pulling Strategy
Highly Catalytic Allylation of Native Carbohydrates in Water with Indium: Kinetic, Mechanistic, and Spectroscopic Studies
Anion-Suppression Strategy Enables Palladium Metallaphotoredox-Catalyzed Desymmetric Carboxylation with CO2
Electrocatalytic Oxidative Coupling of CO with Amines toward Symmetrical and Asymmetrical Urea Derivatives
Synthesis of an o-Benzoquinone Arsenic Mononitride (As≡N) Complex and Its Reaction to Singlet Arsinonitrene
Enantioselective Copper-Catalyzed Synthesis of Hydroxylamines via Hydrofunctionalization of Alkenes using Nitroalkanes
Ring Expansion of Benzofurans by Single-Silicon Insertion
Lateral Boron-Doping Intensifies Diradical State and Stabilizes Spins of peri-Acenoacene: A Nanographene Diradicaloid with Absorption beyond 1300 nm
Stimulus-Responsive Perselenide, Thioselenide, and Selenosulfide Donors for Reactive Selenium Species Chemical Biology
Deciphering Mechanistic Pathways and Selectivity in Electrochemical Oxidative C–N Bond Formation between Olefins and Sulfonamides
Merger of Heterogeneous and Homogeneous Photocatalysis for Arene C–H Amination
Efficient and Selective Hydroxyl-Mediated Photocatalytic Ethane Oxidation to Acetic Acid
Enantioselective Synthesis of Spirolactones and Spirolactams Under Low Catalyst Loadings
Potassium N-Borylisocyanamide: Synthesis, Structure, and Its Utilization as an Amino and Cyano Transfer Reagent
Photodriven Sm-Catalyzed Asymmetric Ketyl-Olefin Coupling
Biomolecular Condensates Power Nitrogen Cycling via Concurrent Redox Activities
Copper(I)-Mediated Direct C–H Functionalization of Carborane Anion: One-Pot Installation of Amino, Hydroxyl, Carbon, and Other Heteroatom Functional Groups at the C1 Vertex
Photoinitiated Enantioselective Cycloisomerization/Addition Cascades of 2-Acyl Benzaldehydes with α,β-Unsaturated Carbonyl Compounds
Catalytic C(sp3)–F Bond Activation at Low-Valent Germanium and Tin Redox Platforms
Upcycling of Vulcanized Rubber via Controlled Backbone Cleavage and Functionalization
Electrolysis-Assisted Reduction of Dimethylformamide for Unactivated Alkene Functionalizations
Steric Engineering of Phenanthrenequinone for Ultrafast and Tunable Visible Light-Induced Photoclick Reaction
Switchable and Selective Synthesis of Unsymmetrical N-Aryl Pyrazoles from 1,2,3-Thiadiazine S-Oxides
A Universal Platform for One-Pot Synthesis of Block Copolymers via Organoborane-Mediated Aerobic Tandem Polymerization
Divergent Asymmetric Synthesis of Four Pentacyclic Homoproaporphine Alkaloids via C–H Elaboration
Enzyme-Catalyzed Intramolecular C–C Coupling Transformation of Nitriles
Dynamic Covalent Boronate Chemistry for In Situ Formation, Interfacial Stabilization, and Cytomimetic Optimization of Coacervates
Ionic Liquid Gating Enol–Keto Tautomerism
Redox- and Protonation-Tunable Diboraheptacenes
Desymmetrization of meso-Pyrrolidines via Oxoammonium-Catalyzed Enantioselective Hydride Transfer
Copper-Catalyzed Asymmetric Vinylation of α-Cyano Substituted Carbonyl Compounds
Iron-Catalyzed anti-Markovnikov Allylzincation of Terminal Alkynes
Redox-Controlled Chalcogen Bonding as a Modulator of ZnCl2 Chelation and Transport
Solar-Driven Upcycling of Polystyrene Enabled by Elemental Sulfur
Leveraging Conformational and Nitrogen Atom Inversion for Room-Temperature Ferroelectricity
Catalytic Remote Dihalogenation of Alkenes Induced by Transposition of Esters
All-Hydrocarbon Polymers with Chemical Recyclability via a Catalyst-Free and Solvent-Free Method
C–H Nucleophilic Substitution for the Diversity-Oriented Modification of Polycyclic Aromatic Hydrocarbons
Photocatalytic Direct Deoxytrifluoromethoxylation of Phenols
Orchestrating the Semiquinone Stability for Catalytic Proton-Coupled Electron Transfer
How Alkali Metal Alkoxides Initiate Organic Radical Reactions
Transformation of Dewar Metallabenzenes: Valence Bond Isomerization to Metallabenzenes and Beyond
Synthesis of α-Deuterated Trifluoromethylated Amines through Isomerization-Deuteration Reaction of Imines
Flexibility Induced by Four Heptagons: A Negatively Curved Polycyclic Aromatic Hydrocarbon Cut-Out of Schwarzite P216
Methane Catalytic Amidation via a Plausible Copper-Nitrene Intermediate
Artificial Spherical Chromatophore Mimicking LH2 and LH1–RC for Highly Efficient Photocatalytic Hydrogen Production with Turnover Number >667,000
Organotellurium Probes Enable One-step Single-cell Analysis of Post-translational Modification
Potassium Bisulfite’s Role in Developing a Robust Platform for Enantioenriched N-Alkylpyridinium Salts as Piperidine Precursors
Chemoenzymatic Synthesis of Arisugacins and Terreulactones via Directed Evolution of a Privileged Sclareolide Dioxygenase
Strategy for the Synthesis of Inverse Sandwich 1,4-Diarylbutadiene Dianionic Rare-Earth Metal Complexes via Directing Coupling of β-Aryl Vinyl Boron Reagents
Biosynthesis of 14-Membered Cyclopeptide Alkaloids via Nonheme Iron- and 2-Oxoglutarate-Dependent Oxidative Decarboxylation
Cation–Cation Photosensitization for Protein Ligation and Intracellular Catalysis
Electrochemically Mediated Depolymerization of Polymers Synthesized by Atom Transfer Radical Polymerization
Ligand Design Enables Introduction of Nonaromatic Arylating Agents in Palladium-Catalyzed C–H Arylation of Arenes
Mechanism-Inspired Ligand Design for Efficient Copper-Catalyzed C–N Coupling of Aryl and Heteroaryl Chlorides
Pseudo–Jahn–Teller Distortion in a One-Dimensional π-Conjugated Polymer
Enantioselective C–H Arylation for Axially Chiral Tetra-ortho-Substituted Heterobiaryl N-Oxides
The Catalytic Asymmetric Mukaiyama–Michael Reaction of Silyl Ketene Acetals with Cyclic Enones: Short Routes to Jasmonates
Synthesis of Spiro Carbocycles via Methyl β-C(sp3)–H Functionalization of Cyclic Aliphatic Acids
Enantioselective Total Synthesis of Two Aromatized Halicyclamines
Myxarylin: Total In Vitro Biosynthesis, Expansion of Substrate Scope, and Bioengineered Thioamidated Biarylitides
Taming Sulfate Radical for Anti-Markovnikov Alkene Hydrosulfation
Photocatalytic Reconstruction of Bicyclo[1.1.0]butanes to Oxygenated Bicycles
Total Synthesis and Complete Stereochemical Assignment of the Marine Bromotriterpenoid (+)-Callicladol through a Combined Approach Using Model Syntheses and Nuclear Magnetic Resonance Calculations
Harnessing Cooperative Hydrogen-Atom Transfer and Nitrene-Primed Radical–Polar Crossover for Asymmetric C–H Amidation of α-Amino Carbonyls
Palladium-Catalyzed Autotandem Hydrogenolysis/Hydrogenation for the Synthesis of Hexahydro-β-carbolines Containing Three Contiguous Stereocenters
Craig Excited-State Aromaticity in Metallabenzenes: How, When, and Why?
A Rational Desymmetrization Approach for Enantioselective Synthesis of Inherently Chiral C1-Symmetric Metal–Organic Cages
Overriding Stereochemical Outcomes in Cyclase Phase Total Synthesis: Enantioselective Synthesis of Habiterpenol and Dasyscyphin A
Enantioconvergent Indole Alkylation Using Diols via Oxocarbenium Intermediate by Borrowing Hydrogen To Access γ-/δ-Chiral Ketones
Copper-Catalyzed Enantioconvergent Radical Deborylative Coupling of Racemic Benzylboronic Esters with Alkynes and Alkenylboronic Esters
Expanding Ullmann Homocoupling to Cross-Coupling: Electrochemical Copper-Catalyzed Cross-Electrophile Coupling of Alkyl and Aryl Halides
Surface Halogen Passivation Enables Ultra-Stable Metal Sulfide for Efficient Methanol Photoactivation
The Radical SAM Enzyme BlsE Can Operate as a Dehydratase, Dehydrogenase, or Epimerase upon Mutation of a Single Active Site Serine Residue
In Situ Heterochiral Helix Coupling Triggered Supramolecular Evolution
Total Synthesis of (±)-Dhilirolide U
Switching Shapes: Reversible Three Species Photoisomerization of Substituted 1,2-Dihydro-1,2-azaborinines
Fused Rubrene Derivatives with Embedded Seven-Membered Rings: Curvature-Dependent Photophysical and Semiconductor Properties
Photoredox Unmasking of Aromatic C–H Bonds in Living Environments Enabled by Thianthrenium Salts
Gomberg’s Earlier “Instance of Trivalent Carbon”
A C1-Homologative Trifluoromethylation: Light-Driven Decarboxylative Trifluoroethylation of Carboxylic Acids
Total Synthesis of (±)- and (+)-Euphohyrisnoid A
Inverse Molecular Design for the Discovery of Organic Energy Transfer Photocatalysts: Bridging Global and Local Chemical Space Exploration
Photodriven Enantioselective 6-endo Hydroaminative Cyclization to Chiral 4-Substituted 3,4-Dihydroisoquinolones
Co-Catalyzed Asymmetric Carbamoyl Radical Addition of Imines
Carbenes Embedded in Cyclic Paraphenylenes: Detection, Ground-State Spin Multiplicity, and Möbius Aromaticity
Visible-Light-Mediated Lewis Acid-Catalyzed Diradical Hydrogen Atom Transfer Reaction of Bicyclo[1.1.0]butanes
Shifting Merocyanine-Imine Exchange with Visible Light
Oxidation of a Dihydrophenazine Molecular Wire Attenuates Molecular Conductance
De Novo Labile C–N Bonds Enable Dynamic Covalent Chemistry and Reversible Bioimaging
Waveform-Enhanced Alternating Current Electrocatalysis Enables Cu-Catalyzed Carbon–Oxygenation of β-Keto Carbonyls with Alkenes and Alkynes
Leveraging Divergent Ligand-to-Metal Charge-Transfer Excited State Pathways for Catalyst Control over Alkoxyl Radical Reactivity
Copper(I)-N-Heterocyclic Carbene-Catalyzed Enantioselective Conjugate Allylation of α,β-Unsaturated Esters
Intermolecular Cyclization of Alkyl Chains of Ketones for Constructing ortho-Diacylbenzenes
Seven-Membered Azacyclic Allenes: Synthesis, Trapping, and Stereochemical Transfer Studies
[2 + 1] and [2 + 1 + 1] Cyclization: Diversifying Alkenes for Small Carbocycles via Photocatalytically Accessed 1,3-Dielectrophiles
Asymmetric Ketone Diene Coupling via Stereodivergent Copper Catalysis
Ring Constraint Strategy Enabled Cycloaddition of Oxazolones and Alkenes via Photoinduced Energy Transfer
Room-Temperature Methane Oxidation to Formaldehyde Mediated by CoMoO+ Gas-Phase Cations
Antiaromaticity Relief-Mediated Intramolecular Charge Transfer Enables Efficient and Stable Radical Emission in Polar Solvents
Diazulenopentalene: Facile Synthesis of Linear Non-Alternant Molecular Carbons through Pt-Mediated Rearrangement
Expedient Synthesis of N-Protected/C-Activated Unnatural Amino Acids for Direct Peptide Synthesis
Engaging Unstabilized Alkyl Radicals with Pyridoxal Radical Biocatalysis: Enantiodivergent Synthesis of Aliphatic Non-Canonical Amino Acids
Thiol-Free Sulfenylation Redefined: A Single-Atom Transfer Pathway to Symmetrical Di(hetero)arylthioethers via B(C6F5)3 Catalysis
Iridium-Catalyzed Borylation of Strong Alkyl C(sp3)–H Bonds of Sulfonamides Enabled by Triflyl Activation
Enantioselective Functionalization of Light Alkanes and C(sp3)–H Bonds via Photoinduced Palladium Catalysis
Copper-Catalyzed Asymmetric Amino Lactonization of Alkenes: Direct Access to Enantioenriched 1,2-Alkylamino Alcohol Derivatives
Iridium-Catalyzed meta-Selective C–H Silylation of Arenes Enabled by Remote Regiocontrol with a Spirobipyridine Ligand
Light-Driven Organocatalytic Birch Reduction for Late-Stage Drug Modification and sp3-Rich Spirocycle Synthesis
Depolymerization-Induced Morphological Transformation
Regulating π-Stacked Micelle-Like Assembly via Anion Coordination to Achieve Frank–Kasper C15 Phases
Confined Chiral Pd(II) Catalyst-Enabled Enantioselective Intramolecular Aminoalkylation of Alkenes: One-Step Construction of Chiral N-Fused Bicyclic Skeletons
Concise Synthesis of Deoxylimonin
Development of Multiple Local Computational Models in Retrosynthetic Analysis: Total Synthesis of (−)-Deoxylimonin
A Hooker Oxygenase Archetype in Polyketide Biosynthesis Challenging the Baeyer–Villiger Monooxygenase Paradigm
Transient Compartmentalization in Coacervates Driven by Chemically Fueled Autocatalysis and Interfacial Remodeling
Ambimodal (2 + 1)/(4 + 1) Pseudopericyclic Transition States in Reactions between Dihalocarbenes and Olefins
Medium-Sized-Molecule Encapsulation in Coordination Cages via Solid-State Mechanochemistry
Observed versus Predicted Reactivity, Selectivity, and Mechanism of Iridium Catalysts with Pyridyl Carbene Ligands for the Borylation of C–H Bonds
The Effect of Allosteric Conformational Regulation on the Crystal Packing of Aromatic Amide Metallomacrocycles via Ligand-Modulated Remote Intramolecular Hydrogen Bonds
Construction of Heteroleptic Copper Complexes in Perylene Diimide-Based COFs for Heterogeneous Metallaphotoredox Catalysis
Catalytic Stereospecific Construction of Aminocyclopropanes from β-Boryl Amides
Photocatalytic Upcycling of Polyethylene Terephthalate via Formate-Mediated Non-Hydrogen Deoxygenative Reduction
Controlling Reductive Elimination Pathways in Ti(IV) Pincer Complexes: Concerted versus Radical Mechanisms via Ligand Design
Tailored Phosphate Leaving Groups Direct Pathway-Dependent Self-Assembly
Rapid and High-Yielding Disulfide Bioconjugation at Any Desired Site in Proteins
An Organoborate Monoxide Radical
How Does Adenine Form from Hydrogen Cyanide?
Molecular Weight-Controlled Cationic Polymerization of Tetrahydrofuran Using a Squaramidinium Hydrogen-Bond Donor Catalyst
A Diazo-free Equivalent of the Unsubstituted Carbyne Cation: Straightforward Synthesis of Naphthalenes and Pyridines via [12/13CH]+ Insertion
Doping a Nanographene with a Formal NiIV Center
Oxidative Peptide Backbone Cleavage by a HEXXH Enzyme during RiPP Biosynthesis
Elucidating Leader Peptide–Enzyme Dynamics in Lactazole Biosynthesis Using mRNA Display
Compatibilization of Polyolefin Blends through Acid–Base Interactions
Engineered Flavin-Dependent Halogenases Catalyze C–C Bond Formation via Enantioselective Semipinacol Rearrangement
Photo- and Copper Dual-Catalyzed Z-Selective Chlorosulfonylation of Allenes for Tetrasubstituted Alkenes
Click-to-Release Reactions for Tertiary Amines and Pyridines
Enantioselective Total Synthesis of (+)-Fusicoccadiene via Photocatalytic Polyene Isomerization
Selective Chemical Looping Combustion of Terminal Alkynes in Mixtures with Alkenes
Iridium-Catalyzed B–H/C–H Dehydrogenative Coupling to Enable Boron–Nitrogen-Embedded Polycyclic Aromatic Hydrocarbons
Positional Isomerization of 1,2-Azaborine through BN-Benzvalene
Palladium-Catalyzed Asymmetric Oxidative Amination of Internal α,β-Unsaturated Esters with Lewis Basic Amines
Enantioselective Radical Addition of Carboxylic Acids to Imines through Cooperative Copper/Acridine Catalysis
Electrochemically Initiated Depolymerization of Poly(Methyl Methacrylate)
Photolysis of CO2 Carbamate for Hydrocarboxylation Reactions
Catalyst Metamorphosis: In Situ Oxidation of Diphosphines in Palladium-Catalyzed Regioselective and Enantioselective Heck Reactions
Catellani-Inspired BN-Aromatic Expansion: A Versatile Tool toward π-Extended 1,2-Azaborines with Tunable Photosensitizing Properties
Electrochemical Indole Skeletal Editing via Single-Carbon Atom Insertion
Unified Synthesis Platform for 1,2,3-Trisubstituted Cyclopentadienyl Ligands Decouples Sterics from Electronics
Accelerated and Green Synthesis of N,S- and N,O-Heterocycles in Microdroplets
Redox-Switchable Halogen Bonding in Haloanthracene Mediators Enables Efficient Electrocatalytic C–N Coupling
A Rational Design of Chiral Iron(III) Complexes for Photocatalytic Asymmetric Radical Cation (4 + 2) Cycloadditions and the Total Synthesis of (+)-Heitziamide A
Total Synthesis of (+)-Melicolone K Enabled by a Late-Stage Programmed C–H Functionalization
Integrating High-Density Frustrated Lewis Pairs with Switchable Pt–O–In Motifs to Break the Activity–Selectivity Trade-Off of Methane Photooxidation
Iron-Catalyzed Synthesis of Unsymmetrical Disilanes
Asymmetric Total Synthesis of Vilmotenitine A and Structural Revision of Hemsleyaconitine F
Asymmetric Desymmetrizing Sulfonylation of Diarylmethanes via Peptidyl-Cu(I)-Catalysis with Remote Stereocontrol
Ambiphilic Reactivity and Switchable Methyl Transfer at a T-Shaped Bi(NNN) Complex Enabled by a Redox-Active Pincer Ligand
Host–Guest Interaction-Controlled Site-Selective C–H Borylation of Aromatic Compounds
The Atroposelective Iodination of 2-Amino-6-arylpyridines Catalyzed by Chiral Disulfonimides Actually Proceeds via Brønsted Base Catalysis: A Combined Experimental, Computational, and Machine-Learning Study
Chemoenzymatic Diazo Synthesis Enabled by Enzymatic Halide Recycling with Vanadium-Dependent Haloperoxidases
Modular Synthesis of Chiral Multi-Substituted Cyclohexanes via Cobalt-Catalyzed Enantioselective Desymmetrizing Hydroalkylation
Mechanistic Study of Cycloisomerization of 1,7-Allenenes and Guidance to Develop a [2 + 1 + 2] Reaction of 1,7-Allenenes with CO for Accessing cis- and trans-5/5 Skeletons
Phosphonium Ionic Imine Cage with an Uncommon Tri24Di6 Topology for Selective Capture of Propyne in Propyne/Propylene Separation
Asymmetric C–H Functionalization of Bicyclo[2.1.1]hexanes and Their 2-Oxa- and 2-Aza Derivatives via Rhodium Carbene Intermediates
Pnictogen Interaction Promotes Nitric Oxide (NO) Release via the NO2 Roaming Mechanism in 2-Nitropyridine
Divergent Total Synthesis of the Harziane Diterpenoids
Asymmetric Carbonium Ion Catalysis: The Intramolecular Hydroalkoxylation of Cyclopropanes
Caging the Chlorine Radical: Chemoselective Photocatalytic C(sp3)–H Functionalization Enabled by Terminal Cu–Cl Sites in a Metal–Organic Framework
Thiol-Regulated Rhodium Nanocatalyst for Electrochemical Reductive Perdeuteration of Alkenes
Using Mechanochemistry to Activate Poly(vinyl chloride) as a Mechanotunable Brønsted-Acid-Releasing Reagent for Organic Synthesis
Mapping the Undirected Borylation of C(sp3)–H Bonds in Strained Rings
Enabling Proteins with Photocatalytic Functions via HisTag–Iridium Coordination
Dynamic Kinetic Control Enables Nickel-Catalyzed Enantioconvergent C(sp3)–O Coupling
Ligand-Relay Strategy Enabling Copper-Catalyzed C–C/C–O/C–N Cascade Trifunctionalization of Internal Alkynes and Propargylic Sites: Synthesis of Benzofuran-β-Lactams
Collective Total Synthesis of 12 C4-Oxygenated Cladiellins and Structure Elucidation of Cladieunicellin D and Cladielloides A/C
Stereoselective Dihalogenation of Alkynes to Access Enantioenriched Z-Vicinal Dihaloalkene Atropisomers
Photochemical Fluoroalkylations with Fluorinated Gases Facilitated by a Robust Metal–Organic Framework
Harnessing CO2 Radical Anion-Mediated Electron Transfer for Scalable Copper-Catalyzed Cross-Coupling
Coordination Cage-Confined Chirality of Non-precious Metals for Enantioselective C–C and C–N Bond Formation
Potentially Prebiotic Synthesis of a 3′-Amino-3′-deoxyribonucleoside
Electrocatalytic Semi-Hydrogenation of Pyridine Derivatives over an In Situ Assembled Cu Cathode
Stereocontrol on Helical Bimetallic DNA Catalysts with Switchable Enantioselectivity via Dynamic Reaction Distance Regulation
Fluorescence Quenching Properties and Bioimaging Applications of Readily Accessible Blue to Far-Red Fluorogenic Triazinium Salts
Crystalline Neutral Boraolympicenyl Radicals with Electronic Regulation through Boron-Doping Sites
Aromatic and Antiaromatic Dehydroannulenes
Enantioselective Construction of 1,3-Stereogenic Centers via 1,3-Borylamination of Conjugated Dienes
Reversible Interconversion between a Carbon–Carbon Double Bond and Diradical beyond External Stimulus
Catalytic Deracemization of 1,2-Aminoalcohols through Enantioselective Hydrogen Atom Abstraction
An Aluminum-Stabilized Aminonitrene
Electrochemical Hydrogenation of Aza-Arenes Using H2O as H Source
Precision Labeling of Native Antibodies with Lock Coupling
Mechanical Energy Drives Dissipative Self-Assembly of Nanocoacervates into Vesicles with Cell-like Properties
Direct Aziridine Synthesis from Amines and Styrene Derivatives via a Base-Promoted Oxidative Cascade Reaction
Catalytic Asymmetric Carbosilylation of Methyl Propiolate with Bis-silyl Ketene Acetals
A Concise Total Synthesis of (+)-Pedrolide
Visible-Light-Induced Nitrogen-Atom Deletion of Unactivated Secondary Amines
Late-Stage Diversification of Native Tryptophan-Containing Peptides and Peptide Drugs through Nitrogen Atom Insertion
Reversible Photoswitching of Donor–Acceptor Stenhouse Adducts in Water
Automated Rapid Synthesis of High-Purity Head-to-Tail Cyclic Peptides via a Diaminonicotinic Acid Scaffold
Enantioselective C–H Activation for the Construction of Chiral Tertiary Fluorides via Migrative Carbofluorination
Dual Cation/Anion Binding in Crown Ether-Based Coordination Cages
Cu-Catalyzed Enantioselective and Divergent Synthesis of 5–5-Membered Atropisomers via Direct Atroposelective C–C/C–N Axial Bond Formation
Positional Isomerism Tunes Molecular Reactivities and Mechanisms toward Pathological Targets in Dementia
Ortho–Ortho Selective Oxidative Coupling of Phenols by Hydroxo Multicopper(II) Clusters
Visible Light-Driven Contra-Thermodynamic Functional Group Transposition of Chalcones
Enantioselective Intramolecular C–H Alkylation Catalyzed by a Nonsymmetric Chiral Cobalt Porphyrin
Asymmetric Catalytic Construction of 1,1-Diheteroquaternary Tetrahydro-β-carbolines Enables Collective Syntheses of Polycyclic Alkaloids
A Divergent Asymmetric Total Synthesis of Coprophilin and Four Trichodermic Acids via a [1,5]-Hydride Shift–Aldol Cascade
Efficient Electrosynthesis of Adipic Acid via a Cascade Reaction at Pickering Droplet Interfaces
Dispersive Fluorine/Bromine Interactions as Key Selectivity Determinant: Asymmetric Cyclopropanations with 3,3,3-Trifluoro-2-diazopropionate Catalyzed by a Heterochiral-at-The-Metal Centers Dirhodium Paddlewheel Complex
Unified Total Synthesis of Phrymarolin and Haedoxan Natural Products
Aza Analogs of Arene Oxygenase Metabolization via Iron Catalysis
Air-Stable Cobalt−Semiquinone Radical Complexes on Carbon Nanotubes: A Redox Switch for Anion Response
O2-Mediated Reactivity of Confined Carbenium Ions in Zeolites
Cascade Dearomative Hydride Transfer/Enantioselective Semipinacol Rearrangement of Quinolines by a Chiral Brønsted Acid
Direct Catalytic Enantioselective C(sp2)–H Allylation of Acrylic Acids: Modular Access to Chiral 1,4-Skipped Dienes
Valorization of CO2 and N2O Gas Enabled by a Single Multi-Photoinduced Electron Transfer Catalyst
Photocatalytic Strain-Release Transformation of Bicyclo[1.1.0]butanes (BCB) Using Strategically Tuned Covalent Organic Frameworks
Total Synthesis of Acoapetaludine A Enabled by a Rhodium-Catalyzed Domino Cyclization
Transforming Amino Acids into Serotonin 5-HT2A Receptor Ligands Using Photochemistry
Evaluation of Elementary Steps in Csp2–Csp3 Cross-Electrophile Coupling Reactions Mediated by a Common Ni Complex
Copper-Dependent Oxidase Catalyzes Aryl Cross-Coupling in the Biosynthesis of a Minimal Ribosomally Derived Natural Product
Boron Nitride-Confined Nanographene as a Metal-Free Catalyst for Acetylene Hydrochlorination
Hydrogen Isotope Exchange of Aromatic C(sp2)–H Bonds via Electron Donor–Acceptor Organic Photocatalysis
Aziridine–Epoxide Heterocoupling: A Straightforward Approach to Stereoselective Synthesis of Complex Morpholine Derivatives
Rhodium-Catalyzed Atroposelective Alkyne Oxyamidation Using Non-Nitrene NH Acyloxyamide Reagents
CO2 Unlocks Reactivity: Boryl Silyl Ketene Acetals Enable Mild and Direct C═C Bond Cleavage
Electrochemical Dehydroxymethylative Functionalization of Unactivated Alcohols via Criegee–Kolbe Radical Relay
Design of Phosphine-Heteroarenesulfonamide Ligands as Dinuclear Silver Catalysts for Enantioselective Construction of α,β-Diamino Acids
Enantioselective Ni–Al Bimetal-Catalyzed Cycloaddition of Cyclopropyl Ketones with Alkynes under Mild Conditions
Boron-Enabled Stereoselective Synthesis of Polysubstituted Housanes
Unified Total Synthesis of C2-Symmetric Bis(cyclotryptamine) Alkaloids Utilizing a Single-Atom Insertion/Deletion Strategy
Elucidating Electronic Coupling of Bimolecular Excited State Electron Transfer
Electrosynthesis of High-Valent Iridium-Oxo Species for Efficient Oxygen Transfer Defluorination
Proton-Regulated C–N Coupling for Efficient Amino Acid Electrosynthesis
Catalytic Enantioselective Cross-Nucleophile Coupling via Valence Tautomerism
Synergizing Structure-Guided Photocaged Linear Diubiquitin-Dha with Biotinylated Linear-Fab for Time-Resolved Profiling of Interactors in Living Cells
Photo-Induced Intermolecular N–N Cross-Coupling via Nitrene Transfer Reaction
Copper-Catalyzed Asymmetric Alkynylation of sp2 Allenic C–H Bonds for the Synthesis of Skipped Diynes
Aryne Generation from Aryl Halides Via Photothermal Red-Light Activation
Alkane Coordination by a Neutral, Lewis Acidic Magnesium Complex
Total Synthesis of Aconicarmisulfonine A, a Sulfonated Diterpene Alkaloid
Unifying Dearomatization and Rearomatization via Stereoselective Chlorination/Dechlorination: Resolution of Axially Chiral 1-Aryl-2-naphthols
Catalytic Enantioselective [6π] Photocyclization Reactions by Chromophore Activation with a Chiral Lewis Acid
Conformationally Adaptive Molecular Cages Enabled by Metal Cluster-Mediated Assembly
Carbonylative Ring Expansion of Cyclic Carboxylic Acids
Constructing a Built-In Electric Field via Polymer Modification to Boost D2O Reorientation and Electron Transfer for Deuteroacetic Acid Electrosynthesis
Annulative Skeletal Diversification of Pyrimidines to Expanded Heteroaromatic Space
Unleashing the Power of Potassium 2-Ethylhexanoate as a Mild and Soluble Base for Pd-Catalyzed C–N Cross-Coupling
Total Synthesis and Anticancer Study of (+)-Verticillin A
Electrocatalytic Proton Borrowing N-Alkylation of Pure Alcohols and Amines
Harnessing the Potent Excited-State Reductive Power of Pyrene-Modified N-Heterocyclic Carbene-Stabilized Au13 Nanoclusters for Four-Electron Nitroarene Reduction with Unity Selectivity
Thianthrenium Chemistry for Identification of Protein–Protein Interactions in Cells
Protocells with ATP-Fueled Dissipative Behaviors as Functional Regulators
Disrupting the Photochemical Landscape of a β-Diketone via Electrostatic Perturbation of Ground-State Tautomers
A Trifunctional, Rare-Earth Theranostic Chelator Platform to Enable Diagnostic Nuclear Imaging, Surgical Resection, and Radiotherapy
A Pragmatic Radical Strategy for Dearomative Hydroalkylation of Unactivated Indoles
Catalytic Enantioselective Synthesis of Planar-Chiral Cyclophanes via a Chiral Octahedral Cobalt(III)-Templated C–H Macrocyclization
Dynamic Electromerism: Correlated Rotational and Cross-Conjugation Dynamics in DAMN (DiAminoMaleoNitrile) and DAFN (DiAminoFumaroNitrile) Derivatives
Synthesis of Phenylenediamines via (4 + 1 + 1) Photocycloaddition of 1,3-Dienes and Isocyanides Enabled by a Gallium(I)/(III) Redox: The Key Role of a Phenalenyl-Based Ligand
Transforming Waste Cooking Oil into Linear and Branched Polyethylene Mimics
Bioorthogonal Photocatalytic Protein Labeling and Cross-Linking Enabled by Stabilized Ketyl Radicals
Facile Access to Tricyclic Molecular Architectures through Photo-Reversible Dearomative 6π-Desymmetrizations: Scope, Applications, Bioactivity Study, and Mechanistic Nuances
Catenanes of Twin-Cavity Cages
Vinigrol Tricyclic Scaffold Biosynthesis Employs an Atypical Terpene Cyclase and a Multipotent Cyclization Cascade
Taming Halogen Radicals via Electrophotocatalysis: Direct Access to Alkenyl Halides
Enantioselective Radical Sulfonylation of 2-Naphthols and β-Ketoamides with Sodium Sulfinates
Convergent Total Synthesis of Papililone A via Pd-Catalyzed Alkenylation/Cyclization Cascade
Hydrogen-Bond-Donor Coupled Electron Transfer Enabled Copper-Catalyzed Asymmetric Radical Alkynylation with a Planar Chiral Ligand
A Unified Synthetic Approach to 2-Alkyl Azetidines, Oxetanes, Thietanes and Cyclobutanes from Unactivated Alkenes
Isolation and Reactivity of a Silylene-Stabilized Borasilylidene
Fluoride-Triggered Protein Activation via a Genetically Encoded Tyrosine Analogue
Antiaromatic Nanographenes via a BODIPY-Fusion Strategy
Pd/SadPhos Enabled Modular and Enantioselective Assembly of Triarylmethanes
Protocell Survival Networks in Spatially Modulated Chemical Gradients
Total Synthesis of Trigocherrins A and C
Asymmetric Synthesis of Diverse P(V) Compounds Bearing a C–P Bond via Desymmetrization of Phosphonic Dichlorides Catalyzed by a Chiral Bicyclic Imidazole
Water-Promoted Molar-Level Photocatalysis and Spontaneous Product Separation with Near-Unity Quantum Efficiency
Entropy-Driven Amino Acid-Based Coacervates with Enzyme-Free Metabolism and Prebiotic Robustness
Steric Control over Heteroleptic Trigonal Prisms: From Integrative Self-Sorting to Programmable Spin-State Modulation through Cage Transformations
Copper-Catalyzed Enantioselective Intra- and Intermolecular Desymmetrization of Azetidiniums by Carbon Nucleophiles
Solar-Driven C–N Coupling over Pd/TiO2 Enables High-Yield Synthesis of Methylamine Hydrochlorides from Methanol and Ammonium Chloride
Adaptive Macromolecular Surfactancy: Dynamic Bottlebrush Polymers Activated by Triggered Interfacial Hydrolysis
Solar-Driven Upcycling of Polylactic Acid to Alanine over Pt/CdS–TiO2 Heterojunction Single-Atom Photocatalyst
Fast and Site-Specific Covalent Targeting of Proteins by Arylfluorosulfate-Modified Aptamers
Short, Enantioselective Total Synthesis of (+)-Ineleganolide
Dual Catalytic Enantioconvergent Carbamoylation of Aziridines
Catalytic Asymmetric Synthesis of 3-Hydroxyindolenines Using Achiral Oxaziridines
On-Surface Synthesis of Nonbenzenoid PAHs Using Intermolecular π-Radical C–C Coupling
Skeletal Editing by Tip-Induced Chemistry
Photoenzymatic C(sp3)–H Functionalization of 1,3-Dicarbonyls Enables Enantioselective Hydroalkylation of Styrenes
Supramolecular Ionic Polymerization: Cellulose-Based Supramolecular Plastics with Broadly Tunable Mechanical Properties
Direct Interconversion between Bis(borylenes) and Diborenes
Multisite Proton-Coupled Electron Transfer Enables Iodanyl Radical Catalysis
Reactions of Radical Anions with Hydrides: Supercharging Electron Upconversion for Electron Catalysis
Selective Chiral Diamine-bisoxazoline Iron(II) Catalysts for Pyrrolidine Formation via Intramolecular C(sp3)–H Amination of Aliphatic Azides
Bulky Phosphine Ligands Promote Palladium-Catalyzed Protodeboronation
Structural Interconversions and Guest Binding Properties of Tetrakis(formylpyridine)-Based Pseudo-Cubic and Trigonal-Prismatic Metal–Organic Capsules
Imine Reductase-Catalyzed, Radical-Mediated Asymmetric Cyano Group Migration
Redox Umpolung of Phenalenyl-Based Molecule Inside Water-Soluble Nanocages
Experimental Mechanistic Studies on Alternating Polarity Electrolysis for Carbon-Centered Radical Generation
Synthesis of Collinoketones via Biomimetic [6 + 4] Cycloaddition
Bimetallic Relay Catalysis for Radical Hydrofunctionalization of Alkenes with Diverse Nucleophiles
Degradation of Postconsumer Thermoset Rubbers via Photo-Oxidation
Chemical Tagging of N-Alkylamine-Containing Natural Products and Pharmaceuticals through C(sp3)–H Functionalization
Selective Electrochemical C–N Coupling via Synergetic Chemical and Electrochemical Microenvironment Regulation Strategies
Asymmetric Synthesis of Quaternary Hydantoins via a Palladium-Catalyzed Aza-Heck Cyclization
Supramolecular Assembly of a Macrocyclic Rhodium(I) Isocyanide Complex with Long-Lived Near-Infrared Luminescence
General Light-Induced Pd-Catalyzed Allylic C–H Alkylation of Internal Alkenes: Direct Access to Tertiary and Quaternary Carbon Centers
β-Substituted Styrenes in Heteroaryl-Directed Hydroalkylative Cross-Couplings: Regio-, Diastereo-, and Enantioselective Formation of β-Stereogenic Tertiary Alcohols
Stereoconvergent Polymerization Driven by Catalytic Racemization
General Photo-Driven Chemoselective and Rapid Hydropentafluorosulfanylation of Alkenes via an Orchestrated Radical Chain Process
Experimentally Derived Charge Density of Halogen Bonds to Heavy Pnictogens: Revealing Electronic Structure and Validating Density Functional Theory Approaches
Cucurbit[8]uril-Induced Self-Sorting Heterodimer for Aqueous Red/NIR Delayed Emission
Electroreduction of Aromatic Carboxylic Derivatives to Aldehydes
Driving Force Dependent Photoinduced Charge Transfer Dynamics in Polymer-Wrapped Semiconducting Single-Walled Carbon Nanotubes
Enzymatic Anti-Baldwin Ring-Closure Cascade for Fused Bicyclic Ether Formation
On-Surface Synthesis of a Nitrogen-Doped Curved Cycloarene: π-Extended Pentaazaquintulene and Its Gold Complex
Palladium-Catalyzed Site– and Enantiodifferentiating Allylic C–H Alkylation of Internal Alkenes
Metal/Oxide Interface Enabling Selective Electrocatalytic Reduction of Oxime to Amine in Neutral Electrolyte
Electronic Activation Enables the Borylation of Alkyl C–H Bonds in Saturated Nitrogen Heterocycles
Effective Recycling Pathways of Commodity Polymers Enabled by Mechanoradical Capture
Direct B–H Bond Activation Polymerization of Boron Clusters
Stereoselective De Novo Construction of Cyclopropane by a Multifunctional Class I Aldolase
Chemical Recycling of Polyesters and Polycarbonates: Why Is Zinc(II) Such an Effective Depolymerization Catalyst?
Application of Asymmetric Catalysis in the E/Z-Stereodivergent Synthesis of Alkenes
Ligand-Controlled Chemodivergent Bismuth Catalysis
A General Strategy to Access All Stereosequences in a Synthetic Polymer
Snap-Trapping Strategy for Amine-Specific Bioconjugation with Pyridotriazole Carbaldehydes
Atoms and Bonds as Synergisms of Interacting Electrons and Nuclei. The Origin of Chemical Bonds in Polyatomic Molecules
Total Synthesis of (+)-Resiniferatoxin via a Pyridinium Salt Photorearrangement
Development, Application, and Mechanistic Interrogation of a Dual Ni Catalysis Approach to Photoredox-Based C(sp3)–C(sp3) Cross-Coupling
Visualizing the Invisible: Dual Click Imaging of Ruthenium-Based Photoactivated Chemotherapy Agents and Their DNA Synthesis Inhibition in Fixed Cancer Cells
1,2-Oxygen Transposition on Arenes Enabled by Palladium/Norbornene Cooperative Catalysis
Engineering Polyketide Stereocenters with Ketoreductase Domain Exchanges
Biocatalytic Activation of Sulfur Heteroaromatics Facilitates Dearomatizing Cross-Couplings to Set Stereogenic Centers or Axes
Enantioselective Synthesis of (+)-Auriculatol A
Ligand-Directed Site-Selective Cysteine Bioconjugation of the KELCH Domain of KEAP1 with Hypervalent Iodine Reagents
Precise Synthesis of Pyrene-Based Molecular Nanocarbons Driven by Dehydro-Diels–Alder Reactions
Electrophotocatalytic Oxygenation of Unactivated Aliphatic C–H Bonds Using Water as a Sustainable Oxygen Source
Enantioselective N-Heteroaryl C–H Functionalization for Piperidine-Azine Conjugation: Alkynes as Allylmetal Pronucleophiles in Dearomative Addition-Hydrogen Auto-Transfer
Copper-Catalyzed Enantioselective Synthesis of N-Heterocycle-Substituted Quaternary Carbon Stereogenic Centers
Pyridine-to-Pyridazine Skeletal Editing
Denitrogenative Carbon Skeleton Cleavage and Reorganization of Pyridines by a Trinuclear Titanium Polyhydride Complex
Cyclopropylmethyl Boronic Esters as General Reagents in Transition-Metal Catalyzed Homoallylation Reactions
Kinetic, Spectroscopic, and Computational Investigation of Oxidative Aminative Alkene Cleavage Reveals an N-Iodonium-Iminoiodinane Pathway
A Heterogenized Molecular Catalyst for the Gas-Phase Cyclotrimerization of Acetylene to Benzene
Catalytic Enantioselective C(sp3)–C(sp3) Cross-Coupling of Tertiary Nitriles with Allyl Halides to Quaternary Stereocenters
Capturing the Hybrid Palladium(I)-Radical Pair Relevant to Photoexcited Palladium Catalysis
A Persistent Open-Shell m-QDM-Type Diindenoanthracene Diradicaloid with a Large Diradical Character
Intramolecular Hydrogen Atom Transfer Enables Hydroperoxyl Radical Formation during the Peroxidation of Unsaturated Lipids
Upgrading Sodium-Mediated Deprotonative Borylation to Catalytic Regimes: Regioselective Control and Mechanistic Implications
From Conjugated to Enantioenriched Skipped Dienes: Co-Catalyzed Asymmetric Cross-Hydrodimerization of 1,3-Dienes and Alkynes
Conjugated Networked Poly(ionic liquid)-Accommodating Organic Cages: A Matter of Interhost Electron Communications
Vicinal Stereocenter Construction via α-Boryl Carbanions from Borylated Cyclopropanes
From Alkylarenes to α-Amino Acid Derivatives via C-Difunctionalization
Asymmetric, Organocatalytic 1,4-Addition of Pyridinyl Acetates with Crystallization-Enabled Diastereoconvergency
Atropisomeric Indene (AtroInd) Libraries: Design, Catalytic Synthesis, and Applications
Integrated Life Cycle Assessment Guides Sustainability in Synthesis: Antiviral Letermovir as a Case Study
Enantioselective Redox-Neutral Radical Addition of α-Imino Esters with Sulfonyl Hydrazides
Peptide-Catalyzed Asymmetric Amination of Sulfenamides Enabled by DFT-Guided Catalyst Optimization
Establishing Selectivity Trends with Reactions of Thioesterases and Semi-Synthetic Polyketides
Stereoselective Photoenzymatic Hydroarylation for the Construction of Quaternary Stereocenters
Neutral Aromatic 2,3-Diboranaphthalenes
Borane/Transition Metal–Catalyzed Allenylic and Allylic Alkylation of Unactivated 2-Alkylbenzoxazoles
Deep-Red to Near-Infrared Light-Driven Radical Generation from Organoboron Compounds via Ligand-Induced Direct Excitation Catalysis
Bioinspired Total Syntheses of Skeletally Diverse Lycopodium Alkaloids
Azaanthraquinone PCET Catalysis Enables Chemoselective Decarboxylative Functionalization of Diverse Carboxylic Acids
Transition-Metal-Free Site-Selective β- and γ-C–H Borylation of Aliphatic Amines
Concise Enantioselective Total Synthesis of (+)-Punctaporonin U
Bifunctional Iminophosphorane Superbases Enable the Highly Enantioselective Sulfa-Michael Addition to Fully Substituted Cyclopropene Carboxylic Acid Derivatives
Curvature-Directed Selective C–C Bond Cleavage Driven by Electric Fields
Skeletal Editing of Quinolines by Single-Atom Carbon Insertion–Deletion
Retrosynthetic Design of Dinuclear Copper Enzymes for Azide–Alkyne Cycloaddition via Clickable Noncanonical Amino Acids
Divergent Total Synthesis of Pleurotinoid Natural Products
Photocatalyst-Regulated Trifluoromethoxylation of Aryl Halides under Silver Promotion
Efficient Assembly of Functional RNA by in Situ Phosphate Activation and Loop-Closing Ligation
Synthesis and Characterization of a π-Extended Clar’s Goblet
Photoetching-Generated Redox Pairs in Confined Layered Structure Boost Single-Electron-Transfer-Mediated Photocatalysis
Virtual Ligand-Assisted Screening for the Generation of Ketyl Radicals from Alkyl Ketones via Photoexcited Palladium Catalysis
Ligand Evolution-Enabled Enantioselective C(spsup3/sup)–H Azidation
Catalytic Enantioselective Diels–Alder Reaction of Dienes with Acyclic and α,β- and β,β-Disubstituted Enones
Deciphering Spin-Governed Dual Emissions in TTM Diradicaloids: Unraveling the Interplay of Singlet and Triplet Fluorescence Pathways
Synthesis of Acyclic All-Carbon Quaternary Stereocenters through Nickel-Catalyzed Enantioselective C(sp3)–H Amination
Rare-Earth-Catalyzed Selective Hydrosilylation of Iminocyclopropanes: Efficient Access to Azasilacyclopentanes
Two Flavoenzymes Convert Fungal Polyketide-Nonribosomal Peptide to cis-2-Butene-1,4-dial-Type Carcinogen via Olefin Dihydroxylation and C–C Bond Cleavage
Catalytic Enantioselective Perezone-Type [5 + 2] Cycloaddition
Interstellar Formation of the Elusive Phosphanyloxyphosphane (H2POPH2) and Phosphanylphosphinous Acid (H2PPHOH) via Nonequilibrium Chemistry: Precursors to the Phosphate Backbone of Nucleotides
Biocatalytic Stereodivergent Construction of Axially Chiral Tri- and Tetrasubstituted Allenols via Desymmetric Hydroxylation
Total Synthesis of Annotinolide B via Sequential Quinoline Dearomatization
Chiral Lithium Amides as Key Reagents in Enantioselective Synthesis of 2-Alkylpyridines with Multiple Stereocenters
Alternating Current-Driven Diol Epimerization via a Deplete–Regenerate Strategy
Visible-Light-Induced Bond Homolysis in Titanacyclopentadienes for the Catalytic Cyclodimerization of Internal Alkynes
Direct Deaminative Halogenation at Hindered Tertiary Centers
Programmable Artificial-Cellular Membrane Dynamics via Ring-Closing Metathesis
Droplets as Cell Models: Chemical Gradient-Induced Directional Filopodia Formation
A Highly Selective Cobalt Catalyst for Primary Amine Synthesis from Carboxylic Acids, Esters, and Vegetable Oils
Kinetically Programmed Signaling Cascades for Molecular Detection
Electrosynthesis of Agrochemicals via Alternating-Current-Driven Selective, Continuous Dehalogenation
Asymmetric Total Syntheses of Hetidine-Type C20-Diterpenoid Alkaloids: Spirasines V and VI, Spiradine D, and the Proposed Structures of Spirafines II and III
Double Disguise: Camouflaging Photocages for Bioorthogonally Controlled Conditional Activation
Single-Crystalline Poly(disulfide)s Enabled by PhotoTriggered Topochemical Ring-Opening Polymerization of 1,2-Dithiolane
Ultradurable Regenerative Propane Dehydrogenation Catalyst by Fluorination-Induced Confining and Positioning
An Electron Donor–Acceptor Complex-Driven Strategy Enables Initiation of Photoiniferter RAFT Polymerization from Amines, Carboxylic Acids, and Alcohols
Enhancing C2+ Product Faradaic Efficiency in CO2 Reduction Using Fluorine-Stabilized Superhydrophobic Copper (δ+)
The Boroxine–Boronic Acid Equilibrium
Development of a Ligand for Cu-Catalyzed Amination of Base-Sensitive (Hetero)aryl Chlorides
Kinetic Resolution for 1,4-Spin-Center Shift-Based Reduction of Azaarene-Functionalized Secondary and Tertiary Allylic Alcohols
Red-Light-Driven C(sp2)–H Sulfonylation of Anilines Using a Recyclable Benzothiadiazole-Based Covalent Organic Framework
Ir(III) Pincer Complex with Solo Coordinatively Active Site as a Surrogate for Half-Sandwich Catalysts: Enabling Asymmetric Acylnitrenoid Transfer and Structure–Activity Relationship Studies
Copper-Catalyzed Asymmetric Nitrenoid Transfer to Access Fused δ-Lactams via HFIP-Assisted Aziridination and Cascade Cyclization
Discovery and Mechanism of a Diiron Enzyme in Ethylidene Azetidine Formation
Photochemical Generation and Characterization of Alanine Imine: A Key Intermediate in Prebiotic Amino Acid Formation
Bridged-Backbone Strategy Enables Asymmetric Synthesis of Highly Functionalized Oxabicyclo[3.3.1]nonanes with Anti-Osimertinib-Resistant NSCLC Activity
Regiodivergent Access to α- and β-Amino Acids via Solvent-Controlled Rh-Catalyzed Carboamidation of β,γ-Unsaturated Carboxylic Acids
In Situ Probing Two Radicals in Halogenation Couplings from Photoanodic Single-Atom Catalysis
A Crystalline Monomeric Diboryl Diazene
Photobiocatalytic Radical Hydroalkylation with C(sp3)–H Bonds Enabled by Engineered Imine Reductase and Redox Buffering
Atomically Precise Copper Cluster for Highly Chemoselective Carbenoid Insertion into the N–H Bond of Aliphatic Amine
Mechanistic Dissymmetry between Crystal Growth and Dissolution Drives Ratcheted Chiral Amplification
Design, Synthesis, and Application of a Type of Chiral Spirocyclic Naphthylamines
Enzyme-like Enantioselectivity in GTM Chiral Zeolite Catalysts upon Preactivation of Ge Sites
Iridium-Catalyzed, Regio- and Stereoselective Silylation of Primary and Secondary C(sp3)–H Bonds in Primary Amines
Overriding Norrish Type II to Access Cyclopropanols
Synthesis of Sterically Congested Carbonyl Compounds via an ipso-Selective Sulfonium Rearrangement
A Biomimetic Procedure for the Synthesis of 1,2-cis C-Vinyl Furanosides from Unprotected Aldoses
Ligand-Controlled Stereodivergent α-Vinylation and α-Arylation of Peptide Backbones
Calochorturils: Chiral Bowl-Shaped Cavitands Obtained by Anisotropic Tangential Substitution
Photoelectrochemical Catalyzed Site-Selective Tryptophan β-Position Functionalization
Synthesis of Metallostannylenes from Transition Metal Polyhydride Complexes
Strain-Induced Quinoidal Character in a Carbon Nanoring Embedding Anthracene Units
Inhibiting Isomerization via Confinement in Ice–Water Interfaces Enhances Stereoselectivity in [2 + 2] Cycloaddition
Copper-Catalyzed Asymmetric C–H Sulfilimination of Arenes via HAT-Primed C–S Radical–Radical Coupling
Controlled Synthesis of Lipoate Homopolymers via Reversible Addition–Fragmentation Chain Transfer Polymerization
Unlocking Difluorocarbene as a Fluorocarbanion and a Fluorocarbon Radical Precursor for Sequential Catalytic Coupling
Controlling Selectivity in Electrochemical Conversion of Organic Mixtures through Dynamic Control of Electrode Microenvironments
Main-Chain Ketone Installation in Polyethylene Chains: A Metal-Free Strategy toward Photodegradable Plastics
Coacervate Droplets Drive Organocatalyzed Aqueous C–C Bond Formation via Interfacial Activation
Rapid Activation of Amino Acids with Cyanide and Hypochlorite
Alkenyl- and Aryl-Borane Nucleophiles in Enantioselective Iridium-Catalyzed Allylic Substitution of Vinyl Epoxides
Paired Pulsed Decarboxylative Hydroxylation Designed by Online Electrochemistry–Mass Spectrometry
Enantioselective Synthesis of Atropisomeric 3-Arylindoles via Cobalt-Catalyzed Electroreductive Cross-Coupling
Total Syntheses of Giraldine I and Heterophyllisine
Biosynthesis of the 5-Isoxazolidinone-Containing Hexacyclic Structure of Parnafungin
An Enantioselective Nucleophilic Aromatic tele-Substitution
An Isolated Lithium ortho-Carboranyl Cuprate Complex for the Synthesis of Multiple-Carborane-Substituted Arenes from (Hetero)Aryl Bromides and Chlorides
A Glutathione S-Transferase Pi Molecular Glue Tethers Splicing Factors and Remodels Cell Metabolism
Pretzelanes with Planar Chirality and Guest Recognition Capabilities
A Convergent Approach to Phragmalin-Type Limonoids: Total Synthesis of Thaigranatin P
Bio-inspired Deconjugative Isomerization of Borylated Dienoates
Total Synthesis of (±)-Crokonoid A
Pd-Catalyzed O-Arylation of Phenols Mediated by a Weak, Soluble Organic Base: Methodology, Mechanism, and Compatibility with Enabling Technologies
Electrochemical C–H Functionalization and Defunctionalization of Polystyrene
Use of Electron-Transfer Mediators to Access Higher Electrochemical Current Densities in Ni-Catalyzed Cross-Electrophile Coupling
Asymmetric Coordination Designed Heterocrown Ether Host–Guest Ferroelectrics with Ultrahigh Tc
Cu(II)-Catalyzed Hydrofunctionalization of Unactivated Alkynes via π-Lewis Acid Activation
Impact of Carbene Ligands on the Properties and Reactivity of Diazoboranes
Ligand Architecture Control Geometry, Self-Sorting, and Postsynthetic Modification in Anthracene-Based Organometallic Assemblies
Selective Toluene Electrooxidation to Benzyl Alcohol
Methylation and Alkylation of Pyridines at the meta Position Using Aldehydes or Aldehyde Surrogates
Cobalt-Catalyzed Enantioselective Hydroalkylation of Oxa- or Azabicyclic Alkenes
Palladium-Catalyzed Asymmetric Carbonylation of Alkynes to Axially Chiral Carbothioate Esters
Electrochemically Mediated Atom Transfer Radical Polymerization Employing Rapid Alternating Polarity
Precision Synthesis of Polyrotaxanes Using Cascade Metathesis Polymerization
Bio-Photo Dual Action of Intracellular Radical Polymerization
A General Copper-Catalyzed Radical Cross-Coupling of Unactivated Alkyl Halides
Nickel-Catalyzed Enantioselective Direct Addition of Styrenes to Imines Enabled by Chiral Spiro Phosphine Ligands
Air- and Water-Stable Sulfide Radical Cations Supported by Cyclic (Alkyl)(amino)carbenes
A General Metallaphotoredox Platform for N-Alkylated Sulfoximines as Bioisosteric Building Blocks
Cyclic BODIPY Arrays: A Class of Macrocycle-Based Molecular Solids for Hydrogen Isotope Separation and Iodine Capture
In Cellulo Cysteine Umpolung for Protein Structure Probing
Seq2Saccharide: Discovering Oligosaccharides and Aminoglycosides Natural Products by Integrating Computational Mass Spectrometry and Genome Mining
Methyl Radical Dominated Highly Selective Methane Oxidation to Liquid Oxygenates
Ligand-Induced Self-Complementing Tag (LiSC-Tag) as an Epitope Tag for Live-Cell Super-Resolution Imaging and Functional Manipulation of Cellular Proteins
Mo-Catalyzed Asymmetric Allylic Alkylation Enabling the Construction of Highly Enantioenriched 1,4-Dicarbonyl Scaffolds
Asymmetric Dearomative [2 + 2] Photocycloaddition of Quinoline and Indole Derivatives with Bicyclo[1.1.0]butanes
Photochemical Metallonitrene Formation for N Atom Transfers. Metal- versus Azide-Centered Excited States and the Role of Their Energetic Order
Iodonitrene-Mediated Nitrogen Transfer to Alkenes for the Direct Synthesis of NH-Aziridines
Stable Isotope Labeling of Pyrimidines Using a Deconstruction–Reconstruction Strategy
Late-Stage Tryptophan Modification of Native Peptides through Photochemical Indole-to-Quinazoline Editing
Sono-uncaging for Spatiotemporal Control of Chemical Reactivity
Highly Selective Photo-Oxidation of Methane to Methanol by Fe–Au Site-Supported SrTiO3 Hollow Nanotubes with Oxygen Vacancies
Molecularly Tuned Carbon Dots for Visible-Light-Driven Boryl Radical Generation via Enhanced Hole Transfer
Harnessing Chromium(V) Hydrazido Intermediates for N2 Functionalization to Multisubstituted Hydrazines through Ligand Migration
Electrophilic Cyanation with Carbon Isotopes: A Versatile Access to 13C, 14C, and 11C Aryl Nitriles from Labeled NCTS
Harnessing Heterogeneous Asymmetric Oxide Interface for Efficient Photodehydrogenation of Isopropanol through α-C–H Bond Activation
Optimizing the Synthesis of Deuterated Isotopomers and Isotopologues of Cyclohexene using Molecular Rotational Resonance Spectroscopy
Modular Access to N-SF5 Azetidines
Automated Reactivity Prediction of Complex Molecules and Its Application to Total Synthesis of Ageliferin
Stereodivergent Synthesis of Allylic All-Carbon Quaternary Centers by Bimetallic Iridium/Magnesium-Catalyzed Allylic Alkylation
Flow Photo-Oxidative Dearomative Cyclization Enables Unified Asymmetric Synthesis of Trichodermamides A–F
Direct Conversion of Ethanol to Ethyl Acetate by Dynamic Polyoxometalate/Carbon Nanohorn Electrocatalytic Interfaces
Ruthenium-Mediated N-Arylation for DNA-Encoded Libraries
Deciphering the Synchronization of Alternating Current Frequency with the Nickel Catalytic Cycle in Selective C–N Cross-Coupling
Ultrastable Copper Cluster Enables Highly Site-Selective and Chemoselective Carbocation C(sp3)–H and C(sp2)–H Bonds Functionalization
Development of Cyclooctyne-Nitrone Based Click Release Chemistry for Bioorthogonal Prodrug Activation both In Vitro and In Vivo
Construction of Zeolite Framework-Anchored Rh–(O–Zn)x Sites for Ethylene Hydroformylation
A Uniquely Structured Heteronuclear Cluster Cage with Anion-Templated Pentagons and Hexagons
Intermolecular Lithium η2-Alkene and κ2-Alkane Complexes: Synthesis, Bonding, and Facile Interconversion
Catalytic Asymmetric (ene–endo)-Carbonyl–Ene Type Cyclizations
Diversity-Oriented C–H Activation Reactions of the Naphthalene Scaffold
A Bifunctional Chiral Disulfide Catalyst for Highly Enantioselective Anti-Markovnikov Hydrophosphinylation
Harnessing Dynamic Heteroleptic Complexation for Self-Assembly of Robust Nested Metallo-Supramolecular Cages
Enantioselective Assembly of (Hetero)aryl Alkyl Sulfilimines via Copper-Catalyzed S-Arylation of S-Alkyl Sulfenamides with (Hetero)aryl Iodides
Ruthenium-Catalyzed Intermolecular [2 + 2] Cycloaddition of Unactivated Allenes and Alkynes with Unusual Regioselectivity
Photocatalytic C–X Bond Cleavage Facilitates Peptide Synthesis
Structural Basis for 3-Amino-3-carboxypropyl Transfer in Nocardicin Biosynthesis
Photocatalytic Oxidative Dimerization of Electronically Diverse Phenols Using Borate to Prevent Overoxidation
Water as an Electron Donor for Cross-Electrophile Coupling Reactions
Pillar-like Macrocycle Reversibly Self-Assembled from a Molecular Thermally Activated Delayed Fluorescence Emitter Based on B ← N Dative Bonds with Intriguing Fluorescence
Divergent Synthesis of 1-Azabicyclo[n.1.1]alkane Bioisosteres via Photoinduced Palladium Catalysis
Interfacial Self-Assembly of Sugars at Nanoscale Membranes Leads to Micron-Scale, Spectroscopically Ice-Like Chiral Suprastructures of Water
C–H Bond Activation via Photolysis of a Mn Nitride Ligand Radical Complex
Iron(III)-Mediated C–H Alkylation: One-Electron Differentiation Increases Activity and Chemoselectivity
Autocatalytic Reaction between HCN and Cysteamine Produces Hydrophobic, Catalytic, Liquid Compartments
Tuning the Conformations of an M4L4 Cage and Their Impact on Catalysis
Targeted Synthesis and Development of Neotype Antiviral Agents with a Radical-Mediated Deoxyphosphoamination Strategy
Chemistry of Sugar Formation in the Gas Phase: Following the Activated Aldehyde
Ultralow Content of Chromium Species in Zeolite for Efficient Catalytic Propane Dehydrogenation
Cu/Ru Relay Catalysis Enables Functionalization of Allenic Alcohols with Stereodivergence and Skeleton Diversity
Modular Access to Medium-to-Large Sized Lactams through Alkyne-Bridging C–C Bond Activation of Unstrained Carbonyls
Divergent Total Syntheses of Elisapterane and Relevant Diterpenoids Assisted by iIn Silico/i Structure Reassignment
Near-Infrared Photoenzymatic Catalysis at ppb Levels Enables Ultrahigh-Molecular-Weight Polymers
Photocatalyzed Decarboxylative B–C Couplings for the Synthesis of Carboranyl Amino Acids and Peptides
Asymmetric Total Synthesis of (−)-Psychotriadine Featuring [3,3]-Rearrangement and Stereo-Controllable Ring-Contraction
Site-Specific Chemoselective Cyclization and Fluorogenic Modification of Protein Cysteine Residues: From Side-Chain to Backbone
A Versatile One-pot Strategy for Thiazolylazo Extensions: Visible Light-Driven Photoswitches
An 18-Porphyrin Nanoring at the Size Limit for Global Aromaticity
Ortho-Carborane-Supported Hypervalent Iodine(III) Reagents: A Scaffold for Enhanced Oxidative Capability
Highly Selective Carbonylation of Olefins Using CO2 and H2
C(spsup3/sup)H/N(spsup2/sup) Cross-Coupling Reaction for the Synthesis of Tertiary Arylamines via Fluxional SOX·Pd(II) Catalysis
Photochemical Insights on Acyl Azolium Salts Enable the Design of a Tandem Hydrogen Atom Transfer/Halogen Atom Transfer Acylation of Alkyl Bromides and Chlorides
Structure–Function Relationships in Sequence-Controlled Copolymers for Rare Earth Element Chelation
A Data Science-Guided Approach for the Development of Nickel-Catalyzed Homo-Diels–Alder Reactions
Total Synthesis of (±)-Crokonoid A
Multiple Template Site Nitrogen Atom Deletions from Rotaxanes, Catenanes, and a Molecular Knot
Heterolytic Cleavage of Lsubn/subPd–SiRsub3/subsup+/sup Bonds Enable the Ring-Opening C–C Functionalization of Nonstrained Ethers
Recyclable Inorganic Subnanowire Plastics
A Crystalline Boravinylidene from an Arrested Hydroboration Reaction
Catalytic Markovnikov Hydrothiolation of Dehydroamino Acids: Unified Total Synthesis of Enteropeptin Sactipeptides
Enhanced Single-Molecule Imaging via Intersystem Crossing Suppression
Catalyst-Enabled Chemoselective Metalloradical Activation for Molecular Rearrangement via Ester Migration and Allylic C(spsup3/sup)–H Amination
Atroposelective Synthesis of Azobenzenes by Palladium-Catalyzed Cross-Coupling of Racemic Biaryl Triflates and Diazenyl Pronucleophiles
Trisilylation of a Formal Cr(−I) Bis-dinitrogen Complex
Functional Al/Cd Heterometallics─From Controlled Al(I) Transfer to Nucleophilic Transfer of Cadmium Ions
Total Synthesis of (−)-Psathyrin A Enabled by Radical Cyclization
Photoinduced, Copper-Catalyzed Enantioconvergent Azidation of Alkyl Halides
Elucidation of Marcus Relationships for Hydride Transfer Reactions Involving Transition Metal Hydrides
Diversity-Oriented Method Development: Multifunctional Homoallylic Amines and Azabicyclooctanes Bearing a Bridgehead Enamine
Controlled Molecular Orders in Layered Multiple Porphyrins
Practical Ligand-Enabled C–H Halogenation of (Hetero)Benzoic and (Hetero)Aryl Acetic Acids
Stereodivergent Synthesis of Enantioenriched Organoboron Compounds with Carbon/Boron Dual Stereocenters via Rh(I)/Cu(I)-Catalyzed Enantioselective Desymmetrization of B–H Insertions
Porous Gold Nanoumbrellas with Adjustable Apical Angles for Selective Electrosynthesis of Styrene Epoxide from Styrene
Radical Ring Expansion Catalyzed by an α-Ketoglutarate-Dependent Dioxygenase in the Biosynthesis of Tropolones
Photo-Triggerable Polymerization and Depolymerization of Stiff-Stilbene Lactones
Bench-Stable Carbamoylzinc Pivalates for Modular Access to Amides, Ureas, and Thiocarbamates
A Functional Assay for Mining Noninhibitory Enzyme Ligands from One Bead One Compound Libraries: Application to E3 Ubiquitin Ligases
Red Light-Driven, Oxygen-Tolerant RAFT Polymerization Enabled by Methylene Blue
Making Sense of Heteroatom Effects in π–π Interactions
Directed Evolution of Copper-Substituted Nonheme Enzymes for Enantioselective Alkene Oxytrifluoromethylation
Application of Solid Higher-Order Zincates Enables a Ni/Lassaletta-Ligand-Catalyzed, Atroposelective Negishi Cross-Coupling Reaction
Photoelectrochemical Asymmetric Epoxidation of Alkenes with Water as an Oxygen Source in a Biphasic System
Organocatalytic imeta/i-C–H Hydroxylation of Azaarene iN/i-Oxides
Catalytic Oxidation of Carbon–Halogen Bonds by Water with H2 Liberation
Carbon-Caged-Yttria Catalysts for Stable Electrosynthesis of H2O2 in Concentrated Acid
Entropy-Regulated Selective Synthesis of Cyclic Polymers and Polycatenanes by Lewis Pair Polymerization
Photocatalytic Asymmetric Oxidation of Phosphines with Water
Total Synthesis of (+)-Pierisketone B
Iron-Catalyzed Asymmetric Reductive Cross-Coupling of Ketimines with Alkyl Iodides
Diversity-Oriented Synthesis of Diaza-Polycyclic Aromatic Hydrocarbons Coupled with Virtual Screening for OLED Applications
Tungsten-Enabled Diels–Alder Cycloaddition and Cycloreversion of Arenes and Alkynes: Divergent Synthesis of Highly Functionalized Barrelenes and Arenes
Enantioselective Total Synthesis of (−)-Novofumigatonin
Enantioselective Synthesis of α-Oxygenated Ketones via Organocatalytic Formal O–H Bond Insertion of Sulfonium Ylides
Fluorinated Twists: A Pathway to a Stable Pdsub8/subLsub16/sub Square Antiprism
Rhodium-Catalyzed Asymmetric Allylic Dearomatization of β-Naphthols via Tandem Etherification/Claisen Rearrangement
Isolation and Reactivity of a BN-Embedded Heterocumulene
Electron Transfer Theory Elucidates the Hidden Role Played by Triethylamine and Triethanolamine during Photocatalysis
Direct Generation of Carboxyl Radicals from Carboxylic Acids Catalyzed by Photoactivated Ketones
Anionic Reversible Addition–Fragmentation Chain-Transfer Polymerization of Methacrylates
Construction of a Chiral Click Chemistry Platform via Enantioselective F/Cl Exchange at S(VI) Centers
A Ring-Deconstructive Carbon-Deletion Approach to the Enantioselective Total Synthesis of [5]-Ladderanoic Acid
Multiple Catalytic Branch Points in the Mechanism of Pyrrolidine Formation During Kainoid Biosynthesis Leads to Diverse Reaction Outcomes
Monocyclic Azetidines via a Visible-Light-Mediated Aza Paternò-Büchi Reaction of Ketone-Derived Sulfonylimines
Nickel-Catalyzed Regio- and Enantioselective Hydroalkenylation of Aldehydes with 2-Azadienes
Late-Stage Aromatic C–H Bond Functionalization for Cysteine/Selenocysteine Bioconjugation
Cyanobacteria Join the Kahalalide Conversation: Genome and Metabolite Evidence for Structurally Related Peptides
Enantioselective Construction of β-Substituted γ-Lactone through Catalytic Asymmetric Oshima–Utimoto Reaction: Divergent Total Syntheses of (−)-Podophyllotoxin and Its Eleven Congeners
Migrating Group Strategy for Remote Functionalization of Seven-Membered Rings
A Dynamic Silver(I) Nanocluster Holds Together a 3 × 3 Self-Assembled Grid
Dendritic Membranized Coacervate Microdroplets: A Robust Platform for Synthetic-Living Cell Consortia
Bimolecular Nucleophilic Substitution (SN2) Reaction Catalyzed by l-Threonine Aldolase
Total Synthesis of (−)-Neocucurbol C Enabled by Pattern Recognition and MHAT Cyclization
Directed Halogen Atom Transfer (DIXAT): A Powerful Tool for Chemoselective Generation of Aryl Radicals Toward Remote C(spsup3/sup)–H Functionalization of Aliphatic Amines
Binuclear Metal-Based Covalent Organic Framework Mimicking Metallohydrolases for Direct Photoreforming of PET Plastic
A Bifunctional Sulfone Reagent for Asymmetric Aminomethylative Sulfonylation of Dienes
Tunable Formal Photocycloaddition of 1-Naphthol Derivatives
Supramolecular Complexation of Quenched Rosamines with Cucurbit[7]Uril: Fluorescence Turn-ON Effect for Super-Resolution Imaging
Acidic Additives Enable Tunable Low Temperature Side Chain Cleavage and Performance Enhancement in Organic Photovoltaics
Photon-Primed Organic Electrosynthesis Enabled by Oxidation of Photon-Induced Intermediates
Preparation of 1,4-Diamines by Enantio- and Diastereoselective Cu–Josiphos-Catalyzed Reductive Couplings of Azatrienes and Imines: Regiodivergence Enabled by Catalyst Structure and Reagent Tailoring
Electrochemical Oxygen Reduction Reaction-Coupled Dechlorination Promoting Acylation Reaction for Aromatic Ester Synthesis
Formation of Lactic Acid (CH3CH(OH)COOH), a Metabolic Keystone for the Molecular Origins of Life, in Interstellar Ice Analogues
π–π Stacking and Structural Configurations in Aromatic Thiophene and Fluorobenzene Dimers Revealed by Rotational Spectroscopy
Macrocycle Side Chain Crowding Enables Tunable Curvature from Planar to Wrinkled and Wavy Hydrogen-Bonded Sheets
Enantioselective Synthesis of Spirocyclic Nitrogen-Containing Heterocycles Catalyzed by an Iridium-Containing Cytochrome
Diblock Copolypeptoid Micelles as Platform for Aqueous Photoredox Cyanation of Arenes
Reversible Electron Transfer in the Formation of Radical Anionic and Dianionic 1,4-Diborabutatrienes
Reversible C–H Bond Activation of Unactivated Arenes by a Nickel-Silylene Complex
Leveraging Data Science to Elucidate Ligand Features for Pd-Catalyzed Enantioretentive iN/i-Arylations of Cyclic α-Substituted Amines in Aqueous Media
Chiral Porous Sheet Assembly for Multiple Chirality Induction in Macrocycle Formation
Modular Synthetic Platform for the Elaboration of Fragments in Three Dimensions for Fragment-Based Drug Discovery
Facile Synthesis of Polyhydroperoxides from Ethylene and Carbon Monoxide
Carbon Reduction Powered by Natural Electrochemical Gradients under Submarine Hydrothermal Vent Conditions
Enantioselective Construction of Aza-bicyclo[3.2.1]octane Skeletons via Substituted π-Allyl Palladium Dipoles Originated from Neutral η3-Propargyl Palladium Species
Phenoxyimine Iron Aryl and Alkoxide Complexes as Reactive Intermediates in Iron-Catalyzed C(spsup2/sup)–C(spsup3/sup) Suzuki-Miyaura Cross-Coupling
Direct Editing of Cysteine to Electrophilic Alkyl Halides in Peptides
Ultraconjugated Electron–Proton Transfer Mechanism in the Product Selectivity-Controllable Electrocatalytic Oxidation of Binary Primary Alcohols
Nanographene-Oxy Radical Stabilized by a Carbaporphyrin Framework
Systematic Synthesis of Large Porous Organic Cages Driven by Steric Hindrance
Induced Bioconjugation via On-Demand Isocyanate Formation
Enantioselective Total Synthesis of Bipolarolides A and B
Interfacial Electric Fields Modulate Redox Reactions in Abiological Coacervates
Cooperative Bimetallic Radical Catalysis Enables Asymmetric Hydrogen-Atom Transfer
Iridium–Lewis Acid Bifunctional Catalyst-Enabled Regio- and Enantioselective C(spsup2/sup)–H imeta/i-Borylation of α,α-Diarylcarboxamides
Ammonia Evolution in Glycine Pyrolysis via Ionic-Pair Reaction Mechanisms
Construction of a De Novo Nucleotide Biosynthesis Pathway in Artificial Cells for RNA Transcription
Asymmetric C–H Functionalization of N-Boc-2,5-dihydro-1H-pyrrole and Its Application as a Key Step in the Synthesis of (−)-Dragocin D
Johnson Solid Gold Nanoclusters as Heterogeneous Visible-Light Photocatalysts for Fukuyama Indole Synthesis
Au-Catalyzed Aerobic Dehydrogenative Aromatization to m-Phenylenediamine Derivatives via Product Selectivity Control
Pushing the Thermodynamic and Kinetic Limits of Near-Infrared Emissive CrsupIII/sup Complexes in Photocatalysis
Sustainable Imine Production Using Alkanes as Substrates via a Plasma-Microdroplet Approach
Remote-Markovnikov Hydrobromination and Hydrochlorination of Allyl Carboxylates via Dual Photoredox/Cobalt Catalysis
Accelerated Discovery of Energy Transfer-Catalyzed Dearomative Cycloadditions through a Data-Driven Three-Layer Screening Strategy
Enzymatic Stereodivergent Synthesis of Azaspiro[2.y]alkanes
Mechanisms and Synthetic Applications of Cyclic, Nonstabilized Isodiazenes: Nitrogen-Atom Insertion into Pyrrolidines and Related Rearrangements
Mono or Di? A Potential-Controlled Electrochemical Halogenation of Anilines
Strain-Release-Driven Synthesis of Pentafluorosulfanylated Four-Membered Rings under Energy Transfer Photocatalysis
Harnessing O-Vinylhydroxylamines for Ring-Annulation: A Scalable Approach to Azaindolines and Azaindoles
Cobalt-Catalyzed Asymmetric Reductive Coupling of Isocyanates with Tertiary Alkyl Halides for Sterically Bulky Chiral Amide Synthesis
Total Synthesis of Paxdaphnine A and Daphlongamine B via an Aza-Prins Cyclization Strategy
C–H Amination of Arenes and Heteroarenes through a Dearomative (3 + 2) Cycloaddition
Breaking Bonds with Short-Wave Infrared Light: BODIPY Photocages for Two-Photon Activation in the 900–1500 nm NIR-II Window
Janus Palladium Membrane Electrode Enables Competent Hydrodehalogenation via Hydride Transfer
BNB-Modified Perylene, Terrylene, and Quaterrylene Diimides: Introduction of the π-Accepting and Aggregation-Suppressing Diborinic Imide Group in Rylene Dyes
Direct N–SF5 and N–SF4CF3 Bond Formation through Strain-Release Functionalization of 3-Substituted [1.1.0]Azabicyclobutanes
Electron Donors in the Intertwined Interface Restore Oxy-Substituted Selenides
Concise Syntheses of Harziane Diterpenoids by Merging Local Desymmetrization and Radical Retrosynthesis
Iridium-Catalyzed Regio- and Enantioselective Reverse Prenylation of Tryptamines and Other 3-Substituted Indoles
Asymmetric Access to δ-Hydroxy α-Amino Acids Bearing Two Adjacent Stereocenters from Inert Allylic Alcohols Via Cu/Ru Relay Catalysis
Complete Structure of Delftibactin A and Its Function in Reductive Formation of Gold Nanoparticles
Controlled Solid-State Ring-Opening Polymerization of Cyclic Carbonates via Mechanochemical H-Bonding Organocatalysis
Chiral Phosphoric Acid-Catalyzed Enantioselective Higher-Order Cycloadditions: Temperature-Dependent Periselectivity
Divergent Kinetic/Thermodynamic Selectivity in Palladium(II)-Mediated C–H Activation to Form 5- and 6-Membered Palladacycles
Disordered Ru–O6 Octahedrons for Efficient and Selective Electro-oxidation of Sulfide to Sulfoxide via Boosted Surface Oxygen Kinetics
Nucleophilic α- and β-Additions Enable Redox-Neutral Aziridination of Conjugated Hydroxamates
Radical 1,3-Difunctionalization of β,γ-Unsaturated Ketones via Concomitant 1,2-Carbonyl Migration: An Entrance to β-SF5-/β-CF3SF4 Ketones
Diastereo- and Enantioselective Synthesis of Polycyclic Amines by Cascade Cyclization of Aromatic Aldimines with Tethered Alkenes via Scandium-Catalyzed C–H Activation
Total Synthesis of (+)-Herpotrichones A–C
Reversible CO Insertion into the Si = Si Double Bond Enables a Disila-Bislactone Formation via Subsequent CO2 Addition
Scaffold Hopping of α,β-Unsaturated Ketones via Divergent Alkyl Amine Insertion
Warhead Strategy for Targeted Protein S-Nitrosation
Correlated Reaction Coordinate Motion Produces Nonadditive Rate Enhancement for Electron and Energy Transfer in Multiacceptor Structures
Synthesis and Properties of Poly(vinyl chloride)-b-polyethylene Multiblock Copolymers through the Hydrodechlorination of PVC with Silylium Ions
Breaking Kasha’s Rule to Enable Higher Reactivity in Photoredox Catalysis
Origin of Selectivity in Alternating Current-Enabled Partial Reduction of (Hetero)Arenes: A Case Study of Two Consecutive Irreversible Electrochemical Steps
Convergent Total Synthesis of Erchinines A and B and Their C20 Epimers
C(spsup3/sup)–N Coupling of Nonactivated Alkyl Boronic Pinacol Esters by the Merger of Amino Radical Transfer and Copper Catalysis
8-Quinox Cobalt Catalyst Enables the Reductive Alkylative Addition of Sulfinylamines with Unactivated Alkyl Halides
α-Ketoglutarate-Dependent Dioxygenase-Catalyzed Macrocyclization in RiPPs
Precise Distal B–H Bond Activation of nido-Carboranes by Copper Catalysis: Synthesis of Benzene Bioisosteres from Boron Clusters
Cobalt-Catalyzed Enantioselective and Diastereodivergent Construction of C–N Atropisomers
Modular One-Pot Access to Boron-Carboxylated Dipyrromethene Dyes as Visible-Light and Two-Photon Activatable Photocages
Direct Formation of C3 Oxygenates through Photocatalytic CH4–CO Coupling
[1,3]-Hydride Shift in α-Boryl Cations: Strategic Design of Fluorine-Triggered Cyclopropanation
Melt Rheology of Dendritic Hyperbranched Polyacrylates Synthesized by Controlled Radical Polymerization: Evidence of Self-Similar Branch Structure Formation
Cu/Ir Relay Catalysis for Regio- and Enantioselective Alkene Borylation/Allylic Alkylation
Enantioconvergent Chan–Lam Coupling: Synthesis of Chiral Benzylic Amides via Cu-Catalyzed Deborylative Amidation
Enantioconvergent Radical–Radical Cross-Coupling via Magnesium-Mediated Charge-Transfer Photocatalysis
Triplet Energy Transfer-Based Deracemization of Axially Chiral Alkenes Enabled by a Dual Catalyst System
Pericyclic Umpolung in a Catalytic Asymmetric Diels–Alder Reaction of Tropone with Enol Ethers
Electrochemical Single-Carbon Insertion via Distonic Radical Cation Intermediates
Ketosynthase Domain Catalyzes β-Lactonization in the Biosynthesis of the HMG-CoA Synthase Inhibitor Hymeglusin
Data Science-Guided Development of Deoxyfluorination Reagents with Enhanced Reactivity, Practicality, and Safety
Taming Enolate Regioselectivity: Catalyst-Guided Divergent Synthesis of Atropisomeric Pyridones via Switchable C- and O-Acylation
Kinetic Resolution of Heterocyclic Lactams by a Photocatalytic Cobalt-Catalyzed Dehydrogenation
A [2.1.0]-Fused Bicyclic Intermediate Is Produced during the Biosynthesis of Oxetane Nucleosides
Light-Driven Crystallization-Induced Dynamic Resolution of Amines
Monofluoromethyl Radical Mediated Halogen-Atom Transfer
Stereoconvergent Aminoboration of (Z/E)-Mixed Alkenes via Bimetallic Asymmetric Relay Catalysis
A Visible-Light-Responsive Octahedral Cage for Efficient and Selective Cross-[2 + 2] Cycloadditions
Unveiling Janus Chemical Processes in Contact-Electro-Chemistry through Oxygen Reduction Reactions
Spin Delocalization of Nitrile-Ligated Diarylboryl Radicals Enables Photochemical Boracycle Synthesis via N-Borylimidoyl Radicals
On-Demand Nonalternating Copolymerization Enables Upcycling of Mixed Polyethylene and Nylon Plastics
Sulfur[n]arenes: Synthesis and Solid-State Supramolecular Dimerization via Multiple Sulfur···Sulfur Interactions
Total Synthesis of Chartelline C
Mechanical Recycling of Mixed Plastics by Supramolecular Dynamic Cross-Linking Strategy
Distal C(sp3)-H Amidation via Ind*RhIII Catalyzed Nitrene Transfer
Unraveling Pathway Complexity in the Supramolecular Polymerization of Z-Shaped Perylenediimides: From Kinetic H-Aggregates to Thermodynamic Null Supramolecular Polymers
Rh-Catalyzed Atroposelective Single-Carbon Insertion
DACH-ZYC-Phos/Pd-Catalyzed Enantioselective Allenylation of Secondary Phosphine Oxides via Ligand Relay
Probing the Oxidative Addition Transition State in Nickel Metallaphotoredox Catalysis Using Intramolecular 13C Kinetic Isotope Effects
Synthesis of Borylated Orphaned Cyclopropanes through a Boron-Enabled Cycloisomerization Reaction
Covalent Template-Guided Synthesis of iendo/i-Functionalized Oligophenylene Cages
Unraveling the Potential-Dependent Selectivity of Propylene Electrooxidation: The Role of Electrochemistry-Induced Reconstruction
Platinum-Catalyzed C–F Bond Reconstruction via the Multi-unit Insertion for Remote Fluorine Migration
Stereodivergent Synthesis of Perhydrobenz[e]indene Terpenoids
Synthesis of 1,n-Diamines via Selective Catalytic C–H Diamination
Room Temperature Ring Opening of Benzene by Four-Electron Reduction and Carbonylation
Deoxygenative [3 + 2] Annulation of α,β-Unsaturated Carbonyl Compounds and Electron-Rich Olefins via Photocatalytic Umpolung of Triarylphosphine
Multireference Theory of Scanning Tunneling Spectroscopy Beyond One-Electron Molecular Orbitals: Can We Image Molecular Orbitals?
Hydrogen Activation by a σσ*-Carbene Through Quantum Tunneling
Unlocking a Nano-Aluminum Oxide Lewis Acid Layer as the Electrocatalyst for Hydrogenation of Thiophene and Other Arenes
Going to Extreme Lengths: Bicyclic Diborane(6) Anions and the Limits of Boron–Boron σ Bonding
Enantioselective Synthesis of 2,3-Disubstituted Azetidines via Copper-Catalyzed Boryl Allylation of Azetines
Introduction of Reactive Thiol Handles into Tyrosine-Tagged Proteins through Enzymatic Oxidative Coupling
Impact of Induced Fitting and Secondary Noncovalent Interactions on Site-Selective and Enantioselective C–H Functionalization of Arylcyclohexanes
Near-Infrared Light-Accelerated Bioorthogonal Drug Uncaging and Photothermal Ablation by Anisotropic Pd@Au Plasmonic Nanorods
Electrons and Their Multiple Kinetic Fates in an Ionic Liquid
Gram-Scale Total Synthesis of Illisimonin A
Photocatalytic 1,2-Dicarboxylation of Unactivated Alkynes with CO2
Biosynthesis of Biphenomycin-like Macrocyclic Peptides by Formation and Cross-Linking of iOrtho/i-Tyrosines
Quantitative Protein Labeling in Live Cells by Controlling the Redox State of Encoded Tetrazines
Single-Molecule Reactor Based on the Excluded Volume Effect of Bottlebrush Polymers
A Concise Total Synthesis of Glycinoeclepin A
Design and Semisynthesis of Ubiquitin Extension Probes for Structural Analysis of Cullin1-Mediated Substrate Polyubiquitination
Asymmetric C–H Amination via Fe(III)-Metalloradical Catalysis Featuring α-Fe(IV)-Aminyl Radicals as Key Intermediates
Diastereo- and Enantioselective Pd-Catalyzed C–P Coupling for Axially and P-Chiral Phosphine Oxides via Simultaneous Dynamic Kinetic Asymmetric Transformation and Kinetic Resolution
Real-Time Optical Control of CB1 Receptor Signaling In Vitro with Tethered Photoswitchable (−)-trans-Δ9-Tetrahydrocannabinol Derivatives
Regiodivergent α- and β-Functionalization of Saturated N-Heterocycles by Photocatalytic Oxidation
General Modular and Convergent Approach to Diversely Functionalized Allylic Systems
Breaking the Strongest Organic Bonds by Water: Defluorosubstitutions at the Air–Water Interface of Microdroplets
Catalytic Asymmetric Reactions of Alkyl Alkynyl Ketimines: A Versatile Approach to Chiral α-Trialkyl Amines
Radical Strategy to the Boron-to-Copper Transmetalation Problem: iN/i-Alkylation with Alkylboronic Esters
Self-Aggregative Recognition and Extraction of Perfluorooctanesulfonate with Flexible Cationic Water-Soluble Deep Cavitands
C–H Functionalization via Single Atom Metathesis of C–H and C–X Bonds
The Science of Polymer Chemical Recycling Catalysis: Uncovering Kinetic and Thermodynamic Linear Free Energy Relationships
In Situ Synthesis of Multifunctional 3D Polymeric Artificial Organelles in Living Cells
Orthogonal Thiol Addition Chemistry Based on Ether Acrylates
Catalytic Asymmetric Synthesis of Axially Chiral Methylenecyclopropanes
Highly Antiaromatic Naphtho-1,2-Diboretes as Precursors for Tunable, Unsymmetrical 1,4-Diboraanthracenes
Quaternary Carbon as a Locus for Skeletal Disconnection. Total Synthesis of (±)-Tubingensin A Featuring Assembly of the Backbone Stereotriad Using a Halo-Prins/Halo-Nazarov Cascad
Guest-Shape-Directed Structural Switching between Two Isomers of a Pd6 Host and Its Structural Adaptability for Selective Photodimerization
Reconfiguration of Active Species under Light for Enhanced Photocatalysis
iMechanometallaphotoredox/i Catalysis: Utilizing Increased Throughput Mechanochemistry to Develop Solvent-Minimized Aryl Amination and C(sp2)-C(sp3) Cross-Coupling Reactions with Increased Tolerance to Aerobic Conditions
Asymmetric Total Synthesis of (−)-Crotonine G and (−)-Crotonolide D
Sulfur Vacancy Boosts Light-Driven C–N Coupling in Upcycling of Polylactic Acid to Alanine
Post-Polymerization Modification of Polyethylene through Photochemical Oximation and Consecutive Ketonization
Copper-Catalyzed Highly Efficient and Asymmetric Allylic C–H Oxidation of 3-Aryl-Substituted Terminal Alkenes
Catalytic Asymmetric P-Site Dearomatization Enables Kinetic Resolution
Selective Iridium-Catalyzed Reductive Amination Inside Living Cells
Simple Strategies to Quantify and Control Polymer Threading into Micropores
Controlled/″Living″ Click Polymerization with Possible Bidirectional Chain-Growth Propagation during Polyaddition
Biomimetic Metal–Organic Nanotubular Host for Straight-Chain Fatty Acids Recognition
A Tailored Quinoline-Locked Covalent Organic Framework for Metal-Free Photocatalytic α-Amino C–H Annulation
Quantitative Determination of Electronic Effects in Free Radicals through Open-Shell Hammett Substituent Constants
Spin–Vibronic Coupling Enhanced Intersystem Crossing beyond El-Sayed Restrictions
Silicon: A Surface Dopant for Stable Alumina-Supported PtGa Propane Dehydrogenation Catalysts by Favoring Redox and Carbon Dynamics
Regioselective Hydropyridylation of Heteroatom-Functionalized Internal Alkenes by Half-Sandwich Rare-Earth Catalysts
Chemoselective Electrochemical Coupling of Thioethers and Primary Amines for Accessing Sulfilimines and Sulfoximines
Pathway to P(V)-Stereogenic Phosphoramidates by Enantioselective Yttrium Catalysis
Ring Expansions of 1,2-Amino Alcohols to Amine Heterocycles Enabled by Proton-Coupled Electron Transfer
Tuning Covalent Organic Frameworks for Nucleic Acid Loading: Toward Creating a Hierarchical Artificial Cell
Keteniminium-Mediated Postpolymerization Modification: Unlocking Emergent Properties in Polyacrylamides
Iridium-Catalyzed Z-Selective Asymmetric Allylic Substitution Reaction via Z/E Kinetic Resolution
Enantiocontrolled Azetidine Library Synthesis via Strain-Release Functionalization of 1-Azabicyclobutanes
Photoinduced Copper-Catalyzed Enantioselective Alkylalkynylation of Alkenes via Polarity-Matched Hydrogen Atom Transfer
Reductively Induced Aryl Transmetalation: An Alternative Catalytically Relevant Ni-Catalyzed Biaryl Coupling Mechanism
Collective Biosynthesis of Plant Spirooxindole Alkaloids through Enzyme Discovery and Engineering
Carbene-Catalyzed Intramolecular Cyclization to Access Inherently Chiral Saddle-Shaped Lactones: Achiral Bases Alternate Product Chirality
Efficient Aminations of Aryl Halides by a Cu(II) Catalyst
Iridium-Catalyzed Nitrene-Mediated Enantioselective 1,2-Hydride Shift Enabled by Attractive Noncovalent Interactions for Chiral δ-Lactam Synthesis
Palladium-Catalyzed Methylene β-C–H Fluorination of Native Amides
Photoinduced Copper-Catalyzed Enantioselective Allylic C(sp3)–H Oxygenation of Acyclic Terminal Olefins Enabled by SphenBOX
Click-Controlled Photo-Uncaging: Click-Assembly of Platinum-Based Photoactive Protecting Groups for Light-Triggered Bioactive Molecule Release
Strained Cyclic Alkyl(amino)carbene-Stabilized Tetraatomic Silicon(0) Cluster
Iridium Polypyridyl Carboxylates as Excited-State PCET Catalysts for the Functionalization of Unactivated C–H Bonds
Reinvestigation of the iC/i-Glycoside Synthase in Alnumycin Biosynthesis Reveals a Conserved Mechanism of C–C Bond Formation
Consecutive Multiphoton-Mediated Defluorinative Amination of Fluoroarenes
Near-Infrared Light-Driven Condensation Using Branched Two-Photon-Absorbing Organic Photocatalysts with Viscosity-Dependent Properties
Vanadium-Mediated Carbon Isotope Exchange of Terminal Alkenes
Spectroscopic and Biochemical Characterization of the Noncanonical Radical SAM Enzyme ArsL, Involved in Arsinothricin Biosynthesis
Concise Syntheses of Lycojapomine Alkaloids Enabled by Radical Dearomatization of a Pyrrole
Rapid C–S+ Bond Cleavage via 1,6-Benzyl Elimination for Traceless Modification of Bioactive Peptides
Divergent Total Syntheses of Rearranged Steroids Swinhoeisterols A–C
C–C Bond Cleavage in the Late-Stage Biosynthesis of Huperzine Alkaloids Occurs via Enzymatic Retro-Aza-Prins Reaction
Silicon Rhodamine-Catalyzed Near-Infrared Light-Induced Photodecaging of Ortho-Nitrobenzyl Groups In Vitro and In Vivo
From Nonclassical to Classical: Crystallization Seeds Reshape Nucleation Mechanisms
Cobalt-Catalyzed Enantioconvergent Decarboxylative N-Alkylation
Tuning the Directional Solubility of Ionic Liquids through Multicomponent Ions for Low-Temperature Desalination
Alkyl Fluoride Synthesis via Cu-Mediated Deacetylative Fluorination
All-Heteroatom-Substituted Carbon Spiro Stereocenters: Synthesis, Resolution, Enantiomeric Stability, and Absolute Configuration
Intramolecular N–O Bond Formation for the Synthesis of iN/i-Alkyl and iN/i-Aryl Isoxazolidines
Peptide Recognition Sequence Guides Catalytic Side Chain Cross-Linking of Plant Peptides by Copper-Dependent Cyclases
Insights into the Mechanisms of Sugar Acceptor Selectivity of Plant Flavonoid Apiosyltransferases
Phosphorus(III)-Compatible Asymmetric Suzuki–Miyaura Cross-Coupling (P-ASMC) Reaction
Stereoselectivity of Aminoacyl-RNA Loop-Closing Ligation
Formation Mechanism of Polycatenane by Direct Catenation
Photoelectrochemical Tandem Chlorination of spsup3/sup C–H Bond in Seawater/Chloroform Two-Phase Electrolyte System by Ti-Doped Fesub2/subOsub3/sub Photoanode
Stable Isotopic Labeling of Dimethylallyl Pyrophosphate (DMAPP) Reveals Compartmentalization of Isoprenoid Biosynthesis during Sporulation in iBacillus subtilis/i
Polarization-Induced Breaching of the Liquid/Liquid Interface Formed with Water-in-Salt Electrolytes
Retrofitting PMMA with a Thermal Trigger for Efficient Depolymerization
Sterically Induced Acceleration of Aryl Halide Activation by Pd(0): A Radical Alternative to 2-Electron Oxidative Addition
Iridium-Catalyzed Asymmetric Hydrogenation of Aryl(4-hydroxyphenyl)ketones
A Nitrilium-Type N-Heterocyclic Aryne
Bridged Boranoanthracenes: Precursors for Free Oxoboranes through Aromatization-Driven Oxidative Extrusion
Reagent-Regulated Organocatalytic Enantiodivergent Synthesis of Chiral Sulfinimidate Esters
Cooperative Organosulfur/Photoredox Catalysis Enables Radical-Polar Crossover C(spsup3/sup)–N Coupling via Inner-Sphere Electron Shuttling
Nickel-Mediated Radical Capture: Evidence for a Concerted Inner-Sphere Mechanism
Formally Stereoretentive SsubN/sub1 Reactions of Homoallylic Tertiary Alcohols Via Nonclassical Carbocation
Piercing Molecular Graphenes: Precision Synthesis and Photophysics of NBN-Edged Porous Molecular Carbons
Persistent Boryl Radicals as Highly Reducing Photoredox Catalysts for Debrominative Borylations
Concentration-Driven Ring Expansion Metathesis Polymerization via Tunable Ring Transfer Processes
Planarity Is Not Plain: Closed- vs Open-Shell Reactivity of a Structurally Constrained, Doubly Reduced Arylborane toward Fluorobenzenes
Carbon-Atom Scavengers Enable Divergent, Selective Carbon Deletion of Azaarenes
Mechanism-Guided Development of Directed C–H Functionalization of Bicyclo[1.1.1]pentanes
Guanine Crystallization by Particle Attachment
Multiple Secondary Bond-Mediated C–N Coupling over N-Doped Carbon Electrocatalysts
Toward Chiral Recognition by Design: Uncovering the Self-Enantioresolving Properties of Chiral Amine Derivatives
Diboron-Incorporated Indenofluorene: Isolation of Crystalline Neutral and Reduced States of 6,12-Diboraindeno[1,2-ib/i]fluorene
Photo- and Copper-Catalyzed Enantioselective Oxidation of Benzylic C(sp3)–H Bonds
3-Selective Pyridine Fluorination via Zincke Imine Intermediates
Discovery of an Interlocked and Interwoven Molecular Topology in Nanocarbons via Dynamic C–C Bond Formation
Unlocking Epoxide Radical Anion Reactivity for Asymmetric Cross-Coupling by Copper Metallaphotoredox
Spontaneous Emergence of Homochiral Suspensions from Racemic Solutions via Stochastic Nucleation
Orthogonal Site-Specific Dual Bioconjugation of Aryl and Alkyl Thiols
Copper-Catalyzed Formal Aldehydic C–H Borylation Enabled by an sp2–sp3 Diboron Reagent
Aza-Michael Addition–Fragmentation Ring-Opening Polymerization
Concise Total Synthesis of Ambiguine P
Non-Aqueous Binary and Ternary in/iHF·Base Fluoride Reagents: Characterization of Structure, Properties, and Reactivity
Photocatalytic Phosphine-Mediated Deoxygenative [3 + 2] Cycloaddition of α,β-Unsaturated Carbonyls and Alkenes
Stereoselective 1,3-Cyclotelomerization of Butadiene with Dienophiles under Nickel Catalysis
Direct Access to Benzofurans and Indoles from Ethylene with 2-Methylphenols/Anilines through Iridium-Catalyzed Dehydrogenative Annulation
Template-Directed Synthesis of Recognition-Encoded Melamine Oligomers Using a Base-Filling Strategy
Phenalenyl Chemistry Revisited: Stable and Bioactive Multisubstituted Phenalenyl Radicals Synthesized via a Protection–Oxidation–Protection Strategy
Total Synthesis of (−)-Illisimonin A Enabled by Pattern Recognition and Olefin Transposition
Kinetic Analysis of the Redox-Neutral Catalytic Mitsunobu Reaction: Dehydration, Kinetic Barriers, and Hopping between Potential Energy Surfaces
Noncatalyzed Intramolecular B–N and B–O Cross-Coupling of “Inert” Carboranes Lead to the Formation of an Unusual Oxoborane, via Reversible Cluster C–B Bond Scission
A Broad-Spectrum Catalyst for Aliphatic Polymer Breakdown
Design and Synthesis of a Cluster-Based Supramolecular Reaction Pump for the Efficient Catalysis of Amination Reactions
Performance-Enhancing Asymmetric Catalysis Driven by Achiral Counterion Design
Iron-Mediated Nitrate Reduction at Ambient Temperature for Deaminative Sulfonylation and Fluorination of Anilines
Catalytic Atroposelective aza-Grob Fragmentation: An Approach toward Axially Chiral Biarylnitriles
Dehomologative C–C Borylation of Aldehydes and Alcohols via a Rh-Catalyzed Dehydroformylation–Borylation Relay
Pd-Catalyzed Photoinduced Interceptive Decarboxylative Allylation
3,6-Anhydrogalactal as a Single-Addition Monomer for Chain-End Functionalization of Metathesis Polymers
Enantioselective Synthesis of Axially Chiral Alkylidenecyclobutanes via Palladium-Catalyzed N-Tosylhydrazone-Based Carbene Coupling
Ni-Doped Perovskite for Photocatalytic Benzylic C–H Amination
Molecular and Structural Characterization of a Chalcone di-C-Methyltransferase RdCMT from Rhododendron dauricum and Its Application in De Novo Biosynthesis of Farrerol in Pichia pastoris
Synthesis and Characterization of Cycloocta[1,2-a:6,5-a′]diindene as an Octagon-Containing Nonalternant Isomer of Pentacyclic Benzenoid Aromatic Hydrocarbons with Hidden Diradical Character That Induces Dimerization
A Catalytic Asymmetric Intramolecular [4 + 1]-Cycloaddition for the Total Synthesis of Terpene Alkaloid Natural Products
Peptide Recognition and Mechanism of the Radical S-Adenosyl-l-methionine Multiple Cyclophane Synthase ChlB
Tuning the Reaction Chemistry for the Sulfo-Bromination of Bismuth, Leading to Dual-Tapered Bi-Sulfobromide Platelet Nanocrystals and Their Heterostructures
Photochemistry of Ni(II) Tolyl Chlorides Supported by Bidentate Ligand Frameworks
Ir-Catalyzed, Stereoselective Total Synthesis of (+)-Rubriflordilactone A
Cage Alkyl Carbenes Provide Experimental Evidence for Isotope-Controlled Selectivity in Competing Tunneling Reactions
A Unified Approach to Chiral α-Aryl Ketones and Aldehydes via Ni-Catalyzed Asymmetric Reductive Cross-Coupling
Asymmetric Vicinal and Remote Hydroamination of Olefins by Employing a Heck-Reaction-Derived Hydride Source
10-Step, Gram-Scale Total Synthesis of (−)-Bipinnatin J
Bioinspired Methionine-Selective Desulfurization Editing of Peptides via the Photocatalysis Strategy
Photoswitchable Fluorescent Hydrazone for Super-Resolution Cell Membrane Imaging
Direct Observation of C–F Bond Formation from Isolable Palladium(IV) Systems via an Outer-Sphere Pathway
Cathode–Anode Synergy Electrosynthesis of Propanamide via a Bipolar C–N Coupling Reaction
Solvent-Controlled Enantioselective Allylic C–H Alkylation of 2,5-Dihydrofuran via Synergistic Palladium/Nickel Catalysis
Elucidating the Iterative Elongation Mechanism in a Type III Polyketide Synthase
2H Quadrupolar Coupling Constant: A Spectroscopic Ruler for Transition Metal–Hydride Bond Distances in Molecular and Surface Sites
167
Diverse Functionalization of Nonpolar Polyolefins through Late-Stage Incorporation of Alkyl Bromides
Aqueous Slurry Polymerization of Ethylene by Phosphinephenolato Nickel(II) Complexes: Catalyst Tailoring and Synthesis of Bimodal Polyethylene
Double-Hydrophilic Polyphosphonate-Block-Polyamine Copolymers via Living Anionic Polymerization
Cationic Polymerization of Pendant-Reactive Styrene Derivatives Using Diaryliodonium Salts as Both a Lewis Acid Catalyst and a Photoreactive Reagent
Mechanistic Insights into Transfer-Dominated Branching Radical Telomerization through Kinetic Monte Carlo Simulation
Lower Critical Solution Temperature-Type Phase Behavior of Poly(N-isopropylacrylamide) in Nonaqueous Organic Solvents
Living Carbanionic Chain-Shuttling Polymerization
Self-Sacrificing Photocatalyst Enables Polymer Synthesis and In Situ Decolorization
Polyacrylic Acid-Mediated Supramolecular Light-Harvesting Platform Enables Reactive Oxygen Species Boosting and Photocatalytic Oxidations
A Single-Chain Nanoparticle-Based Mean-Field Theory for Associative Polymers
Controlled Synthesis of Degradable Lipoate-Vinyl Copolymers via Xanthate-Mediated Reversible Addition–Fragmentation Chain Transfer Polymerization
Design of Pyrazole-Pendant Acrylamide Monomers Enabling Selective Postpolymerization Modification for Library Synthesis of Random/Block Copolymers
One-Pot Orthogonal Synthesis of Branched Polymers Enabled by Dual-Functional Copper(I)–Organic Frameworks Integrating Photo-ATRP and CuAAC
Synthesis of Poly(δ-valerolactone)-poly(N,N-dimethylacrylamide) Supermicelles in Concentrated Aqueous Media via Reverse Sequence Polymerization-Induced Self-Assembly
Organotellurium-Mediated Radical Polymerization of Chloroprene
Measuring Activation and Degradation of Reverse-Blocking-Order PET-RAFT Chain Extension Polymerizations
Ultrasmall Nanogels from Intramolecular Cross-Linking of (Hyper)Branched Cyclic Polyglycerols with Diboronic Acids
Self-Assembly and Structural Polymorphism of Polymer–Lipid Mimetics Prepared by Azide–Alkyne Cycloaddition
Hydration Dynamics of Perdeuterated PNIPAM in Aqueous Solution
Crystal Structure of Poly(α-methylene-δ-valerolactone)
Structural Switching between Binary Alternating and Ternary Periodic with Reversible Lock–Unlock Carbanionic Polymerization Method
Segmental Mobility of Polymer Chains under Molecular Confinement: Insights from Precision Molecular Bottlebrushes
Integrated Synthesis and Purification of Chemically Diverse Abiotic Sequence-Defined Macromolecules via Solvent-Resistant Nanofiltration
Function Meets Circularity: Metal–Ionomer Cross-Links Toughen and Recycle CO2-Derived Polymers
Exclusion-to-Adsorption Transition of Hyperbranched Polymers in Liquid Chromatography: Governed by Configurational Diversity and High Fractal Dimension
Traceless Staudinger–Bertozzi Ligation for Postpolymerization Modification
Characterization of Sequence Distributions in Random and Semi-Random Copolymers
Elucidation of Structure–Reactivity Trends in Free Radical Copolymerization Reactivity Ratios Using Data Science Methods
Steric Effect in Kinetic Monte Carlo Simulation of Arm-First Synthesis of Star Polymers
Trapping Polymer Entanglements via Prolonged Initiation
Enhancing Polystyrene Circularity via Functionalized Weak Linkages
Crystallite-Templated Solid-State Synthesis of Blocky Polyethylene Copolymers
Poly(pentafluorophenyl acrylamide): Novel Platform for Selective Post-Polymerization Modification via para-Fluoro-Thiol Reaction
Hierarchical Dynamic Network Reconfiguration for Co-Rrecycling of Mixed Biodegradable Polyesters
Are Electron-Withdrawing Groups Affecting Polyester Hydrolysis? A Comprehensive Study on Poly(thioether-ester)s and Poly(sulfone-ester)s
Determinants of π-π Stacking Motifs in Polymers with Different Aromatic Side Groups
Cross-Link Location Influences Performance in Acrylic Pressure-Sensitive Adhesives
Synthesis of Highly Syndiotactic Poly(8-Vinylquinoline) via Heteroatom-Assisted Coordination Polymerization
Red-Light-Induced PET-RAFT Polymerization to Afford (Meth)acrylamide-Based Poly(N-oxide) and Other Hydrophilic Polymers Featuring Neutral, Cationic, and Zwitterionic Groups as Solubilizing Side Chains
Synthesis of Deuterated Multicyclic Polystyrenes for a SANS Study to Explore the Structural Characteristics of Multicyclic Architectures in the Bulk
Selective Upcycling of Mixed Polyesters into Valuable Polysulfone
Interlocked Polymerization inside Cocrystal versus Interfacial Polymerization at Solid of Racemic Leucine N-Thiocarboxyanhydride
Chemoselective Polymerization of 2-(Acryloyloxy)ethyl Methacrylate Enabled by B(C6F5)3-Stabilized s-cis and s-trans Monomer Conformations
Phase Coexistence in Thermoresponsive PNIPAM Hydrogels Triggered by Mechanical Forces
Quantitative Evaluation of Cross-Linking Efficiency in Worm-like Nanoparticles Prepared via RAFT-Mediated Aqueous Emulsion PISA
Fabrication of a Multifunctional Fluorescent Supramolecular Assembly via Cucurbituril-Based Host–Guest Interactions in Aqueous Solution
Design, Scalable Synthesis, and Characterization of Poly(Oligourethane Methacrylate)s Bottlebrushes with Discrete, Sequence-Defined, and Stereocontrolled Side-Chains
Amine-Activated Ring-Opening Polymerization of 1,2-Dithiolane in a Cascade Fashion and Organocatalyzed Pendant Modification: A Path to Functional Dynamic Covalent Poly(disulfide)-Based Macromolecules
Varying Monomer Charge in SI-bioATRP Polymer Grafting from Mesoporous Silica
Highly Thermally Stable and Miscible CO2-Based Block Copolymers by the Combination of Ring-Opening and RAFT Copolymerizations through Mediated Hydrogen Bonding Interactions
SuFEx Chemistry Enables Sustainable Side-Chain Modification of Renewable Phenylpropanoid Polymers
Halogen Effect in Dual-Catalysis PhotoATRP
Direct Fluorination of Ethylene–Tetrafluoroethylene Copolymer Films in Liquid Media
Nitroarene-Mediated Photo-oxidative Deconstruction and Upcycling of Unsaturated Rubber Waste
Mechanocatalytic Oxidation Using Alkoxyamine Mechanophores: Ultrasonication-Triggered Release of TEMPO Catalysts
Tracer Diffusivity in Amphiphilic Polymer Model Co-Networks
On-Demand CO Delivery and Incorporation from Solid Surrogate Enable Compatible Slurry-Phase Ethylene Polymerization
Selectivity in Unireactor Oligomerization within a Multiple Tethered-Monomer Reactor
Step Toward Cationic RAFT Polymerization of Less Reactive Monomers: Dithiobenzoates Bearing Electron-Withdrawing Groups as Chain-Transfer Agents
Electrostatic Mediation in Synthesis of Single-Chain Nanoparticles in Concentrated Solutions
Controlled Thermoresponsive Aggregation of Core-Cross-Linked Multiarm Star Poly(N-isopropylacrylamide) for a Highly Dispersed Hydrophobic Nanospace in Water
Effect of Initiator Density, Catalyst Concentration, and Surface Curvature on the Uniformity of Polymers Grafted from Spherical Nanoparticles
Ternary Acrylamide–Aldehyde–Thiol Photopolymerization toward Side Chain-Functionalized Degradable Polyamides
Tailoring Branched Polyethylene with Polar Segments: A Strategic Approach to Multifunctional Polyolefin Materials
Precise Synthesis of Acrylate-Terminated Poly(Triethylene Oxide Glycidyl Ether) via Anionic ROP for Enhanced Lithium-Ion Conductivity in Hybrid Solid Electrolytes
Stereoselective Control of Crystalline Alternating Copolymers Synthesized with an Anion-Migrated Ring-Opening Polymerization Method
Synthesis of Cleavable Polyolefins via Ring-Opening Insertion Metathesis Polymerization (ROIMP) of Cyclopentene with Unsaturated Polyester Oligomers
Radical Cascade Polymerization Involving Dual Cyano Group Migration to Synthesize Periodic Polymers
Reaction Temperature and Solvent Influence Reactivity Ratios in the Copolymerization of Ethylene Oxide and Propylene Oxide
Light-Induced Copolymerization of Ethyl Lipoate and Vinyl Monomers: Increased Efficiency and Degradability
Preparation of Polymer Gel with Homogeneous Network Structure Composed of Photoreactive Star-Shaped N-Isopropylacrylamide Polymers
Thermally Programmable Off-Equilibrium Pathways in Salt-Doped Polyelectrolyte Hydrogels
Kinetic Study of Self-Condensing Vinyl Polymerization via ATRP: A Stochastic Model Coupled with Ab Initio Calculations
Efficient Intermolecular Electron Transfer-Mediated Radical Photopolymerization via Controlled Accessibility of Triplet Excited States in Donor–Acceptor Sensitizers
Seed Oligomers Regulate Sequence Development through a Templating Effect in Simulated Irreversible Step-Growth Copolymerization
Thermo-Driven Dynamic Reversible Self-Assembly of Crystalline Polymersomes and Worms for Active Polymerization Safety Sensors
Modular Synthesis of ABAC-Type Periodic Terpolymers via RAFT Single-Unit Monomer Insertion and RAFT Step-Growth Polymerization
Ionized H-Donors as Simple and Diverse Organobase Catalysts for Selective and Versatile Ethoxylation
Orthogonal Phase Separation through Associative Interactions in Polymer Blends
A Library Synthesis of N-Alkylacrylamide-Hydroxyethyl Vinyl Ether Alternating Copolymers for Studies of Thermoresponsive Features in Water
Fluorinated Phthalocyanine as a Catalyst for NIR-Photocontrolled PET-RAFT Polymerization: From Submicron Dispersion to Surface Immobilization
Stability and Anomalous Aggregation in Suspensions of Polymer-Grafted Nanoparticles
AIEgen Functionalized Polymer Ring
Structure–Property–Performance Relationships of Tetra-Alkylated Phenazine Photoredox Catalysts in Organocatalyzed Atom Transfer Radical Polymerization
Flow RAFT Step-Growth Polymerization
Confined Polymerization in Microphase-Separated Liquid Crystalline Films: Alignment-Controlled Growth of Conjugated Poly(diacetylene) Nanostructures
Rationally Designed Poly(heptazine imide) for Highly Efficient Photoinduced Reversible Deactivation Radical Polymerization
Interfacial Polymerization at a Nonaqueous Acid Interface for the Fabrication of Structurally Unusual Polymer Thin Films
Structure–Property Relationships in Multicyclic Polystyrenes: Synthesis, Physical Properties, and Comparison with Acyclic Counterparts
Bottom-Up Simulation, Reconstruction, and Quantification of Macromolecule Sequences from Experimental Polymerizations
Phenolic Formaldehyde Resin-Based Nano-objects via a Modification-Induced Cooperative Assembly Process Using Poly(4-hydroxystyrene) as the Core-Forming Block
Mechanically Accelerated Chemical Deconstruction for Nondeteriorative Recycling of Industrial Unsaturated Thermosets and Rubbers
Structure and Dynamics of Self-Assembled Thermo-Associative PNIPAM–PDMA-PNIPAM Triblock Copolymers of High Molar Mass
Backbone Dynamics of Bottlebrush Polymers Studied by Neutron Scattering
Rational Design of Zwitterionic Polymers with Tunable Phase Separation Propensity
Direct Comparative Study of Ring-Opening Polymerization between Propylene Oxide and Cyclohexene Oxide: Geometric Control of Epoxide Polymerization Behaviors
Stereospecific Hydroxyl–Yne Click Polymerization to Selectively Construct High-Performance Plastics and Elastomers
Isolated In Situ Cross-Linking-Assisted Polymerization-Induced Self-Assembly to Polymer Cubosomes with Enhanced Stability
Organocatalytic Precision Synthesis of Poly(ester amide)s with Enhanced Thermal Performance and Programmable Microarchitectures
Direct Radical Copolymerization of Vinylidene Fluoride with Vinylphosphonic Acid and Characterization of the Resulting poly(VDF-ico/i-VPA) Copolymers
Morphology Regulation and Quenching Mechanism of AIE Nanobowls by Side Chain Engineering of Azobenzene Homopolymers
Electrochemical C–H Phosphonylation of Dissolved Conjugated Polymers via Direct Electron Transfer at the Electrode
Efficient Deterministic Modeling of Reversible Copolymerizations
Recyclable Biomass-Derived Polyethylene-like Plastics
Synthesis of ABC-Type Periodic Terpolymers through a Reversible Lock–Unlock Mechanism in Living Carbanionic Polymerization
Cyclization in Linear Step-Growth Polymerizations
Single-Unit Comonomer Insertion Initiates Radical Polymerization of Thionolactone to Give Chemically and Thermally Degradable Polythioesters
Synthesis of Polyester-Polystyrene Hybrid Gel by PET-RAFT Polymerization in “RAFT Gel” and the Role of Dynamic Covalent Bonding in Its Self-Healing Properties
Incorporation of Oxime Functionality into Polyolefins via Iron-Catalyzed C–H Imidoylation
Exploring the Removal of Thiocarbonylthio Chain Ends from Poly(styrene-alt-maleic anhydride) Copolymers
Sulfur Treatment of Coordinative Chain Transfer Polymerization Products for Extending Polyolefin Chains with Polysulfide Linkages
Dual-Degradable and Reprocessable Hyperbranched Polymers from Chain Transfer Agent-Lipoic Acid Conjugate
Enlightening the Depolymerization Kinetic Mechanism in Reversed Atom Transfer Radical Polymerization via In Silico Modeling
Uniform Block Copolymer Photonic Microspheres with Tunable Structural Colors across Full Visible Spectrum Enabled by Quaternizing Additives
Cosolvency-Induced UCST/LCST Dual Phase Separation of Poly(2-hydroxyethyl methacrylate) in Nonaqueous Organic Solvent Mixtures
Counterion-Free Ionic Associating Polymers: In Situ Ionization and Coupling of Alkyl Sulfonate Precursors
Thermogels Based on Block versus Gradient Terpolymers: Differences in the Nano- and Macro-Scale
Kinetic Model of Radical Ring-Opening Polymerization of Asymmetric Five-Membered Cyclic Ketene Acetals
Unraveling the Physicochemical Properties of Poly(2-n-propyl-2-oxazoline), a Promising Pharmaceutical Excipient
Organocatalytic Group Transfer Polymerization of α-Methylene-N-methylpyrrolidone: Controlled/Living Property Applied to the Synthesis of Gradient and Block Copolymers with Acrylamide and Methacrylate Polymers
Synthesis and Structural/Physical Properties of Well-Defined Linear and Star-Shaped Polysulfides Constructed by Controlled Insertion Reaction of Thiirane and Carbamic Acid Thioester
Access to Self-Assembled Poly(2-Oxazoline)s through Cationic Ring Opening Polymerization-Induced Self-Assembly (CROPISA)
From Monomer Design to Multifunctional Polymers via Controlled ROMP: Novel Indole-Functionalized Norbornene Dicarboximide Copolymers with Enhanced Thermal, Optical, and Antibacterial Properties
Dithiolane-Ene Copolymerization: Enabling Tunable, Dynamic, Dual-Cure Networks via Real-Time UV–Vis/FTIR Kinetics and Compositional Analysis
Green-Light-Driven PET-RAFT Polymerization Catalyzed by Pyrazino[2,3-f][1,10]phenanthroline Derivatives and Their Mediated Polymerization-Induced Self-Assembly
The RAFT-Mediated Synthesis of Poly(styrene-ico/i-maleic acid) through Direct Copolymerization of Maleic Acid
Bioinspired Dual-Stimulus-Responsive Macromolecular Engineering Enables Chemically Recyclable, High-Performance and Fire-Retardant Plastic
Molecular Bottlebrushes with Programmable Grafting Densities
Rapid Copper-Catalyzed Aqueous Polymerization of Cyclic Propargylic Carbonates
Influence of Intermolecular Interactions on Acrylate–Methacrylate Copolymerization Reactivity Ratios: From Bulk to Aqueous Solution
Streamlined Synthesis of Sequence-Defined Oligomers and In-Chain Multifunctionalized Polymers via Sequential Dual Monomer Insertion
Initiator Activation and Active Chain End Stabilization Strategy via the Dual Hydrogen Bond for the Controlled Synthesis of Poly(fluorosiloxane)
Functional Nano-Objects Prepared via Living Anionic Polymerization-Induced Self-Assembly (LAPISA) of Polar Vinyl Monomers
Iron-Catalyzed C–H Amination of Polyethylenes
Crystallization Regulation Through Monomer Sequence Control in the Carbanionic Copolymerization-Induced Crystallization Method
RAFT Copolymerization of Glycerol-Derived Vinyl Ethers Possessing Acetal-Protected Diols for Biobased Hydrophilic and Thermoresponsive Polymers
1,4-Cyano Group Migration Involved Radical Cascade Polymerization
Facile Synthesis of Graft Polymers with Poly(vinyl ether) Graft Chains Using Poly(cyclic acetal)s as Macroinitiators for Living Cationic Polymerization
Retrograde Depolymerization in Living Anionic Polymerization of α-Methylstyrene
Fluoroalkyl Chain End Groups Regulating Crystal/Amorphous Interfaces of Semicrystalline Polyethylene Films
N-Sulfonyl Aziridine-Derived Trithiocarbonates: Functional RAFT Agents for the Synthesis of Architectural Polymers
Access to Microstructurally Complex Block Copolymers via Switchable Ring-Opening Polymerization of Cyclic Ester Mixtures
Compatibilization of Immiscible Polymer Blends through Pendant Ionic Interactions
Light-Induced Stitching of Folded Polymer Chains
Synthesis and Molecular Characterization of Pyrene-Containing Copolymers as Potential MALDI-TOF MS Matrices
Tethered Cation Size Affects the Imbibition of Polymerized Ionic Liquids and the Ionic Conductivity in Nanopores
Synthesis, Characterization, and Polymerization of 4′-Acyl(oxy) Alkenyl Azlactone Monomers Designed Using a Steglich Rearrangement Approach
Free-Radical (Co)polymerization of Tulipalin A─Analyzing Copolymerization Behavior
Synthesis of Compact Single-Chain Nanoparticles in Concentrated Solutions
Phase Behavior of Reversibly Bonding Polymer Blends
Cationic Dithiocarbamate for Efficient Blue Light-Controlled Photoiniferter Polymerization
Dramatic Effect of Alkali Metal Alkoxides on the Anionic Copolymerization of Styrene and Isoprene
Why Is the Trommsdorff Effect Weak for Styrene? An Investigation Using Small-Angle Neutron and Wide-Angle X-ray Scattering
Force-Accelerated Ring Opening of Episulfide by Pulsed Ultrasonication
Troponoid-Mediated Radical Polymerization of Vinyl Monomers
Microfluidic Reactor for Studying Aqueous Phase Polymerization Events of Relevance to Emulsion Polymerization: Methyl Methacrylate
Open-Vessel and Scalable Synthesis of Linear and Branched Poly(meth)acrylic Acid via Light-Mediated Atom Transfer Radical Polymerization in Water
Simultaneous Click Coupling Reaction and Declick Cyclization Reaction in the Synthesis of Degradable Polymers
Rauhut–Currier Polyaddition: Self-Polymerization of Divalent Aryl Vinyl Ketones for Unsaturated Polyketones
Comprehensive Screening of Conditions for Block Copolymer Nanoaggregate Formation via Automated DLS
Thermodynamic Analysis of Photopolymerization-Induced Phase Separation Processes at Subzero Temperatures to Predict Experimental Conditions Leading to Porous Thermosets
Cyclization of Polyacrylonitrile Nanofibers Enhanced by Cu2O During Electrospinning
Probability Method of Molecular Size, Polydispersity, and Branch Unit Distribution Function for the Three-Dimensional Polymers: A Continuation of Flory’s Work in 1941
Single-Fiber Visualization of Poly(ethylene terephthalate) during Alkaline Hydrolysis: Testing of Surface Reaction Model and Mechanism
Living Anionic Polymerization of 2-Isopropenylthiophene Derivatives
Elucidation of the Termination Mechanism of the Radical Polymerization of Isoprene
Cyclic Poly(Thioester Amide)s via Ring-Opening Copolymerization of Aziridines and Phthalic Thioanhydride: Mechanistic Insights and Enhanced Properties for Sustainable Materials
19
Preferential Reduction of 2-Phenylpyridine under D2: Palladium Nanoparticles Stabilized by N-Heterocyclic Carbenes Prefer D2 to H2
Bromine-Mediated Electrochemical Cascade Valorization of Styrene
Proton Concentration Tunes the Double-Layer Characteristics of Lead Catalysts to Boost the Electrosynthesis of Glyoxylic Acid
Enhanced Diffusion of Single, Lipid-Tethered Enzymes
Dual Metal Complex Functionalization of Black Phosphorus
Biotic–Abiotic Hybrid System for Efficient Soluble Plastic Degradation
Discrete Patterned Functional Polymeric Nanostructures via Controlled Biaxial Iterative Synthesis
Nanoclay–Peptide Interfaces Mediate Prebiotic Chemical Evolution in the Origin of Life
Pressure-Driven Solid-State Radical Polymerization toward Carbon Nanothread
Liquid-Phase Exfoliated 2D Nanomaterials for Enhanced Vibrational Circular Dichroism of Chiral Molecules
Molecular Stacking Patterns Enhance Organic Small-Molecule Electrochemical Stability and Enable Ion Separation
Bioinspired Flavin-Based Supramolecular Materials for Catalyzing Baeyer–Villiger Oxidation
Programmable RNA Nanostructures Enable Nanopore Detection of Cotranscriptionally Introduced RNA Modifications
Temperature-Insensitive Electron Transfer in Quantum Dot–Molecule Hybrids Driven by Nuclear Quantum Tunneling
Sub-Nano Copper Sites on SiO2 with Downshifted d-Band Centers Dominate Non-Radical Selective Oxidation of Benzene to Phenol
Engineered Lipid Coronas for Gold Nanoparticle-Based Bioorthogonal Catalysis
Electrocatalytic Upcycling of Plastic Waste to Organonitrogen Chemicals via Intercepting Carbon Intermediates
Gram-Scale Synthesis of an Ultrastable 38-Nuclei Copper(I) Alkynide Nanocluster for Unraveling Bifunctional Photocatalysis
Highly Elliptic Circular Dichroism of Copper Aspartate One-Dimensional Nanostructures across the Ultraviolet to Terahertz Ranges
35
Decarboxylative alkylation of alkenes
Electronic origin of reorganization energy in interfacial electron transfer
Carbonyl swapping converts cyclic ketones to saturated heterocycles
Direct conversion from alkenes to alkynes
Alcohol group migration by proximity-enhanced H atom abstraction
Markovnikov hydroamination of terminal alkenes via phosphine redox catalysis
Chemical capture of diazo metabolites reveals biosynthetic hydrazone oxidation
Dominant contribution of Asgard archaea to eukaryogenesis
Electrochemical defluorinative Matteson-type homologation
Random heteropolymers as enzyme mimics
The asymmetric synthesis of an acyclic N-stereogenic amine
Synthesis of enantioenriched atropisomers by biocatalytic deracemization
Controlling pyramidal nitrogen chirality by asymmetric organocatalysis
Myriad Aryne Derivatives from Carboxylic Acids
Nanobody-based recombinant antivenom for cobra, mamba and rinkhals bites
Direct deaminative functionalization with N-nitroamines
Selective Methylene Oxidation in α,β-Unsaturated Carbonyl Natural Products
Deaminative cross-coupling of amines by boryl radical β-scission
Photocatalytic oxygen-atom transmutation of oxetanes
Robot-assisted mapping of chemical reaction hyperspaces and networks
Decoding the redox behaviour of copper in Ullmann-type coupling reactions
Stabilizing effect of amino acids on protein and colloidal dispersions
Supervised learning in DNA neural networks
Thioester-mediated RNA aminoacylation and peptidyl-RNA synthesis in water
Discovery of a widespread chemical signalling pathway in the Bacteroidota
Catalytic enantioselective synthesis of alkylidenecyclopropanes
Repurposing haemoproteins for asymmetric metal-catalysed H atom transfer
Synthesis of deuterated acids and bases using bipolar membranes
Boron-mediated modular assembly of tetrasubstituted alkenes
In-line NMR guided orthogonal transformation of real-life plastics
Electricity-driven enzymatic dynamic kinetic oxidation
Pt migration-lockup in zeolite for stable propane dehydrogenation catalyst
C-to-N atom swapping and skeletal editing in indoles and benzofurans
One-carbon homologation of alkenes
Deep origin of eukaryotes outside Heimdallarchaeia within Asgardarchaeota
7
Self-splicing and cyclization mechanisms of the full-length Anabaena pre-tRNA
Biomolecular condensates mediate C–N bond formation
Rapid evolution of a highly efficient RNA polymerase by homologous recombination
pH variations enable guanine crystal formation within iridosomes
SNAP-tag2 for faster and brighter protein labeling
A widespread metabolic gene cluster family in metazoans
Glyceollin biosynthesis in a plant chassis engineered for isoflavone production
67
A Cu(I)-catalysed click reaction generates ROS-triggered cleavable linkages in aqueous media
Reactions of diazoboranes with oxygen enables the synthesis and isolation of dioxaboriranes
Diverse radical C–F functionalizations of hexa- to difluoroarenes using boryl radicals as link-and-lose mediators
A system of paired polyether epoxide hydrolases enables a mouldable enzyme for consecutive ring cyclization cascades
tRNA-deacylase-directed discovery of biosynthetic pathways
Programmable divergent electrochemical ring-opening multifunctionalization of strained rings
Amino acid composition drives aggregation during peptide synthesis
Biocatalytic site- and stereoselective carbonyl desaturation for late-stage functionalization of cyclic ketones
Spontaneous trisulfide metathesis in polar aprotic solvents
Organocatalytic enantioselective synthesis of S(IV)-stereogenic sulfinamides enabled by an air-stable chiral phosphine
Mineral-to-molecule arsenic transfer via photoredox catalysis
Catalytic asymmetric sulfonimidoyl transfer to access chiral sulfonimidoyl fluorides and related derivatives
Biomolecular condensates sustain pH gradients at equilibrium through charge neutralization
Collective asymmetric synthesis of the Strychnos alkaloids via thiophene S,S-dioxide cycloadditions
Hyperpyramidalized alkenes with bond orders near 1.5 as synthetic building blocks
Thermal [2+2] cycloaddition as a route to -difluoro heterobicyclo[.1.1]alkanes
Catalytic acyloin-type heterocoupling of thioesters via a putative cobalt siloxycarbene
Biocompatible ligand balancing in transition metal coordination enables benign in-cell protein arylation
Stereoselective total synthesis of skew-tetramantane
The catalytic enantioselective [1,2]-Wittig rearrangement cascade of allylic ethers
Direct enantioselective C(sp3)−H coupling of N-alkyl anilines via metallaphotoredox catalysis
Stepwise-controllable catalytic asymmetric Atherton–Todd reaction to access diverse P(V)-stereogenic compounds
Photoswitchable olefins as latent metathesis monomers for controlled polymerization
Iridium(III)-catalysed ionic hydrogenation of pyridines to multisubstituted piperidines
Dearomative syn-1,4-hydroalkylation and C(sp2)−H alkylation of arenes controlled by chemoselective electrolysis
Construction of sulfur stereocentres by asymmetric geminate recasting
Stereodivergent construction of non-adjacent stereocentres via migratory functionalization of alkenes
Non-ribosomal peptide cyclase-directed chemoenzymatic synthesis of lariat lipopeptides
Azetidine amino acid biosynthesis by non-haem iron-dependent enzymes
Copper-catalysed asymmetric cross-coupling reactions tolerant of highly reactive radicals
A recursive enzymatic competition network capable of multitask molecular information processing
Core diversification using 1,2-oxaborines as a versatile molecular platform
Triplet state reactivity of iminium ions in organocatalytic asymmetric [2 + 2] photocycloadditions
Enantioconvergent radical addition of racemic alkyl halides to access vicinal stereocentres
Leveraging electron donor–acceptor complexes for kinetic resolution in catalytic asymmetric photochemical synthesis
Selective arylation of atypical C–F bonds in polyfluoroarenes with aryl chlorides
Divergent access to E- or Z-trisubstituted medium-sized cycloalkenes by Pd-catalysed cycloaddition
A two-metalloenzyme cascade constructs the azetidine-containing pharmacophore
Tunable cobalt-catalysed hydrogenation of allenes enabled by multiple metal–ligand cooperative functionalities
Electrifying industrial hydrogen peroxide production via soft interfacial molecular mediation
Bulk water redox chemistry enables radical-mediated C–C coupling in CO2 electroreduction
Diastereo- and enantioselective 1,3-hydrofunctionalization of trisubstituted alkenes by a directing relay
Organocatalysed three-component modular synthesis of BN isosteres and BN-2,1-azaboranaphthalenes via Wolff-type rearrangement
Carbon-to-nitrogen atom swap enables direct access to benzimidazoles from drug-like indoles
Unlocking azole chemical space via modular and regioselective -alkylation
Reversible fluorenol photobases that perform CO capture and concentration from ambient air
Polymer connectivity governs electrophotocatalytic activity in the solid state
Diastereodivergent synthesis of multi-substituted cycloalkanes
Deaminative Giese-type reaction
Bright triplet and bright charge-separated singlet excitons in organic diradicals enable optical read-out and writing of spin states
Catalytic C(sp2) homologation of alkylboranes
Synthesis of highly strained -cyclophanes via ring-expansion [5,5]-sigmatropic rearrangement reaction
Energy transfer-enabled enantioselective photocyclization using a privileged Al–salen catalyst
Mechanochemical pathway for converting fluoropolymers to fluorochemicals
A biocompatible Lossen rearrangement in Escherichia coli
Adaptive dynamic kinetic resolution enables alteration of chiral induction with ring sizes
Accessing sulfonamides via formal SO2 insertion into C–N bonds
Synthesis of diverse terpenoid frameworks via enzyme-enabled abiotic scaffold hop
Modular alkyl growth in amines via the selective insertion of alkynes into C–C bonds
Information propagation through enzyme-free catalytic templating of DNA dimerization with weak product inhibition
Interfacial assembly of biomimetic MOF-based porous membranes on coacervates to build complex protocells and prototissues
A selenoxide for single-atom protein modification of tyrosine residues enabled by water-resistant chalcogen and hydrogen bonding
Photoinduced bulk polymerization strategy in melt state for recyclable polydiene derivatives
Trinucleotide substrates under pH–freeze–thaw cycles enable open-ended exponential RNA replication by a polymerase ribozyme
Abiotic lipid metabolism enables membrane plasticity in artificial cells
Discovery of acylsulfenic acid-featuring natural product sulfenicin and characterization of its biosynthesis
Exo-templating via pseudorotaxane formation reduces pathway complexity in the multicomponent self-assembly of M12L24 nanospheres
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Alternative enzymatic pathways to penicillin antibiotics
Decorating titania with ultrasmall UiO-66-H crystallites enables quantitative photocatalytic oxidation of methane to oxygenates
Mechanochemical atom transfer radical polymerization unlocks functional methacrylate lifecycles of controlled synthesis, force-activated degradation, and depolymerization
Balancing acceleration and turnover in [1 + 1] tetra-imine bis-calix[4]pyrrole reactor for Huisgen cycloadditions
Merging photocatalysis with C-H insertions enabled switchable synthesis of indoles and indolines
Mechanochemically functionalized waste plastics for NO sensing
Electrostatic-confinement-induced regioselective C-H functionalization of polyolefins
Sn catalyst reconstruction and microenvironment modulation for efficient amino acid electrosynthesis via C–N coupling
Designing soft materials through synthetic morphogenesis
Kinetics-controlled radical coupling on dual redox-active sites for selective formamide production
Redox-mediated domino electrosynthesis of -dimethylformamide with industrial-relevant productivity and modularized cathodic integration
Piezocatalytic reforming of plastics into high-value chemicals
Kinetic resolution of amino acids by phosphine oxide catalyzed enantioselective esterification
Room-temperature electrochemical hydroxyalkylation of pyridines
Repurposing trifluoromethyl copper (III) complexes for difluoromethylation of saccharides and complex alcohols
Skeletal editing of tetrahydrofurans to pyrrolidines through O-to-N single atom swap
Sustainable recycling of polyester wastes using a coordinatively unsaturated Zn catalyst
Gallium in liquid state shows nuclease-mimicking activity
Enantioselective Synthesis of 2-Oxabicyclo[2.1.1]hexanes and Bicyclo[2.1.1]hexanes via Catalytic Asymmetric Intramolecular Photocycloadditions
Differentiating interfacial water structures via alkali metal cation promotor for HO electrosynthesis in acid
Photochemical synthesis of oxiranes using DABSO-activated sulfinates and allylic peroxides
Bioinspired total synthesis of (+)-pleuromutilin
Pillar[]arene-catalyzed anti-Markovnikov halogenations through cationic intermediates stabilization in confined spaces
Disulfide modification and thiol protection via tris(trimethylsilyl)silane-mediated hydrosilylation of disulfides
Iontronic click-to-release enables electrically controlled delivery of drugs and biomolecules beyond charge and size limitations
Metal-dependent and metal-free mechanisms of peptide condensate catalysts
Unlocking the reactivity of difluoroketene and its synthetic applications
Hydrogen transfer-triggered C(sp3)−C(sp3) cleavage of 1,3-diols for mono-N-methylation of primary amines
Photoinduced Mn catalysis for efficient platform for C-heteroatom bond coupling of aryl halides
DNA affects the phenotype of fuel-dependent coacervate droplets
A high-affinity split-HaloTag for live-cell protein labeling
Carbene-catalyzed double esterification enables enantioselective conformational self-locking of pillar[5]arenes
Electrochemical tyrosine-click bioconjugation enables multiplexed cytokine sensing and immunoprofiling in native serum
Formaldehyde hydrazone as a methyl reagent for nickel-catalyzed cross-coupling methylation of aryl and heteroaryl electrophiles
Superacid-resistant macrocyclic BODIPYs
Concise synthesis of bufogargarizin B by a conformation-controlled skeletal reorganization approach
Electrochemically mediated disproportionation for selective formaldehyde upcycling in acid
Unlocking the reducing power of metal nitrides by mechanochemical hydrodefluorination of fluorinated compounds
Large-scale multi-omics profiling reveals environmental and evolutionary drivers of fungal phylogeographic and metabolic diversity
Paired electrolysis enables para-C–H amination of phenols with nitroarenes and mechanistic visualization via multifunctional electrochemical mass spectrometry
A cyanide-free route towards the electrosynthesis of nitriles
Precise Quantum Chemistry calculations with few Slater Determinants
Ynimines as versatile precursors to 2-imido- and 2-amido-1,3-dienes for stereodivergent diels–alder reactions
Chlorine radical-mediated electrochemical propylene epoxidation from seawater
Molecular mechanism underlying regulation of chalcone synthase by chalcone isomerase-like protein
Coenzyme-functionalized photo-redox catalysis for low-energy click labeling
Insights into the activation patterns of 1,2-dithiolane unit in biofunctional molecules
Discovery and engineering of bacterial P450s for C-14 hydroxylation in ent-kaurane diterpenoids
Pathway selection between click and acyl transfer reactions driven by aminoacyl phosphates
Auto-crosslinking sporesilk fibers promote endospore and Cry toxin clustering
Carbonylolysis of waste polyesters into high-value organic acids
Covalent warhead assembly in fostriecin biosynthesis involves malonylation-lactonisation by a bifunctional thioesterase and enzymatic demalonylation
Radiolabeling of oligopeptides by selective hydrogen isotope exchange with deuterium and tritium in aqueous buffers
Integrated electrochemical porous solid electrolyte reactor and packed bed reactor for efficient synthesis of nylon-6 precursor
Stereodivergent synthesis of chiral amines bearing vicinal stereocenters via hydroamination of trisubstituted alkenes
Chemodivergent Coupling of 1,3-Enynes with Anilines to Access Dihydropyrrole Skeleton under Palladium Catalysis
Stereoselective depolymerization of chiral polyesters
Non-chelation control in allylations of α-oxy ketones using group-14 allylatranes
Upcycling of atmospheric CO2 to self-healing recyclable polymers under ambient conditions
Topology-controlled dynamic conjugated oligomers from tetra-arylsubstituted alkene building blocks
Asymmetric synthesis of Heteroatom-bridged [3.2.1]Octane scaffolds via enantioselective β-H elimination reaction
Synthesis of 3-desoxycollinoketone B and its ability to reduce Alzheimer-associated misfolded proteins
Ketone displacement and migration enabled by trifunctionalization of vinyl triflates
Crystallization-driven template autocatalysis induces mirror symmetry breaking and amplification
Copper-catalysed dynamic kinetic (4+1) cyclization of 1,3-enynes for atroposelective arylpyrrole synthesis
Direct synthesis of bicyclo[1.1.1]pentane (BCP) boronates from carboxylic acids
Space ionizing radiation triggers the formation of peptides and organophosphates on olivine surfaces
Organocatalyzed bottom-up formation of protocells
Guest-induced porous gating of a fluorescent nonporous adaptive crystal for efficient radioactive iodine sorption
Photooxidative Copper(II) Catalysis for Promoting anti-Markovnikov Hydration of Alkenes
Ligand-enabled next-generation glycosyl Stille cross-coupling for the stereospecific synthesis of sterically hindered aryl -glycosides
COMPASS subunit Bre2 regulates chromatin remodeler Arp9 to control Aspergillus flavus aflatoxin synthesis and virulence
Dual-role iron species in photoelectrocatalytic radical trifluoromethylation with trifluoroacetates
Tuning aromatic cage occupancy in prenyltransferases enables selective and efficient production of rare -prenylated flavonoids
Electrocatalytic C(sp)-H bond functionalization using biomass-derived electrodes
“” photosensitization enables redox neutral acylation and alkylation of quinones
Expression of nano-engineered RNA organelles in bacteria
Solventless, ambient-pressure production of bio-based lactones over earth-abundant, mixed metal oxide catalysts for circular polyesters
Asymmetric biomimetic transamination of α-keto phosphonates enabled by chiral pyridoxamines and synergistic solvent
A synthetic cell with integrated DNA self-replication and lipid biosynthesis
Mechanistic insights into the non-equilibrium thermodynamics of nitrogen fixation via acoustic cavitation
Late-stage N-Me selective alkenylation and alkynylation of drugs and unactivated tertiary amines using photoredox catalysis
Acid-base pair-mediated copolymerization of acid-sensitive epoxides and cyclic anhydride for synthesizing recyclable thermoplastics
Radical defluoroallylation of polyfluoroalkyl compounds with alkenes via synergistic photoredox/cobalt catalysis
Photochemical thiocarbonyl difluoride generation enables azetidine synthesis
Reactive oxygen species-activated bioorthogonal chemistry in living systems enabled by boronate-caged dihydrotetrazines
Chemoenzymatic synthesis of pentalenolactones via stereoselective Riley oxidation by engineered P450
Photoinduced polarity-mismatched transformations of isoquinolines into naphthalenes
Ultrafast solvent-modulated roaming mechanism in bromoform revealed by femtosecond X-ray solution scattering
Trifunctional flavoenzyme-catalyzed asymmetric 4-alkyl-butenolide assembly in avenolide biosynthesis
Cooperative anion activation at a cobalt center through ion pairing and ligand design
Abyssal hydrothermal alteration drives the evolution from simple alkanes to prebiotic molecular complexity
An isolable phosphaalumene(3) capable of small molecule via
Metallic molybdenum sulfide catalyses protometabolic carbon dioxide reaction networks under extreme conditions
Expanding the DNA damaging potential of artificial metallo-nucleases with click chemistry
Solution-synthesized stable triaza[4]triangulene triradical with a quartet ground state
In vivo dual RNA-Seq uncovers key effectors of epithelial barrier disruption by an extracellular pathogen
Nitroreductase-triggered indazole formation
Electrochemical and photocatalytic generation of cis-olefin-bridged carbodication for umpolung [4+1] cycloaddition
Coacervate droplets as pH-regionalized protocells
Delivery of peptide coacervates to form stable interaction hubs in cells
Recycling of polyolefins using recycled PVC under sunlight
Enhanced methane chlorination via RuO-gas convection electrode with in-situ generated dynamical three-phase boundaries
A neutral cyclic aluminium (I) trimer
Engineered alcohol oxidases catalyse transesterification in aqueous media without competing hydrolysis
Divergent photochemical ring-replacement of isoxazoles
Stereoselective cyano translocation reaction enabled by photoenzymatic catalysis
Photo-initiated solvent-mediated depolymerization of consumer poly(methyl methacrylate) without chlorinated reagents
Photo-induced selective N-N bond construction via harnessing nitrene release and transfer
Copper-catalysed enantioconvergent -alkylation of hydrazines with racemic α-haloamides to access enantioenriched hydrazines
Evolution of manganese low-energy photoredox catalysis from high-energy visible light photocatalysis
Unlocking enzymatic deracemization of structurally diverse allenes by designed photoenzymes
Atroposelective interrupted CuAAC reaction using cyclic diaryliodoniums
Chemically guided single-cell transcriptomics reveals sulfotransferase-mediated scaffold remodeling in securinine biosynthesis
Managing electrolyte flow boosts the efficiency of continuous oxime electrosynthesis to over 95%
Outsourcing of energetically costly amino acids at the origin of animals
Harnessing P-oxirene for the modular synthesis of α-Oxy carbonyls
Resurrected nitrogenases recapitulate canonical N-isotope biosignatures over two billion years
Ligand-controlled regiodivergent and enantioselective C–H cyanation of secondary amines
Nickel-catalyzed divergent sulfonations of propargylic carbonate
Expanding the payload scope in antibody-drug conjugates by delivery of hydroxy-containing drugs through self-immolative phosphoramidates
Glycine photosynthesis via C−N coupling of waste plastic and nitrate over diatomic Pd−B catalyst
Spatiotemporally controlled drug release via a click-release system utilizing mono-alkyl-hydroxylamine and cyclooctyne chemistry
An artificial cell capable of signal transduction mediated by ADRB2 for the regulation of glycogenolysis
Electrochemical desulfurative borylation of thiols, disulfides, thioethers and thioacetals
Construction of remote dual stereocenters by electrochemical cobalt-catalyzed enantioselective desymmetrization
Manganese catalyzed oximation of hydrocarbons to oximes
Efficient synthesis of chiral vicinal diamines with four contiguous stereocenters via sequential dynamic kinetic resolution of 2,3-diamino-1,4-diketones
Photo-driven bifunctional iron-catalyzed one-pot assembling of indoles from arylamines and alkanes/carboxylic acids
Ionic glass formers show an inverted relation between fragility and non-exponential alpha-relaxation
Tetrachloromethane as an editable all-carbon quaternary source
Computational design of dynamic biosensors for emerging synthetic opioids
Impact of GC content on de novo gene birth
Mechanochemical upcycling of poly (vinyl chloride) for alcohol halogenation
Formal anti-Markovnikov hydration of alkenes via paired electrolysis intercepting water-splitting
Autonomous biogenesis of all thirty proteins of the Escherichia coli translation machinery
Coupling nitrate electrochemical reduction and nitrite oxidation of ethanol for acetamide synthesis
Mechanochemical ligand-controlled regiodivergent hydroarylation of alkenes via iron-catalyzed C−H activation
Photochromism of pyridine-substituted merocyanine through reversible C-N bond formation
Photoenzymatic catalysis enables enantioselective radical dearomative spirocyclization
Steric and hydrophilic/hydrophobic effects of organic cations on electrochemical CO reduction
High-throughput triazole-based combinatorial click chemistry for the synthesis and identification of functional metal complexes
Unveiling mechanistic patterns of copper-catalyzed radical bond formation through linear free energy relationship
Late-stage adenine N6-alkylation of nucleos(t)ides and oligonucleotides via photoredox and copper co-catalytic decarboxylative C(sp3)–N coupling
Oxyanions stabilized low-coordinated nickel species for efficient and durable nucleophilic electrooxidation
Enantioselective dearomative single-atom skeletal editing of benzofurans
Enantio-selective vibronic coupling revealed via dissymmetry of upconverted emission in double-resonance excitation of chiral polymer
Isolation and reactivity of sodium benzyl cations
Dramatic expansion of bimodal redox window of indigo by two-electron redox processes
Divergent synthesis of Haplomitrium diterpenoids via a late-stage biomimetic skeletal reorganization approach
Reconstituting transcription–translation-coupled DNA replication within complex in vitro biological systems
Biradical-mediated synergistic electrocatalysis using metal-free redox molecular catalysts
Asymmetric synthesis of stereogenic-at-sulfur compounds via biocatalytic oxidation with Unspecific Peroxygenases
Catalytic asymmetric tandem Heck/Sonogashira reaction enabling access to versatile chiral bridged ring scaffolds
Photoredox-controlled alternating copolymerization enables highly crystalline structures and block copolymers from thermoplastic to elastomer
Copper-catalyzed atroposelective hydroarylation of 1-alkynylindoles
Engineering microbial consortia for mixed plastic upcycling
An efficient method for site-selective boronation of peptides and proteins applied in magnified bacterial imaging
Sustainable purification-free synthesis of N–H ketimines by solid acid catalysi
Numerically exact configuration interaction at quadrillion-determinant scale
Vinyloxy radicals unveiled as critical intermediates in Ni/La2O3-catalyzed ethanol steam reforming for hydrogen production
Concise synthesis of chiral tricyclic γ-lactams via synergistic isothiourea/Ir catalyzed asymmetric [3 + 2] annulation
Iridium catalyzed regiodivergent functionalization of all three C–H bonds of arenes by a single ligand
Direct deoxygenative arylation of saccharides via phosphorus-assisted C−OH bond activation
Iron-catalyzed three-component amino(radio)fluorination of alkenes to unprotected β-(radio)fluoroamines
Advancing aerogel recyclability through polyhexahydrotriazine reactivity
Chiral hypervalent iodine catalyzed stereoselective skeletal editing of pyrimidine fused heterocycles
Isolated Ni atoms enable alkali-free photoreforming of waste polylactic acid plastic
Confirmation-dependent organic phosphor reveals amino acid nanoaggregates in ice with insight for prebiotic chemistry
Straightforward construction of functionalized γ-lactams via conjugated-engineered covalent organic framework photocatalysed cascade reactions
Induced endosymbiosis between a fungus and bacterium reveals a shift from antagonism to commensalism
Installation of d3-methyl group to drugs by continuous-flow solid-phase synthesis
Pyridinium ylides as photocatalytic atom transfer reagents
Dual transition metal electrocatalysis for difluoromethylation of Aryl halides using potassium difluoroacetate
Electronic energy levels and optical spectra of trivalent lanthanide ions in water – Ce(III), Pr(III), Nd(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III), and Yb(III)
Abiotic N reduction in submarine hydrothermal systems could quickly fertilize prebiotic oceans
Catalytic photoinduced deoxygenation via B(C6F5)3-enabled oxygen atom transfer for aromatic C–H amination of alkylarenes
Essential oil-derived decomposable polymers via cycloaddition polymerization of silyl ether-linked phenylpropanoids
Iridium(III)-catalyzed remote B(9)−H alkylation of -carboranes with nitrile template
Asymmetric formal [1 + 2 + 2]-cycloaddition of diazoamides with enamines and carbonyl compounds
Direct asymmetric α C(sp3)‒H alkylation of benzylamines with MBH acetates enabled by bifunctional pyridoxal catalysts
Fe disproportionation within iron-rich alkaline vent analogues reveals proto-bioenergetic systems
A DMAP-enabled strategy for C(sp2)-Si coupling of halosilanes with organic halides
Rapid amide ligation between α-halo acylsilanes and amines under aqueous conditions
A virtual platform for automated hybrid organic-enzymatic synthesis planning
Light-driven radical copper-catalyzed allylic amination via allylic copper intermediates
Enzymatically reconfigurable liquid crystalline coacervate microdroplets as protocell models
Challenging the Bredt’s rule in an acid catalyzed cationic cyclization to get bicyclo[3.3.1]nonane derivatives
Regioselective and site-divergent synthesis of tetrahydropyridines by controlled reductive-oxidative dearomative hydroarylation of pyridinium salts
Organocatalytic iminium-assisted asymmetric B(sp²)-to-B(sp³) transformation
Light bulb-inspired high-temperature catalytic depolymerization of polyolefin plastic with high monomer selectivity
Biocompatible decarboxylative coupling enabled by N-hydroxynaphthalimide esters
Nickel-catalyzed highly diastereo- and enantioselective hydroaminocarbonylation and hydrocarboxylation of cyclopropenes
Homogeneous silver catalyst for propylene electrooxidation to propylene glycol
Surfactant-enhanced Cuδ+ and induced electrostatic forces promote the electrocatalytic deuteron-dechlorination of trichloroacetic acid
Ion pairing enhances hydroquinone stability toward oxygen in aqueous electrochemical carbon dioxide capture
Light-controlled synthetic communication networks via paired connexon nanopores
Photocatalytic generation of amidine carbon radicals for aminodihydroquinoline synthesis
Palladium-catalyzed enantioselective dienylation of propargylic carbonates via sulfonimidamide desymmetrization
Determining molecular structure, coordination geometry, and molecular symmetry using a continuous symmetry operation measure software
Scalable reductive deuteration of (Hetero)Aryl chlorides with D2O
Direct detection of an NH-π hydrogen bond in an intrinsically disordered peptide
Diaryl Bismuthides and Acyl Bismuthanes Enable Visible-Light-Induced Reversible Carbon Monoxide Insertion and Extrusion
Controlling solvation in conducting redox polymers for selective electrochemical separation of nitrate from wastewater
Bench-stable reagents for modular access to persulfuranyl scaffolds
Edge-condensation to access a crystalline planar icosagen cation with σ-aromaticity
A chemoenzymatic reaction-diffusion system with local inhibition and distal activation
Cross-sectional survey of the incidence, mortality and socioeconomic burden of snakebite envenoming in India
Electrochemical deutero-(di)carboxylations for the preparation of deuterium-labeled medicinal building blocks
Iron/phosphine-catalyzed reductive cross-coupling to construct quaternary carbon centers
Rhodium-catalyzed construction of boron-based point and axial chirality via asymmetric annulation of alkynylborons
A catalyst-free bioorthogonal reaction for malononitrile addition to azodicarboxylates
Chiral macrocycles forming high-affinity host-guest homoternary complexes for chiral discrimination and amplified circularly polarized luminescence
Copper integrative catalytic pairs with mixed-valence Cu-Cu Species for selective alkyne conversion
Electro-induced C-H/S-H cross-coupling for the functionalization/macrocyclization of cysteine-containing peptides
Upcycling waste polystyrene to adipic acid through a hybrid chemical and biological process
Catalytic asymmetric synthesis of (N, N)- spiroketal via Pd-catalyzed enantioconvergent aminocarbonylation and dearomative nucleophilic aza-addition
The successful impossible radical ring-opening copolymerization of thionolactones and methacrylates via an auxiliary third comonomer
Dynamic radical recombination enabling stereodivergent construction of spirocycles with nonadjacent stereocenters
Photochemical rearrangement of isonitriles via energy transfer catalysis
Formal pyridine meta-azidation and its application for the synthesis of diazepines, ring-fused δ-carbolines and 1,2,3-triazolylpyridines
Photocatalytic non-oxidative dehydrogenation of ethane to ethene with near unit selectivity
Chemical valorization of waste polyacrylonitrile polymers via shuttle catalysis
Copper-catalyzed enantioselective synthesis of γ-butenolides via radical diversification of allenoic acid
A planar chiral organoselenium enabled enantioselective intramolecular oxidation of trisubstituted olefins
Non-equilibrium demixing and dissolution of chiral coacervates via intrinsic catalysis
Differential stability and dynamics of DNA-based and RNA-based coacervates affect non-enzymatic RNA chemistry
Overcoming limitations in Chan-Lam amination with alkylboronic esters via aminyl radical substitution
Photocatalytic streamlined dual-functional group transfer from cyanopyridine to internal alkynes
Stereoselective diversification of α-amino acids enabled by N-heterocyclic carbene catalysis
Heteroaromatic swapping in aromatic ketones
A scope of prebiotic neat reaction conditions and the mechanism of urea-assisted phosphorylations of alcohols
Accessing acyclic vicinal tetrasubstituted stereocenters via biomimetic Cu/squaramide cooperative catalysed asymmetric Mannich reactions
Dinickel-catalyzed enantioselective reductive addition of imines with vinyl halides
Sustainable recycling of polyamides via C–N bond cleavage facilitated by methyl tosylate under mild conditions
Harnessing platinum(IV) prodrugs as versatile photoinitiators and photocrosslinkers for multifunctional hydrogels and protein labeling
Direct and efficient synthesis of nucleosides through the ortho-(tert-butylethynyl)phenyl thioglycosides (BEPTs) protocol
RNA-peptide interactions tune the ribozyme activity within coacervate microdroplet dispersions
Processive ring-opening metathesis polymerization of low ring strain cycloalkenes via molecularly confined catalyst
HFIP-assisted Brønsted acid-catalyzed ring opening of 1-azabicyclo[1.1.0]butane to access diverse C3-quaternary aza-azetidines and indole-azetidines
Self-driven propylene epoxidation on modified titanium silicalite-1 by in situ generated hydrogen peroxide
Regulation of lattice oxygen reactivity of ZrO2 to promote efficient chemical looping oxidative dehydrogenation of ethane
Fe-electrocatalytic deoxygenative Giese reaction
Enantioselective intramolecular cyclopropanation via a cationic sulfoxonium-Rh-carbene
Metal-free para-selective C-H amination and azidation of N-arylhydroxylamines
Constructing an auto triplet excitons supply system for photogenerated radicals in the solid state
Modular synthesis of PAHs from aryl halides and terminal alkynes via photoinduced palladium catalysis
Bioinspired transfer methylation enabled by a photoactive reagent
Salt-templated transformation of waste plastics into single-atom catalysts for environmental and energy applications
Catalytic aromatic C−H borylation via strained Si and Ge metallacycles
Modular multi-enzyme cascades enable green and sustainable synthesis of non-canonical amino acids from glycerol
Oxy-reductive C-N bond formation via pulsed electrolysis
Gram-scale selective telomerization of isoprene and CO toward 100% renewable materials
Dehydroxy-Perfluoro--butylation of alcohols with PhSOC(CF) and insights into the structure of the [C(CF)] anion
Simultaneous in vitro expression of minimal 21 transfer RNAs by tRNA array method
Post-functionalization of polyethers by photoinduced C–H amidation via polar-radical relay
Redox-innocent scandium(III) as the sole catalyst in visible light photooxidations
Harnessing artificial intelligence to identify Bufalin as a molecular glue degrader of estrogen receptor alpha
Exploring the space of self-reproducing ribozymes using generative models
Internally hollow CuO nanoframes with the abundance of {110} facets enhance direct propylene epoxidation
Gymnosperm-specific CYP90Js enable biflavonoid biosynthesis and microbial production of amentoflavone
Near-infrared photon-triggered CH-to-CHOH conversion over plasmonic oxyselenides
Photoredox catalytic asymmetric dearomative [3 + 2] cycloaddition of isoquinolines with enones
An organometallic approach to the synthesis of heteropolycyclic compounds from benzenes
Photochemical permutation of -substituted phenols
A general esterolysis strategy for upcycling waste polyesters into high-value esters
Catalyst-free Ullmann coupling in aqueous microdroplets
Highly selective synthesis of interlocked carbazole-based cages and their applications in photothermal seawater desalination
Development of a versatile chassis for the efficient production of diverse type II polyketides
Mechanistic analysis and kinetic profiling of Soai’s asymmetric autocatalysis for pyridyl and pyrimidyl substrates
Switchable electrochemical pathways for the selective C(sp)-Ge bond formation
Cyano group translocation to alkenyl C(sp)–H site by radical cation catalysis
Asymmetric synthesis of -amino acid derivatives by stereocontrolled C(sp)-C(sp) cross-electrophile coupling via radical 1,2-nitrogen migration
Electroreductive amination of carboxylic acids by cobalt catalysis
Skeletal editing of pyridines to aryldialdehydes
Skeletal editing of 4-arylpyrimidines into diverse nitrogen heteroaromatics via four-atom synthons
Catalytic synthesis of chiral sulfinimidate esters via oxidative esterification of sulfenamides
Coordinatively unsaturated bismuth sites accelerate in-situ hydrogen peroxide electrochemical formation for efficient butanone oxime synthesis
Biosynthesis and bioactivity of anti-inflammatory triterpenoids in Calendula officinalis
A SaBOX/Co catalyst designed for facile access to the challenging copolymers of vinyl ester and methacrylate
Cationic alkyl chain length and nanoaggregate form of ionic liquids dominate biocompatibility and toxicity
Late-stage -sulfation with a bioinspired sulfuryl donor
Electrochemical coupling of carbon monoxide and amine on iodide coordination stabilized Cu site
Entropy-driven denaturation enables sustainable protein regeneration through rapid gel-solid transition
Enantioselective synthesis of chiral 2,3--disubstituted piperidines and C1-substituted tetrahydroisoquinolines by asymmetric Cu-catalyzed cyclizative aminoboration
Dispersity-controlled ring-opening polymerization of epoxide
Photocatalyst-free photochemical deuteration via H/D exchange with D2O
Precise control of selective nitrogen atom insertion into five-membered cyclic β-ketoesters
Multi-component reactions via copper(I) difluorocarbene as carbonyl source for constructing α—aminoamide derivatives
Cobalt catalyst with exclusive metal-centered chirality for asymmetric photocatalysis
Atroposelective construction of axially chiral alkenylindole-fused nine-membered rings via catalytic asymmetric formal (4 + 5) cycloaddition
Chemical circularization of in vitro transcribed RNA for exploring circular mRNA design
Highly parallel optimisation of chemical reactions through automation and machine intelligence
A substrate-multiplexed platform for profiling enzymatic potential of plant family 1 glycosyltransferases
Phylogenomics and metabolic engineering reveal a conserved gene cluster in Solanaceae plants for withanolide biosynthesis
Thiol-thiol cross-clicking using bromo-ynone reagents
Organocatalytic asymmetric synthesis of Tröger’s bases
A zinc boryl compound unlocks diverse reactivity pathways beyond nucleophilic borylation
Organocatalytic kinetic resolution of sulfinamides by N/O exchange
Amines tuned controllable carbonylation for the synthesis of -lactones and 1,4-diones
Catalytic diazene synthesis from sterically hindered amines for deaminative functionalization
[2,3]-Sigmatropic rearrangement with [1.1.1]propellane
Continuous in situ synthesis of a complete set of tRNAs sustains steady-state translation in a recombinant cell-free system
Electro-oxidative amination of benzylic C(sp³)–C(sp³) bonds in aromatic hydrocarbons
LMCT-driven electron relay unlocks alcohols as tunable reductants for nickel-catalyzed cross-electrophilic couplings
Hydroxyl and nitrate co-upgrading to oxime via anode-cathode cascade electrolyzer
Chemoselective synthesis of 1,3,4-thiadiazoles from acyl hydrazines and nitroalkanes using elemental sulfur
SPA-PNN ligand for the kinetic resolution of carbocyclic and heterocyclic spiranes by asymmetric hydrogenation
symmetric chiral ligand dictating allyl-allyl coupling
Pathway-divergent coupling of alkynes and cyclobutenes through enantioselective cobalt catalysis
Waste polystyrene upcycling via the Birch reduction with ball-mill grinding
Self-organizing glycolytic waves tune cellular metabolic states and fuel cancer progression
Stereodivergent synthesis of benzylic alcohol derivatives enabled by Pd/Cu co-catalyzed asymmetric benzylic substitution reaction
Catalytic asymmetric intermolecular [4 + 2] annulation of benzocyclobutenones with Alkynes and activated carbonyls via C—C activation
Structural basis of transfer RNA processing by bacterial minimal RNase P
Highly efficient catalytic propane dehydrogenation driven by MFI zeolite defect sites
Tailored amination enables switchable synthesis of α- and γ-amino acid derivatives from extended quinone methides
Electrochemical cascade access to hetero[8]circulenes as potent organophotocatalysts for diverse C–X bond formations
Syngas from waste plastics and water using Joule heating
Organometallic-type reactivity of stable organoboronates for selective (hetero)arene C−H/C-halogen borylation and beyond
-alkylated polydithiocarbamates derived from thiocarbonyl fluoride as macro-photoiniferters for living 3D printing
Photoenzymatic enantioselective synthesis of fluorinated amides with remote stereocenter
Enantioselective aza-electrophilic dearomatization of naphthalene derivatives
Enzymatic twists evolved stereo-divergent alkaloids in the Solanaceae family
Chemoselective dual functionalization of proteins via 1,6-addition of thiols to trifunctional -alkylpyridinium
Controlling selectivity in the chemical looping oxidative dehydrogenation of propane through interface engineering
Substrate-based discovery of α-hydroxycarboxylic acid derivatives as potential herbicides targeting dihydroxyacid dehydratase
Amino acids catalyse RNA formation under ambient alkaline conditions
Consecutive mechanical-force-induced electron transfer for reduction of aryl halides with high reduction potentials
Copper-catalyzed C(sp3)−H amination and etherification of unactivated hydrocarbons via photoelectrochemical pathway
Photochemical synthesis of natural lipids in artificial and living cells
Photochemical C3-amination of pyridines via Zincke imine intermediates
Birch reductive arylation by mechanochemical anionic activation of polycyclic aromatic compounds
Direct synthesis of N-trifluoromethyl amides via photocatalytic trifluoromethylamidation
Expanded ribosomal synthesis of non-standard cyclic backbones in vitro
Copper-catalyzed enantioselective three-component radical 1,4-perfluoroalkylamination of 1,3-dienes
Expedient access to bora-butenolide bioisosteres by counteranion-mediated trans-hydroboration of alkynes
Cu(I)-catalysed chemo-, regio-, and stereoselective radical 1,2-carboalkynylation with two different terminal alkynes
Nucleophilic aromatic substitutions enable diversity-oriented synthesis of heterocyclic atropisomers via non-atropisomeric intermediates
inCu-click: DNA-enhanced ligand enables live-cell, intracellular click chemistry reaction with copper catalyst
Real-space observation of the dissociation of a transition metal complex and its concurrent energy redistribution
Selection of self-assembled configurational isomers from a dynamic library via a multivariant optimization process
Modular access to alkylfluorides via radical decarboxylative-desulfonylative gem-difunctionalization
Iron-catalyzed aliphatic C–H functionalization to construct carbon–carbon bonds
Switchable organocatalytic enantioselective sulfenocyclization of cyclohexadienes enabling chemodivergent access to chiral bicyclo[m.n.1] ring systems
Asymmetric total synthesis of benzenoid cephalotane-type diterpenoids through a cascade C(sp2) & C(sp3)–H activation
Suppressing COx in oxidative dehydrogenation of propane with dual-atom catalysts
Copper-catalyzed photoinduced carbonylation of C1-C3 gaseous alkanes
Electrochemical synthesis of allenyl silanes and allenyl boronic esters
Boosted high-throughput D⁺ transfer from D₂O to unsaturated bonds via Pdδ+ cathode for solvent-free deuteration
Copper difluorocarbene-involved catalytic gem-difluoropropargylation
Selective radical-type perfluoro-tert-butylation of unsaturated compounds with a stable and scalable reagent
Desymmetric esterification catalysed by bifunctional chiral -heterocyclic carbenes provides access to inherently chiral calix[4]arenes
Designer artificial environments for membrane protein synthesis
Iron-catalyzed sequential hydrosilylation
Diverse redox-mediated transformations to realize the para-quinoid, σ-bond, and ortho-diphenoquinoid forms
Facile visible-light upcycling of diverse waste plastics using a single organocatalyst with minimal loadings
Subnanometric MoO clusters limit overoxidation during photocatalytic CH conversion to oxygenates over TiO
Site- and enantioselective B−H functionalization of carboranes
Floatable organic-inorganic hybrid-TiO2 unlocks superoxide radicals for plastic photoreforming in neutral solution
Ligand-controlled divergent asymmetric C(sp3)−H and C(sp3)−O insertion via vinyl cations
1
Electrogenic protein condensates as intracellular electrochemical reactors
4
Programmable artificial RNA condensates in mammalian cells
Supramolecular chemical recycling of dynamic polymers
An information ratchet improves selectivity in molecular recognition under non-equilibrium conditions
Polymeric stabilization at the gas–liquid interface for durable solar hydrogen production from plastic waste
2
Active assembly and non-reciprocal dynamics of elastic membranes
Membraneless protocell confined by a heat flow
1
Evolutionary analysis reveals the origin of sodium coupling in glutamate transporters
7
A programmable microbial assembly line for plastic upcycling
Catalytic bromine recycling from waste
Safe-and-sustainable-by-design approach to polyesters from non-oestrogenic bisphenols
Catalytic cascade depolymerization for sustainable recycling of waste polyvinyl chloride
Efficient glycerol electro-oxidation at an industrial-level current density
Photocatalytic upcycling of polysulfones at ambient conditions
Upcycling surplus acetone into long-chain chemicals using a tandem electro-biosystem
1895
Photochemical C4-Selective C–H Amination of Quinolines via N-Shift of Heteroaryl Azides
Dual Photoredox/Nickel-Catalyzed Atroposelective C–N Coupling with Carbazoles and Indoles as N-Nucleophiles
Cascade Reaction of α, β-Unsaturated Keto-carboxylic Acid for the Formation of 5-Substituted Isoxazole using NaN3/I2/TBHP
Stereospecific N-Glycosylation Strategy for β-N-Glycoside Synthesis via Base Catalysis
Copper-Catalyzed Decarboxylative Alkynylation of Arylacetic Acids via an Electrophotochemical Approach
Asymmetric Reductive Cross-Coupling of Aldimines
Diazo-Preserving Radical Cascades for the Modular Photoinduced Synthesis of Oxindoles and Pyrazolones
Stereoselective Synthesis of (E)-Allylic Sulfones by Photocatalytic Desilyloxylative Sulfonylation of Allyl Silyl Ethers with Thiosulfonates
Copper-Catalyzed Petasis-Type Reaction Enables Efficient Synthesis of C1-Substituted Tetrahydro-β-carbolines
DFT-Guided Photocatalytic C5-Selective Hydrodechlorination of 4,5-Dichloropyridazinones
tBuONO as the Co-catalyst in Palladium-Catalyzed Aerobic α,β-Dehydrogenation of Ketones
Unified Gold(I/III)-Catalyzed Arylative, Vinylative, and Alkynylative Lactonization via Iminium-Directed Cyclization Enabled by Hemilabile Ligands
Modular Synthesis, Properties, and Fluoride Response of Azaborine-Based Bidentate Boron Complexes Featuring Tri- and Tetracoordinate Centers
Photoredox-Catalyzed N-Centered Radical-Mediated Cascade Annulation/Dearomatization of ortho-Sulfonamide-Tethered Alkylidenecyclopropanes
Electron Donor–Acceptor Complex-Enabled Remote 1,n-Difunctionalization of Alkenes via Distal C(sp3)–H Activation
Silyl-Triflate-Catalyzed Divergent Annulation of Isoquinolines with Ynamides: Direct Access to 2-Aminonaphthalenes and 2-Amino-1-naphthonitriles
Photocatalytic Functionalization of Perfluoroalkyl Alkenyl Iodides via Vinyl Radicals: Synthesis of Perfluoroalkylated Naphthalenes
Photocatalytic Oxidative Generation and Synthetic Application of Phosphine–Boryl Radicals
Pd-Catalyzed β‑H Elimination of Alkenyl Thianthrenium Salts for the Synthesis of Disubstituted Allenes
Multicomponent Reactions in Open-Air Metal-Free Aqueous Visible-Light Catalysis: Radical–Polar Crossover toward γ-Lactams and γ-Aminobutyric Acids
Visible-Light-Induced Copper-Catalyzed Coupling Reaction of Aryl Halides with Phenols at Room Temperature
Rh(II)-Catalyzed Access to [4.3.1]Propellanes via a Formal Dicarbene Cascade Annulation
Photocatalytic Regioselective Four-Component 1,4-Aryl Migration of N-Allylbenzamides To Access β-Arylethylamines
Asymmetric Synthesis of Spirocyclic Sultams via Nickel-Catalyzed Arylative Cyclization
Cu-Catalyzed Z-Selective Carboboration of Acetylene with Hindered Michael Acceptors Enabled by a Buffering Borinate Additive
Benzo[1,2-b:3,4-b′:5,6-b″]trithieno[3,2-b:6,5-b′:9,8-b″]trithiophene: A Thiophene-Rich 3-Fold Symmetric Building Block for π-Extended Materials
Total Synthesis of Eucalyptusdimers A–C
Visible-Light-Driven [3 + 2] Annulation of N-Substituted Aromatic Amines with Nitriles: An Approach to Benzimidazoles
Pd-Catalyzed Tandem Synthesis of Polysubstituted Pyridines Using β-Enamino Esters and β-Ketodinitriles
Vosamidines A–C, Polycyclic 2-Aminoimidazole Alkaloids from a Marine Calcareous Sponge Vosmaeropsis wilsoni
Hypervalent Iodine(III)-Mediated Oxidative C–H Amination of Phenols and Anilines with Azoles
En Route to N-α-Silylated Thioureas via Iridium-Catalyzed C(sp3)–H Silylation
Electrochemical Decarboxylative Coupling for C(sp3)–N Bond Formation of Triazoles and Carboxylic Acids
Visible-Light-Driven Self-Sensitized Photocatalysis: TBAI-Assisted Dioxygenation of 3-Salicyloylindoles
2,3-Diaryl Indanone Construction via the Neophyl Rearrangement
Visible-Light-Driven Manganese-Catalyzed Bromination Reactions with Dibromomethane
Light-Driven EDA–APEX Approach: A One-Pot Access to Phenanthrenes and Naphthalenes
Progressive Chemoselective Reductive Deuteration and Deuterodefluorination of Fluoroalkyl Ketones Using D2O
A General Sonogashira-Type Strategy for Exopolyhedral B–C(sp) Bond Formation on o- and m-Carboranes
Higher-Order [10 + 2] Annulation Strategy for the Synthesis of CF3-Functionalized Benzopentalenes
A Multicomponent Approach for the Synthesis of Indeno-Pyrrolido-Pyrimidino-Azoles: Access to Structurally Diverse Pseudo-Natural Products
Pd(II)-Catalyzed Site-Selective [2 + 2 + 1] Spiroannulation of 2-Pyridone with Alkyne
Red-Light Photoredox C–H Alkylation of Acceptor Heterocycles Enabled by Substoichiometric NADH
Fe-LMCT Photodecarboxylation for (Hetero)arene Chloro- and Bromodifluoromethylation: Rapid Access to Aromatic Acyl Fluorides
Nickel-Photocatalytic Deoxygenative Arylation toward β-Methyl-Branched α-Amino Acids
Easy Access to N,N-Disubstituted 2-Imidazolidinones from Weinreb-Type Amides and Enamides via Visible-Light-Mediated Radical Smiles Rearrangement
Enantioselective Synthesis of an Indenopyrrole Scaffold Containing an All-Carbon Quaternary Stereocenter via a Visible-Light-Mediated Organocatalytic Carbene Transfer Reaction
Boronic Acid-Assisted Site-Selective Benzylation of Unprotected Saccharides
Supertrityl Radical and Cation: The Effect of a Large π-Surface for Intermolecular Interactions and Spin/Charge Delocalization
Povarov-type Reaction of Anilines, Aqueous Acetaldehyde, and tBuONO for Access to N-Nitroso-1,2,3,4-tetrahydroquinolines
Hydromagnesiation of 1-Arylallenes with Magnesium Hydride toward Cinnamylmagnesium Reagents
Total Synthesis of Annonaceae Acetogenins Calamistrin A and Uvarigrin
ortho-Selective C–H Alkenylation of Pyridines Enabled by a Heterometallic Mg–Ni–Mg Complex
Asymmetric α-C–H Allylic Alkylation of α-Amino Acid Esters by Synergistic Carbonyl/Iridium Catalysis
SmI2-Mediated 4-Exo-Trig Cyclization of Trifluoromethyl Alkenyl Aldehydes
Norbornadiene Serves as a Tolyl Group Precursor for Constructing Biphenyl Derivatives by Palladium Catalysis
Energy-Transfer-Mediated Radical-Relay Brook Rearrangement of Electron-Deficient Ketones
Photoactivation of Electron Donor–Acceptor Complexes via Quinolinium Salts and 4-Carboxamide-1,4-dihydropyridines: Synthesis of N-Heteroaryl-2-carboxamides
Chemoselective C-Terminal Activation Platform for Direct Conversion of Native Linear Peptides into Thiazoline/Thiazole Macrocycles
Electrochemical Methylarene Oxidation via Electrolyte Anion Control: Access to 18O-Labeled Aromatic Aldehydes
N-Heterocyclic Carbene-Catalyzed Aza-Benzoin–Michael Addition–Lactamization Cascade Incorporating a Formal [4 + 1] Annulation to Access Tricyclic Indeno[2,1-b]pyrrole Derivatives
Catalytic Aerobic Carboheterocyclization of Functionalized Alkenes Using Secondary Nitroalkanes
Pd/WingPhos-Catalyzed Synthesis of γ-Amino Alcohol Derivatives with β-Axial Stereogenicity via Desymmetrization of Allenylic Cyclic Carbonates
<atl>Sodium iS/i -(difluoromethyl) Sulfurothioate: A Readily Available (Deuterio)difluoromethylthiolating Reagent with SCF sub2/sub H sup+/sup , SCF sub2/sub H sup–/sup , and SCF sub2/sub H sup•/sup Reactivity</atl>
Hyperconjugation-Driven Ester Migration Enabled Aerobic 1,3-Iodohydroxylation with Iodoform: A Triple Functionalization of Allyl Carboxylates
Ir-Catalyzed Asymmetric Synthesis of 3-Allylic Spirotetramic Acid Derivatives with Insecticidal Activities
B(C6F5)3-Catalyzed Chemical Tagging of Bioactive N-Alkylamines through β-Amino C(sp3)–H Functionalization
Asymmetric Organocatalytic (4 + 4) Annulation between 5-Alkenyl Thiazolones and α,β-Ynones: Access to Thiazole-Fused Eight-Membered Cyclic Ethers
A General Platform for Aryl/Alkyl Radical Functionalization Enabled by Photoinduced Electron Donor–Acceptor Complex
Visible-Light-Driven Synthesis of Ketonyl Cysteine Compounds by Cysteine Decysteinylation with Enol Silyl Ethers Coupling
Highly Enantioselective Synthesis of Chiral Hydrocarbazole-4-Carbaldehyde Scaffolds and Constrained Analogue of MS-245 via Iminium Catalysis at Elevated Temperatures
Rh(II)-Catalyzed 1,3-Dichalcogenation of Vinyl Carbenes via [1,4]-Migratory Rearrangement of Sulfur/Selenium Ylides
Synthesis of Multisubstituted Diazatricyclic Molecules Via Intramolecular Cycloaddition of Cyclic Azomethine Ylides
Coumarin-Rewired Benzothiophenes: Skeletal Editing for Peripheral Heterofunctionalization
Formal Regioselective C–H Sulfinylation of Alkenes with Sulfinyl Sulfones
Development and Mechanistic Studies of Oxidative Prins-Semipinacol Cyclization Reactions
Assembly of N-Heterocyclic Carbenes and Nitroalkenes for Access to Isoxazole Derivatives
Old Reagent for a Trick in the Stereoselective Hydromethylation of Alkynes Enabled by Cu(I) Photosensitizer Catalysis
Cobalt-Catalyzed Hydrogen-Bond-Promoted Tandem Cyclization and Oxygen Migration: Access to Sterically Congested Fused Tetrahydro-β-Carbolines
Multicomponent Synthesis of β-Boryl Ketones Triggered by Ketene-Induced Metallate Rearrangement of Alkenylboronic Esters
Bioinspired Alkyl Transfer Enabled by Ca(II)/HFIP Cooperative Catalysis: Modular Synthesis of Functionalized Isoindolinones
A 6/5/6/5-Fused Indeno[7,1-bc]furan Diterpenoid Skeleton from Pinus yunnanensis Resins with Anti-Neuroinflammatory and Antidepressant Activities
Visible-Light-Induced Annulative Ring Expansion of Amino- Oxetane/Azetidin/Thietane Derivatives
Nickel/Photoredox-Catalyzed Allylic Alkylation via C(sp3)–C(sp3) Cross-Coupling of Allyl Boronic Esters and Alkyl Halides
Copper-Catalyzed Asymmetric Synthesis of Heteroaryl Sulfoxide
Electrochemical N-Centered Radical Cyclization of Aryl Propargyl Alcohols toward Quinolines
Enantioselective Palladium-Catalyzed Desymmetric Allenylic Substitution of Allenylic Cyclic Carbonates: Access to Axially Chiral Trisubstituted α-Allenols
Palladium-Catalyzed Polydeuteration of (Hetero)arenes in Heavy Water Using Indazole–Pyridone Ligands
Metallo Protic N-Allyl Enammonium Ylide 3-Aza-Cope Rearrangement Enabled by Resonance-Assisted H-Bonding: Direct Access to Functionalized Pyrroles
Photochemical Iron-Catalyzed Decarboxylative S-Glycosylation
Highly Regio- and Enantioselective Catalytic 1,6-Conjugate Addition of Grignard Reagents to Cyclic Dienones
Regiodivergent Metalation of Pyridines Using Mixed Ti-TMP and Ti–Fe-TMP Amides at Room Temperature
Total Synthesis of Indigotinoline A and Enabled Stereochemical Revision of Isatindigotindoline B
Switchable C or C–N Insertion into N-Alkyl Enamines for Divergent Synthesis of 3-Aminopyrroles or CF3/CN-1,2-Dihydropyrazines
Sequential Groebke–Blackburn–Bienaymé and Pictet–Spengler Reactions for Regioselective Synthesis of Polyheterocyclics
Lewis Acid-Mediated Defluorination of Trifluoromethylarenes To Access Trivalent Phosphines
Iron-Catalyzed Divergent Borylation of α-Aryl-Substituted Allylic Alcohols
Aminophthalimide as a Protected Nitrogen Source for N-Insertion to Indenones
Photocatalytic anti-Markovnikov Chloroalkynylation of Unactivated Alkenes
Highly Enantioselective Oxidation Reactions Using a Tetradentate Mn(II) Catalyst Based on (S,S)-1,2-Diaminocyclohexane
Cascade Azide–Alkyne Cycloaddition/Azetidine Ring-Opening Reactions for Accessing Aminomethyl-Functionalized 1,2,3-Triazole-Fused Bicyclic Heterocycles
Enantioselective Rh/Cu-Catalyzed Addition of Terminal Alkynes to Allenes for the Synthesis of Chiral 1,4-Enynes
Photochemical Alkylation of Heterocycles Enabled by Oxalic Dianion as Traceless Electron Donor
An Exclusive Synthesis of Macrocyclic Trimer over Polymers
Phosphine-Catalyzed Intramolecular 7-endo-trig Annulations for Synthesis of Cycloheptadienes
Regiodivergent Pd-Catalyzed Annulation of Coumarins: Directing-Group-Controlled Coumarin-Fused N-Heterocycles
Synthesis of Axially Chiral Styrenes via Pd-Catalyzed Atroposelective C–H Olefination
Intramolecular Alder-Ene Reaction of 2-Methyl-4-(alkynyloxy)cyclohexa-2,5-dienones: Catalyst-Free Access to Hydrobenzofuran Derivatives
A Cu(NTf2)2-Catalyzed Tandem Mannich-Cyclization Process of N-Boc-1,2,3,4-tetrahydroisoquinolin-1-ols with α-Aryl α-Diazo Ketones for the Construction of Substituted α-2-Furanyl Tetrahydro-1-isoquinolinemethanols
“Addition–Elimination” Transformations for Aminative Isomerization of Bicyclo[1.1.0]butanes (BCBs)
Spirocyclization-Enabled Remote Phosphorothiolation of Nonactivated Arenes via Dual Photoredox/Copper-Catalyzed Dearomatization
Total Synthesis of Isoriccardin C and Isoriccardin D Based on a Hydroxyl-Directed Palladium-Catalyzed Intramolecular C–H Alkenylation
Electrochemically Enabled Synthesis of Carboxylated Allenes via Carbon Dioxide Reduction
Marundihomalkins A–J and Marundisphingalkin A: Triglyceride-Lowering Marine Fungal Alkaloids Featuring Non-amide C–N Linkages between Polyketide and Homoisoleucine or Phytosphingosine
Copper-Catalyzed Divergent Rearrangement Reactions of Propargyl Ethers
Controlled Nitration of Solvent Green 5 as a Platform for Functional Perylene Derivatives
Dynamic Kinetic Resolution Enabled Synthesis of Planar and Central Chiral Ferrocenes
Photocatalytic Semireduction of Propiolamides in Microheterogeneous Solutions via Alkyne Radical Anions
Catalytic Asymmetric Construction of Chiral Indoloazepine-Based Spirooxindoles via Formal [6+1] Cycloadditions
Radical Haloazidation of 1,5-Enenitriles for Making N-Haloimines and Sequential Triazolation to Form Tricyclics
n-BuLi-Catalyzed Amidation Reactions of Aldehydes with 1° Amines
Visible Light-Induced Synthesis of Esterified Quinolines and Pyrrolidones Controlled by Different Electrical Anilines
Pd-Catalyzed meta-C–H Arylation Using a Convertible Directing Group: Streamlined Construction of Biaryl Cores of Peptide Natural Products
Deaminative Fluorination of Sulfonamides via Aminocyclopropenium Activation
Collective Biomimetic Synthesis of Benzoxazole Xanchryones A, B, and I–N Based on Biogenetic Building Blocks
Acetoxy-Peroxyacetals: A Peroxycarbenium Precursor for the Synthesis of Hydroperoxides and Endoperoxides
Total Syntheses of the Cyclobutane-Containing Guaiane-Type Sesquiterpene Daphnepapytone A and Certain Congeners
TiCl3-Mediated Reductive Aminohydroxylation of Alkenes to (Benzo)Furo[3,2-b]Indolines
14-, 30-, and 56-Membered Azamacrocyclic Mannich Bases Built on Bispyrrolylphenylene Platforms: Isolation and Initial Anion Binding
Copper-Catalyzed Decarboxylative Cascade Annulation of Propargylic Cyclic Carbamates with Allenediones
Enantioselective Alkylation of Fused Bicyclic Pyridines Enabled by Chiral Lithium Amides as Traceless Auxiliaries
Electroreductive Cross-Coupling of Cyclopropyl Ketones and Aryl Methyl Ketones to Access 1,2,4-Triarylbenzenes via Acid-Promoted Aromatization
SuFEx-Functionalized Pyrroles via Regioselective 1,3-Dipolar Cycloaddition of Münchnones
Cu-Catalyzed [1,3]-Fluorine Rearrangement Reactions of N-Fluoroanilines
Traceless Silicon-Tether Strategy for the Synthesis of a Tetraphenylammonium Salt
Electrochemical Synthesis of Benzotriazoles and Benzotriazinones
Photoinduced Selective Hydrodefluorination of Trifluoromethylarenes Enabled by Base-Activated Hantzsch Esters
Photoexcited Nitroarenes: A Workhorse for Strategic Synthesis of N-Heterocycles via Reductive C–N Coupling/Cyclization Cascade
Ring-Enlargement of in Situ Generated Cyclopropanones with Carbonyls and Imines: Synthesis of γ-Butyrolactones and -lactams
Synthesis of Dibenzosiloles via Pyridine/Zn System-Enabled Cross-Couplings of Diiodidobiaryls with Dihalosilanes
B2pin2-Mediated Cascade Cyclization of 2-Alkenylanilines To Give 2-Difluoromethylthio/seleno-4-Aryl(alkyl)-Quinolines
Syntheses of Bridged Fenestranes via Stepwise Intramolecular Diels–Alder Reaction and Nitrone Cycloaddition and Their Structural Analyses
DNA-Compatible Strecker Reaction for the Synthesis of α-Aminonitriles
Synthesis and Photophysical Properties of Azaarene-Substituted Hypocrellin B Derivatives
Two-Step Strategy to Design Organo-Fluorophore: Engaging Palladium Catalysis for Carbo-Oxygenative Cyclization of Chloroprene Derivatives
Chiral Betaine-Catalyzed Biomimetic Transamination of α-Keto Esters
Photocatalysis Enables Cross-Electrophile Coupling of Unactivated Ketones with Isothiocyanates
Iodine-Catalyzed Oxidative [3+2] Annulation/Dehydrogenation Cascade: Synthesis of Unexpected Mesoionic [1,2,4]Triazolo[5,1-a]isoquinoliniums
Deep Molecular Bowls with Four Pentagons
Selective Electrochemical Synthesis of the para,para C–C Dimer from Diphenylphenol and Its Conversion into Dibenzofuran
Catalytic Enantioselective Formal (3 + 3) Cycloaddition of 3-Halooxindoles with Pyridinium 1,4-Zwitterionic Thiolates
Photocatalyzed Radical Cross-Coupling of Allylic Esters with N-Aryl Glycinates and Benzyl Amines for sp3 C–C Bond Formation
Photoinduced Deacylative Phosphorylation of Unstrained Ketones
Construction of N–N Atropisomers Bearing Multiple Stereocenters via Desymmetrization of Indole-Derived Maleimides
Synthesis of Reagent FCH2CF2SO2Na: A Source of the FCH2CF2• Radical and Useful for Introduction of the −SCF2CH2F Functionality into Organic Compounds
Collective Total Synthesis of Ergot Alkaloids
Palladium-Catalyzed Photoredox Aminocarbonylative [3 + 2 + 1] Heteroannulation of Propargyl Acetates with α-Aminoazoles and CO
NHC-Catalyzed Desymmetrizative Amidation for C–O Axially Chiral Imides
Pd-Catalyzed Regio- and Atroposelective Hydroalkynylation of Allene to Access Axially Chiral Conjugated 1,3-Enynes
Exploiting Hexafluoroisopropanol-Mediated Stereospecific Thiourea-Catalyzed C-Glycosylation of Indoles Enables Access to 2-Deoxy β-C-Indolyl Glycosides
Ligand-Enabled Regioselective Cross-Coupling of Palladacycles with Aryl Halides via C–H Activation
Synergistic Amino/Amide-Directed C5–H Annulation toward Polycyclic Coumarin Heterocycles
Pd-Catalyzed Annulation of Aryl Iodides with Ynamides for the Synthesis of 9-Aminophenanthrenes: Regioselectivity in Reductive Elimination of Pallada(IV)cycle
Organophotoredox-Catalyzed Vinyl Group Transfer Reaction: An Introduction to 4-Vinyl-1,4-dihydropyridines
Sulfonium Salt-Mediated Regio- and Stereoselective Aminosulfonylation of Alkynes with Sulfinates and Azoles
Gold-Catalyzed Regioselective Remote B(9)–H Activation of o-Carboranes with Silylenynones: Access to B(9)-α-Furylsilyl-o-carboranes
Fast Bioorthogonal Ligation of 2-Aminobenzohydrazides and (2-Acetylphenyl)boronic Acids Providing Stable and Fluorescent Conjugates
Nickel-Catalyzed Aminocarbonylation of Aryl Trifluoromethoxides
Visible-Light Induced Dehydrogenative Cross-Coupling of Enamides with Hydrocarbons Enabled by Aryl Thianthrenium Salt
Methyl Formate Meets Water: Phosphine-Free Mn(I) Catalysis for Chemoselective Olefin amp; Carbonyl Hydrogenation
Alcohol Dehydrogenase-Mediated Generation of Cytotoxic Thiophene-Containing Eremophilane Sesquiterpenes
Access to α-Alkynyl-α-fluoroacetamides via Deacylative Alkynylation of α-Fluoro-β-ketoamides with Alkynyliodonium Salts
Total Synthesis of Fexuprazan
Synthesis-Supported Discovery of Prefusahexin, a Direct Fusahexin Biosynthetic Precursor
Organophotocatalytic Synthesis of Polycyclic Sultones and Sultams with FSO2Cl through Fluorosulfonyl Radical Cation Synthon Strategy
Visible-Light-Induced Carbonylative Synthesis of Aliphatic Thioesters
Access to Regiodefined Tetrahydrofuran-3-one-Derived C-2 Silyl Enol Ethers from α-Triisopropylsilyl-α-diazoketones: The TIPS Trick
Blue Vitriol Catalyzed Decarboxylative C–C Cross-Coupling of α,β-Unsaturated Acids for C–H Functionalization of Unactivated Ethers
Ru(II)-Catalyzed Annulative Linear Dienylation with Allenyl Carbinol Acetates
Rhodium-Catalyzed Atroposelective Synthesis of Conformationally Stable C(sp2)–C(sp3) Atropisomers via C–H Activation and Annulation with 9-Fluorenylacetylene
Construction of Functionalized 2,3-Dihydropyrroles via Visible-Light-Driven Formal [3 + 2] Cycloaddition
Synthesis and Applications of the Se–N Clickable and Orthogonal Linker Based on Bicyclo[1.1.1]pentane
Cyclicurilarenes: Hybridizing Bambusurils with Macrocyclic Arenes
Enantioselective Catalytic Oxidation of Olefins and Organosulfur Compounds by Chiral Mn(II) Diamino-Dicarboxylato or Disulfonato Complexes via a Pentacoordinate Mn(V)-Oxo Cation
Structural Distortion and Arene π-Coordination Dual-Assisted Palladium-Catalyzed Annulation Reaction of Aromatic Carboxylic Acids with 2,2′-Diiodobiphenyls
Photoinduced Multicomponent Difluoromethylation of Imines via Iron-Mediated Ligand-to-Metal Charge Transfer
Stereoselective Z,Z,Z-Trienylation of N-tert-Butanesulfinyl Imidates Enabled by Nucleophilic Ring Cleavage of Tropone Oxime Tosylates
Atroposelective Synthesis of C–N Axially Chiral Biaryls via Catalytic C–H Functionalization at a Remote Site
Tetracyclic β-Acid Meroterpenoids as Potent Anti-neuroinflammatory Agents via NLRP3 Inflammasome
3-Substituted Lawsones from Indanone Chalcones: Application of the House–Meinwald Rearrangement (HMR) for Chemoselective Ring Expansion
Jatropodagines A and B: Lathyrane Diterpenoid Dimers from Jatropha podagrica, Inducing Paraptosis-Like Cell Death
Cobalt-Catalyzed [2+2+2] Cycloadditions of Alkynyl Yndiamides with Nitriles
Remote Stereocontrol in Aryl/Alkyl C–H Insertion Reactions of Rhodium Carbenes: Assembly of Pseudorigidols A and B
Sc(OTf)3-Catalyzed Diastereoselective [3 + 3] Cycloaddition of Chiral Bicyclo[1.1.0]butanyl Imides and Nitrones
Net Oxidative Photocatalytic Strategy toward the o-Trifluoroacetylation of N-Heteroarenes
Bifunctional 2-Aminopyridine-Catalyzed Aza-Friedel–Crafts/Oxa-6π Cascade: Synthesis of 2,2-Disubstituted Chromenes
Asymmetric Construction of 1,4-Diketone Derivatives Containing a Less Accessible Acyclic Quaternary Carbon Stereocenter via Michael Addition/Rearrangement Cascade
Phosphine-Catalyzed Visible-Light-Induced Aminodifluoroalkylation of Alkenes: Access to α,α-Difluoro-γ-lactams
Total Syntheses of Roseochelins A and B Using an Oxidative Decarboxylation Strategy
ipso-Halogenation of Arylsilanes Using a Carborane Sulfide Catalyst
Photocatalytic [4 + 1] Annulation of Vinyl Aziridines with Alkyl Halides
P(NMe2)3-Mediated Umpolung (3 + 2) Annulation of β,γ-Unsaturated α-Keto Carbonyls with p-Quinone Methides: Synthesis of Spirocyclopentenyl p-Dienones
[70]Fullerene-Fused Lactones: Regioselective Synthesis and Electrochemical Derivatization
Photocatalytic Difluoromethylation Cyclization and Dioxygen Trapping: Access to gem-Difluoro-Quinolines
Tandem 1,3-Dipolar Cycloaddition/Rearrangement of Nitronates with Cyclooctyne for the Diastereoselective Synthesis of Spiroaziridine Derivatives
Rh(II)-Catalyzed Enantioselective B–H Insertion of Cyclic Alkyl-Donor Carbene Generated from Diynes
Isoquinolinium Photooxidant for Arene C–H Amination
Iodanyl Radical Catalysis Enables a Decarboxylative Giese Reaction with Alkyl Carboxylic Acids
Visible-Light-Enabled Sulfonyl Radical-Triggered Cyclization Strategy for the Efficient Synthesis of Benzosultams
Copper-Catalyzed Deaminative Amination of Primary Amines Enabled by a Deaminating Reagent
Visible-Light Photoredox Catalysis: Enabling [2π+2σ] Dearomative Cycloaddition of Unactivated Indoles with Bicyclo[1,1,0]butyl Tethers
Palladium-Catalyzed Annulation of Acyl Saccharins with Norbornene via CO Shuttling
Photoinduced Fluoroalkylalkynylation of Unactivated Alkenes with Terminal Alkynes
Blue Light-Promoted O–H Insertions of Silanols and Functionalization of Silicon Nanomaterials
Photoexcited Copper-Catalyzed Atom Transfer Radical Addition (ATRA) Reaction of Unsaturated C–C Bonds with 1-Iodo-o-carboranes
Photochemical Boronate Rearrangement Enables the One-Pot Synthesis of 2,4-Difunctionalized 2H-Chromenes
Modular Synthesis of Tetrasubstituted Thioallenoates via the Tandem Wolff Rearrangement/C–S Bond Insertion Reaction of Alkynyl Diazoketones and N,S-Acetals
Artemverlotolides A and B, Two Sesquiterpenes from Artemisia verlotorum Lamotte: Structural Elucidation, Bioinspired Synthesis, and Antineuroinflammatory Activity
Chemoselective [2+1] Cycloaddition of Difluorocarbene with Conjugated Enynes: Synthesis of Alkenyl Difluorocyclopropenes
Construction of α-Acyl-β-amino Amides via Multicomponent Reactions of β-Acyloxy Alkenyl Amides with Amines and Aldehydes
Difluoro(methoxy)methyl Is a Neglected Group for Medicinal Chemistry─Revival via CF2OMe-Containing Amines
Visible Light-Induced Aerobic Ring-Opening Oxidation of Unstrained Aryl Cycloalkanes
Oxidation-Induced Scaffold Remodeling in Ainsliaea Disesquiterpenoids: Total Synthesis of Macrocephadiolide A
SmI2/Sm-Mediated Desulfurative Fluoroarylation of Thioamides with Polyfluoroarenes via C═S/C─H Bond Cleavage
Improved Total Synthesis of Cannabioxepane, a Minor Phytocannabinoid from Cannabis sativa L
Synthesis of 6-epi-Hypersampsone R by a Desymmetrization Strategy
Nickel Nanoparticles Catalyzed Cross-Coupling of Diazo Compounds with O-Benzoyl Hydroxylamines
Electrochemical Synthesis of γ-Lactams from Amides and Alkenyl Trifluoroborates by [3 + 2] Annulation
Synthesis of Unsymmetrical C2,3-Bis-sulfenylated Indoles via Bimetallic Cu/Fe Relay Catalysis
Metal-Free Photoredox-Catalyzed Anti-Markovnikov Phosphinothiolation of Styrenes: Chemodivergent Access to S-Alkyl-phosphinothioates and β-Keto-phosphinothioates
Visible-Light-Driven (E)-β-Trifluoromethylation of Enamides via In Situ Generated Sulfur(VI) Photosensitizers
Palladium-Catalyzed Tandem Synthesis of Fused Spiroquinolinones from Bicyclobutyl Amides
Cinchona-Functionalized Crown-Ether-Pinioned Calix[4]arene for a Scalable Asymmetric Organocatalytic Aza-Michael Addition Reaction
Photocatalytic Transfer of Trifluoromethylcarbenes for X–H Insertion, Oxetane Skeleton Editing, and Alkene Cyclopropanation
Exploring γ-Nitroketones as 1,4-Dicarbonyl Precursors for Annulation to Pyridazines through Interrupted Nef Reaction
Sustainable Synthesis of N-Substituted Pyrroles via Fe-Catalyzed One-Pot Multicomponent Reaction
Visible Light-Promoted Cascade Cyclization/Allylation of 2-Allyloxyaryl Sulfonium Salts with Morita-Baylis-Hillman Acetates
A Catalyst-Free, Tyrosine-Selective Bioconjugation Strategy via Triazine-Pyridine Chemistry for Antibodies
Ru(II)-Catalyzed peri-C–H Activation with Strained Alkylidene β-Lactones and β-Lactams: Selective Access to Seven- and Four-Membered Heterocycles
Bioinspired Total Synthesis of Mulberrofurans G and J, Inethermulberrofuran C, and Mongolicin C from a Common Intermediate
Et3SiOBpin as a Dual Reagent Enabled Photocatalytic Stereoselective Assembly of Multisubstituted Perfluoroalkyl-boryl Styrenes
Paired Electrolysis-Promoted Ni-Catalyzed Decarboxylative Cross-Couplings of Potassium Malonate Monoesters with Aryl Bromides
Visible-Light-Induced Bi2O3 Catalysis toward 2-fold gem-Difluoroalkylation of Quinoxalinones
Synthesis of Tetrakis(amino)ethylene-Derived Organic Reductants via Thermal Decomposition of Tris(amino)methanes
Difunctionalization of Aldehydes via Electrophilic Acylation: Access to α-Acyloxyphosphonium Salts and Subsequent Diversely Substituted Enol Esters
N-Heterocyclic Carbene-Catalyzed Enantioselective Synthesis of Inherently Chiral Pillar[5]arenes
Access to Substituted Pyrimidines via Isoxazole Ring Transformation in Three-Component Reactions with Amines and Orthoesters
Electrochemical Chemo- and Regioselective Reduction of Vicinal Diketones to α-Hydroxy Ketones
Humupulusones A and B, Two Skeletally Novel Acylphloroglucinol Derivatives from Humulus lupulus
Photoinduced TBADT-Catalyzed Alkylation of Alkyl (E)-3-(2-Methacrylamidoaryl)acrylates to Access 3,4-Dihydroquinolin-2-(1H)-ones
Fully Substituted Cyclobutenes via [2 + 2] Cycloaddition of Ynimines with Cinnamamides
Cu-Catalyzed Reductive Coupling of Allylic and Carbonyl Electrophiles
Photochemical Synthesis of 1,2-Diazepine-Fused β-Lactams via Staudinger-Type [2 + 2] Cyclization
para-Selective C–H Arylation and Alkylation of N-Arylhydroxylamines
Site-Selective Decarboxylative C–H Carbenoid Functionalization Enabled by Pyridotriazole-3-carboxylates
A Pd-Catalyzed (6+2) Cycloaddition/Ring-Contraction Relay for Chemodivergent Access to Chiral Spirooxindoles
Access to Se/S-Containing Heterocycles via Hexafluoroisopropanol-Mediated Tandem Wolff Rearrangement/Cyclization
Copper-Catalyzed Amino-alkoxycarbonylation of Unactivated Alkenes: Synthesis of β-Amino Esters via Primary Tosyl Amidyl Radical
Photocatalytic Perfluoroalkenylation of Ketones and Its Application in the Synthesis of Fluorinated Heterocycles
Photoredox/Copper Dual-Catalyzed Four-Component Regioselective 1,2-Arylsulfonylation of Vinylarenes
Studies on Metastable Heterocycles: 2-Formyl-3-methylene-1-pyrroline
CuCl-Promoted β-Acylation of Cyclopropanols with Thioesters
Rhodium-Catalyzed [3+3] Annulation of N-Sulfonyl-1,2,3-triazole with a Homoallylic Alcohol for the Synthesis of 1,2-Dihydropyridine
Diastereoselective Synthesis of Double Axially Chiral Indole Derivatives via Friedel–Crafts Biarylation
Synthesis of C2-(N-Alkylcarbamoyl)-Substituted Pyrroles via Post-Condensation of Dipole Ugi Adducts
Total Synthesis of Acorane-Type Sesquiterpenes (±)-Bilaiaeacorenol B and (±)-Penicibilaenes A and B
Sulfonium Salt-Mediated Deoxyfluorination of Alcohols
Hexafluoroisopropanol-Mediated Hydroaminoalkylation–Aza-Prins for Construction of α-Amino-butenolide
Electrochemical C–H Phosphonylation of Indole with Phosphine Enabled by Chemoselective C–P Bond Cleavage
Direct Access to Luminescent meta-Substituted Tris(2,4,6-trichlorophenyl)methyl Radicals through Nucleophilic Substitution
Discovery of Coracanols A and B, Two Biological Nitrification Inhibition Diterpenoids from Finger Millet
N,N′-Di-Boc-N″-fluorosulfonyl-guanidine: A SuFEx-Enabled Guanylating Reagent (SuFEx-G) with Enhanced Reactivity on Water
Asymmetric Saddle-Shaped Nanographenes Integrating Helicene and Heptagon Motifs: Synthesis and Chiroptical Properties
Selective Synthesis of 5-Nitroindoles through a Ag-Catalyzed Nitro Rearrangement/Cyclization Cascade of N-(o-Alkynylphenyl)nitramines
Direct Phosphatation via Arylthianthrenium Salts
Synthesis of Spiro[indoline-3,3′-pyridine]-2,2′-diones via an Annulo- and Diastereospecific [2 + 4] Annulation
Organocatalytic Asymmetric α-C–H Allylation of N-Arylidene-Protected Alkyl Amines
Modular Synthesis of (Z)-Allylsilanes via Copper-Catalyzed Cascade Silylation and Horner–Wadsworth–Emmons Reaction
Triplet Energy Transfer-Mediated Intermolecular Paternò–Büchi Reaction for the Synthesis of Trifluoromethylated Oxetanes
Generation of Polysubstituted Tetrahydrofurans via Urea-Enabled, Pd-Catalyzed Olefin Heteroannulation
Photoinduced Dearomative Oxyimination of Indoles Using Oxime Esters as Bifunctional Radical Precursors
Biotransformation of Allium Sulfur Metabolites by Proteus mirabilis Yields Cepathiosoxide, a Trithiabicyclic Sulfoxide
Synthesis of N-(4-Vinylidenetetrahydrofuran-2-yl)amides and Applications in Skeletal Rearrangement to 2,3-Dihydro-1H-pyrrol-2-ols/Substituted Pyrroles and Bridged Bicyclic Scaffold Construction
Computation-Enhanced Structure Elucidation of Cyclopropane-Containing Polyketides Ikeiamides A–M
Base-Promoted Denitrogenative Coupling of Nonactive 1,2,3-Triazoles with Ketones: Stereospecific Access to (Z)-β-Enaminones
SCF3-Alkenes Unlocked: A Gateway via Cu(I)-Catalyzed Stereocontrolled Cross-Coupling
Total Synthesis of (+)-Raistrickindole A
Substituent-Promoted Thio-Belluš–Claisen Rearrangement with Difluoroketene
Expanding Isothiazole Chemical Space: Synthesis and Derivatization of [c]-Fused Saturated Rings
Zinc-Mediated Four-Component Carbonylation toward Direct Synthesis of α-Amino Ketones
Temperature-Controlled Switchable Cascade Reactions of Alkyne-Tethered Ketoximes and Cyanobenziodoxolone for Divergent Synthesis Cyano-Featured Isoxazolines and 3H-Pyrrol-3-ones
Chirality in Abundance: A Reagent-Controlled Access to Multiple Stereoisomers of Functionalized Bishomocubanes
Highly Regioselective Functionalization of Triborane (L·B3H7) through Copper-Catalyzed B–H Bond Insertion Reaction of Tosylhydrazone Compounds
Dearomatization of Aromatic Carbonyl Compounds by Photocycloaddition Reactions to 1,1-Dimethylallene
Electrochemistry Enables O-Arylation of Tyrosine with Aminoisoxazoles: Late-Stage Diversification of Peptides and Pharmaceuticals
Chemodivergent Accesses to Hetero-Bicyclo[3.3.1]nonenes
Access to Imidazolidin-2-ones via Azocarboxamide-Enabled Enantioselective 1,2-Diamination of Aldehyde
Pd(II)-Catalyzed Hydroxyl-acyloxylation of gem-Dimethyl Groups via Dual C(sp3)–H Activation
Rauhut–Currier Reaction-Inspired Intramolecular Cyclization Approach Using DBU to Access Biaryl-Fused Cycloheptatriene Derivatives
An Unexpected Isomerization for the Total Synthesis of Daphnepapytone A
Palladium-Catalyzed Cascade Reaction of Indoles with α,α-Difluoro-β,γ-Unsaturated Ketones: One-Step Access to 2-Fluorocarbazoles
Synthesis of Sterically Congested Z-Selective Secondary β-Enaminal
Catalytic Asymmetric Kinetic Resolution of 2,2-Disubstituted Styrenyl Aziridines via Ring Opening with Amines
Desymmetrization and Atroposelective Cobalt Catalyzed C–H Annulation of Phosphinic Amides with Ynamides
Direct Synthesis of Triarylethynylphosphines from White Phosphorus and Arylacetylidene Lithiums
Palladium(0)-Catalyzed Nucleophilic Cyclization of Conjugated Enyne-Carbonyls Leading to Cyclic Allenic Alcohols
Chiral Pyridoxamines Featuring Proton-Donating Auxiliary Side Chains for Asymmetric Biomimetic Transamination
Synthesis of (S)-Finerenone via Late-Stage Asymmetric Transfer Hydrogenation
Bioinspired Synthesis of Curtachalasin A and Δ6,12-Curtachalasin N Enabled by Tandem Transannular Epoxyalkene Cyclization and α-Ketol Rearrangement
Imidazolidine-Pyrroloimidazolone Pyridine-Cu(OTf)2 Complex Catalyzed Asymmetric Radical Carbo-Esterification
Total Synthesis of (+)-Malbrancheamide B Employing a Bioinspired Strategy
The Electrochemical Functionalization of N–H Bond on N-Heterocycles with Isocyanides to Synthesize Azole Urea Compounds and Methanimines
Electrochemically Driven Decarboxylative Primary Alkylarylation of Alkenes with Aliphatic Carboxylic Acids
Photoinduced Smiles Rearrangement of N-Sulfonylpropargylamines for Highly Stereoselective Access to Tetrasubstituted Allylamines
Copper-Catalyzed Amination of Polyfluoroarenes via Decarbonylative Metallaphotoredox
N-Heteroaromatic Fused BODIPY Dimers: Ring-Size Effects from Five- to Six-Membered Rings
Deconstructive Alkylation of Unstrained Cyclic Amines via Lewis Base–Boryl Radical-Enabled Spin-Center Shift
Synthesis of γ-Carbonyl Aliphatic Sulfoxonium Salts via Site-Selective Ring Opening of In Situ Formed 2-Sulfoxonium Cyclobutanone
Electrochemical Radical Addition-Initiated Ring-Opening/Functionalization of 2-Alkylidenecyclobutanols toward γ,δ-Unsaturated Ketone Synthesis
Photoredox-Catalyzed Modular Synthesis of ε-Lactams via Acrylamides Cyclization Enabled by Radical-Polar Crossover-Mediated Carbanion Trapping
Copper(II)-Catalyzed Radical-Type Selenium(II)–Nitrogen Exchange Chemistry between Benzoselenazolones and Hydrazines
Hypervalent Iodine Diazo Esters as C1 Synthons in [3+2+1] Cascade Cyclization: Access to Fully Substituted Pyridines
Palladium-Catalyzed Intramolecular meta-C–H Arylation Assisted by Nitrile Templates Under Microwave-Accelerated Conditions Accessing Fluorene Frameworks
Iron-Catalyzed Radical-Mediated 1,3-Azidoalkylation of Bicyclo[1.1.0]butanes: Access to 1,1,3,3-Tetrasubstituted Cyclobutanes via Strain Release
Construction of C–S and C–Se Bonds via Deaminative Coupling of Primary Amines
Chemodivergent Multicomponent Reactions of Morita–Baylis–Hillman-Type Yne-allylic Esters with 1,3-Dicarbonyls or Aroylacetonitriles
Nickel-Catalyzed Deallylation for Sustainable Solution and Solid-Phase Peptide Synthesis
Photochemical Synthesis of DNA-Encoded 3H-Azepines via Skeletal Editing of Nitroarenes
Enriching Alkene syn-Dihalogenation: Aryl Alkene, Bromine, Regio-Reversion, and Stereoconvergency
Cyclover-Assisted Liquid-Phase Peptide Synthesis Using T3P® as a Green Coupling Reagent
Photocatalytic 1,2,3-Trifunctionalization of β,γ-Unsaturated Ketones via 1,2-Carbonyl Migration to Access Functionalized Indanones
Palladium-Catalyzed Enantioselective Tandem Allylation/Cyclization of ortho-Alkynylbenzaldehydes with Allyltrimethylsilane: Access to Chiral 1-Allyl-1H-isochromenes
Diastereoselective Cyclopropanation with Secondary Diazoacetamides to Access endo-Azabicyclo[3.1.0]hexane-6-carboxamides
Biosynthesis of the l-Pyridylalanine Moiety in Antimycobacterial Pyridomycin via a PKS-NRPS Hybrid System
Synthesis of α-Trifluoromethylated Amines via Fluoroalkylation and Defluoroamination of Indoles
Visible-Light-Driven Modular Synthesis of Isoquinolinone Derivatives via Palladium-Catalyzed Radical 6-endo Annulation of Aryl Halides
Synthesis of α,β-Unsaturated Ketones from Aldehydes and Ketones Using 1,1-Di(boryl)alk-1-enes
CO2-Driven C(sp2)–H Lactamization to 2-Quinolinones
Photocatalytic SN2′-Type Mono-, Di-, and Trifluoromethylation of gem-Dichlorocyclobutenones
Visible-Light-Induced Radical Cascade [4 + 2]/[4 + 2] Cycloaddition of Underexplored N-Acryloyl Indoles To Access Dihydropyrido[1,2-a]-indolones
Synthesizing C8-Chiral Substituted 5,6,7,8-Tetrahydroquinolines via Palladium-Catalyzed Enantioselective Arylation of Unactivated C(sp3)–H Bonds
Tetrabenz[a,c,h,j]anthracene-Bridged Carbaporphyrin Dimer
DNA-Compatible Synthesis of β-Ketoamides as Intermediates for On-DNA Chemical Diversification
Direct β-C(sp3)–H Functionalization to Carbonyls: A Route to Aldehydic Acid Derivatives
Light-Induced Copper-Catalyzed Arylamination of 1,3-Butadiene
Cobalt-Catalyzed Intramolecular Dearomative Alkylation of Phenols with Alkenes
Iron-Catalyzed Stereospecific Heterocycle N-Glycosylation with Glycal Epoxides
Synthesis of Polycyclic Indolines via Spiroindolenines: Mechanistic Validation and HDAC6 Inhibition Potential
Access to Hindered Homopropargylic Tertiary Alcohols via Nucleophilic Addition of Chiral Copper Species Forming an All-Carbon Quaternary Center
Selective Deprotonated Amide Activation of Dehydroalanine for Peptide Modification
Vinylsilanes as Ethylene Surrogates: Rh(I)-Catalyzed Direct Hydroarylation of In Situ Generated Ethylene
Photoinduced P–Se Bond Cleavage of Diselenophosphinic Esters: En Route to Selenoethers and Phosphine Selenides
HFIP-Promoted Strain-Release-Driven Functionalization of Azabicyclo[1.1.0]butanes with Heterocyclobutane Trichloroacetimidates
Copper-Catalyzed Synthesis of Medium-Sized Cyclic Aminals via Annulation of Ketenimines and N-Acyliminium Ions
Studies toward the Total Synthesis of Griseoviridin
Visible-Light-Induced Carbamoylation for Synthesis of Dibenzo[b,f][1,4]oxazepine Carbonyl Amino Acid/Peptide Derivatives
Enantioselective Synthesis of Chiral 2,2-Difluoro-spiro[indene- [1,3,4]oxadiazines] by NHC-Catalyzed [4 + 2] Cyclization Reactions
Light-Induced PdH-Catalyzed Cross-Dimerization of gem-Difluoroalkenes with Alkenes to Access CF2H Motifs
Asymmetric Inverse-Electron-Demand Diels–Alder Reaction of 2-Pyrones with Acyclic Indolyl Alkenes for the Synthesis of Chiral N-Alkylindoles
Diastereoselective Cyclopropanation of Terminal, Nonconjugated Alkenes with 2-Oxoethylpyridinium Salts via Nucleopalladation
Tertiary C(sp3)–Si Bond Formation via Reactivity Umpolung of Silyl Reagents
Photocatalytic Selective Synthesis of Hemiketals from Alkenes, α-Halo Acylarenes, and Water via N-Methylindole Catalysis
Synthesis of Chiral (hydro)Indoloquinazolinones via Enantioselective Copper-Catalyzed Borylative Cyclization
Pd(II)-Catalyzed [3 + 1 + 1 + 1] Cascade Annulation of N-Substituted Anilines with CO and Amines: Direct Access to N1,N3-Disubstituted Quinazoline-2,4(1H,3H)-diones
Total Synthesis of the Oligostilbenes Anigopreissin A and Fuliginosin A
Electrochemical Synthesis of 1,2-Substituted N-Amido Benzimidazoles by Reduction of Nitroarenes
Synthesis and Biological Evaluation of N–CF3 Diaryl Amines
Enantioselective Synthesis of Triarylmethanes via Palladium-Catalyzed Desymmetric Carbonylation of Cyclic Diaryliodonium Salts
Electroreductive Cross-Electrophile Coupling of Aldimine with Chlorosilanes Enabling the Synthesis of α-Aminosilanes
Construction of Cyclopenta[b]pyridine Frameworks via Pd(0) π-Lewis Base-Initiated Cascade Reaction of Enyne-Tethered Malononitriles
Electrochemical Dearomative Reduction of Indole Derivatives Mediated by Ph3P(O)
Enantioselective Access to Cyclopentanone-Fused Dihydrothiophenes
Visible-Light Photoredox Synthesis of Chroman-4-ones from Sulfoxonium Ylides
Regioselective 1,2-Hydrogen Atom Transfer of N-Centered Radicals for C(sp3)–C(sp3) Coupling to Generate 1,2-Diamine Derivatives
Photocatalyzed Site-Selective Formal β-C(sp3)–H Sulfonylation of Ketones with Sulfinates
Photoinduced Lactamization/Truce–Smiles Rearrangement Cascade Enables Access to Lactam-Fused β-Arylethylamines
Pd-Catalyzed Three-Component Coupling of Aryl Bromides, Alkynes, and Anthranils To Access ortho Carbonyl N-Aryl Indoles
Biomimetic Skeleton Conversion from Tiglianes into Three Euphorbia Diterpenoid Skeletons via Regioselective Cyclopropane Ring-Opening
R3P/ICH2CH2I-Promoted Skeletal Editing of Cyclic Ethers via O/N Exchange
Modular Access to Boron Tripyrrolic Complexes from a Sequential Buchwald–Hartwig Amination/Boron Complexation Reaction
Samarium Diiodide-Mediated Radical Borylation of Alkyl Bromides with Pinacol Borane
Dearomative Indole Annulation with 2-Aminoaryldisulfide – an Approach for Accessing Polycyclic Indoline-Fused-Benzothiazine
Electrochemical Activation of α-Carbonyl Alkoxyamines for Direct Nucleophilic Substitution
Synthesis of Stilbene Derivatives via Phosphine-Catalyzed Cascade [2+4] Annulation/Decarboxylative Aromatization of Yne-Enones with α-Pyrones
Electrochemical Activation of Bicyclo[1.1.0]butanes
Visible-Light-Induced Radical [4 + 1] Annulation of Diazosulfonium Triflates with Cyclopropenes: Direct Synthesis of Benzofulvenes
Photoredox-Enabled Radical Ring-Opening Fluorosulfonamidation/Fluorosulfonylmethylation of Methylenecyclobutanols
C–H Arylation of Imidazo[1,2-a]pyridines and Zolimidines Catalyzed by Synergistic Tripalladium Clusters
One-Pot Access to Dibenzodiazepines and 9-Arylacridines from a Cyclic Dienamine
Pyridine Synthesis via [3 + 2 + 1] Oxidative Cyclization of Enamines, Ethyl Tertiary Amines, and Alcohols: Copper-Catalyzed Cascade Multicomponent Poly C(sp3)–H Functionalization
Yb(OTf)3-Catalyzed [2π + 2σ] Cycloaddition of Bicyclo[1.1.0]butanes with Methylenimines for Modular Synthesis of 1,2,4-Trisubstituted 2-Aza-bicyclo[2.1.1]hexanes
Organocatalyzed Asymmetric Intermolecular Annulation of Nucleophilic Imines with High-Temperature-Dependent Enantioselectivity
Carbon Atom Deletion Strategy Enabled Synthesis of 22-epi-6-Deoxocastasterone Using the Intact Skeleton of Tigogenin
Decarboxylative and Deoxygenative/Decarbonylative Alkylation of Heterocycles with α-Keto Acids
Electrochemical Direct C–H Fluorination of Hydrazones
Room-Temperature Decarboxylative Amination of Electron-Deficient (Hetero)Aromatic Carboxylic Acids
Copper-Catalyzed Intramolecular Carbocyclization/1,2-Migration Reaction of Allenols To Access Substituted 2-Sulfonyl Carbazoles
Construction of PROTAC Library via Liquid-Phase Synthesis Enabled by a Hydrophobic Tag
Synthesis of Tetralin and Chromane Motifs via Pd-Catalyzed Dual C(sp3)–H/C(sp2)–H Bond Activation
Access to Chiral Sulfoxides by Enantioselective Imine Condensation
Cu-Catalyzed Atroposelective Protoboration of Allenes to Access Stereodefined Tetrasubstituted Axially Chiral Alkenylboronates
Catalytic Asymmetric Synthesis of α-Alkenyl Quaternary Amino Acid Esters
A General Iron-Photocatalyzed Decarboxylative Arylalkylation of Carboxylic Acids with Activated Alkenes
Photoinduced 1,2-Chlorothiolation of Unactivated Alkenes via Proton Transfer and Electron Transfer
Nazarov Cyclization of Geminal-Benzoyl-Phenyl Allenes in Triflic Acid: A Synthetic Route to Pallidol-like Structures
Merging Photoredox with Nitro Reduction for the Direct Synthesis of Unsymmetrical Ureas
Palladium-Catalyzed Enantioselective [3 + 2] Cycloaddition of Vinylarylcyclopropanes (VACPs) with Photogenerated Ketenes to Tetrahydrofurans
Dithiane-Alkyne Metathesis Enables Trp(C2)-Alkene-Cross-Linked Cyclic Peptides
Bi-Catalyzed [3 + 2] Cycloaddition of C2-Spirocyclopropyl-indolin-3-ones with Carbonyls: Access to Spiro[furan-3,2′-indolin]-3′-ones
Visible-Light-Induced Lactone-Fused Indoline Construction via Radical Dearomatization of Indoles with Alcohols
Friedel–Crafts-Type Electrophilic Radiocyanation of (Hetero)arenes
N-Annulated [5]Helicenes: Syntheses, (Anti)Aromaticity and Properties
A General Electrochemical C(sp3)–H Amination of Hydrocarbons Suitable for Inactive Alkanes, Alkenes and Alkynes
Photochemical Zincke-like Reactions Enabled the Expeditious Synthesis of 2-Polyene Sulfonylpyridines
Biomimetic Iron-Catalyzed Oxidation of 3-Substituted Indoles to 2-Oxindoles
Synthesis of Stereodefined Cyclopropylamine Derivatives from Cyclopropanols and Sulfinamides
Electron-Shuttle Catalysis by Diaryl Diselenides for Photochemical Anti-Markovnikov Hydroalkoxylation of Alkenes
Photocatalytic Synthesis of α-Fluoro-β-sulfonyl Carbonyl Compounds Using Nucleophilic Fluorine Sources
Dual Photoredox/CpTi(IV)-Catalyzed Reductive Cyclization of Tertiary Bromide with Nitrile for Constructing 4a,9a-Heterocycle-Fused Tetrahydrocarbazole
Regio- and Stereoselective Synthesis of Polysubstituted γ-Lactams Enabled by Photocatalyzed Sequential Radical Aminoalkylation of MBH Acetates
Direct Photoexcitation Enables Nickel-Catalyzed C(sp3)–C(sp3) Coupling of α-Bromonitriles with Alkylzirconocenes
Cu(I)-Catalyzed Radical Coupling of Alkenes with Sulfonimidoyl Chlorides: Synthesis of Vinyl Sulfoximines
[4 + 2] Annulation of CF3-π-Allyl–Pd Species with Isatic Acids for Direct Access to 3-Trifluoroethyl-4-carboxylate Quinolines
Tandem Nitration-Cyclization-Rearrangement of Indole-Tethered 1,6-Enynes To Access NO2-Featured Heterocycles
Enantioselective Total Synthesis of (+)-Subincanadine F via Organo-SOMO Catalysis
Synthesis of Enantioenriched Difluoromethylated Allenes via Copper-Catalyzed Stereospecific Difluoromethylation
Direct Benzylic Phosphination of Toluenes Enabled by a Heterobimetallic LiN(SiMe3)2/Cs2SO4 System
Asymmetric Synthesis of 2,2-Disubstituted Dihydroquinolines via Rhodium-Catalyzed Dearomative Arylation and Alkenylation of 2-Substituted Quinolinium Salts
Homogeneous Reductant Facilitated Cross-Electrophile Coupling of Aryl Bromides with NHP Esters
Hyperacmoses A–C, Three Seco-Norpolyprenylated Acylphloroglucinols from Hypericum acmosepalum with Lipid-Lowering Activity
Enantioselective Synthesis of Medium-Sized Rings via a General Palladium-Catalyzed (6 + n) Annulation Platform
Ligand- and Temperature-Controlled Stereodivergent Nickel-Catalyzed Hydrophenoxylation of Ynamides
HMPA-Enabled Direct γ′-Arylation of Cyclic Vinylogous Esters
Synthesis of the Threoglucin 1,3-Oxazinane Core via Cyclothreonine Rearrangement
Pd-Catalyzed Aqueous Buchwald–Hartwig Amination with Amphiphilic Polymer PEG–PVEG
Halide-Mediated Electrochemical Peptide Synthesis Applicable to Highly Sterically Hindered Amino Acids
Organocatalytic Visible-Light-Driven Metallomimetic Charge Transfer Process: Application in C(sp3)–N Bond Formation
Photoinduced Radical Coupling for Si–N Bond Formation
Iron-Catalyzed Photoredox Decarboxylative Hydroalkylation with Alkynes and Alkenes
Light Illuminates Polarity-Mismatched Cycloaddition to Convert Isoquinoliniums into Phenylnaphthyl Sulfones
Yellow-Light-Mediated Synthesis of Amidoximes via Radical gem-Diamination of Diazo Compounds
Merging Borylation and Desaturation to Access Arylboronates from Carbonyls
Brønsted Base-Catalyzed Aminoxylation of Benzylic and Allylic Compounds with TEMPO
Copper-Catalyzed Intermolecular Aminotrifluoromethylation of Alkenes with Free Anilines
Regioselective Thiolation and Selenylation of Cyclic Diaryl λ3-Bromanes Enabled by Visible-Light Photocatalysis
Chlorjaponoids A and B, Two Lindenane–Guaiane Sesquiterpenoid Dimers with a Cage-like Tetracyclo[8.5.0.02,7.03,13]pentadecane Scaffold from Chloranthus japonicus
Regioselective C2-Sulfonylation of Indoles and Pyrroles via SO2 Insertions
Cu-Catalyzed One-Pot Synthesis of Trifluoromethylated β-Lactams by Reaction of Nitrosoarenes, Trifluorodiazoethane and Arylacetylenes
Copper-Catalyzed Dearomative Cyclopropanation of Benzofurans with Diynes via Vinyl Cations
Hydrocarbon-Involved Sulfoxide Deoxygenation via Bifunctional Iron-Enabled Electron Buffering and Ligand-to-Metal Charge Transfer
(Vinyl tosyloxy)benziodolium Salts: Divergent Construction of Conjugated Diene Derivatives via Sequential Coupling Reactions
A Polarity-Mismatched Photocatalytic Cross-Coupling Enables Diversity-Oriented Synthesis of aza-Heterocycles
H-Bond- and Strain-Release-Guided Photoreaction of Alkenes, p-Quinone Methides, and Ammonium Thiocyanate
Stereoselective Synthesis of the Western Fragment of Vancoresmycin
Total Synthesis of Chrysosporazines B and C
Divergent Total Synthesis of Tacaman Alkaloids: A Skeleton Reorganization Strategy
Strain-Release Asymmetric Multicomponent Reaction to Access Diverse N-α-Bisaryl-C3-quaternary Azetidines
Organophotoredox-Catalyzed Alkylation of Vinylsulfur Pentafluoride: Expanding Access to SF5-Containing Aliphatic Molecules
Enantioselective Total Synthesis of Citrifelin A via the Oxa-Pictet–Spengler Reaction and Acid-Promoted Dihydropyran Formation
DDQ-Mediated Oxidative [5+2] Cycloaddition Reactions of Isochroman-4-ones with Alkynes
A Three-Layer Transformation Strategy toward Functionalized Fused Hydantoins and Diketopiperazines
Uranyl-Enabled Photocatalytic C(sp3)–H Functionalization with Azoles
Tetrazole Synthesis via Cyclopropenium Phase-Transfer Catalysis: A Click Strategy
Direct Synthesis of Fluorinated Polycyclic Aromatic Dioxanes: Mesomorphism, Luminescence, and Charge Transport
Palladium-Catalyzed Regiodivergent [4 + 2] Cycloaddition of Benzosilacyclobutenes with Phenylpropiolonitriles
Chiral Carboxylic Acid Assisted Ir(III)-Catalyzed Asymmetric C–H Activation/Desymmetrization of Sulfoximines
Divergent Reactivity of Diketopyrrolopyrroles: Ring-Opening with Amines
Selective Synthesis of anti-Bisbenzo[b]thieno[2,3-b:2′,3′-e][1,4]dithiin via Copper-Catalyzed Domino Formation of Eight C–S Bonds
Photocatalytic Copper-Promoted Heptafluoroisopropylation of Arylsulfonium Salts with AgCF(CF3)2
Polycyclic Limonoids as Potential Nrf2 Inducers from Trichilia connaroides
Discovery of Diverse Esterified seco-Polycyclic Polyprenylated Acylphloroglucinols from Two Species of Hypericum Linn. and Their Lipid-Lowering Effect
Phosphine-Catalyzed Regio- and Stereoselective Umpolung Addition of Amides to Alkynoates: Access to Complex α,β-Dehydroamino Acid Derivatives
Asymmetric Cycloaddition of 1,6-Diynes with Alkenes Enabled by Ligand-to-Metal Chirality Transfer in Cobalt/Photoredox Cooperative Catalysis
Photoinduced Amination of Inert C(sp3)–H Bonds with Diazirines for Access to Diaziridines
Metabolic Competition between Non-reducing Polyketide Synthases Drives Hidden Chemodiversity in Deep-Sea Fungus Talaromyces radicus
Strain-Release-Driven exo-Cyclization of Bicyclo[1.1.0]butyl Ketones Promoted by Brønsted Acids to Access 2,3-Diazabicyclo[3.1.1]heptenes
Ring-Strain-Driven Annulation of Cyclopropenones with Hydrazones via Nucleophilic Phosphine Catalysis
Synthesis of Unsymmetrical 4,4′-Bipyridines through Base-Mediated Cross-Coupling between 4-Pyridyl Phosphonium Salts
Thermal Dearomative Rearrangement of α-(Prop-2-enyl)-α′-(pyridin-2-yl) Malonate Derivatives toward 4H-Dihydroquinolizines
Experimental Support for a Chiral Pentacoordinate, Axially Symmetric Cationic Mn(V)-Oxo Complex as the Key Reactant in the Highly Enantioselective Catalytic Epoxidation of Olefins
Diastereodivergent and Enantioselective Organocatalytic Synthesis of Spiro-Fused Coumarins via [4+2] Cycloadditions
Copper/Photoredox Dual Catalysis for the Redox-Neutral C(sp3)–CF2H Cross-Coupling between Benzylic Bromides and Tetracoordinated Difluoromethylborates
Synthesis of 1,3-Bis-trifluoromethylated (Hetero)cyclohexane-2-carboxylates from Alkylidenemalononitriles
Reverse Regioselectivity of Aminopalladation: Palladium-Catalyzed Oxidative Tandem Cyclization for the Construction of Aza-oxabicyclo[4.2.1]nonane
Chiral Phosphoric Acid-Catalyzed Asymmetric [4 + 2] Cycloadditions of Photogenerated o-Quinodimethanes with Vinylazaarenes
Seeking Equality from an Asymmetric System: The Convergent Total Synthesis of Prostacyclin Drug (±)-Beraprost Sodium
Solution-Phase and Mechanochemical Brønsted-Acid-Catalyzed N-Alkylation of NH-Heterocycles via Hydroamination of Vinyl Ethers
Palladium-Catalyzed Enantioselective Dearomatization of Furan To Access N,O-Spirocycles
N-Alkylsulfonamide Nucleophilicity: Experimental and Computational Assessment of Nitrogen Nucleophilicity of (S)-2-(Iodomethyl)-1-tosylpyrrolidine
Catalytic Asymmetric Synthesis of 1,2-Fused Tricyclic Indoles Containing an Eight-Membered Biaryl Bridge
Asymmetric Iodoaminocyclization for the Synthesis of Chiral 2-Heteroaryl Pyrrolidines
Direct Synthesis of Tricyclo[3.2.1.02,7]octenes via Palladium-Catalyzed Sequential Reactions of 2-Pyranones with 1,3-Dienes
Enantioselective α,α-Chlorofluorination of Sulfoxonium Ylides
Electrochemical Cascade Reaction for C(sp3)–H Tetrazolation of Saturated Heterocycles: Access to Tetrazole-5-thiones
Thiol–Ene Reaction of 1-Azabuta-1,3-dienes in Synthesis of Functionalized α-Amino Ketones and Fused Aziridines
Thiourea-Mediated Esterification by Redox Dehydration
Shimojilide, a Potent and Selective Antiproliferative Cyclic Lipopeptide from a Marine Cyanobacterium Okeania sp.
Chemodivergent Synthesis of 1,4-Benzo[b]dithiins and 1,4-Benzodithiafulvenes
Asymmetric Synthesis of cis-3α-Aryloctahydroindole Alkaloids by Ene-Reductase Dehydrocyclization
Hydro/Fluoro-phosphoro(di)thiolation of Allenamides: Toward SN2-Selective Transition-Metal-Free Formal Hydrocarbonation
Asymmetric Synthesis of the Tricyclic Core of Ingenane Diterpenoids via a Photocatalytic de Mayo Fragmentation Strategy
Transition Metal- and Catalyst-Free Acylation of Alkyl Halides Using α-Hydroxyketones as Acyl Anion Equivalents
Photocatalytic Radical Relay Strategy for the Synthesis of Allylic gem-Difluorides via 1,4-Difunctionalization of gem-Difluorobuta-1,3-dienes
Synthesis of an A/B-cis-Fused Cyclopenta[b]fluorene (6/5/6/5) Ring System for Embellicine A via the Eight-Membered Silylene-Tethered IMDA Reaction
Deuterated Cyclopropanation of Alkenes by Iron Catalysis
1,2-Amino Alcohols via Visible-Light-Mediated Mannich-Type Reaction Enabled by Brook Rearrangement
Chiral Iminium Salt-Catalyzed Asymmetric Oxidative Dearomatization of Naphthols into ortho-Quinols
Chemodivergent [3+2] and [4+2] Annulations of Isoindigos with Morita–Baylis–Hillman (MBH) Carbonates
A Strategy for the Stereoselective Synthesis of Contiguous Triamines via Aziridine Intermediate
A One-Pot Three-Step Cu-Catalyzed Protocol to Construct Dibenzo[1,4]diazepine Derivatives and Their Analogs with Cyclopropylamine as a Surrogate of Ammonia
Functionalization of the 1,8-Naphthalimide Core with Weak Nucleophiles
Enantioselective [4 + 2] Annulation Reaction of C1-Ammonium Enolate and Azadiene for 3,4-Dihydroquinolinones Synthesis
Green-Light-Induced Cyclopropanation of Alkenes via Cooperative NHN/Ligated Boryl Radical Activation of Dichloromethane
Photocatalytic α-Selective σ-Bond Hydroboration of Bicyclo[1.1.0]butanes
Copper-Catalyzed [3+3] Cycloaddition of Ethynyl Methylene Cyclic Carbamates with N,N′-Cyclic Azomethine Imines Enabled by an Extended C═C Bond
Phosphonium Ylide-Catalyzed Z-Stereoselective Synthesis of α-Substituted Monofluoroalkenes from gem-Difluoroalkenes and Triazoles
A Nonpillar Shaped Pillararene Derivative, Oxgens2 Pillar[6]arene: Synthesis, Structure, and Iodine Adsorption
Mechanochemically Triggered Deaminative Halogenation of Anilines Mediated by a TEMPO-Driven Radical Manifold
Synthesis of Antiaromatic Ni(II) Norcorroles by Mn Powder
Modular Synthesis of Geminal Triarylmethyl and Chiral Diarylmethyl Boronates via Arylation of Solid α-Boryl Organozinc Reagents
Divergent Access to α,β-Unsaturated Thiolated and Selenolated Lactams via a Unified Palladium-Catalyzed Carbonylative Transformation
Electron Donor–Acceptor Chromophore Assembly as an Enabling Process for the Overall Light-Driven Reduction of Phosphine Oxides
Light-Mediated g-C3N4-Catalyzed Anti-Markovnikov Hydroarylation of Enamides: Direct Access to β-Arylethylamine with Nematicidal Activity
Synthesis of 1,3-Alkylphosphoryl Bicyclo[1.1.1]pentane by Photocatalytic Cascade Radical Addition
Electrochemically Enabled [3 + 2] Cycloaddition of Alkenes with Vinyl Azides: Direct Access to 2,4,5-Trisubstituted 1-Pyrrolines
Pentafluoroethyl Sulfoximine Reagent for the Photocatalytic Pentafluoroethylation–Difunctionalization of Styrene Derivatives
Organocatalytic Enantioselective Synthesis of Axially Chiral Tetrasubstituted Allenes via Direct 1,8-Addition to In Situ Formed Alkynyl 8-Methylenenaphthalen-2(8H)-ones
Skeletal Transformation of Benzene Rings to Indoles via Arylthianthrenium Salts Strategy
Dynamic Dual Role as Cationic Cu+ and Cu Alkoxide in Cu-Catalyzed Dearomative Cascade Reactions
Aspersorbiciols A and B, Two Hybrid Sorbicillinoids with an Undescribed Skeleton from a Marine-Derived Fungus Aspergillus sp. GXIMD02072
Arylative Coupling of Pyridylphosphonium Salts with Aryl Thianthrenium Salts Enabled by Palladium Catalysis
Pd/Tl Bimetal-Catalyzed C3(5)–H Activation of Pyridine Derivatives Enables Access to Pyridine-Fused Benzophospholes and Their Transformation into Seven-Membered Phosphepines
Direct Difunctionalization of Unsaturated Peptides: A Strategy for Concurrent Incorporation of Trifluoromethyl and Alkynyl Groups
Enantioselective Construction of Chiral Azahelicenes through Catalytic Asymmetric Povarov-Type Cycloaddition Involving Alkynes
Catalytic Atroposelective Synthesis of C–N Axially Chiral Pyrazolyl Pyrroles via De Novo Construction of a Pyrrole Ring
Acylsilane as Energy Transfer Catalyst for Intermolecular [2 + 2] Cyclization of Alkenyl Triflones and Olefins
Combining Palladium and Metal Alkoxide Enables Chemoselective Access to Flexible Allyl-Pd Oxa-dipoles for Higher-Order Cycloadditions
Synthesis of the Proposed Structure of Celacarfurine and Analogues Using Sequential Cascade Ring Expansion Reactions
Electron-Deficient Confined Space: Synthesis and Recognition Properties of a Covalent Molecular Cage Built upon Naphthalene Diimides and Benzene Triimides
Diazotrifluoroethyl Radical in Photoinduced [3 + 2] Cycloadditions
Copper-Catalyzed C(sp2)–H Thioglycosylation of Tryptophan: Modular Construction of S-Linked Thioglycopeptides
Asymmetric Transfer Hydrogenation of Hemisquaramides: Access to Enantioenriched α-Hydroxy-3-aminocyclobutenone Derivatives
Temperature Dependent Divergent Radical Oxidative Amidation Engaging Arylglyoxyl Radicals
N-Acyl Benzisothiazolinones (N-acyl BITs) Enable Efficient Amide Bond Formation in Aqueous and Organic Media
Total Syntheses of (+)-Penicibilaenes A and B via Enantioselective Desymmetrization
Total Synthesis of Lucidimines/Ganocalicines A/B, Sinensine E, and Ganocochlearine E
Direct Catalytic Decarboxylative C1-Alkylation of Unprotected Tetrahydroisoquinolines via Photoredox Catalysis
Serendipity-Driven Telescoped Synthesis of 2-Aryl Glycidic Esters from Aldehydes
Direct Ether Synthesis Utilizing the Carbonyl Umpolung Reaction
Total Synthesis of Chondrochloren A
Organophotocatalytic Single-Step Oximation through an Olefin [4 + 2] Annulation
Indium-Catalyzed Synthesis of 4-Alkynyl-2-quinolones Accompanied by Alkyne Migration
N═N Coupling and Rearrangement of Arylamines with N-Nitrosoaromatics: Synthesis of Unsymmetric Azobenzenes
Nitrene Generation from Iminophosphoranes: Facilitating Ring-Closing C(sp2)–H Amidation for Disubstituted Oxindoles
Copper-Catalyzed Remote Enantioselective [4 + 1] Cyclization of Yne–Vinyl Allylic Esters with Cyclic 1,3-Dicarbonyl Compounds Enables Access to Spirocyclic Ketones
Photoredox-Catalyzed Defluorinative Carbamoylation of α-Trifluoromethylalkenes
Copper(I)-Catalyzed Amide Oxazoline-Directed, Atom-Economic C–H Selenylation of (Hetero)Arenes under External Oxidant-Free Conditions
Palladium(II)-Catalyzed Direct C7-Acyloxylation of Indoles
Photocatalytic Kharasch-Type Cyclization Cascade for Accessing Polyhalogenated 1-Indanones and Indenes
Base-Mediated Cascade Annulations of β-CF3-1,3-Enynamides with Tosylaminomethyl Enones: Synthesis of Angularly CF3-Substituted Hexahydrocyclopenta[c]pyrrole Frameworks
Direct Amidation of Tertiary N-Benzylamines
Dual Cobalt/Photoredox Catalysis for the Synthesis of α,β-Unsaturated γ-Lactams and α-Enaminones
Fused and Spirocyclic Sulfones for Medicinal Chemistry via [3 + 2] Cycloaddition of Thiocarbonyl Ylide
Cα-Umpolung of Amides Strategy for Enantioselective Propargylic Amination toward Cα-Tetrasubstituted α-Amino Acid Derivatives
Copper-Catalyzed Regioselective Dehydrogenative Borylation: A Modular Platform Enabling C4-Borylated 2,1-Borazaronaphthalenes
O2-Controlled Acid-Mediated Sulfenylation/Cyclization of Tethered Malononitriles and Sulfides toward Divergent Synthesis of Mono/Dithio-cyclopentenones
Employing Arylboronic Acids in Nickel-Catalyzed Enantioselective Suzuki-Type Cross-Couplings: Access to Chiral α-Aryl Phosphonates and α-Aryl Esters
Development of Axially Chiral Phosphoramidite Ligands and Their Application in Pd-Catalyzed Asymmetric Synthesis of Spiro-Pyrazolone–Pyrrolidinones via [2 + 3] Cycloaddition
Synthesis of Axially Chiral Allenes by Pd-Catalyzed Thianthrene-Mediated Functionalization of Alkynes with Arenes
Deoxygenative Asymmetric Cyanation with P(OEt)3 Employing Cooperative Photoredox Catalysis and Copper Catalysis
Ligand-Enabled Photocatalytic Reactivity of Iron(III) Halide Salts with Cyan and Green Light
Unsymmetric Diazaborepin Framework with Fused 6/5/7 Ring and π-Extension to Two Bis-Diazaborepin-Embedded Isomers
Rehmannins A–D, Anti-inflammatory Carotenoid Pigments from the Fresh Root of Rehmannia glutinosa
Visible Light-Promoted Thiobenzoic Acid-Catalyzed Deuteration of Alkylamines and Alkylarenes
Decoupling Radical Generation and Copper Catalysis for the Remote C–H Cyanation of Unfunctionalized Sulfonamides
Visible-Light-Enabled Fluorosulfonylalkynylation of Alkenes
Asymmetric Synthesis of KRAS G12C Inhibitor MK-1084 via a Crystallization-Induced Diastereomer Transformation (CIDT)
Bromination Functionalization of Diazo Compounds with CBr4 via Convergent Paired Electrolysis
Nickel-Catalyzed Atroposelective Synthesis of Axially Chiral Heterobiaryls via De Novo Benzene Formation
Strong Base-Promoted Pd-Catalyzed Asymmetric Hydroalkoxylation of Alkoxyallene
Synthesis of 5,5,6-Fused Tricyclic Lactones: Stereocontrol of Three Consecutive Stereocenters
Access to Hindered Alkyl Aryl Ethers via Radical–Polar Crossover C(sp3)–O Coupling Enabled by Dual Organosulfur/Photoredox Catalysis
Chiral Thiourea Catalysts Containing Fluxional Groups: Synthesis of Fluorinated Chiral Building Blocks
Synthesis of 3-Aminobenzisoxazoles Using an Electrophilic Aminating Reagent
Bifunctional Monothiosquaramide-Catalyzed Enantioselective Addition of Masked Acyl Cyanide to Isatins: Umpolung Strategy for the Total Synthesis of (S)-(−)-Dioxibrassinin and (R)-(+)-Spirobrassinin
Hunterlanines A–F, Neuroprotective Monoterpenoid Indole Alkaloid Heterodimers from Hunteria zeylanica
Chemodivergent Synthesis of γ- and δ-Lactone-Fused Uracils via NHC-Catalyzed Base-Controlled Processes
Michael-Addition-Triggered Release of Substituents from Tertiary Amines
Electrochemical or Photoredox Activation of Latent Electrophiles: Three-Component Mumm Rearrangement Cascade Reactions from Alkoxyamines
Iron-Catalyzed C–H Alkylative Ring Openings of Oxabicyclic Alkenes
Difluoromethylation of Arylsulfonium Salts with TMSCF2H
Photodriven Fluoroalkylation–Alkoxylation of Enol Ethers via Electron Donor–Acceptor Complex of Bromodifluoroacetamides
Divergent C–H Alkylation and Allylation of Indoles with Unactivated Alkene via Mechanochemical Rh(III) Catalysis
Atroposelective Synthesis of Styrenes by Alcohol-Dehydrogenase-Catalyzed Dynamic Kinetic Resolution
Collective Total Synthesis of (+)- and (−)-Baoslingzhines F–H, (+)- and (−)-Chizhiene C, and (+)- and (−)-Lingzhines E and F
Site-Selective Azidation of Arenes via Hypervalent Iodine-Mediated C–H Functionalization
Minisci-Type C–H Methylation and Silylation of Heteroarenes with Visible Light and N-Fluorobenzenesulfonimide
Oxidative Cleavage of β-Substituted Primary Alcohols in Flow
Developing Nitrogen-Rich High-Energy Initiating Materials: Integration of Azidotetrazole into a Heterocycle via a Two-Step Approach
Use of a “Structural Dummy” α-Silyl Substituent in Nazarov Cyclization: Expanding the Substrate Scope to Indanones and Bicyclic 2-Pyrones
Photoredox/Copper-Cocatalyzed Difluoromethylation of Benzylic Bromides with PPh3(CF2H)2
A Recyclable Triangular Phenanthrenequinone (TPQ) Catalyst-in-a-Teabag System for Biomimetic Aerobic Oxidation of Benzylamines
Difluoromethylation of Aryl Halides via Palladium-Catalyzed Redox-Neutral Deacylation
Engaging Photoexcited ortho-Substituted Nitroarenes and Aryl/Alkyl Boronic Acids in Reductive C–N Coupling
Ligand Design Enables Cu-Catalyzed Etherification of Aryl Bromides Using Mild Bases
Synthesis of γ-Aminophosphonates via Photocatalytic Radical Relay Process
Unified Photoredox Strategy for Selective Access to Hydroisoquinoline and Benzosultam via Tether Modulation of Allylamine
Photoinduced Palladium-Catalyzed Denitrogenative Cyclization of N-Aroyl Benzotriazoles to Phenanthridinones
Ni-Catalyzed Asymmetric Reductive Arylation and Alkenylation of N-Sulfonyl Imines
Electron Donor–Acceptor Complex-Driven Minisci Reactions of N-Heteroaromatic and Inert C(sp3)–H without Brønsted Acids and External Oxidants
Photoinduced Synthesis of S-Aryl Dithiocarbamates and Arylamides via Denitrogenation and CS2/CO Insertion of Aryltriazenes
Direct Indazole Synthesis via Ruthenium(II)-Catalyzed Acceptorless Dehydrogenative Annulation of Alcohols and Arylhydrazines
A Multicatalytic Cascade for the Stereoselective Synthesis of 1,4-Chiral Nitro Alcohols
Enantioselective Mannich Reactions of γ,δ-Unsaturated β-Keto Esters and Application in the Synthesis of β’-Amino enones, 2,6-Disubstituted Piperidin-4-ones and (+)-241D
Electrochemical Radical Allylic Trifluoromethylation of Free Allylic Alcohols with Trifunctional Trifluoromethyl Thianthrenium Salts
Access to Fused Indolines with a Quaternary N,N′-Aminal Center: Aza-Wacker-Type Cyclization for a Telescoped Reaction Sequence
Carbene-Catalyzed C–H Arylation of Aldehyde-Hydrazone via Radical Cross-Coupling with Iodobenzene
Asymmetric Synthesis of Axially Chiral Olefins and Heterobiaryls via Rhodium-Catalyzed C–C Activation and [4 + 2] Annulation
Stereoselective Construction of C2-Symmetric Adjacent Bis-α,α′-cis-Disubstituted THF Skeleton via Double Intramolecular Amide Enolate Alkylation: Total Syntheses of (+)-Membranacin and (+)-Squamocin-N
Rhodium-Catalyzed [3 + 2] Annulation of 2-Benzylquinazolinones with Ketones for the Synthesis of Diversely Functionalized Pyrrolo[2,1-b]quinazolinones
Photocatalytic Access to Cyclopropanes Via Triplet Carbene Transfer from Acceptor-Acceptor Diazoalkanes
Phosphoric-Acid-Catalyzed ortho-Selective Intramolecular Cyclodehydration Reaction of Phenols and Anilines
Photoredox-Enabled and Thianthrenation-Promoted Access to Arene Sulfinamides En Route to Other S(VI) Compounds
Diastereoselective Aminoacylation of β-Methylstyrenes through Cooperative N-Heterocyclic Carbene and Photoredox Catalysis
Mallory-Type Reactivity of 1,2-Dihydroazaborinines: 6π-Electrocyclization-[1,5]-H Shift Cascade toward BN-Doped Polycyclic Frameworks
Copper-Catalyzed Trifunctionalization of Alkynes: One-Pot Assembly of Antifungal Benzofuro[3,2-d]pyrimidine-Containing Fused Heterocycles
Ten-Step Synthesis of Potent Anticancer Steroid Withanolide D
AbClick Pro H: Scavenger-Free, Traceless Lys248 Conjugation Via O-Acyl Hydroxamate Chemistry for Homogeneous Antibody–Drug Conjugates (ADCs)
Non-Kekulé Bi-Blatter Diradicals: Phenyl versus Electron-Deficient Heteroaromatic Linkers
Unlocking C–N Bond Formation via a Two-Photon ETU-FRET Relay with Near-Infrared Light
Photoredox 1,4-Hydroxysulfonylation of Methylenecyclobutane via Carbon-Radical-Mediated β-Scission of Cyclobutane
B(C6F5)3-Catalyzed (5 + 1)-Annulation of Enynamides with Trihydrosilanes en Route to the Synthesis of 1,4-Azasilines
Construction of the Dictamnine Framework via an Alkynylation/Cyclization Cascade Enabled by Quinolinone-Fused Cyclic Diaryliodonium Salts
Enantioselective Synthesis of Functionalized 2,2-Disubstituted Piperidines Enabled by Pd-Catalyzed Decarboxylative Asymmetric Allylic Alkylation
Cobalt(III)-Catalyzed Selective β-C(sp2)–H Alkynylation of Acyclic Enamides with Bromoalkynes
Direct Synthesis of (Radio)difluoromethylated Selenides via Organic Photoredox Catalysis
Access to Alkylative/Hydrodefluorination of Trifluoromethyl Ketones Using Photoexcited Dihydropyridines
Synthesis of C2-Iodoindoles via an Aromatic Finkelstein-Type Halide Exchange under Mild Conditions
Enantioselective Cobalt-Catalyzed C–H Activation and Annulation of Indole-3-carboxamides with Alkynes: Access to Axially Chiral γ-Carbolinones
Divergent Total Syntheses of (−)-Galanthamine, (−)-Narwedine, (−)-Lycoraminone and (−)-Lycoramine, and Formal Syntheses of (−)-Morphine and (−)-Codeine
Synthesis of Functionalized Isoxazoline N-Oxides by Palladium-Catalyzed Cyclization of Nitro-Tethered Alkenes
Conia-Ene Cyclization of Pyrazolones with o-Alkynyl Aldehydes: A Strategic Shift from Classical Condensation to Spiroannulation
Air-Stable and Luminescent Trityls via Methoxy Modification
Photoinduced Synthesis of gem-Difluorinated Sulfides from Organic Thiocyanates via Difluorinated Phosphonium Salts
Synthesis of Uracil Containing Oxazolidinone Derivatives by Using Uracil-BX and NaHCO3 as a Solid Surrogate of CO2
Nickel-Catalyzed Alkenylation of N-Heteroarenes with Fluorinated Alcohols: Direct Access to CF3-Embedded Olefins
Reactivity Investigation of Bis-Tetrazole Isomers Prepared through Dimroth Rearrangement
FBMN-Guided Discovery of Five Drimane Sesquiterpenoids with a Rearranged Carbon Skeleton from the Myxobacterium Nannocystis pusilla YN2B1
1,3-Dimethylimidazolidine-Mediated Acylation of Aryl Halides and Triflates via Photoredox/Nickel Dual Catalysis
Access to Biaryls via Anilide C–N Bond Activation through Photocatalytic Radical Truce–Smiles Rearrangement
Total Syntheses of Grandilodines A and C and Lapidilectam via a Photoredox-Catalyzed Decarboxylative (6 + 2) Radical Annulation
Multicomponent Cascade Reactions and Skeletal Rearrangements of Isatins for the Synthesis of Functionalized Pyrrolo[1,2-c]quinazolin-5(6H)-ones
Harnessing the Umpolung Reactivity of 3-Pyrrol-1-yloxindoles: Iodine-Catalyzed Cross-Dehydrogenative Coupling for the Direct Synthesis of 3,3-Disubstituted Oxindoles
e-Carbonyl: Electrochemical Synthesis of α-Keto Esters via α-Carbonyl Carbocations
Selective Bromination and Perbromination of 5,10,19-Trimesityl[20]smaragdyrin
Visible-Light-Induced Direct Methylation of Quinoxalin-2(1H)-ones with N,N,N′,N″,N″-Pentamethyldiethylenetriamine as the Methyl Source
Pd-Catalyzed C–H/C–C Cascade Activation for the Synthesis of γ-Lactams
(CF3S)2C═S: Electrophilic Site at the Thiocarbonyl Sulfur for the Incorporation of Multiple CF3S Groups
Photoredox-Catalyzed Defluorinative [4 + 2] Cycloaddition of α-Fluoro-β-keto Esters and Alkynes by Single Photosensitizer
Copper-Mediated Dehydroamination of Primary Amines for Olefination
Highly Regioselective and Stereoselective Haloazidation of Alkynes Mediated by a Halide-Bridged Charge-Transfer Complex
Visible Light-Induced [2+2+1] Cycloaddition of 1,6-Enones with α-Bromocarbonyls
Photoinduced Copper-Catalyzed Regiodivergent Tertiary Alkylation of α-Imino Carbonyls to Access Sterically Congested α- and β-Amino Acids
Photoinduced Deoxygenation Reduction of Sulfoxides with HCl or HBr and Hydrocarbons
Visible-Light-Induced Acylsilylation of Nitrosoarenes for Synthesis of N-Arylhydroxamic Acid Silicon Esters
Photoinduced Palladium-Catalyzed Controllable Multicomponent Mono- or Di-C-glycosylation for the Construction of Alkyl C-Glycoconjugates
Synthesis of Carborane-Fused Lactones via Electrochemical C(sp3)–H Lactonization: Access to Benzofused Lactone Bioisosteres
Mono- and Bisphosphonylation of Aryl Chlorides via Phenothiazine Organophotoredox Catalysis
Hydrosilafluorenes as Recyclable Coupling Reagents for Direct Amidation of Carboxylic Acids with Amines
Alkyl and Aryl Thioester Synthesis via N-Heterocyclic Carbene-Catalyzed α-Thio Aldehyde Rearrangement
Photochemical Construction of Trifluoromethyl Bicyclo[1.1.1]pentyl-heterocycles
Oxone-Mediated Radical Trifunctionalization of Allyl Carboxylates via 1,2-Ester Migration
Enantioselective Beckmann Rearrangement through Organocatalytic Desymmetrization of Cyclobutanones for the Synthesis of 4,4-Disubstituted γ-Lactams
Construction of Chiral 1,2-Azaborines via Rhodium-Catalyzed Enantioselective Carbene N–H Bond Insertion
UV Light-Mediated Generation of Ketyl Radicals with a Concurrent 1,2-Boron Shift and One-Pot Synthesis of Benzoxaboroles under Continuous-Flow Conditions
Copper-Catalyzed Enantioselective [1,3] O-to-C Rearrangement of Heteroaryl Alkyl Ethers
Phosphorothiolation of Benzylic C(sp3)–H via EnT-Mediated Radical–Radical Cross-Coupling
Iodide-Induced Reductive Radical Generation from Sulfonyl Diazonium Salts: A Metal-Free Iodosulfonylation of Alkynes for (E)-β-Iodovinyl Sulfones Synthesis
Access to Pyrazolo[1,5-a]pyrimidinone Regioisomers from Acylated Meldrum’s Acids
Harnessing Pnictogen and Chalcogen Bonding for Cross-Electrophile C–PIII Coupling of Chlorophosphines with Thianthrenium Salts
(3 + 2) Annulation of Cyclopropanone Acetal with Silyl Enol Ether toward the Synthesis of Polysubstituted Cyclopentanones
Photocatalytic Aminoarylation of Styrenes
Fe(III)-Promoted ortho-Selective C–H Borylation of Aryl Selenoesters
Rh-Catalyzed Cycloaddition Cascade of Allenynes and Maleimides: A Powerful Strategy for Constructing Complex Pentacyclic Structures with a Bicyclo[2.2.2]octene Core
Spatially Decoupled Fluorescent Amphiphiles for pH-Controlled Anion Detection in Water
Electrochemical Nitrooxylation and NO2 Elimination-Grignard Addition for the Oxa-Quaternization of Saturated N-Heterocycles: Access to α-Aryl-α-hydroxy Lactams
Dihydrogen Phosphate Anion-Templated Supramolecular Assembly with Bistable [3]Rotaxane: Application in Selective and Sensitive Picric Acid Detection
How Far Can Trinitromethyl Substitution Be Pushed on a Single 1,2,3-Triazole Ring?
Chiral Phosphoric Acid and BF3·THF Relay Catalytic System Enables a Formal Asymmetric Aza-Baeyer–Villiger Rearrangement
Cyclocarbonickelation–Arylation Cascade under Ligand-Free Conditions: Access to Dibenzoxepine, Oxathiepine, and Thiazepine Frameworks and Mechanistic Insights
Oxidative Alkynylation of Alcohols or Aldehydes Using RuHCl(CO)(PPh3)3: Ynones Made Easy
Practical Post-Functionalizable Iodosulfonylation of Allenes for Integrating Multifunctional Molecules
Synthesis of Benzarsoles by Arsenic Cation-Mediated Formal [3 + 2]-Cycloaddition with Alkynes
Direct α-C–H Alkylation of Alcohols with Alkenes
Copper-Catalyzed Asymmetric Allyl Addition of Imines with Allenylsilanes
Catalytic Asymmetric Benzoin Condensation for the Synthesis of Natural Products and Their Analogs
A Modular Approach to Access 1,4-Benzoxazinones, Spirooxazolidinones, and 4,1-Benzoxazepinones via Oxidative Aryl C–N Bond Formation Using Catalytic Hypervalent Iodine
An Umpolung Strategy for Palladium-Catalyzed Dearomative Allylation toward Eight-Membered N-Heterocycles
Synthesis of Keto Hexafluoro Alkyl Sulfonyl Amides Via Radical Ring-Opening Polymerization of Aryl-Substituted Vinyl Cyclohexafluoropropane-1,3-bis(sulfonyl)amides Followed by Hydrolysis
Biocatalytic Enantioselective Oxidation of N-Acyl-S-Methyl Sulfenamides for the Asymmetric Synthesis of S-Methyl Sulfoximines
Stereochemical Reassignment by Total Synthesis of an Ocular Pyridinium Bisretinoid of Retinal Pigment Epithelium Lipofuscin: iiso-A2E Is i-A2E
Isothioureas as Coupling Partners in P–S Bond Formation through Cross-Dehydrogenative Coupling
Synthesis and Properties of Medium-Sized cis,trans-Cycloocta-1,3-diene–Pt(II) Complexes
Radical-Polar Crossover Enabled Photoredox 1,2-Carbosulfinylation of Alkenes with N-Sulfinyltritylamine
Cyclopropanation of Alkenes with Dichloromethane and Chloroform via Halogen Atom Transfer Using Amine Carboxyborane
Visible-Light-Induced [5 + 1] Annulation of Vinyl Cyclopropane with Nitrene
Dual N-Heterocyclic Carbene/Thiourea Catalysis Enabled Asymmetric Dearomative Michael Addition of C3-Fluorooxindoles to 2-Nitrobenzofurans
Decarboxylative Redox Bicyclo[1.1.1]pentylation: Benchmarking the Influence of Backbone Substituents on C–C Bond-Forming Reactions
Photoreductive Coupling of Unactivated Ketones and Alkenes via Kinetic Suppression of Ketyl Radical Overreduction
Silicon-Assisted Ferrier Rearrangement in Preparation of C3-Silyl Glycosides
Tf2O-Mediated Phospha-Michael Addition to Unactivated α,β-Unsaturated Amides
Enantioselective Alkyne-Mediated Aldehyde Allylation of Alcohol Proelectrophiles Using RuHCl(CO)(PPh3)3 as Precatalyst
Gold-Catalyzed Reactions of o-Alkynylarylaldehydes with Alkenes for the Synthesis of 3,4-Dihydronaphthalene Derivatives
Access to Aryl Thianthrenium Salts via Main Group Metathesis
l-Proline-Derived Chiral Primary Amine/Copper Dual Catalysis: Highly Chemo- and Enantioselective α-Amination Reactions of Branched β-Ketocarbonyls
Ph3N as an Organocatalytic Donor for Photoactivation of Pyridinium-Masked Enols in the Formal [4 + 2] Cycloaddition with Unactivated Olefins
Switchable Access to Quinolines and Isoquinolines via the Diverse Behavior of Transient Directing Groups
Access to Five-Membered Silacycles via Pd-Catalyzed Heck-Type Coupling with Arylthianthrenium Salts
Regioselective Allylic Aminoalkylation Enabled by Dual Chromium/Photoredox Catalysis
Modular One-Step Three-Component Synthesis of Vinyl Ethers by Benzoquinone Trapping of Vinyl Radicals
Photochemical Radical Ring-Opening Alkylation of Cyclopropanols with Katritzky Salts
Unlocking Oxidative Cross-Coupling between Four Nucleophiles: Synthesis of Spiropyrrolo[2,1-a]isoquinolines
Iron-Catalyzed Synthesis of Primary Sulfinamidines from Sulfenamides
Iridium-Catalyzed γ-Hydro(hetero)arylation of α,β-Unsaturated Amides
Microdroplets Catalyze C(sp2)–H Nitration Reactions
KOtBu-Promoted Synthesis of N-Triazolyl Alkylamide Derivatives
Cu-Catalyzed Highly Selective Ritter-Type Reaction of Enaminonitriles with Cycloketoxime Esters: A Direct Route to Diverse α-Tertiary Amines
Radical Borylation of Aryl Sulfones with N-Heterocyclic Carbene Borane: A Modular Approach to Aryl Boranes
Kinetic Resolution of Unprotected BINOLs via Lewis Base-Catalyzed O-Boc Protection
Visible-Light-Mediated Cyclization of Enynes toward Medium-Sized Carbocycles with Copper Catalyst
Synthesis of (E)-Silyl-Acrylates via Ruthenium-Catalyzed Selective Dehydrogenative Si–H/C–H Silylation of Acrylates
Asymmetric Allylation/Retro-Claisen Cascade Reaction of 1,3-Diketones and 1-Hydroxyallylphenols/Aniline Catalyzed by an Iridium Complex
DBU-Mediated Diastereoselective C3-Quaternary Alkylation of Cyclic Dipeptides
O- and S-Functionalized 6-Selenabicyclo[3.2.1]octanes from Elemental Selenium and 4-Vinylcyclohexene
Synthesis of Seven-Membered Nitriles by Formal Anionic Divinylcyclopropane Rearrangement
Copper-Catalyzed Three-Component Radical 1,2-Carboazidation of 1,3-Dienes
Copper-Catalyzed Stereoselective Synthesis of Fluorinated 1,3-Dienes via Sequential Iodine–Fluorine Elimination
Divergent Synthesis of Highly Functional 3-Trifluoromethylated Dihydropyrroles and Pyrroles via 6π-Photocyclization
Enzyme-like Hydrogen Atom Transfer (HAT) Based Endo-Functionalized Molecular Receptors
Modular Synthesis of Heptagon-Embedded Polyarenes by Double Cyclizations with Pyrones-Derived Aryliodonium Salts
Rhodium-Catalyzed Regioselective C–H Amidation of Benzaldehydes with Dioxazolones: Weakly Coordinating Aldehyde as a Traceless Directing Group
Strain-Release-Driven 1,3-Halo-hydroxylamination of Bicyclo[1.1.0]butanes Enabled by Anomeric Amide Reagents
Divergent Total Synthesis of Diterpenoid Natural Products from Salvia miltiorrhiza
Electrochemical Nickel-Catalyzed Selective Defluorination for the Synthesis of α-Fluoroarylacetic Acid Derivatives
NiCl2/Hdipm-Catalyzed 2-OH-Selective Alkylation of Glycoside trans-Diols
Biomimetic Total Synthesis of Dispirocochlearoids A–C and Related Ganoderma Meroterpenoid Dimers
Assembly of Indolo[2,1-a]isoquinolines via a C–H Oxidation/Carbene Insertion Cascade
Heterocyclic Tridentate Ligands for Effective Alkyne Metathesis
Co(III)-Catalyzed Three-Component Cascade for the Synthesis of α-Quaternary Acyclic Nitriles via C–H Bond Activation
Copper-Catalyzed Sonogashira-Type Cross-Coupling of Trifluoroalkyl Bromides with Alkynes
Photoinduced α-Amino Alkylation of Heterocyclic Compounds via Catalytic Electron Donor–Acceptor Complexes
Photoredox/Brønsted Acid-Catalyzed Asymmetric Difluoroalkylation/Rearrangement of Alkenylfurans
Diversity-Oriented Synthesis of Azepinoindoles through sp3 C–H Functionalization and Skeletal Remodeling
Visible-Light-Driven B-to-C Atom Swap: Scalable Skeletal Editing Access to Benzimidazoles from Diazaborines
Aromatization-Driven C–C Bond Cleavage of Unstrained Ketone Access to Vinyl Sulfones
Merging Aldehydic C–H Activation with Strain Release C–C Bond Cleavage of Bicyclo[1.1.0]butanes under Rh(III) Catalysis
KF and Diaryl Iodide Salt-Mediated Ring Opening of Silacyclobutanes with Carbon Disulfide and Amines to Generate 3-(Fluorosilyl)propyl Dithiocarbamates
Copper-Mediated Oxidative Chloro- and Bromodifluoromethylation of Aliphatic Alcohols
Copper-Catalyzed Selective N-Sulfenylation of Tryptophan-Containing Peptides
Red-Light-Driven Recyclable mpg-C3N4-Catalyzed Minisci Reaction: Access to Heterocycle-Substituted Bicyclo[1.1.1]pentanes
Ligand-Promoted Palladium-Catalyzed [4 + 4] Cycloaddition Affording Benzo[d]isothiazole 1,1-Dioxide-Fused Chiral Eight-Membered N-Heterocycles
Copper-Catalyzed Radical Halocyclization of N-4-Pentenamides: Synthesis of Chloro- and Bromo-Substituted γ-Lactams
Accessing Dihydroazepines and Cyclopentanes from Enynyl Ketones
Synthesis of (Hetero)aryl Fused 4H-Quinolizin-4-ones from N-Ts Substituted (Hetero)arylamides and Pyridotriazoles
Synthesis of Carborane-Functionalized Macrocycles: Bond-Angle-Modulated Cavities and Cation-Mediated Assembly
Newcomer to the Calixarene Family: Synthesis and Characterization of Selenacalix[4]arene
Photoinduced Lanthanum Catalysis: C–H Activation and Spirocyclization
Photochemical, Catalyst-Free [2+2] Cycloaddition of Coumarin-3-carboxylates with Alkenes
Redox-Neutral Radical Annulation of Challenging Alkynes with Aryl Sulfoxonium Ylides for 1-Naphthol Synthesis
Visible Light-Mediated Thia-Paternò–Büchi Reaction of Indoles through Energy Transfer: Synthesis of Thietane-Fused Polycyclic Indolines
α-Selective Ring-Opening of Bicyclo[1.1.0]butanes to Access Spirocyclobutyl Lactams
Orthogonal Cleavage of the HMPB Linker from Solid Support Using HFIP
Copper/Nitroxyl-Catalyzed Oxidative Coupling of Methanol and Amines to Formamides
Copper-Catalyzed Regio- and Enantioselective Acylation of 1,3-Enynes
Assembly of α-Aryl Sulfones and Allyl Sulfones and Their Amide Analogues via Copper-Catalyzed Coupling Reactions
Copper/N-Heterocyclic Carbene Cooperatively Catalyzed Remote Asymmetric ε-Alkylation of Yne-Thiophene Esters with Enals
Organoiodine-Catalyzed Desymmetric Fluorolactonization of α,α-Diallylcarboxylic Acids to Access α-Quaternary Fluorinated Lactones
δ-Quaternary Amino Acids and Dihydroisoquinolones from the Addition of Laterally Lithiated Aryl Carboxylates to N-Sulfinyl Ketimines
Zn(II)-Catalyzed Isomerization/Asymmetric [3+2] Cycloaddition of 3-Butynoyl Pyrazole with Nitrones: Subsequent Exocyclic Olefin Isomerization and Capture
Photoredox-Catalyzed Strain-Release-Driven Aminopyridylation of Bicyclo[1.1.0]butanes with N-Aminopyridinium Ylides
Diastereo- and Site-Selective Synthesis of Bishomoallyl Amines by Nickel-Catalyzed Multicomponent Couplings with Imines and Dienes Enabled by a Pyridyl-Phosphine Ligand
Transient Directing Group Enabled Nickel-Catalyzed Satoh–Miura Annulation of Free Benzylamines with Alkynes
Acid-Catalyzed Dehydrative Nucleophilic Substitutions of 2,6-Di(hydroxymethyl) BODIPYs: A Platform for BODIPY Functionalization
Asymmetric Electrooxidation of Indoles: Mechanistic Insights from an Enantioselective Bromoradical Addition Pathway
Electricity-Induced Alkylative Truce–Smiles Rearrangement of N-Arylsulfonylpropiolamides: A Cascade to Functionalized Isothiazolidinones
Total Synthesis of (+)-Norsecurinamine B
Serendipitous Assembly of Chiral Face-Rotating Molecular Boxes Directed by Non-Covalent Templation
Chemo-, Regio- and Diastereoselective Synthesis of Azaspiro Tetra-/Pentacyclic Scaffolds with Anticancer Activity
Photocatalytic Decarboxylative Hydroalkylation of Alkynes and Alkenes
Copper-Catalyzed Diazo Controlled Annulation of Naphthylamines to Benzo[g]indoles
Mechanistic and Kinetic Studies of Reductions of α,β Unsaturated Esters and Ketones by SmI2–Water
Breaking the Scalability Barrier: Diversifiable Pd-Catalyzed Domino Reaction En Route to Dibenzo[b,d]azepines
Rh(III)-Catalyzed Strain-Release-Enabled C–H Alkenylation/[4+1] Annulation of Benzamides with Alkylidenecyclobutanes
Organophotoredox-Catalyzed Alkene Functionalization Reactions Using α-Bromocarbonyl Compounds
Ti-Promoted Pd- and Fe-Catalyzed Regiodivergent C–H Arylation of Pyridines
Synthesis of Multisubstituted Pyridines by Heterocyclization of TosMIC Derivatives: Total Synthesis of Caerulomycins A and K
Discovery and Biosynthesis of Cytotoxic Myroverols: A Phenalenone Scaffold Constructed by a Fungal Highly Reducing Polyketide Synthase and a Cytochrome P450
A Palladium-Catalyzed Cascade Process of 1,3-Enynes and Imines to Construct Multisubstituted Pyrrole Derivatives
Rhodium-Catalyzed O–H Insertion Reactions to (2-Diazo-1,1,3,3,3-pentafluoropropyl)phosphonate: A Convenient Route to Fluorinated β-Alkoxy Vinylphosphonates
Visible-Light-Induced Defluorinative Giese Reaction of gem-Difluorides via the ConPET Process: A Route to tert-Alkyl Fluorides
Switchable Synthesis of Fused Dihydrobenzofuran or Spiro Benzoisoxazole Derivatives Featuring a Migrated or Merged Directing Group
Shuttle Hydrogen Atom Transfer for Hydro-Fluorosulfonylation of Haloalkynes without β-Scission
An Approach to 1,3,4-Oxadiazolidines via N,N′-Diborylated Hydrazine
Photocatalytic Hydro-Fluorosulfonylation of Thioalkynes via Shuttle HAT
Photoinitiated Aerobic α-C–H Oxidation of Amides Enabled by a Cerium(IV)-Nitrate LMCT Pathway
Palladium-Catalyzed Intramolecular Hydroarylation of N-Alkynylindoles: Regioselective Synthesis of Indole-Annulated Sulfur/Phosphorus Heterocycles
Intramolecular Photocyclization of Enamide Linked 1,5-Dienes Enables Divergent Synthesis of Pyridin-2-one Derivatives
Copper–Iron-Catalyzed Cross-Coupling of ortho-Substituted Sulfonamides with Sterically Hindered (Hetero)aryl Chlorides and Alkyl Halides: Synthesis of Sulfonamide Drugs
Glyoxylate Sulfonyl Hydrazone Enables a Scalable Approach to Reformatsky-Type Products from Aliphatic Alcohols via Photocatalytic HAT
Enantioselective Access to Lactam-Fused Eight-Membered Bridged Biaryls via N-Heterocyclic Carbene-Catalyzed [5 + 3]-Domino Annulation
Lewis Base-Catalyzed Sequential [2 + 3]/[4 + 4] Annulations of α-Allylic Allenoates and Aldimine Esters: Construction of Functionalized Pyrrole-Fused Eight-Membered O-Heterocycles
Furan Oxidation-Cyclization to Oxazepines: Favoring 7-exo-trig over 6-endo-trig and 5-exo-trig Trajectories
Nickel-Catalyzed Reductive Alkylation and Arylation of Arylallylamines via C–N Bond Cleavage
Palladium-Catalyzed Decarboxylative (3 + 3) Coupling Cyclization toward Diverse Fully Substituted Unsaturated Glutarimides
Orthogonal Regioselective Synthesis of Folic Acid γ-Conjugates
Unlocking a Grignard Cascade: Three-Component Access to Complex Polycyclic Architectures from Quinolines
Oxidative α-Amination and Aziridination of Cyclic β-Ketoesters Using Aminobenziodoxolones
Single-Atom Skeletal Editing for One-Step Construction of 1,2,3-Triazine N-Oxide from Pyrimidine via C to N→O Transmutation
Solvent-Free Mechanochemistry Overcomes the Low Solubility of Inorganic Silver Fluorides in the Construction of C–F and S–F Bonds
Asymmetric Gold-Redox Catalysis in Cyclobutanol Ring Expansion toward the Formation of Quaternary Carbon Chiral Center with Hemilabile P,N-Ligand
Myrrhain A: Structural Reassignment Highlights the Relevance of Plasticizer Contamination in Chemical and Bioactivity Studies
Pd-Catalyzed Asymmetric Allylic Alkylation of Carboxylic Acids for the Synthesis of Chiral Butenolidyl Ester Prodrugs and Peptide–Drug Conjugates
Oxahelicene-Based Pd2L4 Cages: Synthesis, Optical Properties, and Guest Encapsulation
Phosphine-Catalyzed Allylic Fluorides Addition to gem-Difluoroalkenes
Synthesis of Spiroindenes via Palladium Catalysis Using Oxabicycles as Acetylene Surrogates
Copper-Mediated Photoinduced Trifluoromethylation of Arylsulfonium Salts with Yagupolskii–Umemoto Reagent
Palladium-Catalyzed Diastereoselective Imidoylative Arylation/Carbamoylation of Conjugated 1,3-Enynes
Solvent-Tuned Photocatalytic (Phenylsulfonyl)difluoromethylation of Anilines: Selectivity and Postfunctionalization
Direct Assembly of Privileged α-CF3 Allylamines via Photoinduced Pd-Catalyzed C–H Aminoalkylation of Alkenes
Photoinduced Radical-Polar Crossover Cyclization for the Synthesis of α-Exo-Alkenyl γ-Lactones
Zincke-Imine-Based Peripheral Editing of 2-Arylpyridines to Access 3-Acylpyridines
Total Synthesis of Racemic Benzosceptrins via an Electrocyclization Cascade
Iron-Catalyzed C–N Coupling Using Polycyclic Aromatic Hydrocarbon as a Redox Mediator
Copper-Catalyzed (5+1) Annulation of Imidazolidines with Cyclopropenes: Synthesis of Functionalized 2-Vinylpiperazines
Photoinduced Cleavage of Alkenyl Fluorides for Nucleophilic Acyl Substitution via In Situ Generated Acyl Fluorides
An Orthogonally Functionalizable Tetrazine Building Block for Dual-Conjugated Bioorthogonal Probes
JBIR-160–166 Obtained from the Heterologous Expression of a Cryptic Gene Cluster in Kitasatospora setae
The epi-Matteson Reaction: Addition of Sodium Iodide in the Substitution Step Allows for a Stereodivergent Outcome
A Synthetic Approach to Diverse Indole/Oxindole-Annulated S-Heterocycles
Hypervalent Iodine(III) Carboxylates Enable Direct Radiosynthesis of 18F-Labeled Aliphatic Sulfonyl Fluorides
Mechanistic Insights into Aerobic C(sp3)–H Hydroxylation: A Catalytic Reaction or Not
Trifluoromethylation of Arenes and Heterocycles via a Bench-Stable Photocaged Trifluoromethylation Reagent
Nickel-Catalyzed Desulfurizative Sonogashira Cross-Coupling of Terminal Alkynes with Alkenylsulfonium Salts
Steric Effects of β-Annulated Pyrroles Trigger the Formation of Ethynylene-Bridged Hexaphyrinogen versus Ethynylene-Cumulene-Linked Aromatic [30] π Hexaphyrin
Peri-Annulations Bestow Configurational Stability onto Chiral Molecular Graphene Bowls
The Ylide Dance: Base-Induced Furan Synthesis via Formal [3+2] Annulation of Phenacyl- and Alkenyl Sulfonium Salts
1-Phenoxyanthrapyridone as an Arylotropy-Based Photochromic System
Enantioselective Synthesis of Spiro-bis-N-heterocyclic Lactams via Formal (3+2) Cycloaddition of 3-Methylene Isoindolinones with C3-Substituted 2-Indolylmethanols
Copper-Catalyzed Sulfinylation of Boronic Acids with Sulfinates
DNA-Compatible Synthesis of α-Aminophosphonate Scaffolds via Kabachnik–Fields Reaction
Two-Heptagon Saddle-Shaped Nanographene as a Host for Fullerene Assembly
Mechanochemical Bis-Spirocyclopropanation Reaction and Ring Rearrangement to 1-Oxaspiro[4.5]decadienones
Nickel-Catalyzed Quinoline Synthesis through Skeletal Editing Strategy Using Calcium Carbide as an Inorganic C2 Source
Pristine Facet of Alkynyl-Prins Vinyl Carbocations for the Functionalization of Inactivated C(sp3)–H Bonds: A Highly Selective [1,5]-Hydride Migration vs. Concerted C–H Insertion
Native Amide-Directed C(sp3)–H Alkynylation Using an Electron-Deficient Iridium Catalyst with Pyridone Ligand Assistance
Divergent Annulation of Isoindolinone-Derived Propargyl Alcohols for the peri-Selective Synthesis of Spirofuran-Isoindolinones and Furanylisoindolinones
Synthesis of β-Amino-α-iminonitriles and α,β-Diiminonitriles Enabled by Lewis Acid-Catalyzed Double Isocyanide Insertion with Imines
Organocatalytic Enantioselective Addition of 3-Aryloxindoles to Ethenesulfonyl Fluoride
Visible-Light-Driven C(sp3)–H Bond Carboxylation of Benzyl Amines with CO2 for the Synthesis of α-Amino Acids
Palladium(II)-Catalyzed [3 + 2] Annulation of Aromatic Triflamides via Maleimide-Relayed Dual C–H Activation Process
Selective Conversion of Esters to Ketones via β-Ketosulfone Intermediates
Photoinduced Multicomponent Sulfonylsulfination of Alkenes via Aromatization-Driven Deconstructive and Radical-Polar Crossover Cyclization Strategies
Chemoselective Methionine Bioconjugation with Hydroxylamine Esters for Peptide/Protein Modifications
Photoredox-Mediated C–N Bond Cleavage Enables Synthesis of Tetra-Substituted Olefins via Reductive Radical-Polar Crossover
Catalyst-Free [3 + 2] Cycloaddition of Benzimidazole Esters and Quinone Esters: Divergent Synthesis of N-Heterocycles
Halogen Atom Transfer (XAT)-Enabled Transition-Metal-Free Radical Annulation for the Construction of Phenanthrene-Derived Polycyclic Aromatic Hydrocarbons (PAHs)
One-Pot Iodination and Giese Addition of Glycosyl Esters for the Synthesis of C-Alkyl Glycosides
Photocatalyzed Nitrene Insertion into C–O Bonds: Access to Benzisoxazoline-3-ones
β-Sulfinimidoyl Esters as Sulfenamide Anion Precursors for Accessing Aza-Sulfur Stereogenic Centers
Regioselective Radical 1,4-Difunctionalization of 1,3-Cyclohexadiene via NHC Catalysis
Atroposelective Cobalt-Catalyzed Decarbonylative Transannulation of Phthalimides and Alkynes
NHC-Catalyzed Access to Benzoxazepinones via Aromatization-Driven Rearrangement
Copper-Catalyzed Divergent C–S Bond Cleavage of Vinylsulfonium Salts: Controllable Phosphoryloxylation and Phosphinoylation
Visible-Light-Induced Comprehensive Carboxylation of Benzyl Halides with CO2 via Halogen Atom Transfer
Microwave-Assisted Precise Synthesis of Alkyl/Aryl-Modified Triazolyl-Phenylalanine Hybrids and Peptide Modifications through Multicomponent Reaction
Electrophotochemical Ce-Catalyzed Radical Truce–Smiles Rearrangement of Cycloalkanols
Synthesis of Si-Bridgehead Polycyclic Aromatic Hydrocarbons via Ru-Catalyzed Double Annulation of Secondary Silanes with Internal Alkynes
Copper-Catalyzed Radical-Triggered Annulation–Halocyanomethylation Reaction of Alkynyl-Bearing Bicyclo[1.1.0]butanes (BCBs) Leading to Spirocyclobutyl Quinolinones
Copper-Catalyzed β-Functionalization of Amino Acid Schiff Bases
Ag2O/TBAI Initiated Nucleophilic Difluoromethylation of Carbonyl Compounds with Me3SiCF2H
One-Step Biomimetic Synthesis of the Alkaloids Karachine, Valachine, and Sinometumine E
Formal Reductive Amination of Carboxylic Acids via Iron-Catalyzed Photoredox Decarboxylative α-Aminomethylation
Glycosyl Radical-Based C–H Glycosylation of Coumarins Enabled by Photocatalysis
Electrochemical Cross-Coupling of P(O)-H with Thioesters: Green Synthesis of Phosphorothioates
1,8-Di(2-ethynylaryl)biphenylenes: Palladium-Catalyzed Intramolecular Cycloisomerization and Subsequent Thermal Rearrangement
Photoinduced Deoxygenative Boration of Unactivated Alcohols Involving In-Situ-Formed Alkyl Iodides
Hydrophilic BIPHEPHOS Ligand for Pd-Mediated Cysteine Allylation of Peptides and Proteins in Water
NHC-Catalyzed Synthesis of 3,5-Disubstituted 1,2,4-Oxadiazoles from Amidoximes and Aldehydes
Intramolecular Dearomative [2 + 2] Cycloaddition of (Hetero)arenes via Energy Transfer Catalysis: Exploration of Divergent Three-Dimensional Skeleton Editing
Stereoselective Synthesis of Diaza-Hexatrienes via [1,6]-O-to-N Group Transfer Strategy
Cu/Pd-Catalyzed Ligand-Controlled Regiodivergent Hydroarylation of Allenes Using Diisobutylaluminum Hydride
Photoinduced Pd-Catalyzed Alkylvinylation of Alkenes via C–H Bond Elaboration
Access to Conjugated Dienes and Cyclic Allenes via a Diazo-Dithiane Rearrangement Cascade
Stereocontrolled Synthesis of 8-Hydroxycurvularol, a Sesquiterpene with a Modified Trichothecene Skeleton
Condition-Regulated Regiodivergent Synthesis of Biaryl Sulfones via Sulfonylation of Diaryl λ3-Bromanes and Chloranes
Continuous-Flow Electrochemistry Enables 1,2-Arylheteroarylation of Alkenes
Base-Promoted Azinium-N-imines and Thioamide Dimeric Annulation for the Tunable Synthesis of 1,2,4-Triazole and Polycyclic Indolylhydroquinoline Skeletons
Silyl Lewis Acid-Catalyzed 5-endo-trig Remote Aryl Rearrangement Enabling Dual Migration of Anisole and Amide Groups of N-Cinnamyl-N-alkoxybenzyl Sulfonamides
Photochemical Carbene-Transfer Reaction of Vinyldiazo Compounds: Synthesis of 1-Pyrrolines via Methylenation/[2+3] Annulation
Nickel-Catalyzed 3,2-Hydroallylation of 1,1-Disubstituted Allenes with Vinyl Cyclopropanes: Access to Functionalized 1,4-Dienes
Assembly of Nitrated Isoxazoles via a Multicomponent Cascade Reaction Using Benzoxathiazine-2,2-dioxides as C1 Synthons
Synthesis of 5-Aminooxazoles and Zwitterionic Fused Imidazolones by I2-Mediated C–H Amination
Visible-Light-Induced Regioselective Thioesterification/Thiocyanation of Unactivated Alkenes Enabled by Spiro-NHC-Ir(III) Catalysis
Synthesis of Silyl Dienol Ethers via Peterson Olefination of Siloxyallylpotassium Species
Diazacyclobutene Ring Cleavage Provides 1,2-Diazetidin-3-ones via Intramolecular Nucleophilic Cyclization
Asymmetric para-Functionalization of Anilines Via Chiral Phosphoric Acid Catalysis: Access to CF3-Substituted Indole–Aniline Quaternary Stereocenters
Noncovalent N-Heterocyclic Carbene Catalysis Enables Asymmetric Conjugate Addition of 2-Benzofuranones to Terminal C-Electrophiles
Photocatalytic Cascade Reaction of Allylamines for the Synthesis of Ester-Containing Imidazolines and Oxazolidines
Asymmetric Synthesis of 2-Benzyl-2-arylindolin-3-ones by Iron-Catalyzed Reductive Benzylation of 2-Aryl-3H-indole-3-ones
Copper-Catalyzed Dehydrogenative Cyclization: A Direct Route to Oxazoles from Readily Available Ketones and Amines
Photocatalyzed Dearomative [2 + 2] Cycloaddition of Indoles with Alkynes to Access Cyclobutene-Fused Indolines
Single-Walled Carbon Nanotubes as a Support for Palladium-Catalyzed Aquachemical Cross-Coupling Reactions
Total Synthesis of (−)-Owerreine and (−)-Anhydrovobtusine
Four-Step Synthesis of (±)-Nanolobatolide via Site-Selective Functionalization
Electrochemical N–H Phosphorodithiolation of Sulfoximines with P4S10 and Alcohols
Enzymatic Enantioselective Protonation Regulated by an Artificial Enzyme Harboring an In Situ-Biosynthesized S-(3-Aminophenyl)-cysteine
Syntheses of Quaternary Carboxylic Acid Derivatives via a Photo-Wolff Rearrangement/Pd Catalysis Sequence
XAT-Generated Azirinyl Radicals in Selective Giese-Type Alkylation of 2H-Azirines
Stereoselective Synthesis of 2-Deoxyglycosides: An Efficient Protocol for Alcohol Deoxygenation
Pd-Catalyzed Fluorocarbonylation of Iodoarenes with Difluoromethyl Benzoates
Ligand-Enabled Palladium-Catalyzed Asymmetric Synthesis of Indole-Fused Chiral Eight-Membered N-Heterocycles via [4 + 4] Cycloaddition
Ruthenium-Catalyzed C(sp2)–H Activation Using Pyridine and Imidazopyridine as Directing Groups for Selective Silylation
Chemo- and Regioselective Synthesis of 3,4-Dihydropyrimidin-4-ones from 4,5-Dihydro-1,2,4-oxadiazoles and Chromium Alkoxy Alkynyl Fischer Carbene Complexes
Photo-Triggered Hydrophosphination of Azoarenes: An Additive-Free Methodology
NHC Precursor Catalyzed C3-Chloromethylation of Oxindole with Dichloromethane as C1 Synthon
Iron-Catalyzed C(sp3)–H Amination Enabled by Visible-Light β-Homolysis
Reductant-Controlled Access to Sulfinamides from Aliphatic Primary Amines
Visible-Light-Induced Organobismuth(III)-Initiated Halogen-Atom Transfer for the Alkylation of Heterocycles with Unactivated Alkyl Iodides
Dual-Co/Ni-Catalyzed Radical Hydroarylation of 1,3-Enynes: Selective Access to Tetrasubstituted Allenes
Persistent Radical Cation Catalysis Enables Radical-Polar Crossover Cycloisomerization of Unactivated Alkenes to CF3-Heterocycles
Development of Ts-Protected Selenocysteine for Sec-Conjugate Arylation via a Reductive Coupling Approach
Phosphine-Catalyzed [3 + 2] and [2 + 4] Annulations of Ketenimines with Electron-Deficient Alkenes or α,β-Unsaturated Carbonyl Compounds
Decarboxylative Bromination of Aliphatic Carboxylic Acids via Visible Light-Driven Proton-Coupled Electron Transfer
Rapid Access to Selenium-Containing Heterocycles Exhibiting Diverse Antimicrobial Activity via BF3·Et2O-Mediated [3 + 3] Annulation
Scalable Synthesis of a Dual TLR7/8 Agonist via Highly Selective N2-Alkylation of 1H-Pyrazolo[4,3-d]pyrimidine
Syntheses of Millingtonine and Incargranine A Following a Unified Cross-Dimerization-Aromatization Strategy
Synchronized Aromaticity Enables Syntheses of 2,4-Cyclohexadienones via [3 + 2]/[3,3]-Cascade Reaction
Fluoride-Catalyzed [2 + 2] Cycloadditions of Allenoates: Access to Azetidine and Cyclobutene Scaffolds
A De Novo Approach for the Atroposelective Synthesis of C5 Aryl Pyrazoles via 5-endo-dig Cyclization
Modular Amide Synthesis via Dual C–O and N–O Bond Cleavage: Palladium-Catalyzed Deoxygenative Carbonylation of Benzyl Alcohols with Nitroarenes
Ruthenium(II)-Catalyzed Macrocyclization via Site-Selective Hydroarylation of Alkynes: Access to Indoline-Braced Metacyclophanes
Stereodivergent α-Addition of Yne-allylic Esters by the Z/E-Selective Multicomponent Reaction
Expanding Peptide Chemical Space via Acid-Mediated Arginine Modification
Stabilized Sulfur Ylides as Synthetic Equivalents of the Carbyne Anion: A Domino-Type Double Annulation Approach to Indane-Fused Isoxazoline N-Oxides
Enantioselective Desymmetrization of Sulfonimidamides with 2-Bromoenals via Asymmetric N-Heterocyclic Carbene Catalysis
Asymmetric Synthesis of MK-7845, an Investigational Treatment for COVID-19
From Hydrazones to N-Anilinoindoles
Synthesis and Ultrafast Intramolecular Energy Transfer in BODIPY/Porphyrin-BOPHY Dyads
Development of Cationic Enantioselective Domino Carbopalladation/C(sp3)–Pd Capture Using N-Tosylhydrazones as Diazo Precursors§
Aryl Carboxylic Acids as Structure-Tunable HAT Agents for Photochemical Site-Selective C(sp3)–H gem-Difluoroallylation of Amides
Electricity-Induced Radical 7-endo-Cyclization from Aryldiazonium Salts: Synthesis of Trifluoromethylated Azepines
Stereoselective and Regioselective Synthesis of Chiral Dihydrofurocoumarins as Glycohybrids
Nickel-Catalyzed Regioselective Markovnikov Hydrosilylation of Vinylarenes via Hydrogen Atom Transfer
Ligand-Promoted Copper-Catalyzed Radical Relay for Alkyl-Alkynylation of Alkenes
Visible-Light-Promoted Metal-Free Three-Component Reaction for the Synthesis of Sulfonated 4-Amino-chromans, 4-Amino-tetrahydroquinolines, and 5-Amino-dihydrobenzo[b]oxepines
Synthesis of Dihydroisoquinolone-Fused Cyclobutanes via Tandem Palladium-Mediated Olefin Migration and Photosensitized [2 + 2] Cycloaddition
Photoredox Fe-Catalyzed Truce–Smiles Rearrangement of N-Arylsulfonyl Acrylamides with Aliphatic Carboxylic Acids
An I2-Catalyzed, Visible-Light Photoredox-Mediated Radical Conversion of α-Nitrocarbonyls to Nitrile Oxides: Catalytic Access to Isoxazolines and Isoxazoles from Alkenes and Alkynes
Regiodivergent Synthesis Utilizing Alkyl Hex-5-en-2-ynoates and 3-Homoacyl Coumarins: Phenol-Mediated Controllable Phosphine-Catalyzed Michael and 1,7-Umpolung Addition
Cobalt-Catalyzed Regio- and Enantioselective Reductive Coupling of 1,3-Enynes with Imines
Carbene-Catalyzed Esterification for the Synthesis of Inherently Chiral Saddle-Shaped Eight-Membered Lactones
Catalytic Synergy Drives Triazole-Directed ortho-C(sp2)–H Functionalization
Catalytic Asymmetric Synthesis of Chiral Oxaspirolactones and Tetrahydropyrans via Ammonium-Catalyzed Reactions of Vinyl Ketones and Nitroalcohols
Total Synthesis of Morusalisin A
One-Pot Bioisosteric Replacement of Alkyl Carboxylic Acids via Organic Photoredox Catalysis
Reagent for the Chemoselective Reduction of Carboxylic Acids to Aldehydes
Photocatalytic Addition of N-Oxazolidinone Radicals to Arenes and Heteroarenes in Batch and in Flow Mode
Rh(III)-Catalyzed Regioselective B(4)–H Alkylation of o-Carboranes with Alkenes
Nonenzymatic Formation of Streptoindoles Reveals an Unexplored Chemical Space of Tryptamine-Derived Natural Products
Nickel- and Lewis Acid-Catalyzed Intramolecular Iminocyanation of Alkenes via N(sp2)–CN Activation
Streamlined Assembly of Pyrimidinones via Wolff Rearrangement-Triggered [3 + 3] Cycloaddition of Alkynyl Diazoalkyl Ketones and 2-Aminoheteroarenes
N-Difluoroacetylation of Sulfoximines by TFEDMA
Organocatalytic syn-Selective [3 + 2]/[4 + 2] Annulations of (E)-Pyrazoloneyldiene Oxindole
Photoredox-Mediated Alkylation of Oxime Chlorides for the Stereoselective Synthesis of Ketoximes
Cobalt-Catalyzed Chemo-, Regio-, Diastereo-, and Enantioselective Cascade Coupling of 1,1-Disubstituted Allenes and Aldehydes
Electroreductive α-Aminoalkylation of Sulfonylazoles with Amines and Aldehydes
Annulation of Phthalic Anhydrides with 2-Arylbenzimidazoles toward Phenanthridine-Fused Heterocycles: TBAI-Promoted Palladium Catalysis
Cooperative NHC and Photoredox Catalyzed Deaminative Acylation of Primary Amines via Isonitrile Formation
Rhodium-Catalyzed Atroposelective Hydroarylation of Alkynes with Biarylhemiboronic Esters for Biaryl Atropisomer Synthesis
Copper-Catalyzed Regioselective Hydroamination and Dual Annulation of 2-Alkynyl Indole-3-carbonitriles: An Assembly of Functionalized Amino-Benzo[h]indolo[3,2-c][1,6]naphthyridines
Metal-Free Photoinduced Halogen-Atom Transfer: A Novel Approach for Tetracoordinate Boron Compound Synthesis and One-Carbon Homologation and Amination of Styrenes
Tungstate-Catalyzed Selective Oxidation of Naphthalenols to Afford Diverse Products under Mild Conditions
Nonalternant Acenaphthylene-Fused Carbaporphyrins: Topological Modulation of π-Delocalization, (Anti)aromaticity, and BIII Coordination
Divergent Synthesis of Tetrafluoroethylene-Containing Tetrahydrofuran (THF) and Dihydropyran (DHP) Derivatives
Transition-Metal-Free Base-Promoted Divergent Synthesis of 5-Amide-1,2,3-triazole and 5-Imide-1,2,3-triazole Derivatives
Self-Assembly of Macrocyclic Hosts with Kinetic Inertness
Benzophenone-Based Phenylogous Peptide Linkage via Friedel–Crafts Acylation
Rh-Catalyzed Asymmetric Hydrogenation of α-Aminomethyl Acrylates for Enantioselective Synthesis of Chiral β-Amino Propanoates
Radical Sulfimidation via Visible-Light Photoredox Catalysis: N-Acyloxyamides as Bench-Stable Nitrene Surrogates
Organocatalytic Asymmetric Friedel–Crafts Reaction of Prochiral 3,4-Fused Pyrroles via a Desymmetrization/Kinetic Resolution Sequence
Sarcglabates A/B, Aromatized Pentanor Lindenane Sesquiterpenoid Dimers from Sarcandra glabra
Three-Component Copper-Catalyzed 1,4-Carboamination of 1,3-Dienes
Palladium-Catalyzed ipso-Didefluoroannulation of Allylic gem-Difluorides with Salicylic Acids
Divergent Concerted Proton–Electron Transfer (CPET) and Hydrogen Atom Transfer (HAT) Pathways of Amidyl Radical Reactivity Enable Chemoselective Functionalization
Selective Synthesis of α,α-Difluoro- and α-Monofluoro Methylene Substituted Arenes by Defluoro C–C Bond Coupling
HPLC–UV-Guided Discovery of Eurotamines A–F: Six Pairs of Isoquinoline Derivative Enantiomers from Marine-Derived Fungus Eurotium sp. SCSIO F452
Tandem Palladium-Catalyzed C–H Activation of Biaryls and Ring Opening of Benzofurans: Access to 2-(9-Phenanthryl)phenol Derivatives
Enantioselective Construction of Fluorinated Tertiary Stereocenters by Rh-Catalyzed [2 + 2 + 2] Cycloaddition of 1,6-Enynes with α-Fluoroacrylamides
Palladium-Catalyzed Cyclization of N-(2-Iodoaryl)-N-methylbenzenesulfonamide with Aryl Iodides to Access Phenanthridine Derivatives
Synthesis and Two-Dimensional Chiral Self-Assembly of Oxygen-Incorporated Dibenzo[hi,st]ovalene
Development of Ir(III) Photocatalysts Enabling Blue-Light-Induced Hydrocarboxylation of Unactivated Alkenes and Arenes
A Macrocyclic Arene Derived from Pagoda[4]arene: Cavity Reshaping, Complexation with Neutral Guests, and CPL Property
Enantioselective Synthesis of the Proposed Structure of (−)-Taiwaniadduct F
Anti-inflammatory Alkaloids, Papaversomni A, a Hexacyclic-Membered Morphinan, and Two Pairs of E/Z Nonseparable Stereoisomers, Papaversomni C and Sinoracutinal, from Papaver somniferum
Regioselective Synthesis of Spiro-Ganoderma Meroterpenoid Motifs via Lewis Acid-Catalyzed Divergent Cycloadditions: [3 + 2] and Water Accelerated [5 + 2] Annulations
Enantioselective Friedel–Crafts Alkylation of Aniline Derivatives with 4-Arylidenepyrrolidine-2,3-diones Catalyzed by Chiral Cu(II) Complex Bearing Binaphthyl-Proline-Imidazoline-type Chiral Ligands
Bioinspired Electrochemical Cyclization toward the Divergent Synthesis of Mavacurane- and Akuammiline-Type Alkaloids
Triethoxysilane as a Selective Reagent in Platinum-Catalyzed Hydrosilylation Reactions
DeepSAT-Driven Discovery of Pimarane Diterpenoids from Arthrinium arundinis with Ulcerative Colitis Inhibitory Activity via NF-κB/MAPK Pathways
Skeletal Editing Via CH→N Atom Swapping in Fused Imidazoles: Access to Triazolo[5,1-a]isoquinoline, Triazolo[1,5-a]quinoline, and Triazolo-[1,5-a]pyridines Frameworks
Divergent Construction of Polycyclic Frameworks Enabled by Sequential Ru-Catalyzed [2 + 2 + 2] Cycloaddition of Iododiynes and Pd/Norbornene-Mediated Catellani-Type Annulation
Site-Selective C–H Sulfinamidation through Electron-Donor–Acceptor Complex Photoactivation and Radical Addition into Sulfinylamine Reagents
CuTC-Catalyzed Ortho-Coupling of Chalcones with Malonates via Cascade Annulation and Transannular Ester Migration: Access to 4-Hydroxy-1,3-dicarboxylatedihydronaphthalenones
Electrocatalytic Synthesis of Aryl-Propargyl Alcohols from Arylacetylenes with N,N-Dimethylacetamide and Water
Tandem Nitro Reduction and Amide Condensation for the On-DNA Synthesis of Natural Product-Inspired Skeletons
Palladium-Catalyzed Ring Opening of Vinyl Oxetanes Enables Asymmetric Dearomative [6 + 2] Cycloaddition of 3-Nitroindoles to Access Indoline-Fused Oxa-Eight-Membered Rings
Electrophotocatalytic Radical Cascade Reaction for the Synthesis of Trifluoromethylated Spirocyclobutyl Oxindoles
Ring-Opening Reconstruction of Indoles Enabled by C–N Bond Cleavage: Synthesis of Benzo[c]pyrazolo[3,4-h][2,6]naphthyridine Derivatives
Synthesis and meta-Amination of Pyridines via Multicomponent Cascade Reaction
Three-Component Cycloaddition Reaction of Aryne, Acrylate, and Imine Derivatives: Divergent Synthesis of Hexahydropyrrolo[1,2-a]quinolines and 1,4-Dihydroquinolines
Synthesis of Chromeno[4,3-d][1,3]oxazines through Copper(I)-Catalyzed Cycloisomerization of 1,11-Enynes
Synthesis, Structures, and Properties of Polybenzo[n]spirenes with Carbon-Based Polyspiroconjugation
Chlorobactine A, a Dimeric Dichlorated Metabolite from Marine-Derived iStreptomyces thermolineatus/i NAK03196
Photoinduced Pd-Catalyzed Carbonylative Formal [2 + 2] Cycloaddition of Alkylarenes and Imines
Chemodivergent Synthesis of Multiborylalkanes via Deoxygenative Polyborylation of Silyl Enol Ethers
Three-Component Cyclization/Haloazidation of Bicyclo[1.1.0]butane-1-carboxamides: Construction of Halogenated Spiro[cyclobutane-1,3′-quinolin]-2′-one Derivatives
Copper-Catalyzed Diastereoselective Defluoroborylation of Pentafluoroethyl Alkenes Using (pin)B–B(dan)
Enantioselective Ring-Opening of Cyclic Diaryliodoniums with 3-Hydroxy Benzo[d][1,2,3]triazin-4(3H)-ones: A 1,2-Difunctionalization Strategy
Visible-Light-Excited Lewis Acid Catalyzed Intermolecular [2σ + 3π] Photocycloadditions
Nitrene Transfer Radical Relay: A Light-Enabled Strategy for Accessing Tetrahydropyridine
Cu-Catalyzed SF4-Alkynylation of Quinolones, Chromones and Cyclohexenones
Cobalt-Catalyzed Intramolecular Fluoroalkylative Carbonylation of Unactivated Alkenes
Visible-Light-Induced Direct Photolysis of Phosphorus Iodide Salts for Difluoroalkylation of C(sp2)–H by an Intramolecular Charge-Transfer Complex
Copper-Catalyzed Domino Bis-[3 + 2]-Annulation of Ethynyl Cyclic Carbonates with Trifluoromethyl Azlactones
Introducing N-Carboxyethyl-Ynamides, Precursors of Metalated Ketenimines: Protecting Group Swap in Ynamides and Olefination of Aldehydes
Sc(OTf)sub3/sub-Catalyzed Construction of Fused Bisindolylmethanes: Unified Access to 1,2- and 1,7-Linked Indole Frameworks
Synthesis of Densely Functionalized Pyrroles via Photoinduced C-Insertion into N-Alkylenamines: Sequential C(sp2)–H/C(sp3)–H Activation with Bromine Radicals
From Refrigerant to Reagent: Repurposing HFC-125 into Inorganic and Organic Fluorinating Agents
Bis(sulfone) as Bifunctional Reagent for the Alkylarylation of Alkenes and Alkynes under Photoredox Conditions
Exploring Pd-Catalyzed Hydrocarbation of Allenes: Focusing on Propa-1,2-diene for the Isopropenylation of C(sp2) Halides
Regiodivergent Addition of Allylic Acetals in Ruthenium-Catalyzed C–H/N–H Annulation Reaction
Organophotoredox Dioxygenation of Alkenes via ROH···F-Activated N-Alkoxyphthalimides
Total Synthesis of Honokiol via Oxidative Phenol Coupling
Complete Supramolecular Encapsulation of Paraquat for Detoxification
Palladium-Catalyzed Cross-Couplings of Aryl Thianthrenium Salts with N-Tosylhydrazones for the Synthesis of 1,1-Diarylalkenes
Bidirectional Synthesis of C2-Symmetric Unilateral Substituted Acenes: 1,10,11,12-Tetrafluorotetracene
Remote meta-C–H Functionalization of Baylis–Hillman Adducts
Nickelaelectro-Catalyzed Glycosyl-Donor Activation Enabling α-C-Alkenyl Glycoside Assembly
Easily Separable Racemic and Meso Isomers of a Salen-Based Cryptophane for Selective Guest Binding
Stereocontrolled Divergent Total Syntheses of (+)-7-Deoxypancratistatin, (+)-7-Deoxy-trans-dihydronarciclasine, and (+)-Lycoricidine via Cyclic Boronic Ester-Mediated Diastereoselective Alkenylation
Rapid Alternating Polarity as an Approach for Electrocatalytic Synthesis of Remote meta-C–H Alkenylation
Catalytic Base-Induced Trifluoromethylation of Selenosulfonates and Beyond
Cobalt-Catalyzed Methylselenation of Boronic Reagents with PhSO2SeCH3
N-Selective Difluoromethylation of 4-Hydroxyquinolines
Synthesis of Bicyclo[n,3,0]alkanes and Aza-Bicyclo[n,3,0]alkanes by Phosphine-Mediated Domino Reaction of Enones with Morita–Baylis–Hillman (MBH) Carbonates
Synthesis of α-Substituted β,γ-Unsaturated Cyclobutanecarboxamides via Palladium-Catalyzed Aminocarbonylation of Vinylcyclobutanols
Visible-Light-Induced CdSeS/CdZnSe/ZnSe/ZnS Quantum-Dot-Catalyzed Three-Component Reaction for the Synthesis of α-(4-Pyridyl)benzylaniline Derivatives
Synthesis and Photophysical Properties of Cyclic Homodimer of U-Shaped Dibenzophenazinylene
Synthesis of Oxindole Spiropyrrolidines Based on [1 + 1 + 1 + 2] Spiroannulation Featuring Release and Reuse of Me2NH
Cross-Electrophile Sulfonylation Involving Morita–Baylis–Hillman Acetates and Alkyl Halides: Access to Allyl–Alkyl Sulfones
Construction of Pyridine-Fused Azacorroles through Multicomponent-Coupling Strategy
Synthesis of the Tetracyclic Core of the Daphlongeranines
Cascade C–H Halogenation of Tetraazapyrene with Iodine Halides
Rh-Catalyzed C–H Activation, [5 + 2] Cycloaddition/Oxidative for the Synthesis of Highly Functionalized Benzo[f]pyrazolo[1,5-a][1,3]diazepin-6-ones
A Tsuji–Trost Reaction Using Free Carbenes as Nucleophiles: Palladium-Catalyzed Photoinduced Coupling of Acylsilanes with Allylic Alcohol Derivatives
Deaminative Functionalization of Olefins and Dienes with Katritzky Salts: A Highly Selective Route to Diverse Deuterium-Labeled Molecules
Electrochemical Decyanative Carboxylation of Cyanoaromatics with CO2 Leading to Aryl Carboxylic Acids
Electroreductive 1,4-Hydro(deutero)arylation of 1,3-Enynes Enabled by Terephthalonitrile: Entry to Trisubstituted Allenes
Regiodivergent Deuteration of Pyridine-Based Heterocycles
Total Synthesis of (±)-Larutienine B and (±)-Melokhanine B, D, E, F, and H
Divergent Synthesis of Eudesmane Sesquiterpenoids
Modular Iminophosphorane as Hydrogen Atom Transfer Catalyst for Selective C(spsup3/sup)–H Functionalization
Visible-Light-Mediated Cascade Construction of Polysubstituted Naphthalene Scaffolds from 2-Methylbenzophenones and (Trifluoromethyl)alkenes
Photocatalytic 1,4-Carbocarboxylation of 1,3-Enynes with CO2
One-Pot Synthesis of Sulfilimines from Sulfenamides Using Aldehydes as an Alkyl Source
Synthesis of Neokotalanol and Its Derivatives as Potent α-Glucosidase Inhibitors
Synthesis of 3-Alkenyl Isoquinolines through Redox-Neutral C–H Annulation of Oximes with Alkylacetylenes followed by Dehydrogenation
Diversity-Oriented Synthesis of Spirocyclopentadiene Oxindoles and 2-Acyl Cyclopenta[b]indoles via Intramolecular Wittig Reaction
Asymmetric Synthesis of Benzofused N-Bridged [3.2.1] Skeletons via Bifunctional Phosphonium Salt-Catalyzed Annulation
Photoinduced and Thiophenolate Anion-Enabled Functionalization of Aryl Halides via Catalytic Electron Donor–Acceptor Complex
Synthesis of Dibenzo[a,c]phenazines through Brønsted Acid-Catalyzed Skeletal Editing of 2-Arylindoles with 1,2-Diaminoarenes
Brønsted-Acid-Promoted Diaza-Nazarov Cyclization to Access Tetrasubstituted Pyrazoles
cis and trans Forms of Near-Infrared Diazaborepin Frameworks with Two Tetracoordinate Boron Atoms
Synthesis of Sulfondiimidoates by Desoxychlorination of Sulfonimidamides
Harnessing gem-Diboron Radicals: A Ni-Catalyzed Reductive Coupling Platform for Diverse sp3-Rich Molecular Architectures
Photocatalytic Ring-Opening/1,3-Peroxyesterification of Arylcyclopropanes with Carboxylic Acids and tert-Butyl Hydroperoxide
Energy-Transfer Excitation of Dibenzothiophene S-Oxide Induces Oxomethylation of Styrenes
Sulfinyl-Imine-Assisted Asymmetric [3,3]-Sigmatropic Rearrangement: Generation of Tertiary and Quaternary Stereocenters
Biomimetic Total Synthesis of (±)-Lappaceolides A and B
“Green” Oxidant (Oxygen) Mediated Synthesis of N-(2-(Methylsulfonyl)ethyl)amide Derivatives Using DMSO as a Dual Synthon and Solvent
Ruthenium-Catalyzed Selective C4 C–H Phosphorylation of Indoles and Mechanistic Insights
Optimized and Scalable Synthesis of BOPYRENPY Chromophores: Access to a Seven-Membered BF2–C60 Dyad for Reactive Oxygen Species Generation
Photoirradiation-Promoted ipso-Azidation of 1-Aryltriazenes
Asymmetric Synthesis of the Pentacyclic Framework of Kopsia Alkaloids
Unified Asymmetric Hydrogenation Enables Stereocontrolled Total Synthesis of Tacaman Alkaloids
Synthetic Studies of Spiroschincarins: Construction of 1-Oxaspiro[6.6]tridecanone Skeleton with All-cis Cyclopropane Moiety
On-Resin Synthesis and Late-Stage Functionalization of Macrocyclic Atosiban Mimetics via 5-Iodo-1,4-triazoles
Anion Association and Macrocycle Encapsulation Tune the Fluorescence of N-Alkylpyridinium-Conjugated Push–Pull Thiazolothiazole Derivatives
Benzophenone[3]arene: Supramolecular Modulation of Semi-crystalline toward Crystalline Transformation
Dual-Copper-Catalyzed Enantioselective Decarboxylative [2 + 3] Cycloaddition of Ethynyl Cyclic Carbamates/Carbonates with 4-Hydroxycoumarins
Enantioselective Synthesis of 3-Iodo-4-arylcoumarinyl Atropisomers via Cu-Catalyzed Asymmetric Ring-Opening of Cyclic Hetero Diaryliodoniums
Asymmetric Dearomatization of 3H-Indoles via Copper-Catalyzed Enantioselective [4 + 1] Spiroannulation with Vinyl Ethynylethylene Carbonates
Three-Component Reaction through Rh(III)-Catalyzed Strain Release of Bicyclo[1.1.0]butanes
Oxidative Amination Ring Cleavage of Catechols for Muconic Acid Mononitriles
Dearomatization Reactions of N-OMe Ureas
Curved Nanographene Featuring Two sp3 Stereocenters via Oxidative Cyclodehydrogenation with Aryl Rearrangement
Organophotocatalytic Decarboxylative Allylation of Carboxylic Acids with Allylic Acetates
Photochemical Formal [4 + 2] Cycloaddition of α-Bromo Phenylsulfones and Acetophenones with Alkenes
Electro-Palladium-Catalyzed Asymmetric Allylic Benzylation with Electrophilic Benzylic Reagents
Humulupones A-F, Bitter Acid Derivatives from Humulus lupulus
Construction of the Tetracyclic Core of Isoabietenin A
Toward the Total Synthesis of Myrindole A: Assembly of Fully Functionalized Cyclohexenone
Strain-Relief-Driven Rearrangement of [2.2]Paracyclophane Derivatives in the Synthesis of Biarylophanes
Photoinduced Copper-Catalyzed Radical Cascade Sonogashira-Type Coupling of Unsaturated Oxime Esters with Alkynes
Make it Double: [4]Cumulene Thermal Core Transformation and Chemical Reduction
Deacylative Polyfluoroarylation via C–C Cleavage of Alkyl Ketones
Organoelectrochemistry-Enabled Biomimetic Syntheses of Alstoscholarinoids A and B
Stereoselective Electrosynthesis of Imidazolines through Coupling and Ring Restructuring of Alkoxyoxazoles with α-Amino Carbonyls
Regioselective Formal β-C(sp3)–H Amidation of Ketones by Merging Photocatalysis and Ni-Nitrenoid Transfer
DiazaChrysenes (DC): Nitrogen-Containing π-Extended Molecules for Photocatalytic C–H Amination
Chemoenzymatic Decarboxylative Bromination of Acetylenic Acids Using Vanadium-Dependent Chloroperoxidase
Tropone-Enabled Pd-Catalyzed C(sp2)–H Functionalization of Phenylalanine: Switchable Access to Indoline and Olefinate
4-Nitrophenyl Sulfamates as Precursors Containing Acid-Labile Functional Groups for Sulfamidation with Weakly Nucleophilic Amines
Halophosphonium Salts-Mediated Photochemical C(sp3)–H Functionalization
Catalyst-Controlled Switchable Mono-/Di-C–H Arylation of Aromatic Amides with Arylsilanes
Two Cationic Antiaromatic Free-Base Corroles
Intermolecular Double C–H Annulation via 1,4-Pd Migration: A Modular Strategy for Heteropolycycle Construction
Beyond Friedel–Crafts: Spontaneous and Fluoride-Catalyzed Acylation of 2-(Trialkylsilyl)pyridines
Visible-Light-Induced Palladium-Mediated Allylic C–H Alkylation Reaction
Palladium-Catalyzed Synthesis of Quinolinyl Lactones via Double C(sp3)–H Functionalization
Electrochemical Formal (3 + 2) Cycloaddition/Imidation Cascade: Easy Access to Triazabicyclo-[3.3.0] Scaffolds
Pd/C-Catalyzed Hydrocarboxylation and Carbonylative Esterification of Indoles to Indole-3-carboxylic Acids and Esters
Diversifiable Total Synthesis of Pleurotin Natural Products through Alternative Endgame Strategies Enabling Unprecedented C7/C8-Axial Functionalization
Radical Addition-Induced Dearomative Spirocyclization/1,4-Alkyloximation of Unactivated Arenes
Modular Access to Sulfondiimidoyl Fluorides by NaH-Mediated Fluorination of Sulfenamides
Aryl-Alkenylation and Aryl-Iodination of Strained C–C σ Bonds via Palladium Photoredox Catalysis
A Silicon-Doped Nanographenic Bowl for Supramolecular Assembly with Fullerenes
Bioinspired One-Step Oxidative Cleavage of Paxilline Enables Rapid Generation of Indole Diterpenoid Derivatives with Antibiofilm Activity
Photoexcited Palladium-Catalyzed C–N Bond Formation: A Unified Approach for N-Arylation of NH-Sulfoximines
Palladium-Catalyzed Suzuki–Miyaura Couplings of Glycal Boronates with Aryl Thianthrenium Salts for the Synthesis of C-Aryl Glycals
One-Pot Construction of Polycyclic Indoles through Temperature-Dependent 1,3-Dipolar Cycloaddition and Cascade Rearrangement
Visible-Light-Driven [2+2] Cycloaddition of Coumarins with Diverse Olefins Using a 4CzIPN Photosensitizer: Application to the Total Synthesis of (±)-Lindleyanin
Distahlianins A–C: Architecturally Diverse Cadinane-Type Sesquiterpenoid Dimers from Stahlianthus involucratus
Enantioselective N–H Insertion of Sulfonamides: Access to Chiral α-Aminoesters
Multicomponent Synthesis of Isoquinuclidines via Pd-Catalyzed Selective Dechlorination
Biomimetic Total Synthesis of Sarglamides A, B, C, Unnatural–Natural Sarglamide G, and Their Enantiomers
Asymmetric Dearomative Hydrofunctionalization of Enyne-Tethered Biaryls Via Pd(0)/Chiral Phosphoric Acid Co-Catalysis
Minisci-Type Reaction Enabled by Copper-Mediated Radical-Coupling: Photocatalytic C2-Selective C–H Bis(trifluoromethyl)carbinolation of Quinolines
The Application of Trifluoroacetic Acid in the Minisci Silylation of Heteroarenes
Lewis Acid-Assisted Formal C═S Insertion of Thioindolinones to Bicyclobutanes: Diastereoselective Access to Trisubstituted Cyclobutanethiols
Synthesis of a Phosphate-Bridged Photoaffinity Labeling Probe via Transesterification of Phenols and Alcohols
Multicomponent Assembly of 1,2,3-Dithiazole-5-thiones via Triple Sulfur Donor Integration
Light-Mediated Ring-Opening Functionalization of Epoxides via a Fluorinated Thiolate Mediator
Copper-Catalyzed Remote C(sp3)-H Sulfoximination and Silylation of N-Fluorocarboxamides
Sterically Controlled C(sp2)–H Carboxylation and Formylation: A Complementary Strategy to SEAr Approaches
Synthesis of α-Trifluoromethyl Pyrroles by Formal [3 + 2] Cycloaddition of Vinyl Carbenes and Nitriles
Light-Mediated Tandem Giese/C–H Functionalizations Toward Cyclopenta[b]indoles
Easy Access to Vinylene-Linked Conjugated Homopolymers from Phosphonates via an O2-Mediated Aldehyde-Free Strategy
Visible-Light-Mediated Three-Component Minisci-Type Reaction of 4-Cyanopyridines
Furan Silylethers: Access to Functionalized (Hydro)quinones and Polycyclic Aromatics for Optoelectronic Applications
Safety Letter: Evaluation of the Popular Oxidant 2-Iodoxybenzoic Acid (IBX)
Development of a Cationic Cascade Trailing into Piancatelli Rearrangement En Route to Skeletally Diverse Polycyclic Frameworks
Synthesis of Diazatricyclic Molecules via Intramolecular Cycloaddition of Azomethine Ylides
A Cupin Epoxidase Catalyzes Epoxycyclohexenone Formation in Fungal Meroterpenoid Biosynthesis
Enantioselective Synthesis of N-Cyclopentenyl Sulfoximines via the Catalytic Asymmetric Aza-Piancatelli Reaction
Stereodivergent 3,4-Hydroalkoxylation of 1,3-Dienes Via Dual Photo and Copper Catalysis
Diastereoselective Iron-Catalyzed [4 + 1] Cycloadditions of Imines with Sulfoxonium Ylides Enable Modular Synthesis of Oxazolidin-2-ones: O- versus N-Nucleophilic Attack
Reaching the Limit of Inverted Solvatochromism in π-Extended Bipyridinium-Phenolate Dyes
1,3,5-Triazine-Mediated Electrochemical Carboxylation of Aryl Thianthrenium Salts with CO2
One-Step Radical α–α Coupling Accesses Helical Near-Infrared 3-Pyrrolyl Boron Dipyrromethene Dimers
Conformationally Preorganized Cage Enables Enhanced Anion Binding in Water
Synthesis of N,O-Bidentate Difluoroboron Complexes via Iodide-Promoted Demethylative Borylation
Visible Light-Mediated Syntheses of γ-CF3 Pyridines via 1,2-Radical Migration
Synthesis of a Face-to-Face Porphyrin Nanoring
Direct S-Azidomethylation of Thiols with N-Azidomethyldisulfonimides
Umpolung Approach for the α-Alkylation of Benzylic Amines Enabled by Superelectron Donors
An Approach to Aliphatic Sulfonyl Fluorides
Copper-Catalyzed Coupling of N-Acyl-N′-Substituted Hydrazines with (Hetero)aryl Chlorides/Bromides
Aldol Condensation of Bis(pentafluorophenyl)boron Enolates for the Synthesis of α-Pentafluorophenyl-Substituted α,β-Unsaturated Carbonyl Compounds
Thioesterification of Polyfluoroarenes via Copper-Catalyzed Radical Cross-Coupling with K2S and Aldehydes in Water
Trifluoromethylborylation of Unactivated Alkenes via an Electron Donor–Acceptor (EDA) Complex
Decarboxylative Pyrazolylation of Aryl Carboxylic Acids via Synergetic Organic-Photoredox and Copper Catalysis
Regioselective Dual Gold/Silver-Catalyzed C3–H Alkynylation of Triazolopyridazines
Photoredox/Cobalt Cooperative Catalysis for Cycloisomerization of 1,6-Enynes
Visible-Light-Induced Cascade Annulation of N-Cyanamide Alkenes with Unsaturated α-Halogenocarbonyls
Enantioselective Total Synthesis of (+)-Lucidumone via Organocatalytic Double Michael Addition
Photoredox-Catalyzed Dearomatization of Indoles with Amines: An Approach to Highly Strained Polycyclic Indolines
Photosensitized Radical-Mediated 1,n-Trifluoromethylthioamination of Alkenes with Bifunctional Benzophenonoxime S-(Trifluoromethyl) Thiocarbonate
Enantioselective Construction of Fused N-Heterocycles via Sequential Annulation and Catalytic Transfer Hydrogenation
Lewis Acid-Catalyzed Direct Conversion of Carboxylic Acids into Primary Amides and Nitriles Using Bis(trimethylsilyl)amine
Integration of SuFEx and Sonogashira Cross-Coupling for the Synthesis of Structurally Diverse Aryl Acetylenes on DNA
Scalable Solvent-Free Synthesis of a Linear Heteroaromatic Trimer with Crystallization-Induced Phosphorescence
Isoxazoles to Multisubstituted Thiazoles via an Ammonium Iodide-Catalyzed Formal [3+2] Cycloaddition Reaction
Photoredox Catalytic Synthesis of Indoles via Direct N–H Activation to Generate Putative Aminyl Radicals
A Design for Achieving Robustness in Molecular Machines Based on Self-Assembled Pyrene Cavitands
Visible Light-Driven Benzylic C(sp3)–H Carboxylation Enables Synthesis of 13C-Labeled (±)-α-Amino Acids with 13C-Formate
Asymmetric Synthesis of Cycloartobiloxanthone
Stereoselective Synthesis of α-Aminophosphonates and Their Derivatives via Asymmetric α-Azidation of the CAMDOL-Derived Phosphonates
Light-Promoted C(sp3)–H Functionalization: Alkyl Amines as C2 Synthons in Formal [3+2] Cycloaddition with N-Imino(iso)quinolinium Ylides
Pyrrole-Fused Aza-Nanographene with Two Gulf-Edge Regions as Flexible Sites
Ligand-Controlled Stereodivergent Hydroalkynylation of Purine Allenamines to Access Functionalized trans- and cis-1,3-Enynes
Diverse Ring Opening and Annulation Catalyses of Isoxazole To Construct Valuable Functionalized Pyrroles, Pyridines, and Nicotinamides
Ni-Catalyzed and Pentafluorobenzoate-Leaving-Group-Enabled Stereoselective C-Aryl Glycosylation
NaBr-Mediated Electrochemical Hydration of Alkenes: A Minimalist Synthesis of Anti-Markovnikov Alcohol
Base-Promoted Synthesis of Triazenes via Formal Substitution of Arylazo Sulfones with Amines
HFIP-Mediated Ring Opening of Bicyclo[1.1.0]butanes with Hydroperoxides for Diastereoselective Access to Peroxycyclobutanes
Total Synthesis of Passifetilactone D, Cryptorigidifoliol I, and Cryptorigidifoliol B Isomers Enabled by Ghosez Lactonization
Palladium-Catalyzed Asymmetric Aminomethylative Pyridonation of Conjugated Dienes
Access to Branched 1,3-Dienes via Innate C(sp3)–H Functionalization of 8-Methylquinolines
Conformationally Restricted Amino Cyclopropane-Fused Lactones from Mannich Bases
Manganese-Catalyzed Synthesis of γ-Hydroxy Phosphine Oxides by Addition of Phosphine Oxides to Allylic Alcohols
Metal-Free, Regiodivergent N-Alkylation of 1H-Indazoles Enabled by Brønsted Acid Catalysis
C2-Benzylic C(sp3)–H Alkylation of Indoles Enabled by Photoinduced, EDA-Complex-Mediated Radical–Radical Cross-Coupling
Copper-Catalyzed Selective 1,2-Reduction of Quinolines
Calix[n]azanediyldibenzoate: Intramolecular Hydrogen Bond-Assisted Synthesis, Acidichromism, and Oriented Self-Assembly
De Novo Design and Asymmetric Synthesis of a C-1/2 Benzodioxin Fused Glycoside Analogue of Lincomycin
Organophotoredox Cascade Cyclization for the Synthesis of Silyl/Fluoroalkylated Tetracyclic Pyrrolizidinediones
Asymmetric Total Synthesis of (+)-Spiroapplanatumine G
Iodine-Promoted Ring-Opening α,β-Difunctionalization of Cyclopropanols with Enaminones: A Selective Route to 2,4-Diacylpyrroles
NiII and CuII Complexes of 5-Oxa-, 5-Sulfa-, 5-Selena-, and 5-Telluracorroles
Photocatalyst-Free Visible-Light-Induced Decarbonylation/Truce–Smiles Rearrangement Cascade to Access 2-Aminobenzophenones
Photochemical Flow Synthesis of Trisubstituted Oxazoles Enabled by High-Power UV–B LED Modules
Anti-Bredt-Like Triterpenoids from Mycelial Cultures of the Edible Mushroom Oudemansiella cf. canarii
Iron-Catalyzed Decarboxylative Sulfinylation of Alkyl Carboxylic Acids
Photocatalytic Synthesis of 1,2-Sulfinate-Sulfonate Esters by Four-Component Radical-Polar Crossover Cyclization
Structurally Flexible (Thiazol-2-ylidene)Pd(Allyl)Cl Complexes for Suzuki–Miyaura Cross-Coupling of Aryl Halides and Amides
Iron(III)-Catalyzed Methanesulfonic-Acid-Mediated [3 + 2 + 1C] Annulation of Enaminones with 1,3-Dioxolane: Access to 2-Hydroxy-1,2-dihydropyridines
Exploring the Radical Addition to Sydnones: A Gateway to Perfluoroalkyl-Substituted Pyrazoles
Palladium-Catalyzed Synthesis of Amino β-Lactones Using Aryl Amines and Alkenyl Carboxylic Acidss
Transition Metal-Free γ-C(sp3)–H Functionalization of Enaminones for Methylene 1,2-Dihydropyridine Synthesis and Application in Fused Tricyclic Pyrido[1,2-a]indole Construction
Organic Photoredox Catalytic Functionalization of Alkynones To Acess Heterocycles Containing 1,4-Dicarbonyl Structures and 3-Thioarylated Thioflavones
Manganese-Catalyzed Asymmetric Hydrogenation of Multi-Nitrogen Heteroaromatic Compounds
B(C6F5)3-Catalyzed Coupling of N-Alkyl Arylamines and Alkenes for the Synthesis of Tetrahydroquinolines
Regioselective Divergent Benzannulations of Vinyl Sulfoxonium Ylides with Electron-Deficient Alkynes
Biomimetic Oxidation of Disulfides for the Synthesis of Sulfonyl Fluorides and Primary Sulfonamides Catalyzed by Copper/Lewis Acid
Domino Grignard Addition/Cope–House Reaction for the Synthesis of Polyhydroxylated 3-Methylindolizidines Analogous to Castanospermine
Dearomative Cyclization of Ynamides toward the Formation of Fused Diazabicycles
Visible-Light-Driven C-3 Selenocyanation of Indoles with Elemental Selenium and TMSCN
Directed Secondary C(sp3)–H Borylation by a Phenoxyimine Iridium Catalyst at Room Temperature
Cu-Catalyzed Desaturation-Relay Imidation of 2-Piperidones
Effects of π-Extended Aromatic Fragments on Tris(hexa-peri-hexabenzocoronenyl)methyl Radical and Cation: Synthesis, Radical Transformation, and Reactivity Insights
Bench-Stable Copper Complex for Trifluoromethylation and 18F-Labeling of Aryl Iodides
Palladium-Catalyzed Allylic C–F Bond Functionalization of Pentafluoroethyl Alkenes with Heteroatom Nucleophiles
Fluoranthene-Containing Distorted Nanographenes Exhibiting Two-Photon Absorption Response
Divergent Synthesis of gem-Difluoro-2-oxabicyclo[2.1.1]hexanes Enabled by 1,3-Oxygen Rearrangement
Iron-Catalyzed Photochemical Defluorinative Functionalization of Polyfluorinated Aromatics
Reactivity of 2H-Azirines in Copper-Catalyzed Azide–Alkyne Cycloaddition Reactions
Photocatalytic [4 + 1] Cycloaddition Access to Multisubstituted 2-Imino-2,5-dihydrofurans
Tunable Site Selectivity and Chemo- and Regioselectivity: Diversification of Indole Alkaloid Privileged Scaffolds Enabled by λ3-Iodane-Mediated Cross-Nucleophile Coupling Cascade
A Synthesis of 4-(Hydroxymethyl)-1H-isochromen-1-one Analogs by Hydroxyl Oxetane Rearrangement in Protonic Acids
Arylthianthrenium Salts Enabled Palladium-Catalyzed Regioselective Arylation: Access to Value-Added 7-Azaindoles
Gold-Catalyzed Highly Regioselective Cage B(9)-H Alkylation of io/i-Carboranes with 1,6-Enynes
Visible-Light-Catalyzed Regioselective 1,4-Carbon/Carboxylation of 1,3-Enynes with Malonates and COsub2/sub toward 2,3-Allenoic Acids
Strain-Release Functionalization of iN/i-Aryl Bicyclo[1.1.0]butane Sulfonamides to Access Spirocyclic Sultams
Alkene Oxyamination: One-Pot Synthesis of Unprotected N–H Amino γ-Lactones
Photoactivation of Electron Donor–Acceptor Complexes for C(spsup2/sup)–H Amination of Arenes Using an Organocatalytic Acceptor
Modulation of Koelsch Radical Stability and Aromaticity through Nonhexagonal Ring Fusion
Access to Pyrrolo- and Dihydropyrrolofuranthridones via Phosphine-Mediated MBH-Type/O-Acylation/Wittig Reaction Sequence
Computationally Designed Dearomative Claisen-Type Rearrangement of a Benzyl Alkynyl Ether and Cascade Reaction To Provide a Dihydroindenone
Copper-Catalyzed Electrophilic Amination of Aryl and Pyridylzinc Pivalates Mediated by N-Based Hypervalent Iodine(III) Reagents
Synthesis of Indole-Fused Bicyclo[3.1.1]heptanes through (3+3) Cycloaddition of 2-Indolylmethanols with Bicyclo[1.1.0]butanes
Development of a HAT Reagent for the Decarboxylative Thiocyanation of Aliphatic Carboxylic Acids
Photoinduced Amination of Endocyclic 1-Azaallyl Radicals
Oxidative Chloro- and Bromodifluoromethylation of Thiophenols
Photo/Copper-Catalyzed Sulfinamidation of Arenes and Alkenes
Site-Selective C–H Mono- and Bis-Thianthrenation of Polycyclic Aromatic Hydrocarbons
Synthesis of Nanographene-Fused Carbaporphyrin(2.1.0.1) and Its Organopalladium(II) Complex
Visible-Light-Driven Photoredox-Catalyzed Radical Cyclization via a TEMPO-Intercepted Cascade: Regioselective and Access to Cyclopentene Skeletons
Iron-Catalyzed Radical Addition Reaction of Dehydroglycine with Aliphatic Carboxylic Acids
meta-Substituted Diaryliodonium Salts Enabled Aryne 1,2,4′-Trifunctionalization
Diastereoselective Synthesis of iN/i-Glycosides via Buchwald–Hartwig Coupling
Visible-Light-Induced sp3 C–H Functionalization of Alkyl Amines toward Tetrahydroquinoline Spiro[5.6] Compounds
Nickel-Catalyzed Carbonylative Cyclization of Bromodifluoroacetamides with Arylboronic Acids toward δ-Lactams
Photoinduced EDA Complexes Enabled C3 (Hetero)arylation of Indoles Using Amine as a Transient Occupying Group
Chemoselective Benzylic C–H Deuteration Using Deuterium Gas
Cooperative Copper/Eosin Y-Catalyzed Photochemical Oxidative Coupling Reactions of Indolines for the Synthesis of 1,5′-Biindoles
Photoinduced Asymmetric Dearomative Hydroalkylation of Electron-Deficient Indoles with Alkyltrifluoroborates
Construction of Fused Polycyclic Skeletons via Palladium-Catalyzed Dearomatization of Naphthalenes and Benzenes
Kinetically Controlled aza-Michael/Epimerization Cascade Enables a Scalable Total Synthesis of Putative (i+/i)-Fumigaclavine F
A Visible-Light Organophotoredox-Catalyzed ianti/i-Markovnikov Hydrocarbamoylation of Unactivated Alkene and Cyclization Cascade via Radical Relay
iDe Novo/i Construction of Highly Substituted Chromones and Benzo[ib/i]furans via a Switchable Transformation of 3-Alkynyl-4-pyrones with Active Methylene Compounds
Photocatalyzed C(spsup3/sup)–N Bond Activation of Isonitriles for Mizoroki–Heck Cross-Coupling with Vinyl Arenes
Chiral Phosphoric Acid-Catalyzed Asymmetric Doyle Indolization: Enantiodivergent Access to Indolizinylindoles
B2pin2-Enabled Nickel/Brønsted Acid Relay-Catalyzed Reductive [2+2+2] Cycloaddition: Facile Access to Unsymmetric Pentacyclic Pyridine Derivatives
Synthesis of Pandaroside D from iPandaros acanthifolium/i via Construction of a Rare Enone System in the Steroid D Ring
Late-Stage Pyridination via Pd-Catalyzed Transformation of Arylthianthrenium Salts
Asymmetric Total Synthesis of Leptosphin C
Palladium-Catalyzed Denitrative Sulfoximination of Nitroarenes
Mild Direct Single-Step Conversion of Propargyl Amines to Highly Substituted 3-Pyrrolin-2-ones
Irradiation of Bifunctional Masked Ketone Pro-Aromatics Unveils Autoinductive Autocatalysis via Electron Donor–Acceptor (EDA) Complexes
Copper-Catalyzed Enantioselective Reduction of Biaryl Dialdehydes via Bora-Brook Rearrangement
Synthesis and Enantioselective Recognition of Chiral Macrocycles with Abundant Binding Sites
Pillarureaarenes: Urea-Embedded Pillararenes for Amino Acid Derivative Recognition
Oxygenative Amidation of Metal Carbynoids via Pd-Catalyzed Three-Component Reaction of Alcohols, Imines, and α-Bromo Diazoacetates
Stereoselective Fluoro-Deuteration/Chalcogenation/Halogenation of gem-Difluoroallenes (DFAs)
Strategic Leverage of β-OH Elimination for Catalytic Assembly of Alkylidenecyclopropanes
Catalytic Enantioselective Synthesis of Oxazolines with Vinylogous Isocyano Esters
Radical 1,2-Boron Shift-Enabled Synthesis of β-Thioalkylboronic Esters from β-Boryl NHPI Esters
Copper-Mediated C4–H Sulfonylation of Indoles via a Transient Directing Group Strategy
Synthesis of Indoloazepinone Scaffolds Using Sequential Photochemical and Photocatalytic Reactions
Alectinib Synthesis through Formal α-Arylation of Enone
Construction of Acyclic Vicinal All-Carbon Quaternary and Tertiary Carbon Stereocenters via a Stereoselective Claisen Rearrangement
A Quadruple Relay Approach Toward Highly Functionalized Furans: Merging Carbene Insertion, Semi-Pinacol Rearrangement, Decarbonylation, and Paal–Knorr Cyclization
Synthesis of 2-Aminodihydrobenzofurans through Copper-Catalyzed iN/i-Alkenylation/[3,3]-Rearrangement of Aryloxyamines with Alkenyl Boronic Acids
Visible-Light-Driven Photocatalytic Cascade Multioxidation: A Route to α-Sulfinylphthalides
Rhodium(III)-Catalyzed C–H Activation/Annulation of Indoles with Cyclopropanols: A Rapid Assembly of Indole-Fused Diazepinones
A Dual Functional Molecular Tweezer: pH-Driven C60 Capture/Release and Ba2+ Selective Recognition
Dual Copper/Photoredox Catalysis: Photoreductive 1,4-Dicarbofunctionalization of 1,3-Enynes with Dibenzothiophenium Salts and Trimethylsilyl Cyanide
Naphthylpyridyl–Cu(II)-Catalyzed Oxidative Coupling of 2-Naphthylamines to Access BINAM Derivatives
A Unified Photocatalytic Strategy for Fluoroalkylated and Cyanated α-Tertiary Amino/Glycolic Acids via a Radical-Polar Cascade
Electrochemical Hydroarylation of Alkenes To Access Dihydroquinazolin-4(1iH/i)-ones
On-DNA Synthesis of Privileged Dihydropteridinones via Diboron-Mediated Cyclizations
Catalytic Atroposelective Coumarin Alkenylation
Ligand-Enabled Room-Temperature Three-Component Strategy for Mono-α-arylation of Acetone with Cyclic Diaryliodonium Salts and Alkenes
Mild Cu-Catalyzed Nitrogen–Iodine Exchange Strategy for the Synthesis of Non-Symmetric iN/i,iN′/i-Bicarbazole Scaffolds Using Cyclic Iodoniums
Copper-Catalyzed Selective C(sp3)–H Esterification Using Azidobenziodoxole Derivatives as the Mediator
A Synthesis of the Carbon Skeleton of Erectcyanthin C
Büchner Ring Expansion/Isomerization: Photoactivation of Imide-Annulated N-Heterocyclic Carbenes Affords Vicinal Diamino Cycloheptatrienes
A Thermal [2+2] Cycloaddition/Retro-4π-Electrocyclization Reaction of ip/i-Quinone Methides with Alkyne and a Mechanistic Investigation: Ingress of a Vinyl Fuchsone Pharmacophore
Photocatalytic Smiles Rearrangement at Remote C(spsup3/sup)–H Bonds
Visible-Light-Induced α-Trifluoromethylation of Unactivated α,β-Unsaturated Carbonyl Compounds: Pyruvic Acid as an Additive
Palladium-Catalyzed Carbonylative Fluoroalkylation of 1,3-Enynes to Access Allenyl Primary Amides
Photochemical Copper-Catalyzed Reductive Arylation of Nitroarenes with Arylboronic Acids
Palladium-Catalyzed Cycloisomerization of Bicyclobutyl (BCB) Amides to Access Polycyclic Quinolinones
Electrochemical [2+2+1] Dimerization Annulation of Styrenes and TMSNsub3/sub via Schmidt Rearrangement: Direct Access to 1-Pyrrolines
Ring Expansion Strategy toward Seven/Eight-Membered 1,4-Diazaheterocycle Ketones from Imidazolidines with Cyclobutenones/Diarylcyclopropenones
Synergistic Organophotoredox and Copper Catalysis Enabling the Difluoromethylation of Alkyl Bromides
Decarboxylative Fluorination Catalyzed by Pyridine-Containing Charge-Transfer Complex
One-Pot Multicomponent Synthesis of 2-Amino-3,4,6-triarylpyridine
Palladium-Catalyzed Late-Stage Maleimidation of Phenylalanine-Containing Peptides
Modular α-Functionalization of Bowl-Shaped Subphthalocyanine Aromatics
Arylboration of Cyclic Enones via Cooperative Copper/Palladium Catalysis
Photocatalytic Alkene Hydrofunctionalization with Benzoic Esters of Fluorinated Alcohols Mediated by Tin(II) Chloride
Enantioselective NHC-Catalyzed Annulation via Umpolung for the Construction of Hydroxylamine Architectures with Variable Ring Sizes
De Novo Synthesis of Oligofurans via Copper-Catalyzed Dimerization of Ethynylethylene Carbonates
Iodine(III)-Mediated Cyclization Cascade of Diynes to Benzofulvene Derivatives
Umpolung C–N Bond Formation Enabled by Rhodium-Catalyzed Arylation of Sulfilimines with Arylboronic Acids
Cobalt-Catalyzed Bicycloaddition of Alkynes with Conjugated Trienes Yielding Bicyclo[3.2.1]octadienes
Noncovalent Interactions in the Palladium-Catalyzed Diastereo- and Enantioselective Hydroalkylation of Alkoxyallenes with 2-Acylimidazoles
Balz–Schiemann-Type Oxidative C(spsup3/sup)–H Fluorination of Alkanes and Alkylarenes
Naphthyl-Separated Stone–Wales Defect-Type Nanographene via Scholl Cyclization of Tetra(1-naphthyl)naphthalene
Nickel-Catalyzed Intramolecular Direct Arylation of Cyclopropanols: Synthesis of Indanones
Intermolecular Synthesis of Coumarins from Acid Chlorides and Unactivated Alkynes through Palladium Catalysis
gem-Difluoroalkenes as C1 Building Blocks: Iron-Catalyzed Synthesis of Trisubstituted 2-Aroyl-1,3,5-Triazines
Copper-Catalyzed Enantioselective ε-Site Yne-Allylic Amination
Total Synthesis of (−)-Steganacin via Stereocontrolled Atroposelective Intramolecular Mizoroki-Heck Reaction and Evaluation of Biological Activity
Access to Tetrahydropyrido[1,2-a]indol-6-one Derivatives via NHC-Catalyzed Radical Dearomatization of Indoles
One-Pot Three-Component Reaction for the Synthesis of 3-Sulfonyl-2-aminopyridines
Silver-Catalyzed [3 + 2] Annulation of 2iH/i-Azirines and CFsub3/sub-Imidoyl Sulfoxonium Ylides: Access to CFsub3/sub-Substituted 1iH/i- and 2iH/i-Pyrroles
Fold-in Synthesis of an Ovalene Analogue Composed of Four Peripheral Amide Linkages
Alkyl Sulfinate Anion-Mediated Hydrosulfonylation of Alkenes/Alkynes via SO2 Insertion: Access to Alkyl Sulfones
DAST Enabled Synthesis of Fluorinated Amides and Fatty Acid Amides Including Drugs under Ambient Conditions
Modular Construction of a Three-Layered π-System Using Cruciform Azaacene Dimers
Formal α-Nucleophilic Addition to Electron-Deficient Alkenes by Photoredox and Copper Dual Catalysis
Isolation of a Transition-State Geometry via Intermolecular Stabilization in the Solid State
A Catalyst-Free Approach to Cyclic Sulfides via Tandem Nucleophilic Substitution and Intramolecular Thiosulfonylation
Iridium-Catalyzed Regio- and Enantioselective C7-Allylic Alkylation of 4-Aminoindoles
Photoinduced Ligated Boryl Radical-Mediated Alkynylation of Inert Iodoalkanes
Light-Mediated Binaphthyl Enhanced [2 + 2] Dearomatization of Heterocycles via an Energy-Transfer Process
Phosphine Oxide-Induced Strong Emission and Multistimuli-Responsive Fluorochromism of o-Carborane-Based Luminogens
Synthesis of a Highly Luminescent Pyrrole-Fused Dicorannulene as a Corrugated π-Extended Carbazole
Asymmetric Nickel-Catalyzed Denitrogenative Transannulation to Construct Axially Chiral C–N Atropisomers
Photocatalytic Aminative Suzuki–Miyaura C(sp2)–N–C(sp3) Cross-Coupling
Addition of Organometallic Reagents to an Episulfoxide Delivers Sulfenate Anions: Modular Synthesis of Sulfoxides and Sulfinamides
Inherent Weakly Coordinating Oxo-Group-Directed Ruthenium(II)-Catalyzed C5 Functionalization of 2-Arylquinolin-4(1H)-ones
Unified Enantioselective Synthesis of 5-Phenylmorphans and cis-Octahydroisoquinolines
Adaptive Cyclooctatetrathiophene-Tetrazine Macrocycles: Efficient Synthesis, Structures, and Fullerene Recognition
Cu(I)-Catalyzed Tetradehydro-Diels–Alder Reaction of Enediynols: Modular Assembly of Multi-substituted Fluorenols
Deaminative Cyanation of Anilines by Oxylanion Radical Transfer
Acid-Promoted Cyclization of N,N-Disubstituted Malononitriles with Substituted Propiolaldehydes: A Metal-Free Strategy for the Construction of 3-Dicyanovinylindoles
Synthesis and Mechanistic Study of Unsymmetric Dibenzo[d,d′]thieno[2,3-b;4,5-b′]dithiophenes from 1-Haloethynyl-2-halobenzenes
DNA-Compatible Synthesis of Pyrrolidine-Fused Scaffolds via a One-Pot Three-Component Cycloaddition Strategy
Asymmetric (4 + 2) Cyclization of γ-Substituted Propargyl Carboxylates with o-Quinone Methides Catalyzed by Chiral Tertiary Phosphine
Switchable Divergent Synthesis of Cyclopropane Scaffolds Enabled by Photoredox Catalytic Cascade
Photoinduced Diastereoselective Hydrophosphination of Cyclopropenes with Diarylphosphine Oxides via EDA Complex
Photocatalyzed Oxycarboranylation and Hydrocarboranylation of Unsaturated C–C Bonds with 1-Iodo-2-methyl-io/i-carboranes as the Synthon
Iron-Catalyzed Radical Hydrothiolation of gem-Difluoroalkenes
Organocatalytic Enantioselective Construction of Chiral Tetraarylmethanes from 4-(2-Hydroxyphenyl)benzyl Alcohols
Strategy for the Synthesis of Phenylalanine Derivatives through the Addition of Aryl Radicals to Dehydroamino Acid via Photoinduced Decarboxylation or Deboronation
Visible-Light Catalyzed Desulfurative Cyclization for Synthesis of 3-Amino-[1,2,4]-triazolo Pyridine
Enantioselective Vinylogous Michael Organocascade of COCF3-Tethered Enediones and Pyrazolinones: Access to Spiro-Fused Linear Oxa-Triquinanes
Rhodium-Catalyzed [3 + 1 + 2] Cycloaddition of Type II Diene-Vinylcyclopropanes and Carbon Monoxide for the Synthesis of 5/6 Skeletons with Two Adjacent Bridgehead Quaternary Centers
Asymmetric Total Synthesis of (+)-Shearilicine
Tetralone Formation through Visible-Light-Driven Photocyclization of Aryl Sulfoxonium Ylides with Unactivated Alkenes
Copper(I)-Catalyzed Cycloisomerization of 1H-Indole N-Tethered o-Alkynylnitroarenes to C2-Spiropseudoindoxyl Compounds
Electrochemical Conversions of Sulfinamidines into Sulfonimidoyl Fluorides
Annulation of α-Diazo Sulfonium Salts with α-Vinylanilines via a Dicationic Intermediate toward Quinolines
C–F Bond Functionalization: Controlled Didefluorination of o-Trifluoromethyl Benzylamines
Total Synthesis, Stereochemical Assignment, and Structural Revision of HA 23
Synthesis of Cyclobuta[cd]pentalenes via an Intramolecular Double Michael Addition Reaction of 1,3-Cyclopentanedione Derivatives
Visible-Light/Copper-Catalyzed Three-Component Synthesis of Unprotected β-Arylethylamines and β-Aryl Isothiocyanates via Thianthrenium Salts
NaOH-Mediated Intermolecular Cascade Cyclization Reaction of Conjugated Dieneimines with α-Halomalonates to Access Functionalized Cyclopentene Cores
Phosphine-Promoted Photoredox [3+2] Cycloaddition of Alkynes and Isocyanides
Visible-Light-Driven Photocatalytic [3+2]- and [3+2+3]-Annulation Reactions of N-[(Trimethylsilyl)methyl]phthalimide with Electron-Deficient Alkenes and Alkynes
Substantial Effects of Ring Size on the Structure and Properties of 2,9-Anthrylene Cyclic Oligomers
Copper Hydride-Catalyzed Net Hydroformylation of Unactivated Terminal Olefins
Synthesis of Azuleno[1,2,3-cd]phenalene and Its π-Extended Buckybowl Derivative
Synthesis of Tricyclic Azepine Derivatives and ε-Caprolactam-Tethered β-Diaminoacrylates and Guanidines via Reactions of DBU with Ketenimines or Carbodiimides
Synthesis of 2,5-Substituted 1,3,4-Oxadiazoles via a Tandem Reaction Involving a Cobalt-Catalyzed Carbene Transfer to iN/i-Isocyaniminotriphenylphosphorane
A Palladium-Catalyzed Cascade Double Annulation Strategy for Modular Access to Dihydrocyclopenta[b]chromenes
Base-Controlled Rhodium(III)-Catalyzed Regioselective C–H Alkylation and Annulation of 2-Arylindoles with α-Cl Ketones
Construction of the Lactone-Bridged Scaffold of Alstoscholactine through an Acid-Catalyzed Prins Cyclization/Lactonization Cascade
Seco-Prenylated Butylphloroglucinol Derivatives from Hypericum elodeoides and Their Anti-Alzheimer’s Disease Activities
Electrochemical Synthesis of Sulfonimidoyl Fluorides from Sulfenamides
A Modular Approach to Trisubstituted Chiral Piperidines
1,4-Reduction of α,β-Unsaturated Ketones Catalyzed by Tetraarylhydrophosphoranes
Photoredox Catalytic Approach for Difluoroallylation of Electron-Deficient sp3 C–H Bonds
Copper-Catalyzed Enantioselective Acylcyanation of Alkenes
Diastereoselective Synthesis of Cyclic and Spirocyclic Quaternary Carbons via Iron-Catalyzed Ring Contraction of Cyclic Ketones: A Formal Synthesis of Perhydrohistrionicotoxin
Stereoselective Synthesis of trans-3-Amino-2,2,4,4-tetramethylcyclobutanol
HFIP-Assisted Denitrogenative Radical Fragmentation Pathway of Areneazo-2-(2-nitro)propanes: Cross-Coupling of Aryl Radicals with Alkynes and Coupling Reagents
Enantioselective Propargylic Substitution of Ketone Enolates with Propargylic Alcohol Derivatives through Cooperative B/Cu Catalysis
Pyridine-N-oxide-Catalyzed N-Acylative Kinetic Resolution of Sulfoximines
Access to SCF3-Substituted Indolizines via a Photocatalytic Late-Stage Functionalization Protocol
Fluoride-Effect-Directed Catalyst-Controlled Regioselective Acylation of Carbohydrate Diols and Triols
Convergent Synthesis of Functionalized Indolines from Alkyl Aryl Tertiary Amines and Diazoesters via Visible Light-Driven [4 + 1]-Annulation Approach
Synthesis of 2-Sulfenylindoles via Palladium-Catalyzed Thiolative Annulation of Ynamides
An iS/isub4/sub-Symmetrical Multi-Macrocyclic Nanohoop Derived from a 1,3-Alternate Calix[4]arene Core
Synthesis of Cyclobuta[b]acetylindolines via Gold Photocatalysis
Nickel-Catalyzed Umpolung Allylation of Imines with Allylic Alcohols
Self-Assembled Cationic Cages for Anion Recognition in Aqueous Solution
Amide-Enabled Distal and Multiple Dehydrogenative C–H Alkynylation with Tuning Site Selectivity
BOQUIPHY: Synthesis of a Family of Unsymmetrical Difluoroboron Chromophores
Asymmetric Permanganate Oxidative Cyclization of 1,4-Dienoates Enables Direct Access to Chiral Tetrahydrofurans
Bioinspired Total Synthesis of (+)-α-Tocopherol
Silica Gel-Promoted Tryptamine-Ynamide Cyclization Strategy Enabling Total Synthesis of Elacomine
Additive-Free EDA Photochemical Arylative Trifluoromethylation of Enamides with Trifluoromethyl Benzothiazole Sulfones
Rh(III)-Catalyzed Direct C–H Selenylation/Cyclization of Benzylamines with Elemental Selenium for the Rapid Construction of Benzoisoselenazole Frameworks
Electrochemical Ni-Catalyzed α-Selective Hydrocarboxylation of Styrenes with CO2
Chiral Transient Directing Group Enabled Palladium-Catalyzed Atroposelective C–H Vinylation of Biaryl Aldehydes with Vinyl Silane
Stereoselective Synthesis of (E)-α-Bromo- and (E)-α-Iodoacrylates from Readily Available tert-Butyl Diphenylphosphonoacetate
Selectivity Control in Visible-Light-Induced Three-Component Cascade Thiolation–Difluoroalkylation of Alkynes
Camphor-Based NHC Ligands with a Sulfur Ligator Atom in Rhodium Catalysis: Catalytic Advances in the Asymmetric Ring Opening of N-Protected Azabenzonorbornenes
Visible-Light-Mediated Cascade Arylcarboxylation/Cyclization of N-Aryl/Benzoyl Acrylamide with CO2
Base-Mediated Alkylation of Pyrimidines via Sulfur Deletion
Indole Synthesis from an Alkynyl-Containing Conjugated System: Substrate Scope and Application in Total Synthesis
Cr-Catalyzed Cyclic Homoallylic 1,2-Diol Synthesis through Photoredox Direct Hydrogen Atom Transfer
NBS-Enabled Rapid Cyclization of 5,6-Diaryl Dipyrroethenes to Access imeso/i-Tetraaryl Porphycenes
Rh(III)-Catalyzed Ipso and Remote Hydroamidation of Alkenyl Carboxylic Acids to Access Valuable β-Amino Acids
Noncovalent Interaction Effects on the Acyl Radical Reaction of Bicyclo[2.2.2]octanone: Selective Formation of Rearrangement and Cyclization Products
E-Selective 1,2-Bromochalcogenation of Acetylene under Mild Conditions
Electron-Donating Boronic Salicylhydrazones as Dual-State Emissive Fluorophores for Lipid Droplet Imaging
Hypervalent Iodine(III)-Promoted Cyclization of Imidazoles with Alkenes: Divergent Synthesis of Ring-Fused Tricyclic Imidazoles Bearing Azide or Exocyclic Olefin Substituents
Iridium-Catalyzed Enantioselective Allenylic Cyanomethylation
Palladium-Catalyzed Intermolecular Tandem Difunctional Carbonylation of 1,3-Enynes: Synthesis of Fluoroalkylated Butenolides
Visible-Light-Promoted Selenylative Radical Cyclization of 2-Vinyl-N-Aryl Imines to 3H-Indoles via Oxygen Photosensitization
Enantioselective Organophotocatalytic α-Functionalization of Aldehydes with iN/i-Lactam Radicals: A Viable Strategy for the Telescoped Synthesis of Levetiracetam
Silicon-Assisted Photocatalyzed C–O Bond Cleavage: Broader Applications and Mechanistic Investigations
Ligand-Controlled Acyl and Decarbonylative Sonogashira Cross-Coupling of α,β-Unsaturated Thioesters
Electrochemical Site-Specific Dehydrogenative Hydroxyalkylation of Purine Nucleosides with Alcohols
Discovery of Diverse Seven-Membered Ring Vibsane Diterpenoids from Viburnum awabuki Utilizing a MassQL-Integrated Strategy and Their Antihepatoma Effect
Rh(III)-Catalyzed Atroposelective C–H Cyanation of 1-Aryl benzo[h]isoquinolines
Catalytic Decarboxylative Alkylation of Glycine Derivatives by Aliphatic Carboxylic Acids
Unified Photoredox-Catalyzed Aerobic Oxidative Dynamic Kinetic Asymmetric Transformation for C–N Atropoisomers Mediated by Chiral Organophosphites
Enantioselective Formal Synthesis of (−)-Aflatoxin Bsub2/sub Enabled by Pd-Catalyzed Carboetherification of 2,3-Dihydrofuran
Ruthenium(II)-Catalyzed Annulation of Vinyl Sulfoxonium Ylides with Arynes for the Rapid Synthesis of Functionalized 1-Naphthols
Strain Release Cycloadditions of 2H-Azirines: Access to Polycyclic Heterocycles
Telescoping Synthesis of γ-Lactone-Fused Indanones via C–H Activation and Rearrangement-Cyclization
Chemoselective Cleavage of N-Aryl Phthalimides through a Transamidation Reaction with Solid Sources of Ammonia
Uracil-BX: Bench-Stable Cyclic Hypervalent Iodine Reagents for Umpolung Functionalization
Sulfonium Salt-Mediated Difunctionalization of Alkynes for Access to Z-Alkenyl Phosphorothioates and Selenophosphates
Selective Acetalization in Pyridine: A Sustainable 5′-O-(2-Methoxypropyl) Protecting Group in the Synthesis of Nucleic Acid Analogs
Asymmetric Synthesis of Chiral Diamines via a Low-Loading Ir-Catalyzed Umpolung Allylation of Imines
α-Ketol Rearrangement for Accessing Tetracyclic Natural Products
Palladium-Catalyzed Decarbonylative C–H Difluoromethylation of Azoles
Nitrite-Catalyzed Stereoselective Bromocyclization to Access Tetrahydrofuran Scaffolds under Batch and Flow: An Economic and Sustainable Approach to Gram-Scale Total Synthesis of Posaconazole
Palladium-Catalyzed Substrate-Controlled Regiodivergent Hydroamination of gem-Difluoroallenes
Annulation of Enyne-Amide with Enaminone Enables Divergent Synthesis of Furo[2,3-b]pyridine Derivatives
Photochemical Synthesis of α-Substituted Vinylazaarenes Enabled by Thia-Paternò–Büchi Reactions
Bromodifluoromethyl Phenoxathiinium Salt: A Practical and Competent Reagent Enabling Visible-Light-Promoted Bromodifluoromethylation of C(sp3)–H and Alkenes
Photocatalytic Hydrosilylation of Azobenzenes with Hydrosilanes for Radical N–Si Bond Construction
Synthesis of Citrifurans A and D through Assembly of the Natural Products Citrinin and Gregatin A
Nickel-Catalyzed Direct Enantioselective Alkynylation of Alkynyl Bromide with Secondary Phosphine Oxides
Intramolecular Friedel–Crafts Arylation of Achmatowicz Rearrangement Products for Construction of 1,5-Oxygen-Bridged Medium-Sized Carbocycles
Unexpected Reactivity of Nitrones: Catalytic Insertion of CS2
Stereospecific Insertion of Cyclic Amidines into Aryl-Substituted Cyclopropanones: Access to Complex Spirocyclic Aminals
Palladium/Norbornene-Catalyzed C–H/C–H [3 + 2] Annulation of Imidazopyridines with 2-Halobenzoic Acids via Six-Membered Palladacycles
Rhodium-Catalyzed Regio- and Enantioselective Synthesis of Conjugated Enynyl Amines
Synthesis of 4-Pyrrolin-3-ones via the 5-endo-trig Cyclization of Conjugated 2-Azaallyl Radicals
The Enantioselective Total Synthesis of (+)-3-Ketobrassicicene W and (−)-Alterbrassicicene B
HFIP-Mediated Spiro-annulation of Bicyclo[1.1.0]butanes with α-Halo Hydroxamates: Access to Functionalized Spirocyclobutenes
Thermolides D and E: Total Synthesis and Stereochemical Revision
Aldehyde-Assisted Oxidative [3 + 2] Cascade Annulation of Indolecarbaldehydes with Alkynes: Access to Cyclopenta[b]indol-1(4H)-one and Spirooxindole Derivatives
Unveiling Palladium Catalysis to Access Oxepino-indole through Sequential Oxycyclization Utilizing η3-π-Allyl Reactivity
Photoinduced, Pd-Catalyzed Enantioselective Cascade Carboamidation of Dienes to Access γ-Lactams
Palladium-Catalyzed Enantioselective Aryl-thiolation of Indoles: An Approach to Chiral Thioindoline
Dual Photoredox/Ni-Catalyzed Decarboxylative Coupling of α-Amino Acids to Uridine Derivatives
An Asymmetric Approach toward the iAristotelia/i Alkaloid (−)-Penduncularine
Construction of Eight-Membered N-Heterocycles via Palladium-Catalyzed Cyclization of Allenyl Isocyanides
A Heptagon-Embedded Structural Isomer of Azacorannulene
Organocatalytic Diastereo- and Enantioselective Synthesis of Chlorinated and Trifluoromethylated Pyrrolidines Featuring a Removable Nitro Group
Zn(II)-Catalyzed Asymmetric Reactions of Aminocyclopropanes: (3 + 2) Cycloaddition with Thioketones and Ring Opening with Thioureas
Short Synthesis of the Tricyclic Core Common to Lycopodine-Like Lycopodium Alkaloids: Discovery of a Separable Pair of Keto-Enol Tautomers
Photoredox-Catalyzed Decarboxylative Nitro-Mannich Reaction
Synthesis of the Spirotetracyclic Core of the Ginkgolides via a Malonyl Radical Cascade
Synthesis of Spiro[2.2]pentanes and Vinylcyclopropanes Using Sulfones as Carbene Equivalents
Z-Selective Iron-Catalyzed C–H Alkylations with Allenes: Access to Stereodefined Olefins
Ir(III)-Photocatalyzed Stereoselective Synthesis of 2-Azadienes
One-Pot Synthesis of Alkynyl-Conjugated Phenylalanine Analogues for Peptide-Based Fluorescent Imaging
2-Arylphthalazine-1,4-diones as Nitrene Precursors for the Synthesis of Phenazine Derivatives
Electrochemically Driven Dearomative Spirocyclization of Anisole-Based Cyclopropanols: Total Synthesis of Anhydro-β-rotunol
Embedding a Planar Antiaromatic Cyclooctatetraene into a Truxene-Derived Polycyclic Aromatic Hydrocarbon
NBS-Promoted Synthesis of Maleimides by Oxidative Dearomatization of Pyrroles: Mechanistic Investigations Using Online MS in Real-Time
Photosensitized Energy-Transfer-Mediated Aminoformylation of Alkenes
Visible-Light-Mediated Desulfonylation of gem-Difluorovinyl Sulfonates for the Synthesis of α-Difluorothiomethylated Ketones
Palladium-Catalyzed Direct C(sp3 )−H Arylations of Benzylsilanes with Aryl Halides
One-Pot Synthesis of Iptycenes and Dissymmetric Triptycenes Using Ynolate-Benzyne Triple Cycloaddition
Asymmetric Total Syntheses of (−)-Ervatamine and (+)-19,20-Dehydroervatamine via Late-Stage Directed Indolization
Triphenylamine-Mediated Intramolecular Remote Cyano Migration via Electron Donor–Acceptor Complex Photoactivation
Traceless Nitro Group Directing Strategy: Modular Syntheses of the Scaffolds of Polycyclic Alkaloids
Four-Component Selenoazaindolylation-Alkoxylation of Styrenes for the Synthesis of Azaindolyl β-Alkoxyalkyl Selenoethers
Synthesis of Chemoproteomic Photoaffinity Probes via Sequential Azidation/Staudinger Ligation from Alcohols and a Benzylic C–H bond
t-BuOK-Induced, NH3·MeOH-Promoted Electrochemical C(sp3)–H Amination of Saturated Heterocycles with Sulfoximines
Elucidation of Acetyl-Branched Sugar Pathway in Type II Polyketide Biosynthesis via One-Pot Enzymatic Synthesis
Palladium-Catalyzed Hydroalkynylation of 1,3-Dienes: Access to 1,5-Enynes
Photocatalytic Fluorosulfonylation/Fluorosulfonamidation of N-Homoallyl Aldehyde Hydrazones to Access FSO2-/FSO2N-Functionalized Tetrahydropyridazines
Chemodivergent Construction of Seven-Membered Silacycles via Palladium-Catalyzed Ring Expansion from 4- to 7-Membered Rings
1,3-Stereocontrol in Stereoconvergent Allenylic Alkylation Enabled by Palladium and Chiral Phase-Transfer Cooperative Catalysis
Copper-Catalyzed Chemoselective Ring-Opening Hydroselenation and C–H Selenylation of Isoxazol-5-amines
I2-Mediated One-Pot Three-Component Tandem Cyclization: Synthesis of 1H-Pyrrolo[3,4-c]quinoline-1,3(2H)-diones and Their Photophysical Property Studies
Total Syntheses of Avapyran and Dysiquinol D through a Stereoconvergent Fusion of Dihydrobenzopyran
Total Synthesis of (−)-Dimatairesinol via Regioselective Intermolecular Oxidative Phenol Coupling
Electrochemical Continuous-Flow Fluorosulfonylation of Allenols
Palladium-Catalyzed Sequential Hydroamination and Hydroxylation of 1,3-Enynes with 2-Aminophenols
Iron-Catalyzed Intermolecular N–H Insertion Using Acceptor–Acceptor Carbenes Derived from Iodonium Ylides
All-Aza meso-Benzo-Fused Triphyrins(2.1.1): Large Bathochromic Shift and Intensified Absorption via π-Extended Conjugation
Visible-Light-Induced Flavin Catalysis: A Green Route to Naphtho[2,1-b]furans via an o-(Naphtho)quinone Intermediate
Sodium Trifluoromethanesulfinate-Promoted Photocatalytic C–H Acylation of N-Heterocycles with 4-Acyl-1,4-dihydropyridines in Air
Synthesis of Polysubstituted Cyclohexenes via Pyridine-Boryl Radical-Catalyzed Formal [4 + 2] Cycloadditions of Cyclobutanes with Alkynes
Cascade Grignard Addition: Propargyl Claisen Rearrangement for the Stereoselective Synthesis of α-Allene Quaternary Centers in Cyclohexanones
Photoinduced Formal Intermolecular Ene-Yne Metathesis: Regioselective Synthesis of Chromene Derivatives via an Electron Donor–Acceptor Complex
Light-Driven Dehydrogenative Construction of Thioester Linkages from Thiols and Aldehydes
Electrochemical 1,5-Aryl Migration for Stereo- and Regioselective Synthesis of Tetrasubstituted Alkenes
Electrochemical-Promoted Homocoupling of 2′-Hydroxychalcones for the Synthesis of 1,6-Diketones
Cooperative NHC and Photoredox-Catalyzed Radical Azidoacylation of Alkenes to β-Amino Ketones
Cycloaddition Reaction of N-Homoallylacetohydrazides with O-Benzoylhydroxylamines under Copper Catalysis: Access to Tetrahydropyridazine Skeletons
Photocatalytic Reactions of α-CF3 Alkenes with Alcohols by Controllable Non-, Mono- and Dual-Defluorination
Copper-Catalyzed Formal C(sp3)–H Insertions via 1,5-Diyne Cyclization Triggered by a 1,6-Hydride Shift
Ti-Catalyzed Functional Group Tolerant and Regioselective Cross Couplings of (Hetero)aryl Grignard Reagents with Halopyridines
Light-Induced 1,4-Difunctionalization of Doubly Activated Cyclopropanes for the Synthesis of 3-Ethylacylamino-2-quinolones
A Catalytic Approach to Intramolecular Wittig Reaction: Sulfonyl-Masked EDO Precursors Enabling Access to Heteroarenes
(Methyl)thianthrenium Salt Enabled Monoselective N-Methylation and N-(13C-Methyl) Labeling: Late-Stage Functionalization of Arylamides
Phase-Transfer-Catalyzed Asymmetric Isomerization of Allylic Amines to Enamides via Kinetic Resolution
Enantioselective Palladium-Catalyzed Domino Carboetherification Reaction: Access to Isoxazoline-Linked Bis-Heterocycles
Asymmetric Total Synthesis of (−)-Lemnalemnane C
Thiolate-Promoted Carbo/Carboxylation or Thio/Carboxylation of Unsaturated Carbon–Carbon Bonds with CO2
Enantioenriched α-Quaternary α-Amino Amides via Copper-Catalyzed Propargylic Amination
A Convenient Methodology for the Hydrophosphorylation of Exoglycals via EDA Complex
Photoredox/Copper Dual-Catalyzed Regioselective 1,4-Arylcyanation of 1,3-Enynes for Multifunctionalized Allenyl Nitriles
Mimicking Nature in Reshaping the Triterpene Skeleton: Synthesis of a Class of Unnatural Oleanane Derivatives
Rapid Synthesis of Naphthol Derivatives through a Photocontrolled Exothermic Process
Pd-Catalyzed Selective ortho-C–H Silylation of Benzaldehydes Using Transient Directing Group
Substrate-Controlled Palladium(II)-Catalyzed Regiodivergent Oxypalladation/C–H Annulation of Alkynylaryl Carboxylates with o-Bromobenzoic Acids
Total Syntheses of Ganodilactone and Related Ganoderma-Derived Meroterpenoid Dimers via Intramolecular Vinylogous Michael Addition
Access to 2,5-Disubstituted Thiazoles Via Cyclization of N-Substituted α-Amino Acids
Late-Stage Aryl C–H Bond Carboxylation with CO2 via Combining Metal-Free C–H Bond Borylation and ZnEt2-Promoted C–B Bond Carboxylation
Hupserrine A, a Caged Lycopodium Alkaloid with a 6/6/5/6/7 Pentacyclic Skeleton from Huperzia serrata
Synthesis of 2-Phosphorus-Substituted Indoles via Ring Expansion of Benzocyclobutenone Oxime Sulfonates
Palladium-Catalyzed Selenylative Alkoxycarbonylation of Alkynes toward β-Selenated Cinnamic Acid Esters
Isodesmic C(sp2)–H Iodination of 2-Phenethylamines Directed by Native Primary Amino Groups
Visible-Light-Induced Decarbonylative Truce–Smiles Rearrangement of N-Sulfonylbenzamides
Nickel-Catalyzed Cascade Carbocyclization/Alkenylation of Bisallenes and Organoboronic Acids
Total Synthesis of Jerangolid B via spsup3/sup–spsup2/sup Stille Coupling
Pd-Catalyzed Convergent Coupling of Alkenyl Bromide, Isocyanides, and Thiocarboxylate to Synthesize Thiophene Derivatives
Synthesis of Okaramine M, Its Conversion to Amauromines, and Concise Bidirectional and Biomimetic Total Synthesis of Amauromines
Regioselective Spirocyclopropyl C–C Cleavage and Ketene–Imine-Triggered Skeletal Rearrangement for the Synthesis of α-Carboline
α-Amination at BODIPY and BOPHY Core via Metal-Free Regiospecific Cross Dehydrogenative Coupling Reaction Toward the Development of Lysotracker
Chan-Evans-Lam Cu(II)-Catalyzed C–O Cross-Couplings: Broadening Synthetic Access to Functionalized Vinylic Ethers
Iodine-Mediated Photocatalytic Disulfonylation of Allenes with Sodium Sulfinates
BOPYRENPY: A Modular Strategy toward Structurally Tunable Seven-Membered BF2‑Chelated Chromophores
Dual 1,2-Migration-Enabled β-Boryl Amide Synthesis
B(C6F5)3-Catalyzed [2π + 2σ] Cycloadditions of Carbodiimides with Bicyclo[1.1.0]butanes
Diastereodivergent Synthesis of Vinylsilanes Using Solid Silylzinc Reagent
Stable Vinylogous Aminal Salt as a Reactive Synthon for the Synthesis of Homologated β-Fluoroenamides
Electron-Catalyzed Cross-Coupling Reaction of Arylzinc Reagents with Aryl Triflates Accelerated by Photoirradiation
Syntheses of [17O]Aryl Sulfoxides, Selenoxides, Phosphine Oxides, and Arsine Oxide by Photo-oxidation Using [17O2]Dioxygen Generated Ex Situ
Enantioselective 3,4-Oxyamination of 1,3-Dienes Enabled by an Electron-Rich Planar Chiral Rhodium Indenyl Catalyst
Asymmetric Synthesis of Unnatural (−)-Gracilamine
Photoinduced Three-Component 1,2-Dicarbofunctionalization of Unactivated Alkenes via Polarity-Matched Control
Catalytic Enantioselective (4+4) Annulation of o-Hydroxybenzyl Alcohols with 4-Indolylmethanols
Kinetic Resolution of BINAMs by Stereoselective Copper-Catalyzed Dehydrogenative Si–N Coupling with Prochiral Dihydrosilanes
Copper-Catalyzed Difluoroalkylative Benzylation of Alkenes
Synthesis of Doubly Mislinked N,N’-Diphenyl Amethyrin and Its Dithia-, Diseleno-, and Ditelluro Analogues Via Zr(II)-Mediated Cyclometalation Reactions
Selective Synthesis of Unsymmetrical Disulfides from Thiols via Water-Removable SuFEx Reagent
Switchable Photocatalytic Stereoselective Synthesis of C- and S-Glycosides with Ethyl Xanthate Donors
Desymmetrization of Bisallylic Amides: A Catalytic Enantioselective Diastereoselective Chlorocyclization Strategy
Photoredox-Catalyzed Formal [4 + 2] Cycloaddition of Pyridinium Masked Enols with Unactivated Olefins
Cu-Catalyzed Asymmetric Olefinative Conjugate Addition of Dialkylzinc Reagents
Diaporlabanoids A–C, Immunosuppressive Dinorlabdane Diterpene Alkaloids with an Unprecedented Carbon Skeleton from Mangrove Endophytic Fungus Diaporthe phaseolorum H3-2
Direct Assembly of Functionalized 3-Hydroxypyridine N-Oxides via Cascade Nitration/Hydroxylative aza-Annulation Reactions
Visible-Light-Promoted Copper-Catalyzed Etherification of Aryl Bromides via Energy Transfer
Total Synthesis of Daphenylline via Diels–Alder Cycloaddition and Rhodium-Catalyzed C–H Alkynylation
Catalytic Quantities of Inorganic Salt Promote an Electron Donor–Acceptor Complex to Achieve Defluorinated Cycloaddition
Porphyrin AuIII Complexes Bearing Bulky Meso-Substituents as Building Blocks of Stacking-Frustrated Ion-Pairing Assemblies
Nickel-Catalyzed C–N Bond Formation from Ring Remodeling through C–C Bond Activation
Preparation of 211At-Labeled (Hetero)aryl Compounds from Triarylsulfonium and Dibenzothiophenium Salts
Atroposelective N-Allylic Alkylation Enables Construction of Axially Chiral Arylimidazoles
Alkyl-Trifluoromethylation of Glycine Derivatives
Reductive Dicarbofunctionalization of Unactivated Internal Alkenes via Iron Catalysis
Cobalt-Catalyzed C−H Annulation of Aryl Sulfonamides and Benzamides with CaC2 as the Acetylene Source
Acceptorless Dehydrogenative Aminoalkylation of Allylic C(sp3 )−H Bonds via Reversible Hydrogen Atom Transfer
Ternary Synthon Strategy for 1,3,5-Trisubstituted Benzenes via [3 + 3] Benzannulation of Propargyl Alcohols
Palladium-Catalyzed Construction of Trisubstituted Oxazoles from Trifluoroalanine Derivatives
B(C6F5)3-Catalyzed Decarboxylative Formation of Benzofurans via Intermolecular (3 + 2) Cyclization from Phenols
Visible Light-Promoted Construction of Cage-Like Frameworks by Sequential [2 + 2] Cycloaddition
Site-Selective α-Alkoxylation of Iodonium Ylides with Alcohols via Ruthenium Catalysis
Difunctionalization of Sulfamate-Derived Cyclic Imines through Phosphine Catalysis
Silver-Mediated Dual Oxidation of 1,3-Dicarbonyls for Migration–Annulation
Photochemical Dearomative Vicinal Aminooximation of Heteroarenes with N-Nitrosamines
Anion-Mediated Synthesis of Diethynyl-Substituted Doubly N-Confused Dioxohexaphyrin Dyes That Exhibit Enhanced Photoacoustic Signals in the NIR-II Region
Synthesis and Characterization of Atropdiastereomeric Macrocyclic Metacyclophanes
Photocatalytic Decyanative Radical Addition Based on Cyano Group Transfer Mediated by Amine-Ligated Boryl Radicals
Biomimetic Skeleton Conversion from Lathyrane into Euphoractine A-Type Euphorbia Diterpenes: Semisynthesis of Natural Diterpenes Euphoractins M and N
Ligand-Controlled Cobalt-Catalyzed Regioselective Annulation: Divergent Synthesis of Indenols from o-Haloaromatic Ketones and Terminal Alkynes
Self-Assembled Topologically Chiral Catenane via Ketone–Hydrazide Condensation
Palladium(0)-Catalyzed Asymmetric Cross Inverse-Electron-Demand Diels–Alder Reaction between Distinct Electron-Deficient Dienes
A Visible Light Promoted Regioselective Cascade Radical Trifluoromethylation/Cyclization of N-Isopentenyl Aldehyde Hydrazones: Access to Trifluoromethylated Tetrahydropyridazine Derivatives
Harnessing Radicals for the Selenotrifluoromethylation within a Confined Metal–Organic Framework
Copper-Catalyzed Chan–Lam Reaction and Sequential Oxidative Fischer Indole Synthesis to Prepare Indole Derivatives
Transformation of α,β-Unsaturated Aldehydes with a Small Amount of Electricity: Cyanosilylation, Isomerization, and Nucleophilic Addition
Chemodivergent Sulfenylation of Trifluoromethylalkenes: Controlled Synthesis of Fluorinated 1,3-Dithioethers and β-Trifluoromethyl Thioethers
Selective Modification of Carboxylic Acids with Oximoyl Chlorides under Aqueous Conditions
Visible-Light-Driven Synthesis of Sulfinamides via Deoxygenative Sulfinamidation of Alcohols with iN/i-Sulfinyltritylamine
Light Promoted Vinylogous Arbuzov Reaction with Electron Deficient Alkyl Halides
Enantioselective Synthesis of Chiral Triarylmethanes via Cu-Catalyzed Desymmetric Acyloxylation of Cyclic Non-coordinating Diaryliodoniums
Norcolocynins A and B, Ring B seco-Norcucurbitane Triterpenoids from the Fruits of Citrullus colocynthis and Their Cytotoxicity
Sustainable Synthesis of Diverse 1,1-Aminosilane Libraries Using a Multicomponent Cu-Catalyzed Reaction
Unified Synthesis of Cycloheptatriene-Fused Heterobicyclo[3.1.1]heptanes by Lewis Acid-Catalyzed Higher-Order (8 + 3) Cycloaddition of Bicyclo[1.1.0]butanes with Troponoids
Stereoselective Synthesis of Tetrasubstituted Alkenes from 1,2-Diketones via Oxyphosphonium Salts-Engaged Suzuki–Miyaura Coupling
Synthesis and Characterization of Perhydroxy-asar[6]arene and Perhydroxy-asar[6]quinone
Electrochemical Synthesis of Disubstituted Alkynes from Dihydrazones
Fungal Sulfotransferase from iMetarhizium majus/i Catalyzes the Formation of iPPZ/i Pathway Intermediate Peramine-8-iO/i-sulfate
Iron-Catalyzed Reductive Carboxylation of Arenes with CO2 via Thianthrenium Salts
Photochemical CO Release from a Bench-Stable, Recyclable Organic Platform: Applications to Carbonylative Cross-Coupling
Regioselective Sulfenylation/Phosphorylation of Unactivated Alkenes via Thianthrenation
Polyene Cyclization/Mannich Cascade for Streamlined Construction of the A/E/F Tricyclic System of Diterpenoid Alkaloids
General Strategy to Access N-Aryl Heptamethine Indocyanines for Optical Tuning
Proton Relay Catalysis Enables the Synthesis of 2-Oxa- and 2-Azabicyclo[2.2.1]heptanes
Synthesis of Perfluoro-itert/i-butyl Triazoles via Decarboxylative CuAAC of (Perfluoro-itert/i-butyl)propiolic Acid with Azides
Asymmetric Synthesis of Biaryl Sulfilimines Bearing Multiple Chiral Elements Involving Cyclic Diaryliodoniums
Palladium-Catalyzed Aminocarbonylation Using Nitroarenes under NMP-Mediated Photochemical Conditions
Palladium-Catalyzed “Cut-and-Sew” Reaction of C(sp3)–NC: Direct Synthesis of Bulky Nitriles Containing an All-Carbon Quaternary Center
Phosphine-Catalyzed Asymmetric Dearomative Annulation of 4-Nitroisoxazoles with Allenoates: Construction of Isoxazoline-Fused Bicyclo[3.3.0]octenes
Nanoconfinement in a Supramolecular Capsule Promotes the Formation of 5- to 8-Membered Rings in Cycloalkane-[b]-indoles
Diethylzinc Amylates: Selective Iodine–Zinc Exchange Reagents at Room Temperature
Chemoselective Difluoromethylation of Nucleosides
Photocatalytic Functionalization of Olefins with Triaryl Phosphine and Dibenzyl Sulfoxide: Preparation of Tertiary Phosphine Oxide
Base-Mediated Formal Denitrogenative Insertion of Nonactivated Triazoles into Aldehydes: Stereospecific Synthesis of Highly Substituted Acrylamides
Catalyst- and Base-Free Synthesis of Pyridine-Fused Uracils from 6-Methyluracils, Aldehydes, and Ammonium Iodide via a One-Pot Multicomponent Reaction
Cobalt-Catalyzed Regio-, Diastereo-, and Enantioselective Reductive Coupling of Internal Alkynes with Cyclobutenes
Copper-Promoted Reductive Cross-Coupling for Cyanodifluoromethylation of (Hetero)aryl Iodides with BrCFsub2/subCN
Stereoselective Synthesis of Delgocitinib and Its Diastereomer Using Organocatalyzed Michael Addition
Phosphine-Catalyzed Modular Synthesis of (iE/i)-Allyl Hydrazones, Tetrahydropyridazines, and Pyridazines
Divergent Annulations via Organocatalysis: Remote-Controlled and Switchable Reactions of Pyrrolidinone-Based Morita–Baylis–Hillman Carbonates with 2-Arylideneindane-1,3-diones
Isolation and Computer-Based Structural Determination of Madangolide B
Lewis Base-Catalyzed DYKAT of Racemic Chlorosilanes En Route to Si-Stereogenic Silazanes
Strategic Acetylation of BODIPY Dyes: Tuning Excited-State Geometry for the Design of Fluorogenic Sensing Probes
Highly Active Catalyst for Suzuki–Miyaura Coupling to Form Sterically Demanding Biaryls: Electronic Control of Pd through the Secondary Interaction Using a Buchwald-Type Ligand Bearing a Fluorinated Aryl Ring
Formal [3 + 2] Annulation of β,β-Disubstituted Enesulfinamides with Vinyl Thianthrenium Salt: Asymmetric Construction of 3,3-Disubstituted 1-Pyrrolines
Cu-Catalyzed Asymmetric Olefinative Conjugate Addition of Aryl and Alkenyl Boronic Esters
Annulative π-Extension of Phospholes by Sequential Site-Selective C–H Iodination and Pd-Catalyzed C–H Coupling with Alkynes
Copper-Mediated Divergent Reactivity of Allene-Tethered Carbamates under Radical Conditions
Direct Access of Heteroaryl Difunctional Monomers for Arene-Enriched Polysiloxane Synthesis
Synthesis of 8H-Indolo[3,2,1-de]phenanthridin-8-ones via Pd(OAc)2-Catalyzed Double Oxidative Coupling Dehydrogenations
Photoinduced Copper-Catalyzed Coupling of Acylsilanes with Indoles or Electron-Rich Arenes
Palladium-Catalyzed Regio- and Monoselective B(2)–H Alkylation of Zwitterionic nido-Carboranes at Room Temperature in Water
An Oxidative Palladium-Catalyzed Remote imeta/i-Selective Homo-Biaryl Coupling Assisted by Nitrile Directing Templates
Asymmetric Allylboration of α-Alkoxy-enones: Access to Enantioenriched Tertiary α-Hydroxy Ketones
Photocatalyzed Oxycarboranylation of Alkenes with 1-Iodo-io/i-carboranes through a Halogen-Atom Transfer Strategy
Divergent Synthesis of Symmetric Benzenes and Fluorenones
Photoinduced Aminosulfonylation of Unactivated Alkenes via N–N Bond Cleavage and Distal Migration of Imine
Direct Pd-Catalyzed β-C(spsup3/sup)–H Hydroxylation of Aliphatic Carboxylic Acids
Rh(III)-Catalyzed [3 + 4] Annulation of 3-Arylisoindolinones with 2-Methylidenetrimethylene Carbonate via C–H Activation to Access Isoindolinone Spirobenzoxepines
Efficient Synthesis of Pseudoindoxyls from 2-Nitrobenzylidenemalonates and Indoles
Visible-Light-Driven Fischer-Type Indole Synthesis: Direct Synthesis of 2-Phosphinoylindoles from Anilines
Triconnarins A–D: Four Secophragmalin-Type Limonoids from the Twigs and Leaves of iTrichilia connaroides/i
Intramolecular Radical Oxidative Cyclization: Access to Fused-Bicyclo[3.1.0] Hexanes from igem/i-Dihalo Olefins
Chromium(II)-Catalyzed Decarboxylative Alkyl Acylation under Visible Light Irradiation
Enantioselective Synthesis of Tetrahydroanthraquinones via Pd-Catalyzed Asymmetric [2 + 4] Annulation
Catalytic Intramolecular Reductive Amination Using Secondary Amines: Expanding Access to Chiral Tertiary Amine Heterocycles
Catalytic Asymmetric Total Synthesis of Naturally Occurring iAmaryllidaceae/i Alkaloid, (+)-11-Hydroxyvittatine
Iron Photocatalysis Enabling Decarboxylative Bromination of (Hetero)Aryl Carboxylic Acids
Electro-enzymatic Cascade Stereodivergent Synthesis of β-Hydroxy Selenides via Engineered Ketoreductases
Phosphine-Mediated ide Novo/i Arylamidation of α-Allylic Allenoates and Isocyanates via Bicyclo[3.1.0]hexene Access to Aryl Amides
One-Pot Regioselective Functionalization of Quinone Imine Ketals: Direct Access to iortho/i-Substituted Anilines from Arylamines
Synthesis of Pyridinone-Fused [2.2]Paracyclophane by Ruthenium(II)-Catalyzed C–H Activation
Iridium(III)-Catalyzed C–H Bond Activation of Phenols to Build Up Phenothiazine-Containing 2-(2-Hydroxyphenyl)azoles: Access to Single-Molecule White-Light Materials and Room-Temperature Phosphorescence Materials
Oxidative Kinetic Resolution of Alkyl-Substituted 1,2-Diamines
Cascade Pd-Catalyzed Intermolecular N-Arylation/Intramolecular Alkene Carboamination Reactions for the Synthesis of Dihydroindoloindoles
[2 + 3] Cycloaddition of para-Quinamines and para-Quinols with C,N-Cyclic Azomethine Imines: Access to 6/5/6/6-Fused Tetracyclic Pyrazolidines
Dearomatization of Electron-Deficient Indoles with N-Alkylanilines via Visible-Light-Induced Hydroalkylation
Discovery and Biomimetic Syntheses of Phloroglucinol-Monoterpene-Triketone Hybrids from Chamelaucium uncinatum with Hypoglycemic Activity
Synthesis of Benzo[a]carbazoles via Palladium-Catalyzed Tandem Cyclization of Diarylalkynes with Isocyanides
Sterically Hindered and Electron-Deficient 2,4,6-Tri-itert/i-butylpyrimidinium as a π-Lewis Acid Toward Organocatalytic Silyl Protection of Carbohydrates Using Trialkyl/aryl Silanes
Macrocyclization of Unprotected Peptides via Cycloaddition between o-Diones and Furan-2(3H)-one
Ascomycotols A–C: Rare Sulfur/Sulfone-Containing Scaffolds from Mushroom Endophytes with Dual Anti-inflammatory and Antirenal Fibrosis Effects
Synthesis of γ-Carboline Derivatives via the Rh(III)-Catalyzed Regioselective C–H Activation/[4+2] Annulation Cascade
Electrochemical Synthesis of β-Keto Phosphorodithioates via Difunctionalization of Alkenes under Metal-Free Conditions
Iron-Catalyzed Reductive Deuteration of Ketones and Imines
Total Synthesis of Epicoccolides A and B by Oxidative Skeleton Rearrangement Leads to a Structural Revision and Questions the Proposed Biosynthesis
Photocatalytic Dealkylation of Aryl Alkyl Ethers
Late-Stage Oxime iO/i-Glycosylation with Unprotected Glycosyl Fluorides
Collective Biomimetic Synthesis of Myrcaulones A and C and Myrcauones B–D
Closed-Loop Sulfur Dioxide Utilization in Photocatalytic Smiles Rearrangement
The NHC-Catalyzed Enantio- and Diastereoselective [2 + 3] Annulation of Phthalide-Derived Alkenes with Enal Access to Bispiroheterocyclic Compounds Bearing Three Vicinal Stereogenic Centers
Oxidative Couplings of iN/i-Aryl Peptides in Organic Solvent: Preventing Amino Acid Side Chain Loss
C3-Formylation of Pyridines via Streptocyanine Intermediates
Ligand-Enabled Palladium-Catalyzed Asymmetric Synthesis of Cyclic Sulfamidate-Fused Imidazolidinones
Ag(I)-Catalyzed C–C Bond Cleavage and Re-Assembly Reactions Between 2H-Azirines and α-Carbonyl Sulfoxonium Ylides
Rh-Catalyzed in Situ Generation of Phenanthrocyclobutadienes from Tetraaryl-Diynes and Their Cycloadditions with Cycloalkenediones and io/i-Chloranil
Peptide Functionalization with Dithioate and Trithioate Groups: A CSsub2/sub-Mediated Solid-Phase Approach
Synthesis of Fused Polycyclic Indole-Indenone Scaffolds via Pd-Catalyzed Sequential Cycloaddition Reactions
Accommodating Styrenes and Unactivated Olefins: Hydrotrifluoromethylation Using O,O′-Dimethyldithiophosphoric Acid as SET Reductant and H Atom Donor
Synthesis of Parent Peropyrene and Its Derivatization
Iron-Catalyzed Double Annulation of O-Acyl Oximes with Fumaronitrile for the Synthesis of 4-Cyano-7-azaindoles
Synthesis of Remote C–N Diaxially Chiral Compounds via Cobalt-Catalyzed Atroposelective C–H Activation
P(O)Me2–Alkenes: From Synthesis to Applications
Scalable Photoinduced Cycloaddition for the Synthesis of Biorelevant Oxazoles
Synthesis of Rhodocorane L Using Gold-Catalyzed Dearomative Spirocyclization
Isolation of Noncrystalline Compounds via Adsorption on a Solid Support
Stable Tribrominated Phenalenyl Radical Exhibiting Long-Lived Luminescence from a Monomer−π-Dimer Equilibrium
Catalytic Asymmetric Intramolecular Domino Allylic O-Alkylation/Allylic Dearomatization of Allyl Aryl Ethers
Elucidation of a Parasitic Proton-Coupled Electron Transfer in a Photocatalytic Benzylic C–H Sulfonamidation
Dipolar Cycloaddition Approach toward Harmicine-Type Alkaloids: Synthesis and Stereochemical Determination
Traceless Aminoalkyl Radical-Induced Halogen-Atom Transfer for Minisci Reactions
Atroposelective Suzuki–Miyaura Coupling Reaction with Benzoxaboroles
An RNA Chemical Phosphorylation Reagent Based on the “DMT-On” Strategy
Synthesis of γ-Ketoamides from Nitrones and Ynamides through a Copper-Catalyzed Cascade Reaction
Enantio- and E-Selective Copper-Catalyzed Three-Component Hydrofunctionalization of Internal Allenes Bearing Methylidenecyclobutanes with Diborons and Ketones
Mild Lewis-Acid-Promoted Cysteine–Tryptophan Conjugation Involving a Radical Process
Chiral Phosphoric Acid-Catalyzed Enantioselective Pictet–Spengler Reaction for Concise Synthesis of CF3-Substituted Tetrahydro-β-Carbolines
1,6-Reduction-Type Hydride Shift/Cyclization Process without Adjacent Heteroatom: Stereoselective Synthesis of Hexahydrofluorene Derivatives via Internal Redox Reaction/Friedel–Crafts Reaction Sequence
Sorbicillalanines A and B, Two [6,5,6] Hybrid-Sorbicillinoid Alkaloids from Deep-Sea-Derived Penicillium sp. Co-Cultured with Sponge-Derived Setosphaeria sp.
Manganese Complex-Catalyzed (De)hydrogenative Cyclization toward the Selective Synthesis of 2-Substituted and 2,3-Disubstituted 4-Quinolones
Base-Catalyzed Chemo-, Regio- and Stereoselective Addition of Quinazolinones to Trifluoromethylated Internal Alkynes for Access to N3-Vinylquinazolinones
A Unified Strategy for Transition-Metal-Free Synthesis of Benzothienopyridines, Benzoselenopyridines, and Benzotelluropyridines and Related Analogues
EDA Complex-Mediated Aerobic Three-Component CDC Reactions of Quinoxalinones under Visible-Light Irradiation
Bioinspired Total Synthesis of Penisuloxazin A
Direct Carbon Isotope Exchange of α-Keto Acids Enabled by Photoredox Self-Catalysis
Ir-Catalyzed Friedel–Crafts-Type Asymmetric Allylation of Furans
Copper-Catalyzed Stereoconvergent 1,4-Protosilylation of E/Z Dienes
Identification of a Privileged Scaffold for Induction of Lysosomal Biogenesis through Synthesis of the Scaffold of Cipadonoid A
Steric Gating of Excited-State Channel: Controllable AIE/RTP Switching through Tuning π-Bond Twisting
Photoinduced Double 1,2-Carbon Migration toward All-Carbon Tetrasubstituted Olefins
Direct Synthesis of cis-Bicyclic γ-Lactam Derivatives from Iminosugar C-Coumarinyl Glycosides
Dechlorinative Pyrazinylation of Glycine Derivatives
Lewis Acid-Mediated Deoxygenative Synthesis of Trivalent Sterically Hindered Phosphines from Aldehydes
Application of Indolyl Ynones in the Construction of Chiral Carbazoles and Pyrroloindolines by Organo and Metal Sequential Catalysis
Total Synthesis of (±)-Streptoglyceride A and of Putative (±)-Streptoglyceride C
NHC-Catalyzed Allylation of Aldehydes with MBH Carbonates and Their Michael Addition–Elimination-Cope Rearrangement Cascade: A Route to rac-Sacubitril
Room-Temperature Copper Cross-Coupling Reactions of Anilines with Aryl Bromides
Radical Addition to 2-Allenylaryl Isocyanides for the Preparation of 2,3-Difunctionalized Quinolines
Triplet Excited Nitroarene Converts Aryl Alkynes to Ketones by Deleting a Carbon Atom
Decatungstate-Catalyzed Photochemical Reactions of Ethenesulfonyl Fluoride: A Linchpin Reagent for C–H Functionalization
Iron-Catalyzed [3 + 2] Annulation of O-Acyl Oximes with 2-Hydroxy-1-Naphthoates for the Synthesis of Benzo[g]indoles
Total Synthesis of (±)-Rhazinilam via Red-Light-Driven Zinc(II)porphyrin-Catalyzed Radical Cyclization of iN/i-Substituted Pyrrole
(Vinyl triflimide)benziodolium Salts: Palladium-Catalyzed Cascade Reactions toward Unsymmetrical Benzils
Boron Catalysis-Enabled Regioselective Ring-Retentive Hydrosilylation of Methylenecyclopropanes
Design of Fast Redox-Controlled Self-Immolative Selenium-Based Cysteine Surrogates
Iron-Catalyzed Borylation of Aryl Trifluoromethoxides
C3–H Trifluoroacetylation of Quinolines and Pyridines: Access to Heteroaryl Ketones, Carboxylic Acids, and Amides
A General Deoxygenative Hydrosilylation of Oxo Chemicals Catalyzed by a Bipyridine-Ligated Chromium Complex
Flexible Synthesis of Highly Substituted Pyridines Bearing 2-Fluoroalkyl Groups
Biocatalytic Thioketal Cleavage Enabled by Enzymatic Bromide Recycling by Vanadium-Dependent Haloperoxidases
Trichloroacetonitrile-Mediated Oxidation of Sulfides and Benzylic C–H Bonds via Photoexcited Radical Reactions under Clean Conditions
Cascade Reactions of α-Carbonyl Radicals Enabled by Photocatalytic Hydrogen Atom Transfer for the Synthesis of Benzonaphthyridinone Derivatives
Mechanochemical Buchwald–Hartwig Cross-Coupling Reactions of Aromatic Primary Amines and Their Application to Two-Step One-Pot Rapid Synthesis of Unsymmetrical Triarylamines
P450 Biarylitide Synthase ShyB Catalyzes the Cross-Link Between His-C2 and Tyr-O4 on the Precursor Peptide
Photocatalytic Ring-Closing Metathesis/Amination of 1,6-Enynes and 1,7-Enynes: Synthesis of α,β-Unsaturated γ-Lactams and Quinolin-2-ones
Leveraging Borylcupration for Enantioselective Cascade Spiroannulation: Access to Spirophthalide Boronates
Electrocatalytic 1,6-Difunctionalization of Bicyclopropanes
Dipole-Transmissive 1,3-Dipolar Cycloadditions: Modular, Diversity-Oriented Synthesis of Polycyclic Alkaloid Scaffolds
Alkynyl Sulfide: An Unexplored yet Versatile Alkynyl Species for Chemoselective Cross-Electrophile Coupling
Scalable Synthesis of 1,5-Diazabicyclo[3.1.0]hexanes Using iN/i-Chlorosuccinimide as Chlorinating Agent
A Reductive Ugi Reaction with Carboxylic Acids Replacing Aldehydes
A Modular Cyclopentene Annulation
Visible-Light-Induced Arylcarboxylation of Activated Alkenes with Aryl Halides and Oxalate Enabled by Electron Donor–Acceptor Complex Formation
Energy-Transfer-Enabled 1,4-Amino Migration and C–O Diradical Recombination for Norrish–Yang-Type Epoxidation
Pd-Catalyzed Regioselective Homobenzannulation of Enynals
Synthesis and Nucleophilic Ring-Opening of 1,1-Dicyanocyclopropanes: Accessing β-Aminocarbonyl Derivatives from Olefins
Remote Copper-Catalyzed Atroposelective Synthesis of N–N Axially Chiral Compounds Bearing Minimally Different Alkyl Groups
Reductive N-Heterocyclic Carbene Catalysis via Hydride Transfer: Generating Homoenolates from Unsaturated Esters
Radical Fluorosulfonylation/Double Diels–Alder Sequence to Access Tricyclo[3.2.1.02,7]octanes
Unveiling the True Identity of Carborane-Fused Phosphorus Heterocycles
Sequential EDA/HAT Enables C(spsup3/sup)–C(spsup3/sup) Cross-Dehydrogenative Coupling: Accessing Non-Canonical Amino Acids with Quaternary Carbon Centers from Activated and Non-Activated Alkanes
Synthesis of 3,4-Fused Pyrroles with Seven-Membered Carbocycles via Cascade C–C σ-Bond Cleavage/Intramolecular Cyclization Reactions
Visible Light-Mediated Anaerobic Oxidation of α-Glucoside: Site-Selective Dehydrogenation Promoted by Aromatic Aldehydes
Photoinduced 1,2-Carbosulfenylation of Alkenes
Copper-Catalyzed Cysteine S-Arylation via Photoredox Mediation
Visible-Light-Initiated Aggregation-Enabled Transformation of Thiophenols to Unsymmetrical Disulfides via Photo-Fries Rearrangement
Intramolecular Cyclopropanation of Alkene-Tethered CF3-Imidoyl Sulfoxonium Ylides: Synthesis of Cyclopropane-Fused Quinolines
Photoexcited Copper-Catalyzed Difunctionalization of Alkenes for the Synthesis of 2,5-Diamino Acid Derivatives via Uncommon 1,2-Hydrogen Atom Transfer of Amidyl Radicals
Annulative Editing of Peptide Side Chains: N-Pyridination of Lysine via Chichibabin Pyridine Synthesis in Hexafluoroisopropanol
2-(Cyanomethyl)benzimidazole Derivatives as 1,3-Dicarbonyl Analogues for a Kinetically Controlled Diastereo- and Enantioselective Mannich-Type Reaction Catalyzed by Chiral Phosphoric Acid
Vitamin Bsub12/sub and Micellar Solution Enable Regioselective Ring Opening of Epoxides and Aziridines with Electrophilic Olefins
TEMPO-Mediated Polyyne Cyclization
Nine-Membered Ketolactams by Oxidative Cyclization Expansion
Enantioselective Total Synthesis of (−)-Vallesamidine Enabled by Asymmetric Hydrogenation and Aza-Wacker Cyclization to Construct the Core Spirocyclopentane-1,2′-indoline Structure
Balancing Reactivity and Specificity: Fc-Binding O-Acyl Hydroxamate Reagents for Site-Selective Antibody Labeling at Lys248
Synthesis of Nonsymmetrical 3,3′-Bicoumarins: Total Synthesis of Arteminorin C, 3,3′-Biisofraxidin, and Biscopoletin
Asymmetric Synthesis of Small Molecule Inhibitors of IL-17A via Crystallization-Induced Diastereoselective Strecker Reaction
Synthesis of the Pentacyclic Core of Sanguinone B Enabled by Alkyne Functionalization
Cu-Catalyzed Cycloaromatization and Amination of 2-Bromoaryl Nitriles, Terminal Alkynes, and Amines for 1-Aminoisoquinoline Synthesis
Base-Mediated Synthesis of Polysubstituted Pyrroles from iN/i-Allyl Ketimines and Alkynes: Interplay of Carbanions
Stereoselective [2 + 2 + 2] Cycloaddition of Benzocyclobutanones and Norbornadienes through Nickel-Catalyzed C–C Bond Activation
Directed Cascade C–H Functionalization/2-Fold Annulation with Vinylcyclopropanes: Access to Tetrahydrobenzo[g]isochromen-10-ones
Visible Light-Promoted Ir(III)-Catalyzed Stereoselective Synthesis of Azauracil-C-Nucleosides from 1-Bromosugar
Iron-Catalyzed Alkylative Aminosulfonylation of Alkenes and Alkynes via Radical-Anion Relay
Bioinspired Stereoselective Total Synthesis of the Caged Sesquiterpenoid Daphnepapytone A
Organocatalytic Asymmetric [4 + 4] Annulation Reaction of Ynones with Unsaturated Pyrazolones: Synthesis of Eight-Membered Ether-Embedded 4,5-Fused Pyrazoles
Palladium(II)-Catalyzed Desymmetrization of 2-Alkynylbenzoate-Tethered Cyclohexadienones for the Synthesis of Polycyclic Compounds
Automated Alkylation of Heteroaromatic Thioethers with Organozinc Reagents for Library Synthesis
Highly Convergent Modular Access to Carbonylative Difunctionalized Cyclopropanes via Palladium-Catalyzed Thioether-Thiocarbonylation of Cyclopropenes
B(C6F5)3-Catalyzed Regioselective Deuteration of Terminal Olefins Using D2O as the Deuterium Source
Photoinduced Diastereoselective and Stereodivergent Synthesis of C-Styryl Glycosides
Racemic Meroterpenoid with a 6/6/4/6/6/10/3 Skeleton via [2 + 2] and [4 + 2] Coupling of Sesquiterpenoid and Pyrone Units
Difluorocarbene/H2O Serving as a CO2 Equivalent for Insertion into Oxiranes
Pd-Catalyzed Regioselective Tandem Heck/C–H Activation/Bisamination Reactions with Ynamides and Diaziridinone. Rapid Access to 3-Aminoindoles
A Metal-Free Oxidative Azidation Method for Selective Azidation of C(sp3)–H Bonds and Diazidation of Alkenes
Unmatched-Electron-Demand Diels–Alder Reaction of Lindenane-Based Electron-Deficient Trienes
Pd(II)/Cu(I) Co-catalyzed Dual C–H Functionalization of Indoles at C2 and C3 Positions Using Bifunctional Arylsulfonyl Reagents
Late-Stage iN/i-Arylation of Tryptophan-Containing Peptides and Drug Molecules via Arylthianthrenium Salts
One-Step Synthesis of Indoloquinoline Alkaloids via the Pd-Catalyzed Larock/Ligand-Accelerated C–H Activation Cascade Reaction
Asymmetric Formal Synthesis of (−)-Paroxetine
Alkyl Azetidines Via Batch and Flow Photochemistry
Rhodium-Catalyzed Tandem Reaction of N-(Pivaloyloxy)acrylamides with 1,3-Diynes for the Synthesis of Furo[2,3-b]pyridines
Energy-Transfer-Enabled Truce–Smiles Rearrangement Using Sulfonamides as Sulfonyl Radical Precursors
MsOH Promoted Divergent Synthesis of 4-Arylidene Isoxazolidines and Isoxazolines from iO/i-Propargyl Hydroxylamines and Aldehydes
Heteroarylation of Sulfenamides for Modular Synthesis of Antimicrobial Sulfilimines via Sulfinimidoyl Fluoride Intermediates
Direct Photocatalytic Reductive Amidation of Nitroarenes: A Tandem Reduction–Decarboxylation Approach to Amide Bond Construction
Formal Total Synthesis of icis/i-Sylvaticin and Sylvaticin
Cobalt-Catalyzed versus Base-Promoted Skeletal- and Stereodivergent Synthesis of Bicyclic α-C-, β-O-, and α-O-Glycosides
Corymbinols A and B: Bis-β-triketone Conjugates of Sesquiterpene and Chalcone from the Fruit of Corymbia citriodora
Construction of Chiral Spiro-Bridged Rings with Four Consecutive Stereocenters via Dearomative Diels–Alder Reactions of Anthracenes
Iridium-Catalyzed Asymmetric Allylic Substitution with Sequential Boron Incorporation
Copper-Catalyzed Stereoselective Cyanation/Phosphorylation of Formamides with TMSCN and P(O)–H Bonds
Anionic Fries Rearrangement of ortho-Iodophenyl Carboxylate Initiated by Potassium Hydride
Asymmetric Olefin Isomerization via Phase-Transfer-Catalyzed [1,3]-Hydrogen Transfer for Access to Axially Chiral Furan-Benzimidazoles
Stereoselective Assembly of α-Fluoroacrylate-Substituted β-Lactams via Acid–Base Microenvironment-Controlled Carbonylation
Denitrative Iodination of Nitroarenes via Light-Promoted Reduction
Pd-Catalyzed Three-Component 1,1-Carboamination of 4-Pentenoic Acid
Cobalt-Catalyzed Regio- and Stereoselective C(sp2)–H Alkylation of Enamides with 4-Alkyl-1,4-dihydropyridines
Decoding Guaianolide Biosynthesis: Synthetic Insights into Pseudoguaianolides and Seco-Guaianolides
Pd-Catalyzed Regio- and Stereoselective Synthesis of Tertiary Enamides via a Three-Component Coupling of 2-Arylaziridines with Diazo Esters and Cyclic Ethers
Group-Directed [5+2] Cycloaddition Approach to 10π-Electron Cyclohepta[c]furans and Derivatives
Direct Amination of Anilines Utilizing Dearomatized Phenolate Species
Photocatalytic Dual-Defluorination Thiolation of Trifluoromethyl Hydrazones
Regioselective Oxyamination of Biaryls Using Nitroarenes
Copper-Catalyzed Defluorinative C(sp3)–C(sp2) Cross-Coupling of Polyfluoroarenes with gem-Diborylalkanes
Access to [2.2]Paracyclophane-Fused N-Heterocycles via Palladium-Catalyzed C–H Activation and Cyclization of [2.2]Paracyclophaneacylhydrazones with Vinyl Azides
Rapid Access to a Cyclobutane-Containing Skeleton Fused with Chromane through In(III)-Catalyzed Intramolecular Annulation of 5-Hydroxy Benzochromene
NHC-Catalyzed and Brønsted Acid Copromoted E → Z Isomerization Mode of Breslow Intermediates Leading to Ralfuranones
Umpolung (4 + 1) Annulations of Bifunctional Hydroxylamines: A Modular Approach to Pyrrolidines
Late-Stage N-Alkenylative Modifications of Indolic Scaffolds with Propiolates: Toward Bisconjugation and Macrocyclization
Enantioselective and Divergent Trienamine-Mediated Reactions of Halogenated Maleimides
Iron-Catalyzed Tunable Alkene Migratory Silylation and Transposition
Photoinduced Copper-Catalyzed Regio- and Diastereoselective Multicomponent [3 + 2 + 1] Radical Cyclization To Access Tetrahydropyridines
N-Activation of 2-PySO2CF2H for Electrophilic Difluoromethylthiolation of Electron-Rich Heteroarenes
Nickel(II)-Catalyzed Unexpected [3 + 2] Cycloaddition/[3,3]-Rearrangement of N-Vinyl α,β-Unsaturated Nitrones with 2-Alkynyl Quinazolinones
Synthesis of Chiral 3-Piperidin-2-ones and 3-Piperidines via Ni-Catalyzed Reductive Coupling
Copper-Catalyzed Formal [4 + 1] Annulation of Diynes with Isoxazoles: Synthesis of Pyrrolo[3,4-b]indoles
Ruthenium(II)-Catalyzed Construction of 2,3-Disubstituted Benzo[b]thiophene-1,1-dioxides and Naphtho[1,2-b]thiophene-1,1-dioxides
Zn-Mediated Fragmentation of β-Boryl NHPI Esters Enabling the Radical 1,2-Boron Shift for the Synthesis of gem-Difluoroalkenyl Boronates
Synthesis of Axially Chiral N-Arylpyrroles through the Enantioselective Annulation of Yne-Allylic Esters with a Cooperative Copper-Squaramide Catalysis
Regioselective 1,2-Di(hetero)arylation of Activated and Unactivated Alkenes with (Hetero)aryl Chlorides
Site-Selective Nitration of Arene via Hypervalent Iodine-Mediated C–H Functionalization
Ce(OTf)3-Catalyzed Asymmetric 6π Cyclization of Triaryldivinyl Ketones
Diastereoselective Radical Cyclization of Imine and Olefin: Rapid Access to 1,2,3,4-Tetrahydroquinoline Scaffolds
Coupling of Acyl Radical Precursors with 2-Azaallyl Anions for the Synthesis of α-Amino Ketones
Visible-Light-Mediated Copper-Catalyzed S-Arylation of Sulfenamides with Aryl Thianthrenium Salts
Photosensitized Imino-Sulfamoylation of Alkenes with Oxime Carbamates
Photochemical Branched Hydrothiocarbonylation of Vinyl Arenes with DHP-Thioesters
DABSO-Mediated Hydrosulfonylation of Activated Alkenes
Sulfur–Azide Exchange (SuAEx): A Click Reaction for Chemoselective Sulfonate Ester Formation
Double [8]Helicene Featuring a Dibenzo[g,p]chrysene Core: Synthesis and Chiroptical Response
Racemization of Cross-Chain Bridging Cryptands: Effects of Linker Combination on Racemization Rate
Self-Sorting via Macrocyclization by External Templation in Water
Nickel-Catalyzed Gas-Free Reductive Carbonylation of Aryl Thianthrenium Salts to Access Aryl Amides and Aryl Thioesters
Access to Polysubstituted Pyrimidin-2-ones by Pd-Catalyzed [2 + 2 + 2] Cycloaddition of Alkyne-Tethered Malononitriles and Isocyanates
Stereodivergent Ruthenium/Copper Relay Catalysis for Modular Access to δ-Lactones with Two Nonadjacent Carbon Stereocenters
Radical Arylboration of Unactivated Alkenes via Visible-Light Catalysis
Visible-Light Induced Etherification of C(sp3)–H Bonds with Phenols
Access to Chiral Oxindoles via Ir-Catalyzed Asymmetric Pudovik Addition/[1,2]-Phospha-Brook Rearrangement/Allylation Cascade
Strongly Oxidizing Thiapyrylium Salt for Organophotoredox Catalysis
A Two-Step Process for the Synthesis of Densely Functionalized N-Bridged Octahydrobenzofurans and Hexahydrobenzofurans
Lewis Acid-Catalyzed Domino Inverse Electron-Demand Diels–Alder/Thermal Ring Expansion Reaction for the Synthesis of Arene-Annulated Eight-Membered Nitrogen Heterocycles
Total Synthesis of (+)-Leucolusine and (−)-7-iepi/i-Leucolusine
A RhII-Catalyzed [4 + 3]-Cycloaddition via the Stereoselective Cyclopropanation of Vinyl Allenes En Route to Oxepino[b]indoles and Subsequent Elaboration to Spirooxindole Frameworks
Thiolative Annulation of N-Benzyl-N-cyanopropiolamides Leading to Divergent Synthesis of Pyrroloquinazolin-1-ones and Maleimides
Gold/Copper Dual-Catalyzed Annulation of Arynes with Phosphites: A Synthetic Strategy for Dibenzophospholes
Stereoselective [1,2]-Phospha-Brook Rearrangement of CAMDOL-Derived H-Phosphonate: Synthesis of α-Trifluoromethyl Alcohols
Heterogeneous g-C3N4/NaI Dual Catalytic Difunctionalization of Alkenes with Heteroarenes and Methyl Carbazate under Visible Light
Tandem Cu(I)-Catalyzed Dipolar Cycloaddition–C–H Activation for the In-Flow Synthesis of N-Pyridyl-5-amino-1,2,3-triazole-4-carboxylates
Boronate Formation-Triggered Azide–Alkyne Cycloaddition
CuOTf(Tol)1/2-Catalyzed O-Trifluoroethylation of Alcohols with 2,2,2-Trifluorodiazoethane
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Selection for growth drives the emergence of genetic heredity in protocells
5
The adapt-to-nutrient NRPS-like secondary metabolite gene cluster facilitates Verticillium dahliae adaptation to different nutrient environments
Genome-wide identification of genes involved in beetle odoriferous defensive stink gland function recognizes Laccase2 as the phenoloxidase responsible for toxic para-benzoquinone synthesis
FaTRAB1, a bZIP transcription factor, enhances anthocyanin biosynthesis in strawberry leaves via tissue-specific regulation
The PavMYB.C2-UFGT module contributes to fruit coloration via modulating anthocyanin biosynthesis in sweet cherry
Methanogenesis marker 16 metalloprotein is the primary coenzyme M synthase in Methanosarcina acetivorans.
3
Investigating anharmonicities in polarization-orientation Raman spectra of acene crystals with machine learning
Accelerating ground-state auxiliary-field quantum Monte Carlo simulations by delayed update and block force-bias update
Efficient periodic density functional theory calculations of charged molecules and surfaces using Coulomb kernel truncation
9
Synergistic Motifs in Gaussian Systems
Global Framework for Emulation of Nuclear Calculations
Violation of Local Reciprocity in Charge-Orbital Interconversion
Ultrafast Transient Cyclization of Doubly Charged Acetonitrile
Quantum Chemistry for Solids Made Simple on the Clifford Torus
Self-Propulsion via Nontransitive Phase Coexistence in Chemically Active Mixtures
Non-Markovian Linear Vibrational Absorption Spectroscopy for Nonharmonic Bond Potentials: A Perturbative Approach
Attosecond Optical Orientation
Universal Effective Charges in the 𝑠⁢𝑑 and 𝑓⁡𝑝 Shells
31
DcH3.3 and DcNAC1 Regulate the Expression of UGT73A93 Involved in the Changes in Flower Colour and Fungal Resistance in Carnation
Transcriptional Regulation of the Novel Theacrine Synthase Gene CsTcS2 by the CsTINY–CsWRKY33 Module Underpins Theacrine Biosynthesis in Camellia sinensis
Regulatory Mechanism of CsMYB1-CsMYB82/CsbHLH48‑CsCAD4 Model for Resistance Against Colletotrichum gloeosporioides in Camellia sinensis
<atl>Multi‐Omics Insights Into Anthraquinone Biosynthesis in iRheum tanguticum/i</atl>
Natural Variations in the Activity of Hydroxycinnamoyl Transferases Promote Accumulation of Metabolites Conferring Rice Resistance
Loss‐of‐Function Mutation in scpCER/scp2‐scpLIKE/scp1 Reduced Accumulation of Cuticular Wax and Susceptibility to Thrips in Welsh Onion
Genome Assembly Revealed MdZAT5 Coordinates Anthocyanin Biosynthesis in Apple Fruit Peel and Flesh by Interacting With MdHY5
The PtrC2H2.2-6-PtrCYP86A7/A8 Module Regulates Poplar Drought Tolerance Through Mediating Cutin and Wax Biosynthesis Pathways
Glycoalkaloid-Free Starch Potatoes Generated by CRISPR/Cas9-Mediated Mutations of Genes in the Glycoalkaloid Biosynthesis Pathway Enable More Sustainable Uses of By-Products From Starch Production
VvERF045 Integrates Ethylene, Brassinosteroid and Abscisic Acid Pathways to Orchestrate Anthocyanin Biosynthesis in Grapevine
Overexpression of a Tonoplast Malate Transporter Gene Leads to Enhanced Anthocyanin Biosynthesis in Apple
Aquilaria sinensis MYB-Like Transcription Factor AsMYB1 Promotes 2-(2-Phenylethyl)Chromone Biosynthesis Through Interacting With 14-3-3 Family Protein AsGRF1
CYP82G1 Enzyme Functions as Chromone Hydroxylase in the Biosynthesis of 6-Hydroxy-2-(2-Phenylethyl)chromone in Aquilaria sinensis
Polyacylated Delphinidin Biosynthesis Catalysed by PhF3′5′H-PhBGLU12-PhSCPL2 Determines the Blue Pigmentation in Cineraria (Pericallis hybrida)
A Repression-Activation System Involving miR164a-NACs Regulates Tissue-Specific Anthocyanin Accumulation in Peach Fruit
PME10 Is a Pectin Methylesterase Driving PME Activity and Immunity Against Botrytis cinerea in Grapevine (Vitis vinifera L.)
A Novel ZjbZIP33-ZjPRX1 Module Positively Regulates Lignin Formation in the Jujube Fruit Stone
Identification of a hydroxycinnamoyl-CoA double bond reductase (HDR) affirms multiple pathways for dihydrochalcone formation in apple
Spatial regulation of chlorophyll degradation in kiwifruit: AcNAC2-AcSGR1/2 cascades mediate rapid de-greening in the inner pericarp
Modulation of lignin and anthocyanin homeostasis by iGTP cyclohydrolase1/i in maize
Unveiling the catalytical roles of three glycosyltransferases in triterpenoid saponins in quinoa
A novel function for the transcription factor sensitive to proton rhizotoxicity1 in promoting anthocyanin accumulation in strawberry
PpMYC2 and PpJAM2/3 antagonistically regulate lignin synthesis to cope with the disease in peach fruit
Calcium disrupts CML38/WRKY46-NAC187-CCR cascade to inhibit the formation of lignin-related physiological disorders in pear fruit
Phosphorylation of MdWRKY70L by MdMPK6/02G mediates reactive oxygen accumulation to regulate apple fruit senescence
Molecular characterization and structural basis of a promiscuous glycosyltransferase for β-(1,6) oligoglucoside chain glycosides biosynthesis
Ecotype-specific phenolic acid accumulation and root softness in Salvia miltiorrhiza are driven by environmental and genetic factors
Bi-functional transcription factor SlbHLH95 regulates fruits flavonoid metabolism and grey mould resistance in tomato
Elucidating the enzyme network driving Amaryllidaceae alkaloids biosynthesis in Leucojum aestivum
Structure‐based virtual screening aids the identification of glycosyltransferases in the biosynthesis of salidroside
Two tandem R2R3 MYB transcription factor genes cooperatively regulate anthocyanin accumulation in potato tuber flesh
54
Phase separation induced by active polymerization makes protocells robust against environmental changes
Compositional memory matters for early molecular systems
Diffusive spreading across dynamic mitochondrial network architectures
Chemputer and chemputation—A universal chemical compound synthesis machine
Extracellular matrix chemistry tunes bacterial biofilm metabolism and optimizes fitness
A rare glycoalkaloid biosynthetic pathway from wild potato unlocks genetic routes to Colorado potato beetle resistance
Spider venom phospholipase D toxin structure: Interfacial binding site, mechanism, activation, and head group preference
Mineral-facilitated aqueous synthesis of hydrogen cyanide from prebiotically abundant amino acids for chemical evolution
The radical SAM enzyme EpeE exhibits distinct site reactivity during the biosynthesis of the RiPP natural product epipeptide
Transiently amplified fluctuations assemble dissipative materials
Imported, not invented, genes prevail among Escherichia coli ORFans
Leveraging antibiotic hormesis for cryptic natural product discovery
Coevolution of RNase P and the ribosome
From peptides to DNA: All required steps can be catalyzed
Leaderless RiPPs expand the repertoire of fungal secondary metabolites
A ribosomally synthesized and posttranslationally modified peptide with ADP-ribosylation
Methionine-specific nonreversible bioconjugation: Advancing precision protein modification
Multiple formation pathways for amino acids in the early Solar System based on carbon and nitrogen isotopes in asteroid Bennu samples
Theoretical limits for sensing through phase separation
Proximity-driven acceleration of challenging solid-phase peptide couplings
Conformationally gated multisite proton-coupled electron transfer in the ribonucleotide reductase β subunit
Theory for sequence selection via phase separation and oligomerization
Interstep compatibility of a model for the prebiotic synthesis of RNA consistent with Hadean natural history
A balance between glycitein and glyceollins governed by isoflavone 6-hydroxylase confers soybean resistance to Phytophthora sojae
Deciphering guanidine assimilation and riboswitch-based gene regulation in cyanobacteria for synthetic biology applications
An Archean atmosphere rich in sulfur biomolecules
Diversification of diterpene biosynthesis occurred early in octocoral evolution
Artificial cells with liquid–liquid phase separation–regulated cell-free protein synthesis
Quantification of redox thermodynamics shifts within coacervates
Structure and encapsulation of carbonic anhydrase within the α-carboxysome
<atl>The role of active mRNA–ribosome dynamics and closing constriction in daughter chromosome separation in iEscherichia coli/i</atl>
Global profiling of polyketide synthases in facultative multicellular eukaryotes
Mechanism of controlled radical initiation in radical SAM GTP 3’,8-cyclase
Optimizing multifunctional fluorescent ligands for intracellular labeling
Living/controlled supramolecular protein polymerization
Protopeptide backbone affects assembly in aqueous solutions
A supporting-electrolyte-free four-compartment electrochemical reactor for aqueous and organic phase electrosynthesis
Glycosylated cannabinoids in Cannabis sativa and enzyme design to modulate their synthesis
Anion–π interaction–induced phase separation as a prebiotic pathway to oxygenation
Divergent sustainability profiles of molnupiravir synthesis routes are governed by solvent use and process design
Characterization of SrUGT76G4 reveals a key residue for regioselectivity and efficient Reb M synthesis
Magnetic decoupling as a proofreading strategy for high-yield, time-efficient microscale self-assembly
Evolutionary features in a minimal physical system: Diversity, selection, growth, inheritance, and adaptation
Thioether editing generally increases the photostability of rhodamine dyes on self-labeling tags
An enzyme-based approach for highly efficient self-replication of DNA origami dimers
Reactive mixing enables enzymatic depolymerization of recalcitrant or unsortable polyester wastes
Photothermal catalysis of waste plastics into propionic acid and hydrogen via Ni single-atom site isolation effect
On the mechanism of photodriven hydrogenations of N2 and other substrates by Hantzsch ester: Buffer is key to reactive H-atom donors
Self-reproduction as an autonomous process of growth and reorganization in fully abiotic, artificial and synthetic cells
Nonenzymatic RNA copying with a potentially primordial genetic alphabet
Autocatalytic symmetry breaking and chiral amplification in a feedback network combining amino acid synthesis and ligation
Synergistic regulation of metal–organic cage architectures via temperature- and solvent-driven atropisomerism
Stereoselective construction of coconformational mechanically helical and topologically chiral [2]catenanes induced by point chirality
Thermodynamic consistency of autocatalytic cycles
1
A phylogenetic approach to bridge the food–medicine continuum at the continental scale
28
Divergent and consecutive skeletal editing of saturated primary amines
Scanning nitrogen in sp3-rich scaffolds enabled by carbonyl-to-nitrogen atom swap
Precision indole skeletal editing for single-carbon replacement
Toward life with a 19–amino acid alphabet through generative artificial intelligence design
Chiral S(VI) platform unifies selective C–H amination of complex molecules and alkane feedstocks
Divergent and programmable skeletal remodeling of complex macrocycles with a small method set
Bromine-mediated electrochemical propane dehydrogenation by self-assembled ionic liquid-SnO2 hollow spheres
A molecule with half-Möbius topology
Organocatalyst-controlled stereoselective head-to-tail macrocyclizations
Single-molecule infrared spectroscopy with scanning tunneling microscopy
A small polymerase ribozyme that can synthesize itself and its complementary strand
Engineered aldehyde dehydrogenases for amide bond formation
Access to four-membered cyclic sulfinamides by energy transfer catalysis
Intracellular competition shapes plasmid population dynamics
Three-component assembly and structure–function relationships of (–)-gukulenin A
Biocatalytic, asymmetric radical hydrogenation of unactivated alkenes
Integrated low-temperature PVC and polyolefin upgrading
Artificial farnesol epoxidase enables a concise synthesis of meroterpenoids
Enantioconvergent benzylic C(sp3)‒N coupling with a copper-substituted nonheme enzyme
Diversity-oriented photobiocatalytic synthesis via stereoselective three-component radical coupling
Bridging the pyridine-pyridazine synthesis gap by skeletal editing
Skeletal editing of pyrrolidines by nitrogen-atom insertion
Harnessing carbene polarity: Unified catalytic access to donor, neutral, and acceptor carbenes
Carbonyl-to-sulfur swap enabled by sequential double carbon-carbon bond activation
Excision of organic macrocycles from covalent organic frameworks
Efficient super-reducing organic photoredox catalysis with proton-coupled electron transfer mitigated back electron transfer
In-insect synthesis of oxygen-doped molecular nanocarbons
1,2-Acyl transposition through photochemical skeletal rearrangement of 2,3-dihydrobenzofurans
42
Dynamic breaking of mirror symmetry in spin-dependent electron transport through chiral media causes enantiomeric excesses
Synergy of liberated anions and intense electric field in frustrated ion pairs for enhancing CO2 cycloaddition
Experimental insights into the azotosome hypothesis in Titan’s lake fluids
Rational design of tetrahydrotetrazinones as potent nonclassical radical-trapping antioxidants for inhibition of ferroptosis
CH•••S hydrogen bonds drive molecular recognition of ergothioneine by the microbial transporter
A dual role of Arabidopsis PAL nuclear localization in fine tuning flavonoid biosynthesis
Electrochemically deuterated silane synthesis with D2O
Three-component synthesis of β-thio tertiary alkylamines from simple alkenes via SH2 homolytic substitution
β-Carbon functionalization of amines via α-amino Cu-carbenes
Molecular computation at equilibrium via programmable entropy
Enantioselective rapid assembly of bis-heterocycles by sequential palladium-catalyzed aza-Heck cyclization coupling reaction
Anode-induced arylthiol-amine cross-coupling: A nontraditional strategy to access sulfinamides
Transition-metal-free electrochemical cross-electrophile coupling of activated benzyl alcohols and primary alkyl bromides
In situ NMR–guided design of alkaline electrochemical ammonia synthesis
Photoredox-controlled chemo-divergent, regio-, and stereoselective difunctionalization of olefins via switchable SO2 reintegration
Asymmetric synthesis of chiral boronic esters featuring nonadjacent axial and flexible, acyclic central chirality
Achieving cysteine-selective peptide/protein bioconjugation via tunable triazine-pyridine chemistry
Molecular basis of very-long-chain fatty acid elongation by the CER6-GL2 enzyme complex in plant wax biosynthesis
How ATP and dATP reposition class III ribonucleotide reductase cone domains to regulate enzyme activity
Magmatic immiscibility provides phosphate for prebiotic chemistry
Electrochemical C4 alkylation of pyridine derivatives: Enhanced regioselectivity via silane assistance
Functional divergence of tandem duplicate SCPL acyltransferase genes reveals convergent evolution of chicoric acid biosynthesis
Attenuated LMCT photocatalysis enables C─H allylation of methane and other gaseous alkanes
β-Acyloxyl alkenyl amide synthesis via multiple defluorination: α-Trifluoromethyl ketone–amine as synergystic peptide coupling reagent
Organocatalyzed atroposelective dynamic kinetic resolutions via transient seven-membered cyclic hemiacetals
Comprehensive engineering of novel glycosyltransferase for efficient, donor-promiscuous, and regioselective glycosylation of flavonoids
Molecular basis of the biogenesis of a protein organelle for ethanolamine utilization
Ultrafast photooxidation of semireduced flavin in fatty acid photodecarboxylase
Repurposing polyethylene terephthalate plastic waste to capture carbon dioxide
Preparation of ketonyl C-glycosides from designed glycosyl sulfides and styrenes by a radical pathway
Difluoroboronated tetrazine probes for rapid bioorthogonal fluorescence activation, no-wash STED imaging, and triggered drug release
Asymmetric catalytic reductive transformation of S(VI) to S(IV) for modular access to S(IV)-stereogenic sulfilimine derivatives
A general leaving group assisted strategy for synthesis of pentafluorosulfanyl allylic compounds
The minimal chemotactic cell
Insertion of anthranilyl unit into inert amides: A facile route to oligoamides and cyclic peptides
Geography-guided industrial-level upcycling of polyethylene terephthalate plastics through alkaline seawater-based processes
Predicting three-component reaction outcomes from ~40,000 miniaturized reactant combinations
Palladium-catalyzed intermolecular asymmetric dearomatizative arylation of indoles and benzofurans
Controlled reversible methionine-selective sulfimidation of peptides
Beyond Flory’s principle: Cyclization and unequal reactivity in step-growth linear polymerization
Triple cross-electrophile coupling enabled by palladium/norbornene cooperative catalysis
Assembly of catalytic complexes from randomized oligonucleotides
2
Proton Irradiation of Primitive Atmospheres of Young Exoplanets and Early Earth: N2O Greenhouse Warming and Prebiotic Synthesis
A Deep Search for Ethylene Glycol and Glycolonitrile in the V883 Ori Protoplanetary Disk
1
Uptake and leakage rates differentially shape community arrangement and composition of microbial consortia
66
Volumetric Properties and Microscopic Interactions of Allyl-Functionalized Imidazolium Ionic Liquid Aqueous Dilute Solutions: A Combined Experimental, Machine Learning, and Pitzer Modeling Study
Vibrational Quantum-State-Controlled Reactivity in the O2+ + C3H4 Reaction
Molecular Mode Selective Diels–Alder Cycloreversion under Vibrational Strong Coupling
Chiral Supramolecular Structures Formed by Dibenzo-18-crown-6-ether and NaCl/KCl on Au(111) and Cu(111) Surfaces
Excited-State Proton Transfer in Solution under Vibrational Strong Coupling
Charge-Dependent Interfacial and Optical Properties of Ionic Liquid Microdroplets Formed in Vacuum
Amphidynamic Molecular Crystal with Temperature-Controlled Helical Hydrogen-Bonded Network: Proton Dynamics and Order–Disorder Phase Transition
Orbital Topology Overcomes Energetic Constraints: Conjugation Expansion Breaks the Inverse Relationship between SOMO Splitting and Spin Coupling for Giant Ferromagnetic Coupling in Organic Diradicals
Intrinsic Spin Effect beyond Aqueous Systems: Selectivity Control in Organic Electrochemistry via Spin-Polarized Radical Intermediates
Reverse Engineering Atomic Densities for Charge Model 5 (CM5) to Compute Atomic Properties Beyond Charges
Electronic Shannon Entropy as an Effective Descriptor of Nonradiative Dynamics in Dense Manifolds of Excited States: Case Study of C20, C60, C70, C76, C84, C86, and C90 Fullerenes
Unconventional Formation of Cyanamide, a Key Intermediate in Prebiotic Chemical Evolution, in Interstellar Ice Analogues
High-Performance Semiempirical Excited-State Molecular Dynamics Powered by Graphics Processing Units
Selective Oxidative Dehydrogenation of Cyclohexene into 1,3-Cyclohexadiene on TiO2
Accurate Prediction of Photoinduced Electron Transfer Timescales with Nonadiabatic Microcanonical Rate Theory
Disentangling Cooperative Electron Correlation and Primary Coordination Sphere Effects in [4Fe-4S]+ Structural Isomerism and π-Acid Activation
Pyrrole without Life: Reaction of Aminomethylene with the Propargyl Radical
The Hidden Path to the Resonance-Stabilized Fulvenallenyl Radical (C7H5) via the Bimolecular Reaction of Tricarbon (C3, X1Σg+) with 1,3-Butadiene (C4H6; X1Ag)
Excited-State Sudden Polarization Dynamics of Sulfone-Functionalized Symmetric Stable Diradicaloids
Metastable Materials with Linear Chains: Photoinduced Chemical Reactions in K2X2 (X = S, Se, Te)
Vibrational-State-Regulated Hot-Band Thermal Activation for Anti-Stokes Luminescence
Symmetry-Regulated Argentophilic Interactions via Homochiral Proline Dodecamers
Mechanistic Explanation of Enhanced E → Z Photocatalyzed Isomerization Kinetics
Gas-Phase Formation of Trioxy Acid via OH-Initiated Aldehyde Oxidation under Atmospheric Conditions
Tuning the Hydroxyl Microenvironment of Fe-Zeolite for Selective Oxidation of Benzene by N2O
Mixed Domain IR-Hyper-Raman Four Wave Mixing Spectroscopy
Deciphering Carbene Reactivity: Ultrafast Spectroscopy and Computational Insights into Photochemical Heterocycle Formation
Effect of Halide Ions on Single-Electron Oxidation Reactions in Microdroplets
Infrared-Induced Isomerization of Invisible Isomers (I5) using Nanosecond Laser Spectroscopy
Making Charge Recombination Spin-Forbidden for Efficient Generation and Excitation of Perylene Diimide Radical Anion by Pump–Pump–Probe Spectroscopy
Tethered from the Head and from the Tail: The Structure of Hydroxyl-Functionalized Ionic Liquids
An In-Depth Quantum Chemical Investigation of INVEST TADF Dyes
An Ultrafast Infrared and UV–Vis Study of the Photochemistry of 2-Naphthaloxycarbonyl Azide
Differentiating Between Enantiomers with Nuclear Quadrupole Coupling Using Microwave Three-Wave Mixing
Mapping the Relationship of the Dynamic Active Site and the Activation Barrier for Cross-Coupling Reactions on Geminal-Cu Catalyst
Spin-Vibronic Effect in Photoinduced Electron Transfer
Fragmentation Dynamics of Benzoyl Peroxide: Insights from Rotational Spectroscopy
Anode Potential Evolution During Zinc Metal Plating and Stripping in Dual-Solvent Battery Electrolytes
Dithiocarbamate-Based Self-Assembled Monolayers – The Preparation Method Has a Crucial Impact on Structure and Stability
Rational Design of a Metal-Free Organic Radical Cation Exhibiting Mid-IR π–π* Transition Based on the Exchange Interaction
Chemical Bonding from the Perspective of In Situ Orbital Correlation
Quantum Tunneling Governs Dual-Pathway Amino Acid Racemization via Water Bridges
ATP Can Act as a Stabilizer on Neutral Macromolecules
Accelerated Free Energy Estimation in Ab Initio Path Integral Monte Carlo Simulations
Accurate, Affordable and Unsupervised: Analytical F12 Gradients Driven by Generalized Internal Coordinates
Ultrafast Excited-State Dynamics of the Organic Photoredox Catalyst DDQ
Enantioselective Radical Reactions Can Be Induced by Electron Spin Polarization: A Quantum Mechanism for Nature’s Emergent Homochirality?
From Ground to Excited State: Revealing Bond Polarity Change via K–2V Spectroscopy and Brillouin Inverse Theorem (BIT)
Facet-Engineered Highly Active and Stable Ag/TiO2 Photocatalysts for Selective Oxidative Coupling of Methane
A Molecular Descriptor for Characterizing the Strength of Through-Space Conjugation for Luminescent Property in Organic Materials
Impact of Dark Polariton States on Collective Strong Light–Matter Coupling in Molecules
Photochromic Phenoxyl–Imidazolyl Radical Complex via Homolytic C–O Bond Cleavage
Expanded View of NMR Spin–Lattice Relaxation in Fluorine-Containing Ionic Liquids
Revisiting the Linear Relationship between Hydroxyl Stretch Frequency and Bond Length: A Data-Driven Analysis Connecting Structure to Electrostatic Potential
syn- and anti-Isomers and Fermi Resonance of Acetic Acid in Acetonitrile Revealed by 2D IR
Composite Gradient Schemes for Accurate Molecular Geometries: A Flexible Interface and Hierarchical Optimization Workflow
Orientational and Solvent Couplings of Molecules at Interfaces by Interface-Specific Two-Dimensional Vibrational-Electronic (i2D-VE) Spectroscopy
Exploring Peptide Bond Formation Using Transition State Search and Wave Packet Dynamics
Biomimetic Geminal-Atom Catalysts Empowered by Jahn–Teller Distortion: A Theoretical Study for Efficient PET Degradation
Controlling Intramolecular Vibrational Redistribution with an Infrared Photonic Cavity
Unraveling the Hidden Pathway of Catalyst-Free Direct Photochemical Conversion of Sulfides to Sulfoxides: A Universal Pathway under UVA Radiation
Light on Catalytic Reaction Mechanisms: Uncovering the Conformation of Thiourea-Based Organocatalysts and Their Interaction with Nitroolefins Using Mid-infrared Spectroscopy
Improving Performance and Stability of Solution-Processed Organic Poly-gridofluorene Light-Emitting Diodes via Deuterated Solvents
Photoinduced Dissociation of Halobenzenes: Nonadiabatic Molecular Dynamics Simulations Reveal Key Pathways
Quantifying Design Principles for Light-Emitting Materials with Inverted Singlet–Triplet Energy Gaps
Rational Design and Reaction Mechanism Study of the Photochemical Rearrangement of Fulvene Derivatives
1
Vepdegestrant, a PROTAC Estrogen Receptor Degrader, in Advanced Breast Cancer
2
The deubiquitinase UBP15 and the E3 ubiquitin ligase PUB17 coordinate GLK1 stability in apple anthocyanin deposition
Reduced proteasome degradation of HsfB2a at higher temperatures is responsible for the inhibition of anthocyanin synthesis in pear
4
Unraveling the phototransformation of 2,4,6-tribromophenol: Aqueous mechanisms involving ·OH and the emergence of hydroxylated PBDEs
Dynamic Inner-Outer Dual-Cycles Drive Selective Periodate Activation for Nearly Exclusive Singlet Oxygen Production toward Sustainable Water Purification
Thermal Stimulation Unlocks Ligand-Dependent Selective Pathways in Cu(II)/PMS Oxidation of Recalcitrant Phosphonates
Photoinduced thiol formation in dissolved organic matter: The role of sulfur-containing precursor and source of electron

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